| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 41 | Process for preparing heterocyclic polymer | JP12301676 | 1976-10-15 | JPS5313699A | 1978-02-07 | TATSUDO ERU PATSUTON |
| 42 | Reaction method of isosyanates | JP7038577 | 1977-06-14 | JPS52156801A | 1977-12-27 | JIRI ERITSUKU KURESUTA; CHIEN SHIYAN SHIEN |
| 43 | Isocyanate reaction method using hydroxyalkyl tertiary amine catalyst | JP6702676 | 1976-06-08 | JPS51149292A | 1976-12-22 | EIBURAHAMU SERIMU BEHARA; FUERITSUKUSU PATORITSUKU KIYAR; ROKO ROORENSU MASUSHIORI |
| 44 | Composition Comprising Oligomeric Polyol Compositions and Polyisocyanates | US16105126 | 2018-08-20 | US20180355097A1 | 2018-12-13 | James Henry Blumson; Andrew John Tennant; James A. Cella; David Goldwasser; Daniel J. Brunelle; Stephen Burks; Richard Heggs |
| There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both of one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength. | ||||||
| 45 | Method for isocyanate modification using catalysts with an NPN sequence | US15119179 | 2015-02-13 | US10131736B2 | 2018-11-20 | Frank Richter |
| The invention relates to a method for modifying isocyanates, wherein at least one organic monomer isocyanate having an NCO functionality >1 is oligomerised in the presence of at least one catalyst, said method being characterised in that the catalyst comprises at least one specific compound having an NPN sequence selected from compounds of formula I (formula I), and/or from compounds of formula II (formula II) where HX represents an acid with a pKa value ≥2, X− represents the anion of an acid with a pKa value ≥2, and n represents an integer or fractional number between 0 and 20, wherein Y represents R12(R13)N— and/or one or more substituents of the structure of formula III (formula III) and wherein R1 to R19 independently represent identical or different substituents selected from C1-C20 alkyl-, C1-C20 cycloalkyl- and C6-C20 aryl groups, or wherein R1 and R2, R3 and R4, R5 and R6, R7 and R8, R9 and R10, R12 and R13, R14 and R15, R16 and R17, R18 and R19 independently represent identical or different substituents selected from C1-C20 alkylene-, C1-C20 cycloalkylene-, C6-C20 arylene groups, and can form a 3- to 12-membered ring with the N atom joined to the P atom. The invention also relates to the use of a catalyst of this type. | ||||||
| 46 | Oligomeric polyol compositions | US15589182 | 2017-05-08 | US10053533B1 | 2018-08-21 | James Henry Blumsom; Andrew John Tennant; James A. Cella; David Goldwasser; Daniel J. Brunelle; Stephen Burks; Richard Heggs |
| There is provided an oligomeric polyol composition having (a) an oligomeric network containing residues of at least one polyhydroxylated aromatic compound and residues of at least one polyol having at least three hydroxyl groups; and (b) a plurality of peripheral groups having one or more pendant hydroxyl groups bound to the oligomeric network by a plurality of linking units. The residues of the polyol may optionally contain one or more oxygen ether groups, one or more amino ether groups, or both one or more oxygen ether groups and one or more amino ether groups. Reaction of the oligomeric polyols with isocyanate monomers affords a new class of polyurethanes having superior heat and water resistance. The new polyurethanes exhibit lower peak exotherms, typically less than 250° F. during in-mold polymerization. Articles prepared from polyurethanes incorporating such oligomeric polyol compositions exhibit flexural strengths and moduli in excess of 10,000 psi and 400,000 psi respectively, and outstanding green strength. | ||||||
| 47 | Flexible-to-rigid tubing | US15423709 | 2017-02-03 | US09894754B2 | 2018-02-13 | Dylan J. Boday; Joseph Kuczynski; Robert E. Meyer, III |
| A flexible-to-rigid tube is flexible when routed and is then rigidized to increase burst strength. According to the preferred embodiments of the present invention, the flexible-to-rigid tube is included in a cooling plate assembly for transferring heat from electronic components mounted on a circuit board. In one embodiment, the flexible-to-rigid tube (while in a flexible state) includes a polydimethylsiloxane (PDMS) or other silicone containing pendant or terminal epoxy, vinyl and/or acrylate functional groups and an initiator (e.g., a sulfonium salt photoinitiator, a free radical photoinitiator, or a thermal initiator). In another embodiment, triallyl isocyanurate (TAIC) and an initiator are incorporated into a conventional PVC-based tubing material. The flexible-to-rigid tube changes from the flexible state to a rigid state via formation of a cross-linked network upon exposure to actinic radiation or heat. | ||||||
| 48 | Process for isocyanate modification using spirocyclic ammonium salts as catalyst | US15119177 | 2015-02-13 | US09850338B2 | 2017-12-26 | Frank Richter |
| The Invention relates to a process for modifying isocyanates, in which at least one monomeric organic isocyanate having an NCO functionality>1 is oligomerized in the presence of at least one spirocyclic ammonium salt having a cation of the formula I as catalysts for the isocyanate modification, where substituents X and Y in the N positions are identical or different, substituted or unsubstituted C2-C20-alkylene chains optionally interrupted by heteroatoms (O, N, S) and by aromatic rings. The invention further relates to the use of such a catalyst. | ||||||
| 49 | Coating method and hardener for polyurethane paint | US14410183 | 2013-07-03 | US09802223B2 | 2017-10-31 | Tomokazu Shigemori; Hiroshi Morita |
| [Problem] In a coating method of a two-coat one-bake system where a clear coat paint is coated after a base coat paint is coated, then these two coated layers are simultaneously hardened, adhesive strength between the two coated layers is to increase in comparison with the conventional method.[Solution] Provided is a coating method; A specific hardener is used in the clear coat paint. The hardener is one containing a polyisocyanate derived from 1,6-hexamethylene diisocyanate, satisfying all the following conditions: 1) Hardener does not virtually include diisocyanate monomer, 2) Viscosity of hardener is not more than 1000 mPa·s/23° C., 3) Content of HDI trimer in hardener is not less than 60 weight %, and 4) Content of HDI dimer in hardener is less than 10 weight %. | ||||||
| 50 | Flexible-to-rigid tubing | US15423745 | 2017-02-03 | US09801271B2 | 2017-10-24 | Dylan J. Boday; Joseph Kuczynski; Robert E. Meyer, III |
| A flexible-to-rigid tube is flexible when routed and is then rigidized to increase burst strength. According to the preferred embodiments of the present invention, the flexible-to-rigid tube is included in a cooling plate assembly for transferring heat from electronic components mounted on a circuit board. In one embodiment, the flexible-to-rigid tube (while in a flexible state) includes a polydimethylsiloxane (PDMS) or other silicone containing pendant or terminal epoxy, vinyl and/or acrylate functional groups and an initiator (e.g., a sulfonium salt photoinitiator, a free radical photoinitiator, or a thermal initiator). In another embodiment, triallyl isocyanurate (TAIC) and an initiator are incorporated into a conventional PVC-based tubing material. The flexible-to-rigid tube changes from the flexible state to a rigid state via formation of a cross-linked network upon exposure to actinic radiation or heat. | ||||||
| 51 | SURFACE-TREATING AGENT FOR VULCANIZED RUBBER | US15512022 | 2015-09-18 | US20170292037A1 | 2017-10-12 | Natsumi KIMURA; Katsumi ABE |
| A surface-treating agent for vulcanized rubber, comprising 10 to 160 parts by weight of a wax having a softening point of 40 to 160° C. and 10 to 160 parts by weight of fluororesin particles based on 100 parts by weight of the total amount of isocyanate group-containing 1,2-polybutadiene and an OH group-containing fluororesin composition that has the following formulation:a copolymer [I] of (A) a perfluoroalkylalkyl (meth)acrylate and (B) a hydroxyl group-containing (meth)acrylate, a polymer [II] of an acrylic acid alkyl ester,a polymer [III] of a fluorinated olefin, anda curing agent [IV];wherein the weight ratio of the isocyanate group-containing 1,2-polybutadiene and the OH group-containing fluororesin composition is 50:50 to 95:5. | ||||||
| 52 | Ethoxylate isocyanate compound and its use as a emulsifier | US14436993 | 2013-10-28 | US09771318B2 | 2017-09-26 | Yongchun Chen; Shiling Zhang; Ling Yuan; Guoling Hou |
| Provided is a composition comprising one or more compound having the structure of formula II: wherein A is a residue of a polyisocyanate, L is a linking group formed by a reaction of an isocyanate group with an isocyanate-reactive group, n is 5 to 25, m is 0 to 100, and Z is methyl or ethyl or propyl, and wherein the ratio of the sum of the moles of isocyanate groups plus the moles of said L groups to the moles of said Z groups is 2:1 to 30:1. Also provided is an emulsion in which the particles comprise such a composition and further comprise one or more water-insoluble compound that does not have the structure A-NCO. | ||||||
| 53 | CARPET WASTE COMPOSITE | US15472806 | 2017-03-29 | US20170260746A1 | 2017-09-14 | David E. Murdock; Douglas Mancosh; James P. Przybylinski |
| A composite material is produced from carpet waste and a binding agent, in intimate association, and may also include wood fiber or chips and/or other additives. A method of manufacturing a composite material includes shredding carpet waste, coating the carpet waste with a binding agent, and subjecting the shredded, coated carpet waste to elevated heat and pressure. As an additional step, the composite material may be actively cooled to prevent deformation of the material. | ||||||
| 54 | Method for the preparation of microcellular polyurethane elastomers | US14369011 | 2012-12-27 | US09745437B2 | 2017-08-29 | Jae Soo Yang; Hee Young Choi; Jeongmoo Kim; Joon Mo Lee |
| This invention relates to a method of preparing a microcellular polyurethane elastomer by reacting naphthalene diisocyanate with a polyol to prepare a prepolymer containing an isocyanate (NCO) group, followed by mixing the prepared polyurethane prepolymer with a plasticizer, water, an emulsifier and the like, and then foaming the prepolymer blend to prepare a polyurethane elastomer, wherein the emulsifier is a mixture of (a) a compound selected from the group consisting of 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 2,4-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, hexamethylene diisocyanate, 1,4′-cyclohexane diisocyanate and mixtures thereof, and (b) a C2-10 hydrocarbon having a molecular weight of 500 or less with two to four hydroxyl groups, or mixtures thereof. The method of the invention can optimize the viscosity and properties of the prepolymer resulting from the reaction of naphthalene diisocyanate with a polyol, thus improving processability. | ||||||
| 55 | FLEXIBLE-TO-RIGID TUBING | US15423745 | 2017-02-03 | US20170150597A1 | 2017-05-25 | Dylan J. Boday; Joseph Kuczynski; Robert E. Meyer, III |
| A flexible-to-rigid tube is flexible when routed and is then rigidized to increase burst strength. According to the preferred embodiments of the present invention, the flexible-to-rigid tube is included in a cooling plate assembly for transferring heat from electronic components mounted on a circuit board. In one embodiment, the flexible-to-rigid tube (while in a flexible state) includes a polydimethylsiloxane (PDMS) or other silicone containing pendant or terminal epoxy, vinyl and/or acrylate functional groups and an initiator (e.g., a sulfonium salt photoinitiator, a free radical photoinitiator, or a thermal initiator). In another embodiment, triallyl isocyanurate (TAIC) and an initiator are incorporated into a conventional PVC-based tubing material. The flexible-to-rigid tube changes from the flexible state to a rigid state via formation of a cross-linked network upon exposure to actinic radiation or heat. | ||||||
| 56 | BIS[3-ISOPROPENYL-ALPHA,ALPHA-DIMETHYLBENZYL]CARBODIIMIDE, PRODUCTION METHODS, AND USE OF SAID COMPOUND | US15315498 | 2015-06-03 | US20170088509A1 | 2017-03-30 | Wilhelm LAUFER; Martina SCHOENHABER; Armin ECKERT; Oliver HERD; Rolf SPERBER |
| The present invention relates to novel processes for producing bis[3-isopropenyl-α,α-dimethylbenzyl]carbodiimide, to the thus-produced bis[3-isopropenyl-α,α-dimethylbenzyl]carbodiimide and to the use thereof as a hydrolysis inhibitor in polyurethane (PU)-based systems, preferably thermoplastic TPU, PU adhesives, PU casting resins, PU elastomers or PU foams. | ||||||
| 57 | POLYURETHANE MATERIALS FORMED FROM EPOXIDIZED PLANT OILS | US14862847 | 2015-09-23 | US20170081460A1 | 2017-03-23 | Brandon M. Kobilka; Joseph Kuczynski; Timothy C. Mauldin; Jason T. Wertz |
| In an example, a process of forming a polyurethane material is disclosed. The process includes forming carboxylic acid-terminated aliphatic polyol molecules from an epoxidized plant oil. The process also includes chemically reacting the carboxylic acid-terminated aliphatic polyol molecules with an azide material to form monoisocyanate-functionalized aliphatic polyol molecules. The process further includes polymerizing the monoisocyanate-functionalized aliphatic polyol molecules to form a first polyurethane material. | ||||||
| 58 | PREPARATION OF NOVEL FLUOROCOMPOUNDS, METHODS OF PREPARATION AND COMPOSITIONS MADE THEREFROM | US15357413 | 2016-11-21 | US20170066864A1 | 2017-03-09 | Tianzhi Zhang; Matthew P. Burdzy; Dingsong Feng; Yonghui Zhang |
| Novel fluorinated compounds, their method of preparation and use are disclosed, as well as the incorporation of new and old fluorinated compounds in controlled radical polymerization processes to efficiently produce polymer compositions with unique and enhanced properties. Various cure mechanisms and types of end-uses are disclosed. | ||||||
| 59 | POLYCARBONATE DIOL AND THERMOPLASTIC POLYURETHANE MADE FROM THE SAME | US15238926 | 2016-08-17 | US20170051104A1 | 2017-02-23 | Fu-Shen Lin; June-Yen Chou; Hsing-Yun Wang; Chih-Jung Chen; Wei-Lun Hsieh |
| A polycarbonate diol is provided, including three kinds of repeating diol units, wherein one of the repeating diol units is chosen from an alkoxylated diol monomer. | ||||||
| 60 | Coating method and hardener for polyurethane paint | US14412714 | 2013-07-03 | US09567485B2 | 2017-02-14 | Tomokazu Shigemori; Hiroshi Morita |
| [Problem] To increase adhesive strength between an aqueous base coat layer and a clear coat layer in a coating method by a two-coat one-bake system where an aqueous base coat paint is coated, then a clear coat paint is coated, and these two coated films are simultaneously hardened, in comparison with the conventional method.[Solution] Provided is a coating method using a specific hardener in a clear coat paint. Namely, the hardener is characterized in that (1) it includes a reaction product of (i) a derivative of 1,6-hexamethylene diisocyanate including a trimer and virtually not including a diisocyanate monomer, and (ii) a compound having both an active hydrogen and a hydrophilic group; and (2) viscosity at 23° C. is not more than 1,000 mPa·s. The compound having both an active hydrogen and a hydrophilic group herein is a compound having an active hydrogen-containing group and a sulfo group represented by formula (I), and preferably the sulfo group in a hardener is neutralized with a tertiary amine. X—R—SO3H Formula (I) (in the formula, X is an amino group, alkylamino group, cycloalkylamino group, or hydroxyl group, R is an aliphatic and/or alicyclic hydrocarbon group.) | ||||||
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