序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 涂料组合物和由其制备的可低温固化涂层及其用途 CN201480052055.5 2014-08-07 CN105555821A 2016-05-04 P·霍夫曼; R·克洛普施; M·格罗尼沃尔特; E·维斯林; A·弗洛雷斯-菲圭罗阿; K·米歇尔
发明涉及非性涂料组合物,其包含:至少一种具有至少两个基的化合物(A),和至少一种具有至少两个亚烷基-1,3-二戊环-2-基团的低聚和/或聚合化合物(B),其中化合物(B)可使用以下单体得到:至少一种式(I)的单体(B1),其中R1、R2相互独立地为氢、C1-C6烷基、C1-C4烷氧基-C1-C4烷基、C5-C6环烷基、苯基或苯基-C1-C4烷基;R3为氢、C1-C6烷基、C1-C4烷氧基-C1-C4烷基、C5-C6环烷基、苯基或苯基-C1-C4烷基、R3更特别为氢;R4为氢、C1-C4烷基、CH2COOR8、苯基或苯基-C1-C4烷基;R5、R6相互独立地为氢或C1-C4烷基,或者R5或R6基团中的一个可以为COOR8或CH2COOR8;A为化学键或C1-C4亚烷基,A更特别是C1-C4亚烷基;X为O或NR7;Z为化学键、PO2、SO2或C=O,Z更特别是C=O;Y为化学键、CH2或CHCH3;R7如果存在的话为C1-C6烷基;且R8如果存在的话为氢或C1-C6烷基;和各自不同于单体(B1)的至少两种不同共聚单体(B2)和(B3)。本发明进一步提供由这些涂料组合物制备的涂层及其用途。
2 木质纤维材料粘合法的改进 CN85102125 1985-04-01 CN85102125A 1987-01-31 查普曼; 詹金
这一发明是关于纤维板,碎料板和胶合板等复制木制品生产过程中,以可热固的树脂粘合如木头等的木质纤维素材料的一种方法。根据这种方法,制作过程中在木纤维、碎料或薄木片中加进一种产生放热反应的化学物质。在对纤维、碎料或薄木片加压时,那种产生放热反应的化学物质在生产的纤维板,碎料板或胶合板内参与放热反应,提供热。这些热使可热固树脂较其它情况下更快凝固。这一方法的产品也请求专利权。
3 交联组合物 CN200480008686.3 2004-02-26 CN100503674C 2009-06-24 L-T·W·林; W·雅各布斯三世
发明涉及一种交联组合物,包含具有式I结构的化合物:A′-NRA-RD,其中,A′是源自下列基团的部分:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环甲酸酯,以及它们的混合物,或包含式II结构的部分:其中,RA是RD、氢、1-20个原子的烷基,或与A’一起形成环化合物;RD是-CHRCORB,其中RB是氢、有1-24个碳原子的烷基、芳基、芳烷基或烷芳基,RC是有1-24个碳原子的烷基、卤化烷基、芳基、芳烷基、卤化芳烷基、烷基烷基或烷芳基;A是源自下列基团的部分:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环氨基甲酸酯,以及它们的混合物;B是有n个基的多(烷基醛)的残基;n是2-8的整数;RA是RD、氢、1-20个碳原子的烷基,或与A一起形成环状化合物;其中RD是CHRCORB,其中RB是氢、有1-24个碳原子的烷基、芳基、芳烷基或烷芳基,RC是有1-24个碳原子的烷基、卤化烷基、芳基、芳烷基、卤化芳烷基、烷氧基烷基或烷芳基;各基团上的烷基或芳基还可以在其结构中有杂原子。本发明还涉及制备交联组合物的方法,包括使含氨基的氨基化合物;单(烷基醛)和/或多(烷基醛);和醇反应;所述氨基化合物选自下列:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环氨基甲酸酯,以及它们的混合物。
4 交联组合物 CN200480008686.3 2004-02-26 CN1768087A 2006-05-03 L-T·W·林; W·雅各布斯三世
发明涉及一种交联组合物,包含具有式I结构的化合物:A′-NRA-RD,其中,A′是源自下列基团的部分:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环甲酸酯,以及它们的混合物,或包含式II结构的部分:其中,RA是RD、氢、1-20个原子的烷基,或与A′一起形成环化合物;RD是-CHRCORB,其中RB是氢、有1-24个碳原子的烷基、芳基、芳烷基或烷芳基,RC是有1-24个碳原子的烷基、卤化烷基、芳基、芳烷基、卤化芳烷基、烷基烷基或烷芳基;A是源自下列基团的部分:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环氨基甲酸酯,以及它们的混合物;B是有n个基的多(烷基醛)的残基;n是2-8的整数;RA是RD、氢、1-20个碳原子的烷基,或与A一起形成环状化合物;其中RD是CHRCORB,其中RB是氢、有1-24个碳原子的烷基、芳基、芳烷基或烷芳基,RC是有1-24个碳原子的烷基、卤化烷基、芳基、芳烷基、卤化芳烷基、烷氧基烷基或烷芳基;各基团上的烷基或芳基还可以在其结构中有杂原子。本发明还涉及制备交联组合物的方法,包括使含氨基的氨基化合物;单(烷基醛)和/或多(烷基醛);和醇反应;所述氨基化合物选自下列:线型或环脲、氰尿酸、取代的氰尿酸、线型或环酰胺、甘脲、乙内酰脲、线型或环氨基甲酸酯,以及它们的混合物。
5 직물처리 조성물 KR1019810003562 1981-09-23 KR1019830007949A 1983-11-09 브루노키슬링
내용없음
6 N-methylol derivative of polycondensate, and preparation and use thereof JP2576995 1995-01-23 JPH07238167A 1995-09-12 UDOOBINFURIITO HENDORIKUSU; RARUFU HAINEN
PURPOSE: To obtain an N-methylol deriv. of a polycondensate which is useful as an agent for improving the wet fastness properties of dyeings and prints by reacting a specific basic urea compd., a polyamine, and a bifunctional alkylating agent. CONSTITUTION: A basic urea compd. of formula I (wherein X 1 is 2-4C alkylene; R 1 and R 2 are each H, 1-4C alkyl or the like; R 3 and R 4 are each H, 1-4C alkyl, 2-4C hydroxyalkyl or the like; and R 5 is H, 1-4C alkyl, 2-4C hydroxyalkyl or a group of formula II or III), a polyamine of formula IV (wherein X 2 is 2-6C alkylene or the like; R 10 is H or 1-4C alkyl; and R 6 to R 9 are each H, 1-4C alkyl, 2-4C aminoalkyl or the like), and a bifunctional alkylating agent are reacted in a molar ratio of (0.5-2.5):1: (1.0-3.2) in water or a polar org. solvent. The resultant product is reacted with formaldehyde (or a formaldehyde-releasing compd.) in an amt. of 0.5-1.2 mol, based on 1 mol of urea group: -N(R 2)-CO-NH (R 1)- of the product, at 40-130°C at a pH of 8-11. COPYRIGHT: (C)1995,JPO
7 JPS6241605B2 - JP16674782 1982-09-27 JPS6241605B2 1987-09-03 TEODOORU AA BIRUGE; YURUKU BIDOMAA; TEODOORU MEIYAA; URURITSUHI ZURUSAA
8 Dyeing, printing and fluorescent brightening method of spun fiber JP27498784 1984-12-28 JPS60155788A 1985-08-15 YURUKU HERAA; BURUNO KITSUSHIYURINKU; TEIBORU ROBINSON; SARUBATOORE BARENTEI; PIITAA JIINZU; JIEIMUZU MAACHIN TEIRAA
9 Treatment of dispersion liquid of capsule JP10937879 1979-08-27 JPS5633030A 1981-04-03 HORIIKE TETSUROU; OKIMOTO SATOYUKI; SHIOZAKI TOMOHARU
PURPOSE:To remove the residual formaldehyde without spoiling the capacity of membrane, by adjusting the dispersion liquid of microcapsule having the wall membrane of aldehyde polycondensation resin in alkaline condition and then, heating and stirring after adding the reaction catalyst, such as metal hydroxide. CONSTITUTION:Residual formaldehyde in the dispersion liquid of microcapsule having the wall membrane of aldehyde polycondensation resin whicn is formed by the curing reaction of acid catalyst by using formaldehyde as one component, is heated and stirred in alkaline solution and then, is removed after adding the reaction catalyst, such as metal hydroxides or phosphates. By this method, formaldehyde can be effectively removed by the chemical denaturation treatment without spoiling a superior capacity of the capsule wall membrane.
10 Polyaddition product of ammonia and epoxy compound and its denaturing method JP4576780 1980-04-09 JPS55149318A 1980-11-20 FURITSUTSU ERUTOMAN KEMUPUTAA; EBERUHARUTO SHIYUTSUPU; HANSUUUUBUE SHIENKU; EERIHI GURUBINSU
11 JPS5427312B1 - JP4607071 1971-06-26 JPS5427312B1 1979-09-08
12 Method of making aminoplast dispersion and its use JP2937876 1976-03-19 JPS51117793A 1976-10-16 KUUNO BAAGUNERU; YURUGEN ITSUKU; GERUHARUTO BAREE
13 JPS50109295A - JP1226675 1975-01-29 JPS50109295A 1975-08-28
14 CROSSLINKING COMPOSITION EP04715054.5 2004-02-26 EP1608691B8 2018-06-13 LIN, Lon-Tang, Wilson; JACOBS, William, III
This invention relates to a crosslinking composition comprising a compound having the structure of Formula I: A'-NRA-RD where A' is a moiety derived from the group consisting of linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof, or a moiety comprising the structure: where RA is RD, hydrogen, an alkyl of 1 to 20 carbon atoms, or taken together with A' forms a cyclic compound; RD is -CHRC ORB, wherein RB is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms and RC is an alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; A is a moiety derived from the group consisting of linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof; B is a residue of a poly(alkylaldehyde) with n aldehyde groups; n is an integer of 2 to about 8; Ra is Rd, hydrogen, an alkyl of 1 to about 20 carbon atoms, or taken together with A forms a cyclic compound; where Rd is CHRcORb or where Rb is hydrogen, alkyl, aryl, aralkyl or an alkaryl having from 1 to about 24 carbon atoms and Rc is an alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; and where the alkyl or aryl groups in each radical may optionally have heteroatoms in their structure. This invention also relates to a process for producing the crosslinking composition by reacting an amino compound containing amino groups; a mono(alkylaldehyde) and/or a poly(alkylaldehyde), and an alcohol; where said amino compound is selected from the group consisting of: linear or cyclic ureas, cyanuric acid, substituted cyanuric acids, linear or cyclic amides, glycolurils, hydantoins, linear or cyclic carbamates and mixtures thereof.
15 High molecular weight amine containing antiozonants EP93118562.3 1993-11-18 EP0654489A1 1995-05-24 Sturm, Budd Harvey; Kuczkowski, Joseph Andrew; Sandstrom, Paul Harry; Balogh, George Frank

The present invention relates to a composition which exhibits antiozonant activity in diene containing rubbers comprising the reaction product of a multi-step process comprising:

  • (1) reacting under condensation conditions reactants consisting of an aldehyde and an amine containing compound to form a condensation product, wherein

       said aldehyde is selected from the group consisting of formaldehyde, acetaldehyde or mixtures thereof; and

       said amine containing compound is selected from the group consisting of:

       N,N'-di-substituted-p-phenylene diamines of the structural formula: wherein R¹ and R² are independently selected from the group of radicals consisting of alkyls having 3 to 12 carbon atoms, aryls having 6 to 12 carbon atoms and aralkyls having 7 to 12 carbon atoms; and wherein said condensation conditions include:
    • (i) the presence of an acid catalyst,
    • (ii) a mole ratio of aldehyde to amine containing compound ranging from about 1.01:2 to 2:1, and
    • (iii) said amine containing compound is dissolved in an organic solvent;
  • (2) removing water from said condensation product;
  • (3) adjusting the pH of the condensation reaction product to above 7 to form a basic reaction mixture;
  • (4) filtering off neutralized catalyst to form a solvent reaction mixture;
  • (5) heating said solvent reaction mixture under vacuum to a temperature ranging from about 110°C to 250°C;
  • (6) isolating from the heated solvent reaction mixture the reaction product derived solely from derived solely from said aldehyde and said amine and wherein said reaction product exhibits antiozonant activity in diene containing rubbers.

16 Dyeing and printing fibres EP84810651.4 1984-12-20 EP0151370B1 1990-03-14 Heller, Jürg; Kissling, Bruno; Robinson, Tibor; Valenti, Salvatore; Ginns, Peter; Taylor, James Martin
17 Process for bonding water penetrable cellulosic particles EP87600007.6 1987-05-29 EP0252867A1 1988-01-13 Markessini, Vergopoulou Efthalia

A substitute for amino and phenolic resins is disclosed. It is used in the polycondensation of such resins based on formaldehyde for bonding water penetrable cellulosic particles. The substitute comprises an aqueous solution of

  • a) either at least one aldehyde together with at least one amide and/or together with at least one phenol, or a non-resinous condensation product of formaldehyde and urea, and
  • b) a sugar or a sugar derivative or their by-products or a starch or its degradation products or a mixture thereof, and/ or
  • c) a raw and/or treated lignosulfonate.

This substitute also reduces the free formaldehyde of the resulting board without impairing the other properties thereof.

18 Baustoffe,enthaltend ein Polykondensationsprodukt EP82108240.1 1982-09-08 EP0077904B1 1987-08-05 Bürge, Theodor; Widmer, Jürg; Meyer, Theodor; Sulser, Ulrich
19 Umsetzungsprodukte und Kondensationsprodukte auf Basis substituierter Propylenharnstoffe, deren Herstellung und Verwendung EP86109185.8 1986-07-04 EP0210471A2 1987-02-04 Goeckel, Ulrich, Dr.; Petersen, Harro, Dr.; Osterloh, Rolf, Dr.; Schupp, Eberhard, Dr.; Loch, Werner, Dr.; Schwerzel, Thomas, Dr.

Die Erfindung betrifft Kodensationsprodukte auf Basis substituierter Harnstoffe, deren Umsetzugspro- dukte mit Di-und/oder Polyisocyanaten, Derivaten von Di-und/oder Polycarbonsäuren oder p-substituierten Phenolen und/oder deren Methylolderivaten, deren Herstellung und Verwendung.

Diese Kondensationsprodukte enthalten jeweils mindestens zwei cyclische Harnstoffeinheiten und lassen sich entweder durch Umsetzung primärer Di-oder Polyamine mit Harnstoffen und anschließende Reaktion mit überwiegend C-H-aciden Aldehyden oder durch Umsetzung primärer Amine mit lsocyanaten und anschließende Reaktion mit überwiegend C-H-aciden Aldehyden in Gegenwart saurer Katalysatoren herstellen.

Diese Kondensationsprodukte und deren Umsetzungsprodukte eignen sich zur Herstellung hitzehärtbarer Überzugsmittel sowie zur Herstellung von Bindemitteln für die kathodische Elektrotauchlackierung.

20 Hemiacetals of adducts of acrolein and isocyanuric acid and polymer compositions thereof EP81305945.8 1981-12-18 EP0055091B1 1985-07-31 Cohen, Saul Mark; LeBlanc, John Roger
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