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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 fulvalenes derivatives DE3666039 1986-04-25 DE3666039D1 1989-11-09 INOKUCHI HIROO; SAITO GUNJI; SEKI KAZUHIKO; MORI TAKEHIKO
42 DD27120184 1984-12-20 DD248583A1 1987-08-12 FANGHAENEL EGON; KUEHNEMUND KARL-HEINZ; RICHTER ANDREAS
43 DD25145883 1983-05-31 DD215783A1 1984-11-21 FANGHAENEL EGON; RICHTER ANDREAS M; KUEHNEMUND KARL-HEINZ
44 DD24488482 1982-11-16 DD211356A1 1984-07-11 FANGHAENEL EGON; TSCHOETSCH CHRISTOPH; RICHTER ANDREAS M
45 FR2372824B1 - FR7723003 1977-07-21 FR2372824B1 1980-03-28
46 COUPLING OF MOLECULAR UNITS BY DESELENIZATION OF SELENOCARBONYL OUNDS CA223170 1975-03-21 CA1058624A 1979-07-17 ENGLER EDWARD M; PATEL VISHNUBHAI V
of the Invention Organic molecules can be coupled via their selenocarbonyl derivatives. Generally, the synthesis can be described by the following reaction equation: where can be a cyclic or heterocyclic organic compound and R can be alkoxy, phenoxy or phenyl, preferably CH3O, C2H5O, C6H5O, C6H5 and the like. The reaction is usually carried out in a refluxing solvent, the choice of the solvent being determined by the stability and by the ease of coupling of a particular substrate. Groups that tend to stabilize the selenocarbonyl require higher boiling solvents and longer refluxing times. Aromatic solvents, such as benzene or toluene are well-suited for the coupling reaction. In some cases, refluxing the substrate in the alkoxy-phosphorus base as solvent may be advantageous. This new coupling procedure permits the synthesis of the hitherto unknown compounds: tetraselenofulvalene (TScF), the selenium analogue of tetrathiofulvalene (TTF), and disolenodithiofulvalene (DSeDTF). Highly conducting char?e transfer salts of tetraselenofulvalere and diselenodithiofulvalene with totracyano-p-quinodimethane have also been prepared. The materials of this invention are useful in the organic electronic devices described the United States Patent No. 3,953,874, issued April 27, 1970, to Arieh Aviram et al. and assigned to the same assignee as is the present application.
47 FR2273811B1 - FR7514036 1975-04-29 FR2273811B1 1977-07-08
48 A process for producing di- (polychlorbenzo) -thiophenen, -1, 4-Dithiins and -1, 4-oxathiins DEF0033912 1961-05-12 DE1222508B 1966-08-11 KLUG DR HELMUT
49 A process for preparing highly chlorinated aryl sulfides DEF0031716 1960-07-21 DE1123663B 1962-02-15 KLUG DR HELMUT
50 ESTRY CHOLINY PL10790043 2010-06-15 PL2442645T3 2015-02-27 GARNER WILLIAM; GARNER MARGARET; MINNO GEORGE; GOODEN DAVID
51 CHOLINESTERE DK10790043 2010-06-15 DK2442645T3 2014-11-24 GARNER WILLIAM; GARNER MARGARET; MINNO GEORGE; GOODEN DAVID
52 Heterocyclic compounds for use in the treatment of disorders of the urinary tract DK02782863 2002-10-07 DK1432701T3 2006-05-08 CORBETT JEFF W; LEONARDI AMEDEO; MOTTA GIANNI; TESTA RODOLFO; RIVA CARLO
53 SPECIFIC KINASE INHIBITORS CA2581375 2005-09-26 CA2581375A1 2006-04-06 LAU JANICE; HUTCHINSON RICHARD C; SUNDERMANN KURT F; SANTI DANIEL V; REID RALPH C
Resorcylic acid lactones having a C5-C6 cis double bond and a ketone at C7 and other compounds capable of Michael adduct formation are potent and stable inhibitors of a subset of protein kinases having a specific cysteine residue in the ATP binding site.
54 1,2-DIOXETANOS QUIMIOLUMINISCENTES MEJORADOS. MX9802120 1998-03-18 MX9802120A 1998-11-30 BRONSTEIN IRENA; EDWARDS BROOKS; SPARKS ALISON; VOYTA JOHN C
Se proporcionan dioxetanos que pueden ser activados por bases los cuales pueden ser usados para detectar la liberacion de bases de varios marcadores, así como un medio para detectar la presencia de una base liberada por procesos físicos o naturales, para calibrar aparatos de medicion de luz y determinar la cantidad de un agente reductor u oxidante presente en la muestra.
55 Cyclic organoselenium compounds, their preparation and their uses AU5860598 1997-12-23 AU5860598A 1998-07-31 ERDELMEIER IRENE; TAILHAN-LOMONT CATHERINE; MOUTET MARC; CHAUDIERE JEAN; YADAN JEAN-CLAUDE
56 Fast photographic silver halide emulsion DE19616498 1996-04-25 DE19616498A1 1997-10-30 BERGTHALLER PETER DR; BORST HANS-ULRICH DR
In a photographic silver halide emulsion, (a) >= 50% of the projected area consists of tabular crystals with an aspect ratio of >= 3 and (b) the emulsion is ripened with telluronium compound(s) (I) of formula R1-Te<+>(R2)-R3 X<-> (IA) or R1-Te(R2)(R3)-X (IB); in which R1, R2 = alkyl, aryl, aralkyl, hetaryl, hetaralkyl; or TeR1R2 = a 5-7-membered ring; R3 = optionally substituted alkyl, cycloalkyl or aryl; X = an anionic group or a group released as anion.
57 MACROCYCLIC THIOETHER LIGANDS AND THEIR USE AS INTERMEDIATES FOR BINDING IONS TO SUBSTRATES CA2105872 1992-03-19 CA2105872A1 1992-09-21 BLOWER PHILIP J; RICHARDSON ADRIAN P; SMITH RAYMOND J
2105872 9216520 PCTABS00016 1,4,7-Trithiacyclononane (9S3) and related compounds of formula (I), where one T is S or Se or Te, another T is S or Se or Te and the third T is S, Se, Te, >PX or >AsX, X being a univalent atom or group, and where A1 is -C2H4- or (a), or -C3H6-, A2 is -C2H4- or (a), and A3 is -C2H3R- or (b), or except when A1 is -C3H6-, -C3H5R-, where R is alkyl or substituted alkyl or, if the third T contains P or As, R may also be H, may be substituted with a linker group which can bind to a substrate such as a protein and which itself retains co-ordinating functionality to chelate a radionuclide for diagnosis or therapy.
58 DD25145783 1983-05-31 DD215782A1 1984-11-21 FANGHAENEL EGON; RICHTER ANDREAS M; KUEHNEMUND KARL-HEINZ
59 A METHOD OF FABRICATING DITHIAFULVEN GEMINAL DITHIOLATE COMPOUNDS AND THEIR SELENIUM ANALOGS DE3065582 1980-04-10 DE3065582D1 1983-12-22 ENGLER EDWARD MARTIN; PATEL VISHNUBHAI VITTHALBHAI; SCHUMAKER ROBERT RHEES
60 HETEROFULVALENE GEMINAL DITHIOLATE COMPOUNDS AND THEIR SELENIUM AND TELLURIUM ANALOGS AND A METHOD OF FABRICATING THE SAME CA348150 1980-03-21 CA1155860A 1983-10-25 ENGLER EDWARD M; PATEL VISHNUBHAI V; SCHUMAKER ROBERT R
The invention is directed to novel heterofulvalence geminal dithioiate compounds and their selenium and tellurium analogs having the general formula Wherein X is selected from S, Se and Te. R is selected from hydrogen, alkyl, aryl, or together form a ring of carbon atoms, cyano and dithiocarbonate groups and R1 is selected from alkali, alkaline earth and transition metals, alkyl, aryl, cyclic and heterocyclic groups. A novel method for preparing these compounds is also provided.
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