| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 21 | Huge ring Fushimi ether compound-containing photographic elements | JP18200188 | 1988-07-22 | JP2633634B2 | 1997-07-23 | AASAA HAAMAN HAATSU; ROJAA RII KURAUSU |
| 22 | Benzotrichalcogenols, their radical cation derivatives and production thereof | JP13347994 | 1994-06-16 | JPH083157A | 1996-01-09 | SATOU KIYOSHI; KIKUCHI TAKAMASA; SAITO SATOSHI; KAWAI YASUSHI; OGAWA SATOSHI |
| PURPOSE:To obtain the subject compounds capable of exhibiting coloring and discoloring with reversible oxidation/reduction process and suitable as electrochromic materials by reacting a specific benzodichalcogenastanol with thionyl chloride and reducing the reactional product. CONSTITUTION:Thus compound of formula I [R<1> and R<2> are each an alkyl or a (substituted)aryl; X<1> to X<2> are each S or selenium atom], e.g. 4,7- dimethoxy-1,2,3-benzotrithiol is obtained by reacting a benzodichalcogenastanol of formula II (R<3> and R<4> are each an alkyl) with thionyl chloride and reducing the reactional product with sodium iodide and perchloric acid or reacting the benzodichalcogenastanol with selenium tetrachloride. | ||||||
| 23 | Thia and/or selena-fluvalene group-containing compound | JP11353291 | 1991-05-17 | JPH04342584A | 1992-11-30 | MIZUTANI MAKOTO; IKEDA KIYOSHI; TANAKA KEIJI |
| PURPOSE: To provide the subject novel compound having a good electron- donating property, capable of directly forming a complex with an electron acceptor, and having excellent thermal stability. CONSTITUTION: A compound of the formula [X 1a-X 4a and X 1b-X 4b are S, Se; Y is multicyclic aromatic group comprising two or more benzene rings condensed with each other, hetero atom-containing aromatic five-membered ring; Z 1a, Z 2a, Z 1b, Z 2b are H, C nH 2n+1]. For example, 2,6-bis[2-(tetrathiafluvalen-2-yl) vinyl)-naphthalene. The compound of the formula is produced by reacting 1 mole of formyltetrathiafluvalene, etc., with 0.5 mole of a condensed multi-cyclic aromatic compound phosphonic acid such as a naphthalene phosphonic acid ester in the presence of 1 mole of a base such as lithium ethoxide in an ether solvent at room temperature for several minutes to 10 hours. COPYRIGHT: (C)1992,JPO&Japio | ||||||
| 24 | Manufacture of conductive thin film | JP10047590 | 1990-04-18 | JPH042009A | 1992-01-07 | KAWABATA KAZUE; MIZUTANI MAKOTO; TANAKA KEIJI |
| PURPOSE: To easily and effectively manufacture a thin film homogeneous, having a wide area, being oriented and single phased and superior in its conductivity, by allowing halogen element vapor to exist when a conductive thin film is formed on substrate. CONSTITUTION: Crucibles 2, 2', a substrate 3, a film thickness gauge 4 a halogen gas introduction tube 5, are installed within a chamber 1. And a shutter 6 is placed between the crucible 2 and the substrate 3. Necessary charge-transfer complex is placed in the crucible 2 and pressure within the chamber is reduced to required degree of vacuum via an exhaust valve 7, and then the crucible 2 is heated close to sublimation point of charge-transfer complex, after which gaseous halogen element is introduced in the chamber from the introduction tube 5. Adjustment of the while being thickness of a vapor deposition film is made by opening and closing a shutter 6, monitored by the quartz oscillator film thickness gauge 4. Thus gained charge-transfer complex film has a wide area, oriented that high electric conductivity direction becomes parallel to the substrate surface, and consists of a single phase. COPYRIGHT: (C)1992,JPO&Japio | ||||||
| 25 | Photographic element containing giant cyclic ether compound | JP18200188 | 1988-07-22 | JPS6442644A | 1989-02-14 | AASAA HAAMAN HAATSU; ROJIYAA RII KURAUSU |
| PURPOSE: To effectively alter the growth of silver halide crystals by incorporating a radiation sensitive silver halide emulsion layer and a specified macrocyclic ether compd. CONSTITUTION: This photographic element contains a radiation sensitive silver halide emulsion layer and a macrocyclic ether compd. having 12 to <30 ring forming atoms including 2 to <10 O atoms and 1-4 Se atoms and/or 1 or 2 S atoms. When no Se atom is contained in the macrocyclic ring, S atoms existing in the ring are kept apart from each other by a divalent <6 C alkylene chain. Superior silver halide growth altering characteristics are ensured. | ||||||
| 26 | Selenium-containing new plastic lens and a method of manufacturing the same | JP3784697 | 1997-02-21 | JP3953134B2 | 2007-08-08 | 光樹 岡崎; 史朗 本間; 博之 森尻; 昌彦 楠本; 守 田中; 芳信 金村 |
| 27 | Silver halide emulsion, silver halide light-sensitive material, heat developing photosensitive material | JP2000047160 | 2000-02-24 | JP3948184B2 | 2007-07-25 | 智寛 押山; 大 池水; 宣明 香川 |
| 28 | Cyclic organic selenium compounds, their preparation and their use | JP52961098 | 1997-12-23 | JP2001510468A | 2001-07-31 | イレーヌ・エルデルマイアー; キャトリンヌ・テラン−ロモン; ジャン−クロード・ヤダン; ジャン・ショーディエール; マルク・ムッテ |
| (57)【要約】 本発明の主な目的は：−新規の環状有機セレン化合物；−抗酸化剤としての上記新規化合物の使用；−これを含有する薬用組成物；−上記新規化合物の製造方法である。 上記新規の環状有機セレン化合物は一般式（Ｉ）を持つものである： | ||||||
| 29 | New selenium-containing plastic lens and its production | JP3784697 | 1997-02-21 | JPH10237042A | 1998-09-08 | OKAZAKI MITSUKI; TANAKA MAMORU; HONMA SHIRO; MORIJIRI HIROYUKI; KANEMURA YOSHINOBU; KUSUMOTO MASAHIKO |
| PROBLEM TO BE SOLVED: To obtain the subject optical material having an improved refractive index and useful as an eye-glass lens, etc., by introducing selenium atom(s) into a molecule of which an optical material is produced. SOLUTION: These optical material and plastic lens can be obtained by subjecting a composition, which contains at least one or more kinds selected from a reactive monomer having at least one or more selenium atoms in a molecule and its oligomer, to cast polymerization. Examples of the monomer or oligomer include a selenium atom-containing active hydrogen compound having at least one or more functional groups selected from hydroxy, mercapto, seleno and amino in a molecule and a selenium atom-containing self- polymerizable compound having at least one or more functional groups selected from (meth)acrylic, allyl carbonate, etc., in a molecule. The plastic lens can be obtained, for example, by mixing 4-thia-1-selenane-2,6-dimercaptomethyl, m-xylylenediisocyanate, dibutyltin dichloride and dioctyl phosphate to obtain a homogeneous solution, and subsequently heating the solution to cure it. | ||||||
| 30 | Benzotrichalcogenols, radical cation derivative thereof and production threof | JP9954894 | 1994-05-13 | JPH07304766A | 1995-11-21 | SATOU KIYOSHI; KIKUCHI TAKAMASA; SASAKI ATSUKO; OGAWA SATOSHI |
| PURPOSE:To provide a new benzotrichalcogenol compound suitable as an electrochromic element, applicable to a recording or displaying device and useful as an electrophotographic receptor, etc. CONSTITUTION:This benzotrichalcogenol compound is expressed by formula I (R<1> and R<2> each is H or an alkyl; X<1> to X<3> each is S or Se), e.g. 4,7- diethyl-1,2,3-benzotrithiol of formula II. The compound (X2 is S) can be produced, e.g. by reacting a benzodichalcogenastannol of formula III (R<3> and R<4> each is an alkyl) with thionyl chloride and reducing the product with sodium iodide and perchloric acid. The compound of formula I wherein X2 is Se can be produced, e.g. by reacting a compound of formula III with selenium tetrachloride. | ||||||
| 31 | JPH06505975A - | JP50605692 | 1992-03-19 | JPH06505975A | 1994-07-07 | |
| 32 | Fulvalene derivative | JP4055386 | 1986-02-26 | JPH0631219B2 | 1994-04-27 | IGUCHI HIROO; SAITO GUNJI; SEKI KAZUHIKO; MORI TAKEHIKO |
| 33 | Organic superconductor | JP16189890 | 1990-06-20 | JPH0456010A | 1992-02-24 | MIZUTANI MAKOTO; TANAKA KEIJI; KAWABATA KAZUE |
| PURPOSE: To have a transiting temp. much higher than conventional by using a complex body of an electron doner and an electron receptor as expressed by specific equation. CONSTITUTION: Equation 1 ≫ expresses a complex body - where, X1, X2, X3, X4, X1', X2', X3', and take either S or Se independently; Y is an electron donative or receptive substitute radical having such a size as not hindering overlap of molecules; m is integer between 0-4; Z1, Z2, Z1', Z2' take independently either hydrogen atom, C nH 2n+1, XC nH 2n+1, X(CH 2) n or C nH 2n where Z1, Z2 and Z1', Z2' are coupled, or X(X=S or Se); R1', R2', R3', R1, R2, R3 take independently either hydrogen atom or C nH 2n+1; A is electron doner; and lis as number between 0.1-10. COPYRIGHT: (C)1992,JPO&Japio | ||||||
| 34 | N,n'-biscyano-p-benzoquinonebisimine, charge-transfer complex compound containing same and its radical ionic salt | JP13454788 | 1988-06-02 | JPS643158A | 1989-01-06 | AREKISANDAA AUMIYURAA; JIIKUFURIITO FUYUUNITSUHI; PEETAA ERUKU; FUUBERUTO MAIKUSUNAA; TOBIASU METSUTSUENCHIN |
| NEW MATERIAL: A biscyanoimine of formula I (where R 1 is propyl, 5-20C alkyl, 3-20C alkenyl or I and each of R 2-R 4 is H, Cl, Br, I, F, phenyl, 1-20C alkyl, 3-20C alkenyl or 1-8C alkoxy). EXAMPLE: 2-Dodecyl-N,N'-cyano-1,4-benzoquinonediimine. USE: Starting material for a charge-transfer complex compound. This complex compd. and its radical ionic salt are used as an electric semiconductor and a photoconductor and are useful for the antistatic finishing of a synthetic resin and as an electrode of a cell, an electricity accumulating material, etc. PROCESS: The compd. of the formula I is obtd. by allowing quinone of formula II to react with bistrimethylsilylcarbodiimide in an inert solvent in the presence of a catalyst such as TiCl 4. The charge-transfer complex compd. is derived by allowing the compd. of the formula I to react with a fluvalene compd. in a specified molar ratio. COPYRIGHT: (C)1989,JPO | ||||||
| 35 | JPS562554B2 - | JP6309175 | 1975-05-28 | JPS562554B2 | 1981-01-20 | |
| 36 | Jukikanshikikagobutsuoketsugosaseruhoho | JP6309175 | 1975-05-28 | JPS511472A | 1976-01-08 | EDOWAADO EMU ENGURAA; BISHUNUBIHAI UII PEITERU |
| 37 | PT97954472 | 1997-12-23 | PT948500E | 2004-07-30 | TAILHAN-LOMONT CATHERINE; ERDELMEIER IRENE; MOUTET MARC; CHAUDIERE JEAN; YADAN JEAN-CLAUDE | |
| 38 | Improved chemiluminescent 1,2-dioxetanes | AU7359696 | 1996-10-17 | AU720542B2 | 2000-06-01 | BRONSTEIN IRENA; EDWARDS BROOKS; SPARKS ALISON; VOYTA JOHN C |
| 39 | Cyclic compounds organoselenium, their preparation and their uses, including therapeutic | FR9616102 | 1996-12-27 | FR2757860B1 | 1999-04-23 | ERDELMEIER IRENE; TAILHAN LOMONT CATHERINE; MOUTET MARC; CHAUDIERE JEAN R; YADAN JEAN CLAUDE |
| 40 | Cyclic ligands | GB9205992 | 1992-03-19 | GB2253850B | 1994-11-09 | BLOWER PHILIP JOHN; RICHARDSON ADRIAN PETER; SMITH RAYMOND JOHN |
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