序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 Purification of organometallic compound JP2006311645 2006-11-17 JP2007137883A 2007-06-07 SHENAI-KHATKHATE DEODATTA V; DICARLO RONALD L JR
PROBLEM TO BE SOLVED: To provide a method for purifying an organometallic compound in respect to field of purification of the organometallic compound, particularly a material used in the vapor deposition of metal-containing films. SOLUTION: The present invention provides a method for purifying the organometallic compound by heating the organometallic compound in the presence of a trialkyl aluminum compound and a catalyst. COPYRIGHT: (C)2007,JPO&INPIT
102 Organic ammonium tungstate and molybdate compounds, and methods of preparing such compounds JP2006501264 2004-04-08 JP2006524191A 2006-10-26 ジェイ. ティニック ロバート
新規な有機アンモニウム化合物であって、潤滑組成物の耐磨耗および減摩性状を改良する添加剤として有用である化合物を提供している。 この化合物は、金属酸和物を1種または複数のアルキルアミンと反応させるステップにより生成される。 具体例は、タングステン酸ジトリデシルアンモニウム、タングステン酸ジ−n−オクチルアンモニウム、およびモリブデン酸ジトリデシルアンモニウムの調製である
103 有機テルル化合物、その製造方法、リビングラジカル重合開始剤、それを用いるポリマーの製造方法及びポリマー JP2004527297 2002-08-06 JPWO2004014848A1 2005-12-02 茂 山子; 吉田 潤一; 潤一 吉田
式(1)で表される有機テルル化合物はリビングラジカル重合開始剤として有用で、温和な条件下で、精密な分子量及び分子量分布制御を可能とする。〔式中、R1は、C1〜C8のアルキル基を示す。R2及びR3は、原子又はC1〜C8のアルキル基を示す。R4は、アリール基、置換アリール基、芳香族ヘテロ環基、オキシカルボニル基又はシアノ基を示す。〕
104 Method for producing organotellurium compound JP2003121825 2003-04-25 JP2004323437A 2004-11-18 YAMAKO SHIGERU; YOSHIDA JUNICHI; KAMESHIMA TAKASHI
PROBLEM TO BE SOLVED: To provide a new method for producing an organotellurium compound, for example, useful as a living radical polymerization initiator. SOLUTION: The method for producing the organotellurium compound comprises reacting an azo-based polymerization initiator with a compound represented by formula (1): R 1Te-TeR 2---(1) (wherein, R 1 and R 2 are each a 1-8C alkyl group, an aryl group, a substituted aryl group or an aromatic heterocyclic group). COPYRIGHT: (C)2005,JPO&NCIPI
105 Organic metallic compound JP2004099110 2004-03-30 JP2004308007A 2004-11-04 SHENAI-KHATKHATE DEODATTA V; POWER MICHAEL BRENDAN
PROBLEM TO BE SOLVED: To provide a specific organic metallic compound suitable for use relating to a field of organic metallic compounds in general, more particularly in a vapor deposition process. SOLUTION: The organic metallic compound suitable for use as a vapor deposition precursor for a group IV metal-containing film is provided. A method of depositing the group IV metal-containing film using a certain organic metal precursor is also provided. The group IV metal-containing film is particularly useful in the manufacture of electronic devices. COPYRIGHT: (C)2005,JPO&NCIPI
106 The analysis method of the dry immunoassay element and an immunologically reactive ligand JP14619396 1996-06-07 JP3545536B2 2004-07-21 アン デカン キャロル; ルイス スノッドグラス ゲイリー; エリザベス ローガン マーガレット; デニス ベイル オーニック マーシャ; オージーン スノーク ロイ
A dry immunoassay analytical element for assaying a ligand, comprising a support bearing: 1. an enzyme labeled ligand or an enzyme labeled receptor zone; 2. a spreading zone; and 3. a receptor zone containing a fixed concentration of an immobilized receptor for the ligand and the labeled ligand when present and the receptor is covalently bonded to polymeric beads having a diameter in the range of 0.1 to 5 mu m; characterized in that the element contains a diaryl telluride (DAT) compound and the zones can be in the same or separate layers.
107 Novel radical Bamo dichloride telluride compound JP10664492 1992-04-24 JP2709775B2 1998-02-04 博友 佐々木; 亨 藤森
108 Fluorine-containing chiral smectic liquid crystal JP21646994 1994-08-08 JP2705714B2 1998-01-28 ピーター ヤヌリス ユージン
109 Production of dialkyl tellurium and selenium dialkyl JP50671293 1992-09-29 JPH08505358A 1996-06-11 コール−ハミルトン,デイビツド・ジヨン; マツクイーン,ユーアン
(57)【要約】 ジアルキルテルル、ジアルキルセレン、二テルル化ジアルキル及び二セレン化ジアルキルの製造方法を提供する。 本方法は、カルコゲン化ナトリウムをハロゲン化アルキルと反応させることからなり、前記反応を二相系で実施し、相移動触媒を加えることを特徴とする。
110 Carboxy, coordination complexes consisting of carboalkoxy and carbamyl substituted isonitrile radionuclides JP20357386 1986-08-29 JP2504750B2 1996-06-05 ARAN JII JOONZU; ARAN DEEUISON; JEEMUZU KURONAAJI; MAIKERU JEI EIBURAMUSU
111 Fluorine-containing chiral smectic liquid crystal JP16220587 1987-06-29 JPH07116107B2 1995-12-13 ピーター ヤヌリス ユージン
112 Fluorine-containing chiral smectic liquid crystal JP21646994 1994-08-08 JPH07324051A 1995-12-12 YUUJIN PIITAA YANURISU
PURPOSE: To obtain a new compound useful as an intermediate for chiral smectic liqiud crystal compounds optically active and exhibiting ferroelectric behavior. CONSTITUTION: This new compound is shown by formula I or formula II ((x) is 4-20), e.g. S-4-(4-methylhexyloxy)benzoic acid. The compound of formula I is obtained by coupling reaction between a compound of formula III and a compound of formula IV (X, Y and Z are each H, Cl, F, CH 3, OH, Br or the like; (l), (m) and (n) are each 0-4; (a), (b) and (c) are each 0-3; A is CH=N, CH 2-O, C≡C or the like; B' and B" are each OH, COOH, SH or the like; M, N and P are each cyclohexane ring or the like; R is C 9H 29-X or the like; X is H or F). This new compound is especially useful in surface-stabilized ferroelectric liquid crystal displays. COPYRIGHT: (C)1995,JPO
113 Cytokine production stimulating compound JP25097785 1985-11-11 JPH0791286B2 1995-10-04 スレドニ ベンジヤミン; アルベツク マイケル
114 Kit containing coordination complex JP29009194 1994-11-24 JPH07206884A 1995-08-08 ARAN JII JIYOONZU; ARAN DEEBUISON; JIEEMUZU KURONAAJI; MAIKERU JIEI EIBURAMUSU
PURPOSE: To provide a kit for producing a coordination complex comprising a substd. isonitrile and a radionuclide and an isonitrile-containing aseptic vial. CONSTITUTION: This kit is the one for producing a coordination complex comprising an isonitrile ligand represented by the formula, (CNX)R [wherein X is a 1-4C lower alkyl group and R is selected from a group consisting of COOR 1 and CONR 2R 3 (wherein R 1 is H, a pharmacologically acceptable cation or a substd. or unsubstd. 1-4C alkyl group; and R 2 and R 3 are each H or a substd. or unsubstd. 1-4C alkyl group and same or different)] and a radionuclide selected from a group consisting of radioactive isotopes of Tc, Ru, Co, Pt and Re. An aseptic vial contains the kit comprising a predetermined amt. of a reducing agent capable of reducing a predetermined amt. of the isonitrile ligand and a predetermined amt. of the radionuclide preliminarily selected from the radioisotopes to form the complex and the isonitrile ligand. COPYRIGHT: (C)1995,JPO
115 New dicarbamoyl telluride compound JP10664392 1992-04-24 JPH05306268A 1993-11-19 SASAKI HIROTOMO; FUJIMORI TORU
PURPOSE:To provide a new compound useful as a synthetic intermediate for pharmaceuticals, agricultural chemicals, photographic chemicals, etc. CONSTITUTION:The compound of formula I (R1 and R2 are aliphatic or aromatic group), e.g. the compound of formula II. The compound of formula I can be produced e.g. by reacting a carbamoyl chloride (R1R2NCOCl) with Na2Ten (n is natural number) which is a reagent produced by reducing tellurium with sodium hydride, etc.
116 Production of oxazoles JP26051791 1991-09-12 JPH0570445A 1993-03-23 OGURA FUMIO; OTSUBO TETSUO; ASO YOSHIO; FUKUMOTO TAKAHIRO
PURPOSE:To directly obtain the subject compounds applicable to scintillators, etc., from an acetylene compound in high yield by reacting the acetylene compound with a nitrile compound using a specific organotellurium compound as a mediator. CONSTITUTION:An acetylene compound (e.g. diphenylacetylene) is reacted with a nitrile compound (e.g. acetonitrile) using an organotellurinyl compound (e.g. benzenetellurinyl trifluoroacetate) expressed by the formula (Ar is aryl or substituted aryl; R is alkyl or halogen-substituted alkyl; A is CO or SO2) as a mediator to readily afford oxazoles (e.g. 2-methyl-4,5-diphenyl-oxazole) according to intramolecular reaction without isolating an intermediate. The oxazole compounds are directly obtained from the acetylene compound in excellent regioselectivity and high yield under conditions without requiring high temperatures by the above-mentioned method. The resultant oxazole compounds are useful as scintillators, fluorescent brighteners, etc., in the field of analgesic, antiphlogistic, antimicrobial and hypotensive agents, medicines for diabetes, etc.
117 JPH03501481A - JP50094589 1988-12-02 JPH03501481A 1991-04-04
118 Composition for inducing cytokine formation and method of induction JP1596290 1990-01-25 JPH02258723A 1990-10-19 BENJIYAMIN SUREDONI; MAIKERU ARUBETSUKU
PURPOSE: To obtain a composition for inducing cytokine formation by compounding a tellurium tetrahalide as an active component. CONSTITUTION: This pharmaceutical composition is composed of a tellurium tetrahalide and a pharmaceutically permissible support. The treatment of cancer, immunodeficiency, an autoimmune disease or an infectious disease is performed by using a tellurium tetrahalide as a supplemental agent or a primary treating agent. The composition stimulates cytokine formation in a living body. Further, the dose of the compound for treating said disease is 0.01-1 mg/kg-body weight, preferably 0.02-0.5mg/kg-body weight, and in the case of in vitro use, the compound in the range of 1×10<-8> to 1×10<-4> g, preferably 1×10<-7> to 1×10<-5> g is used for 10<6> cells/ml.
119 Complex of tellurium and selenium derivative JP6341789 1989-03-14 JPH0242056A 1990-02-13 BENJIYAMIN SUREDONII; MAIKERU ARUBETSUKU; REO PABURIFU
NEW MATERIAL: A complex of a compd. represented by formula I or II, or the formula; TeO 2 or the formula; phTecl 3 or formula III (wherein Q is The or Se, t, u and v are each 1 or 0, R, R 1 to R 9 are each H, a 1-5C hydroxyalkyl, hydroxy, 1-5C alkyl, halogen, 1-5C haloalkyl or carboxy and X is a halogen) and an innoxious complexing agent. USE: This new material is used in a medicine compsn. and useful as a synthetic intermediate of lymphokine and cytokine useful for treating cancer, immunity deficiency or an infection disease. PROCESS: A compd. represented by formula I or II, or the formula; TeO 2 or the formula; phTecl 3 or formula III is brought into contact with a complexing agent selected from the group consisting of a hydroxypolycarboxylic acid, polycarboxylic acid and polyhydroxypolycarboxylic acid to obtain the objective complex. COPYRIGHT: (C)1990,JPO
120 Production of 2-oxazolidinones JP22292687 1987-09-08 JPS6466176A 1989-03-13 OGURA FUMIO; OTSUBO TETSUO; ASO YOSHIO; KO NANSEI
PURPOSE:To directly obtain the titled substance in high yield and stereo- selectivity, by reacting an olefin compound with a carbamic acid ester in the presence of a Lewis acid using an organic tellurinyl compound as a mediator. CONSTITUTION:The titled substance can be produced by reacting an olefin compound with a carbamic acid ester in the presence of Lewis acid (preferably a boron trifluoride complex) using an organic tellurinyl compound as a mediator and cyclizing the addition product under mild heating (at >=70 deg.C). The reaction is preferably carried out by using chlorinated hydrocarbons as a solvent. The titled substance is useful as an intermediate for pharmaceuticals and a raw material for polymers having hydrophilic nature, polarity and specific adsorption capability.
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