| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 一种用于制备重氮烷的方法 | CN201380014473.0 | 2013-01-23 | CN104203907A | 2014-12-10 | 李·普罗克特 |
| 本发明涉及形成重氮烷的方法。本发明的一个方面提供了用于由起始材料制备N-烷基-N-亚硝基化合物的方法，所述方法包括使用三元酸对胺进行酸化。本发明的第二方面提供了用于制备重氮烷的方法，所述方法包括使N-烷基-N-亚硝基化合物与碱和相转移催化剂反应，其中没有使用有机溶剂。 | ||||||
| 2 | 三(N-亚硝基-N-苯基羟胺)铝盐的制备方法 | CN200610113558.6 | 2006-09-30 | CN101153014B | 2010-05-12 | 罗鹏; 赵文超; 闫庆金; 邵俊峰 |
| 本发明涉及式(1)所示三(N-亚硝基-N-苯基羟胺)铝盐的制备方法，所述方法是在C1-4醇类与水混合溶剂体系中，采用硝酸铝与N-亚硝基-N-苯基羟胺铵盐发生复分解反应，使用缓冲溶液控制反应液的pH值在5.5～5.7，高收率地制备出式(1)化合物。 | ||||||
| 3 | 三(N－亚硝基－N－苯基羟胺)铝盐的制备方法 | CN200610113558.6 | 2006-09-30 | CN101153014A | 2008-04-02 | 罗鹏; 赵文超; 闫庆金; 邵俊峰 |
| 本发明涉及式(1)所示三(N－亚硝基－N－苯基羟胺)铝盐的制备方法，所述方法是在醇－谁混合溶剂中，采用硝酸铝与N－亚硝基－N－苯基羟胺铵盐发生复分解反应，使用缓冲溶液控制反应液的pH值在5.5～5.7，高收率地制备出式(1)化合物。 | ||||||
| 4 | 一种氘代化合物的制备方法 | CN201680053153.X | 2016-09-18 | CN108026030B | 2020-10-09 | 张寅生; 高勇; 柳英帅; 林志强 |
| 本发明属于化学合成领域，具体而言涉及一种氘代化合物的制备方法。本发明的制备方法，是在氘源的存在下，将至少含有一个式C‑N‑X的结构要素非氘代化合物转化为相应的氘代化合物，其中X为亚硝基、硝基、羟基、氰基或卤素，所用的氘源选自重水或氘代醇，氘源容易获得，且价格较低，操作简便易制备，氘代时间短，氘代率高，一次氘代率可达90%以上，所述氘代过程没有使用毒性较大的试剂，绿色环保，特别适合应用于开发氘代药物。 | ||||||
| 5 | 一种氘代化合物的制备方法 | CN201680053153.X | 2016-09-18 | CN108026030A | 2018-05-11 | 张寅生; 高勇; 柳英帅; 林志强 |
| 本发明属于化学合成领域，具体而言涉及一种氘代化合物的制备方法。本发明的制备方法，是在氘源的存在下，将至少含有一个式C‑N‑X的结构要素非氘代化合物转化为相应的氘代化合物，其中X为亚硝基、硝基、羟基、氰基或卤素，所用的氘源选自重水或氘代醇，氘源容易获得，且价格较低，操作简便易制备，氘代时间短，氘代率高，一次氘代率可达90%以上，所述氘代过程没有使用毒性较大的试剂，绿色环保，特别适合应用于开发氘代药物。 | ||||||
| 6 | 一种用于制备重氮烷的方法 | CN201380014473.0 | 2013-01-23 | CN104203907B | 2017-08-29 | 李·普罗克特 |
| 本发明涉及形成重氮烷的方法。本发明的一个方面提供了用于由起始材料制备N‑烷基‑N‑亚硝基化合物的方法，所述方法包括使用三元酸对胺进行酸化。本发明的第二方面提供了用于制备重氮烷的方法，所述方法包括使N‑烷基‑N‑亚硝基化合物与碱和相转移催化剂反应，其中没有使用有机溶剂。 | ||||||
| 7 | N-亚硝基-N-苯基羟胺铵盐的合成工艺 | CN201010166318.9 | 2010-05-05 | CN102234243A | 2011-11-09 | 张永昶 |
| 本发明是通过以下技术方案实现的：本发明所涉及N-亚硝基-N-苯基羟胺铵盐的合成工艺，以硝基苯为原料，经锌粉还原后，与亚硝基酯反应得到粗品，用合适的溶剂精制粗品得到纯度合格的产品。具有如下的有益效果：反应选择性好，产率高好，产品质量高。本发明制备方法简单，成本低，有一定的工业应用前景。得到白色鳞片状晶体22.5g，产率：88％，HPLC纯度：99.1％。适用于UV油墨、UV涂料、UV胶粘剂、光阻剂、以及不饱和聚酯类树脂、乙烯基单体和丙烯酸酯齐聚物等中。 | ||||||
| 8 | 使用吸附物质对N－亚硝基羟胺的稳定化作用 | CN00809275.3 | 2000-06-12 | CN1241905C | 2006-02-15 | 达里尔·V·哈利斯; 小鲍尔·J·罗曼; 吴志宏; 厄尔·G·亚当斯; 埃里克·L·威廉姆斯 |
| 本发明公开了一种表现出很少分解或不分解的N-亚硝基羟胺化合物。N-亚硝基羟胺化合物可以在能够从环境中除去水分的化合物的存在下被稳定。 | ||||||
| 9 | 使用吸附物质对N－亚硝基羟胺的稳定化作用 | CN00809275.3 | 2000-06-12 | CN1356978A | 2002-07-03 | 达里尔·V·哈利斯; 小鲍尔·J·罗曼; 吴志宏; 厄尔·G·亚当斯; 埃里克·L·威廉姆斯 |
| 本发明公开了一种表现出很少分解或不分解的N－亚硝基羟胺化合物。N－亚硝基羟胺化合物可以在能够从环境中除去水分的化合物的存在下被稳定。 | ||||||
| 10 | Nonlinear optical material | JP31872190 | 1990-11-22 | JPH04188118A | 1992-07-06 | WAKITA KATSUYA; SONODA NOBUO; MINEMOTO TAKASHI; KAWAMURA TATSURO |
| PURPOSE: To obtain nonlinear optical material having short absorption edge and large nonlinear optical characteristic by using a specific organic compound. CONSTITUTION: The organic compound shown in the formula I, peclon (N- nitrophenyl hydroxylamine ammonium salt) is used. Because this organic compound has short π-conjugate length, the absorption edge is short and there is little fear to absorb output higher harmonics, and because the construction is of intermolecular salt, the crystallizing condition is stable and the crystal is easily made. Hereby, nonlinear optical material having large nonlinear optical characteristic and short absorption edge can be obtained. COPYRIGHT: (C)1992,JPO&Japio | ||||||
| 11 | JPS5817180B2 - | JP11567273 | 1973-10-15 | JPS5817180B2 | 1983-04-05 | UIREMU YOSEFU WATSUSEN |
| 12 | JPS49100007A - | JP11567273 | 1973-10-15 | JPS49100007A | 1974-09-20 | |
| 13 | Method for the preparation of diazoalkanes | US14373828 | 2013-01-23 | US09593073B2 | 2017-03-14 | Lee Proctor |
| The present invention relates to a method of forming diazoalkanes. One aspect of the present invention provides a method for the production of a N-alkyl-N-nitroso compound from a starting material, comprising the use of a tribasic acid to acidify an amine. A second aspect of the present invention provides a method for the production of a diazoalkane, comprising reacting a N-alkyl-N-nitroso compound with a base and a phase transfer catalyst, wherein no organic solvent is used. | ||||||
| 14 | Oxygen substituted derivatives of nucleophile-nitric oxide adducts as nitric oxide donor prodrugs | US950637 | 1992-09-23 | US5366997A | 1994-11-22 | Larry K. Keefer; Tambra M. Dunams; Joseph E. Saavedra |
| There are disclosed cardiovascularly active compounds possessing antihypertensive properties, and pharmaceutical compositions containing these agents and a method of treating cardiovascular disorders with the compounds. The active components of the pharmaceutical compositions are compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are independently chosen from straight chain and branched chain alkyl and olefinic groups, which may be unsubstituted or substituted; or R.sub.1 and R.sub.2 together with the nitrogen atom they are bonded to form a heterocyclic group; and R.sub.3 is a pharmaceutically acceptable organic group selected from alkyl and olefinic groups which may be unsubstituted or substituted, acyl, a sulfonyl, sulfinyl, sulfenyl, carbonate, or carbamate derivative; or R.sub.3 is a group of the formula--(CH.sub.2).sub.n ONN(O)NR.sub.1 R.sub.2, wherein n is 2-8, and R.sub.1 and R.sub.2 are as described above. Novel compounds are disclosed wherein at least one of R.sub.1, R.sub.2 and R.sub.3 is an olefinic group or heteroatom-substituted straight or branched chain alkyl or olefinic group. Novel methods of synthesizing the compounds are also disclosed. | ||||||
| 15 | Salts of N-nitrosophenylhydroxylamine | US111256 | 1993-08-24 | US5292920A | 1994-03-08 | Rita K. Upmacis; William Bauer, Jr.; Samuel F. Reed, Jr. |
| Disclosed are salts of N-nitrosophenylhydroxylamine and their use as polymerization inhibitors. | ||||||
| 16 | Antihypertensive compositions and use thereof | US423279 | 1989-10-18 | US5212204A | 1993-05-18 | Larry K. Keefer; David A. Wink; Tambra M. Dunams; Joseph A. Hrabie |
| This invention concerns antihypertensive compositions and a method of lowering blood pressure in mammals. The active component of the compositions is a compound of the formula: ##STR1## wherein J is an organic or inorganic moiety, M.sup.+x is a pharmaceutically acceptable cation and the compound decomposes under physiological conditions to release nitric oxide (NO). | ||||||
| 17 | Method for producing crystalline n-nitroso-n-phenylhydroxylamine aluminum salt | JP2005264042 | 2005-09-12 | JP2007077038A | 2007-03-29 | KUTSUMA TERUO |
| <P>PROBLEM TO BE SOLVED: To facilitate the control of a reaction system in the production of a crystalline N-nitroso-N-phenylhydroxylamine aluminum salt and solve various problems on environment and working hygiene. <P>SOLUTION: The production method comprises the first step to drop nitrobenzene into a liquid mixture of a lower alcohol and water containing metallic zinc powder and ammonium chloride to form N-phenylhydroxylamine, the second step to drop an alkyl nitrite to the N-phenylhydroxylamine obtained by the first step in the presence of ammonium carbamate, ammonium bicarbonate or ammonium carbonate to obtain N-nitroso-N-phenylhydroxylamine ammonium salt and the third step to react cupferron obtained by the second step with an aluminum compound, dissolve the produced N-nitroso-N-phenylhydroxylamine aluminum salt in ethyl acetate or chloroform and reflux the product with a lower alcohol by heating. <P>COPYRIGHT: (C)2007,JPO&INPIT | ||||||
| 18 | Novel nitrosation polymer in organic synthesis | JP2004540593 | 2003-09-06 | JP2006501335A | 2006-01-12 | クロード ラルディ、; ディディエ ロシュ、 |
| 本発明は、式（Ａ）［式中、Ｘ、Ｙ、Ｒ
1 、Ｒ
2およびＲ
3は請求項１に定義されたとおりである］の新規なニトロソ化ポリマーに関する。 本発明はまた、前記ポリマーを調製する方法に関する。
【化１】 |
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| 19 | Stabilized monomer composition and its production | JP2000254164 | 2000-08-24 | JP2001089417A | 2001-04-03 | SCHARF JAKOB; RAU HARTMUT; GOETZEN FRIEDRICH |
| PROBLEM TO BE SOLVED: To provide a monomer composition which has good storage stability for a long time and can be polymerized into a polymer having a high polymerization degree without separating an inhibitor. SOLUTION: This monomer composition comprises at least one ethylenic unsaturated monomer and a combination of N,N-diethylhydroxylamine with N-nitroso-N-phenylhydroxylamine in a stabilizing amount. COPYRIGHT: (C)2001,JPO | ||||||
| 20 | JPH05504760A - | JP51500790 | 1990-10-15 | JPH05504760A | 1993-07-22 | |
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