序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 Preparation of 4-substituted aryl olefins US315674 1989-02-27 US4965361A 1990-10-23 Kevin J. Edgar
Process is disclosed for the preparation of 4-substituted aryl olefins from 4-substituted aryl iodides. 4-Substituted aryl iodides are contacted with an olefin in an ester solvent in the presence of a catalyst system comprising a palladium compound and a Bronsted base.
2 JPH04503674A - JP50522090 1990-02-22 JPH04503674A 1992-07-02
3 Halogen-substituted cyclic ether compound and its preparation JP1615984 1984-02-02 JPS60161942A 1985-08-23 ITOU HIROSHI; NITSUTA ATSUHIKO; TANAKA TOMIO; KAMIO HIDEO; TSUBOI KENJI
NEW MATERIAL:The compound of formula I (R is carbon ring or heterocylic group; Z is alkylene, alkenylene, oxyalkylene or aminoalkylene; A is halogen, alkyl, alkenyl, haloalkyl, OH, alkoxy, cyano, amino, etc.; B is O, CO, S, SO or azo; X is halogen; l is 0W5; m is 4W20; α and β are 0W4 and α+β>1; p is 1W2; q is 0W1; when p is 1, then q is 0, and when p is 2, then q is 0W1; etc.). EXAMPLE: 1-Bromo-4-furfuryloxybutane. USE: An intermediate raw material useful to introduce various functional groups into amide compound, amine, OH-substituted compound, etc. PREPARATION: The compound of formula I can be prepared economically in one step by reacting the OH-substituted compound of formula II with the halogen- substituted compound of formula III in an aprotic polar solvent in the presence of a strongly basic substance. COPYRIGHT: (C)1985,JPO&Japio
4 Process for the preparation of a secondary or tertiary hydroxylated amine compound from a primary or secondary amine compound and a product made by the process US268530 1994-07-06 US5594150A 1997-01-14 Catherine David; Gilles Teral; Henry Ledon; Jean-Pierre Boiteux
Process for the preparation of a hydroxylated secondary or tertiary amine compound having a hydroxyl function .beta. to the amine function, according to which a primary or secondary amine compound is reacted with a compound containing an epoxy function in the presence of a phase transfer catalyst.
5 Phenyl-substituted hydroxy-cyclopentenone and a method of manufacturing a method for manufacturing the same, and phenyl-substituted hydroxy cyclopentanone JP5121794 1994-02-24 JP3541418B2 2004-07-14 史衛 佐藤
6 Phenyl-substituted hydroxycyclopentenones, production thereof and production of phenyl-substituted hydroxycycklopentanone JP5121794 1994-02-24 JPH07238045A 1995-09-12 SATOU FUMIE
PURPOSE:To obtain a novel intermediate for a phenyl-substituted prostaglandin E which is useful as a variety of medicines. CONSTITUTION:A compound is represented by formula I[Z<1> is H, a protecting group for OH; X<1> is H, halogen, 1-6C alkoxy, nitro; X<2> is a halogen,-Y<1>h(CR<1> R<2>)mAn(CH2)p, Y<2>q(CR<3>R<4>)rQs (Y<1>, Y<2> are O, S; A is a divalent group; R<1>-R<4> are H, a 1-4C alkyl; Q is H, cyano, OH; h, n, q, s are 0, 1; m, p, r are 0-5]. The compound of formula I is obtained by rearrangement of a furan derivative of formula II in the presence of an acid catalyst, isomerization under acidic or basic conditions and, when needed, protection of the hydroxyl group. A mixture of both antipodes of the compound of formula l is treated with an enzyme to give an optically active compound.
7 Cyclic halogen-substituted ether compounds and methods of manufacturing the JP1615984 1984-02-02 JPH0710786B2 1995-02-08 伊藤  博; 賢次 坪井; 敦彦 新田; 富夫 田中; 秀雄 神尾
8 Preparation of N- [4-chloro-2-fluoro-5- (pentyloxy-carbonylmethyloxy) -phenyl] -3,4,5,6-tetrahydrophthalimides. DE3853605 1988-08-19 DE3853605T2 1995-10-19 FUNAKI YUJI; FUKUSHIMA MASAYUKI
9 AT90905293 1990-02-22 ATE98209T1 1993-12-15 EDGAR KEVIN JOSEPH
10 ENANTIOSELECTIVE PREPARATION OF ACETYLENIC OR OLEFINIC SUBSTITUTED CYCLOALKENYL DIHYDROXYBUTYRATES AND 4-HYDROXY-TETRAHYDROPYRAN-2-ONES AU2023292 1992-02-11 AU2023292A 1992-09-15 ULLRICH JOHN W; REGAN JOHN R
11 PREPARATION OF 4-SUBSTITUTED ARYL OLEFINS CA2046643 1990-02-22 CA2046643A1 1990-08-28 EDGAR KEVIN J
2046643 9009973 PCTABS00002 Process is disclosed for the preparation of 4-substituted aryl olefins from 4-substituted aryl iodides. 4-Substituted aryl iodides are contacted with an olefin in an ester solvent in the presence of a catalyst system comprising a palladium compound and a Bronsted base.
12 BR8906055 1989-11-30 BR8906055A 1990-06-26 AUSTIN PETER WILLIAM
13 The production of N-[4-chloro-2-fluoro-5-(pentyloxycarbonylmethyloxy)phenyl]-3,4,5,6-tetrahydrophthalimide EP88113510.7 1988-08-19 EP0305826B1 1995-04-19 Funaki, Yuji; Fukushima, Masayuki
14 Novel bicycloheptene derivatives and process for the preparation thereof AU4143100 2000-04-27 AU4143100A 2000-11-17 YAGIHARA TOMIO; YAMANAKA HIROYUKI
15 Photoactive benzene monomers IL11450495 1995-07-07 IL114504A 1999-12-31
16 FUEL COMPOSITIONS CONTAINING POLY(OXYALKYLENE) AROMATIC ETHERS CA2151713 1994-10-27 CA2151713A1 1995-05-04
Fuel compositions containing a major amount of hydrocarbons boiling in the gasoline or diesel range and an effective deposit-controlling amount of a poly(oxyalkylene) aromatic ether having formula (I) where A1 is nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,Ndialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R1 and R2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R3 and R4 are independently hydrogen or lower alkyl and each R3 and R4 is independently selected in each -O-CHR3-CHR4- unit; R5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of formula (a) where R6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.
17 MX1833789 1989-11-13 MX173148B 1994-02-02 AUSTIN PETER WILLIAM
18 Preparation of 4-substituted aryl olefins. DE69005102 1990-02-22 DE69005102D1 1994-01-20 EDGAR KEVIN
19 Compounds of use in the treatment of herrickschen syndrome. DE3778576 1987-03-26 DE3778576D1 1992-06-04 ABRAHAM DONALD J; CRAGOE JR; WOLTERSDORF JR
20 PROCESS FOR PRODUCING POLYHYDROXY-BENZAYLOXY-PROPANOLAMINES AND PHARMACEUTICAL COMPOSITIONS CONTAINING THEM AS ACTIVE COMPONENT HU663689 1989-12-15 HUT53591A 1990-11-28 PATIL GHANSHYAM; MATIER WILLIAM L; MAI KHUONG H X
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