序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 用于生产橡胶离聚物以及聚合物纳米复合材料的方法 CN201180015515.3 2011-03-23 CN102822207A 2012-12-12 约尔格·基希霍夫; 罗尔夫·费尔勒; 保尔·瓦格纳; 汉斯-因戈尔夫·保罗; 阿达姆·戈罗诺斯基; 约翰·洛夫格罗夫; 菲尔·马吉尔; 达娜·阿德金森
发明涉及用于制备不含以及溶剂橡胶离聚物和/或含有所述橡胶离聚物的聚合物纳米复合材料的一种高能效的、环境有利的方法。
22 不含溶剂聚合物的生产方法 CN201180015555.8 2011-03-23 CN102822206A 2012-12-12 保尔·瓦格纳; 汉斯-因戈尔夫·保罗; 罗尔夫·费尔勒; 沃尔夫冈·克鲁姆贝; 阿莉西亚·勒-扎特勒; 海克·克洛彭堡; 马丁·西比埃格; 约翰·洛夫格罗夫
发明涉及不含溶剂聚合物,具体而言为不含水和溶剂的合成橡胶产品,像苯乙烯-丁二烯橡胶产品以及丁二烯橡胶产品连同用于它们的生产方法。本发明进一步涉及一种适合于完成所述方法的装置。
23 不含溶剂聚合物的生产方法 CN201180015574.0 2011-03-23 CN102821929A 2012-12-12 约尔格·基希霍夫; 维尔纳·贝克尔; 罗尔夫·费尔勒; 保尔·瓦格纳; 汉斯-因戈尔夫·保罗; 约翰·洛夫格罗夫
发明涉及不含溶剂聚合物,具体而言为不含水和溶剂的合成橡胶产品,像非卤化的以及卤化丁基橡胶产品连同用于它们的生产方法。本发明进一步涉及一种适合于完成所述方法的装置。
24 磷酸酯/混合物终止阴离子聚合的方法 CN200710106461.7 2007-05-29 CN101182363A 2008-05-21 金三珉; 金荣镇; 金升日; 柳志欣
发明涉及用磷酸酯/混合物终止阴离子聚合的方法,更具体地,涉及用于终止阴离子聚合的新方法,其中在通过阴离子聚合制成的活性聚合物溶液中采用磷酸酯/水混合物作为聚合终止剂,以使得可以有效终止聚合而没有偶联或变色,以及还较少产生影响抗化剂的性物质,由此能够控制酸度而无需进一步的中和过程。
25 RUBBER EXTRACTION METHOD US15773024 2016-11-03 US20180319904A1 2018-11-08 Peter Johannes VAN DIJK; Rolf André MANK
The present invention relates to a method for obtaining rubber from rubber-containing plant material, the method comprising the steps of subjecting a composition comprising rubber-containing plant material and a fermentation culture to conditions allowing anaerobic fermentation, wherein the composition preferably has a water content of less than 95 wt. %. The fermentation preferably does not involve movement of the rubber-containing plant material (or parts thereof), and preferably the fermentation is performed in the absence of oxygen ventilation. Additionally, it is preferred that the fermentation culture is cycled through the composition by percolation. A further step of the method involves obtaining the rubber from the composition.
26 INTEGRATED PROCESS FOR PROCESSING AND UTILISING THE GUAYULE PLANT US15515299 2015-10-21 US20170218094A1 2017-08-03 Ezio BATTISTEL; Stefano RAMELLO; Cecilia QUERCI
The present invention relates to an integrated process for processing and utilising every part of the guayule plant (Parthenium argentatum) which comprises the following steps in sequence: separating the stem and branches (3) from the leaves (2) of said plant with a mechanical treatment (1); treating the leaves (100) to produce waxes and essential oils (102), and a fraction (101) containing cellulose, hemicellulose (carbohydrates) and, to a minor extent, salts, organic compounds and lignin; extracting (200) from the stem and branches a liquid phase (4), so forming a first solid woody residue (5), indicated with bagasse in the present text; treating said first solid woody residue (5) to prepare sugars, resin, rubber and lignin.
27 PROCESS FOR THE PRODUCTION OF WATER AND SOLVENT-FREE POLYMERS US14603482 2015-01-23 US20150203600A1 2015-07-23 Jorg KIRCHHOFF; Werner BACKER; Rolf FELLER; Paul WAGNER; Hanns-Ingolf PAUL; John LOVEGROVE
The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like non-halogenated and halogenated butyl rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.
28 Process and a device for the continuous treatment of mixed substances US13148133 2010-02-05 US08519093B2 2013-08-27 Andreas Diener; Pierre-Alain Fleury; Thomas Isenschmid; Alfred Kunz; Alain Schwick; Manuel Steiner; Daniel Witte
A process for the continuous thermal treatment of mixed substances, especially of solutions, suspensions and emulsions, wherein the continuous treatment of the mixed substances is divided into a main vaporization and a degassing stage, in which instance the main vaporization and the degassing take place in each case takes place in a separate mixer-kneader.
29 PROCESS FOR THE PRODUCTION OF RUBBER IONOMERS AND POLYMER NANOCOMPOSITES US13635793 2011-03-23 US20130217833A1 2013-08-22 Hanns-Ingolf Paul; Rolf Feller; Paul Wagner; John Lovegrove; Phil Magill; Dana Adkinson; Jörg Kirchhoff
The invention relates to an energy efficient, environmentally favourable process for preparing water and solvent-free rubber ionomers and/or polymer nanocomposites comprising said rubber ionomers.
30 High temperature process for solution polymerization US12229499 2008-08-22 US07650930B2 2010-01-26 Eric Cheluget; Arun Sood; Rob VanAsseldonk; Ryan McCabe
A process for the solution polymerization of olefins with improved on-stream time is provided. The solution polymerization process of the current invention comprises a method for the on-line removal of foulant material from one or more heat exchangers downstream of a polymerization reactor. Removal of foulant material is accomplished by deliberately applying a positive pressure differential across a heat exchanger. In the process of the current invention, reactor shut down is not required for the purpose of cleaning foulant material from a heat exchanger.
31 METHOD FOR SEPARATING POLYMER SYSTEMS AND PORE-FREE POLYMER FILMS USED IN SAID METHOD US10539410 2003-12-17 US20090032461A1 2009-02-05 Andreas Greiner; Joachim H. Wendorff; Phillip Hanefeld; Stefan Kreiling
The subject matter of the invention is an innovative method for the separation of polymer systems regarding their molecular weight, chemical structure, chain architecture, and colloidal additives. Such separations are currently accomplished by selective precipitation from solution, by a fractionated crystallization also from solution, and by means of gel chromatographic methods.The invention pertains to a separation of polymer systems by means of permeation through polymer films—semi-crystalline, cross-linked, amorphous—with thicknesses in a nanometer scale. The restriction to thicknesses in a nanometer scale is essential for a high throughput of polymers. Of particular significance is the selectivity towards colloidal additives with a structure that is not in chain form.
32 Process for the production of hydrogenated nitrile rubber US10027735 2001-12-19 US06602962B2 2003-08-05 Paul Nguyen; Carl Walter Von Hellens
Disclosed herein is a process for the production of hydrogenated nitrile rubber. The appearance of corrosion in the plant equipment in which hydrogenated nitrile rubber is produced is due to the unexpected presence of relatively large amounts of HCl, generated, surprisingly, by the hydro-dehalogenation of the monochlorobenzene solvent under the reaction conditions. The addition of a compatible weakly basic additive, such as Epoxidized Soy Bean Oil (ESBO), to the reaction mixture has alleviated this serious problem.
33 Process for the production of hydrogenated nitrile rubber US10027735 2001-12-19 US20020123574A1 2002-09-05 Paul Nguyen; Carl Walter Von Hellens
Disclosed herein is a process for the production of hydrogenated nitrile rubber. The appearance of corrosion in the plant equipment in which hydrogenated nitrile rubber is produced is due to the unexpected presence of relatively large amounts of HCl, generated, surprisingly, by the hydro-dehalogenation of the monochlorobenzene solvent under the reaction conditions. The addition of a compatible weakly basic additive, such as Epoxidized Soy Bean Oil (ESBO), to the reaction mixture has alleviated this serious problem.
34 Treatment of diene elastomers with boron compounds US3520865D 1969-01-23 US3520865A 1970-07-21 PAMPUS GOTTFRIED; SCHON NIKOLAUS; WITTE JOSEF
35 Production of polybutadiene US29560963 1963-07-15 US3245894A 1966-04-12 HINTON ROBERT A
36 Concentration of polymers from solutions by flash vaporization US27583263 1963-04-26 US3234994A 1966-02-15 DANCE ELDRED L
37 Process for treatment of solutions of chlorinated rubber US5593635 1935-12-23 US2104069A 1938-01-04 PHILIP BAXTER JOHN; GRANGE MOORE JOSEPH
38 Integrated process for processing and utilising the guayule plant US15515299 2015-10-21 US09969818B2 2018-05-15 Ezio Battistel; Stefano Ramello; Cecilia Querci
The present invention relates to an integrated process for processing and utilizing every part of the guayule plant (Parthenium argnetatum) which comprises the following steps in sequence: separating the stem and branches from the leaves of said plant with a mechanical treatment; treating the leaves to produce waxes and essential oils, and a fraction containing cellulose, hemicellulose (carbohydrates) and, to a minor extent, salts, organic compounds and lignin; extracting from the stem and branches a liquid phase, so forming a first solid woody residue, indicated with bagasse in the present text; treating said first solid woody residue to prepare sugars, resin, rubber and lignin.
39 Method for producing polymer US14761356 2014-01-08 US09738742B2 2017-08-22 Yoshifumi Araki; Eiji Sasaya; Takuya Suzuki
A method for producing a polymer has: a polymerization step of polymerizing at least a conjugated diene monomer in a hydrocarbon solvent using an organolithium compound as a polymerization initiator, and obtaining a polymer; and, following steps (1) to (4), successively performing after the polymerization step: (1) a step of mixing an acid and water of 20 to 300 parts by mass into the solution containing the polymer of 100 parts by mass, (2) a step of adjusting an amount of the water to 10 parts by mass or less based on 100 parts by mass of the solution containing the polymer, (3) a step of adding a carbon oxide gas and/or a compound to be decarboxylated to the solution containing the polymer, and (4) a step of removing a solvent from the solution containing the polymer until a concentration of the polymer reaches 95 mass % or more.
40 Process for the production of water and solvent-free polymers US13063227 2009-09-17 US09512240B2 2016-12-06 Jörg Kirchhoff; Werner Bäcker; Rolf Feller; Paul Wagner; John Lovegrove; Hanns-Ingolf Paul
The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like non-halogenated and halogenated butyl rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.
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