序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 JPH0254390B2 - JP1562682 1982-02-04 JPH0254390B2 1990-11-21 JEEMUZU PIITAA BURAUN; ROBAATO SUCHUAATO HANPUSON; FUREDERIKU TEIRAA KERII
22 Isocyanates derived from dienes and manufacture JP27591287 1987-11-02 JPS63190865A 1988-08-08 POORU SHIERUDON UOOTAAMAN; ARAN EMU FUERUDOMAN
23 Preparation of cyclohexylmono- and -urethane by adding methylcarbamate to limonene, isocyanate derived therefrom, method and composition JP27591387 1987-11-02 JPS63183553A 1988-07-28 ROORENSU JIYON NAMII
24 Diisocyanate, manufacture and use JP24596187 1987-10-01 JPS6391355A 1988-04-22 MANFURETSUDO SHIYUMITSUTO; KURAUSU KEENINGU; PEETERU HAITOKEMUPERU; YOZEFU PEDAIN
25 Aliphatic diisocyanates and use for manufacturing polyurethane plastic JP5431787 1987-03-11 JPS62221661A 1987-09-29 PIITAA HAITOKEMUPAA
26 JPS6214170B2 - JP6733184 1984-04-04 JPS6214170B2 1987-04-01 ZOLLINGER JOSEPH LAMAR; MITSCH RONALD ALLEN
27 JPS6135200B2 - JP4669985 1985-03-11 JPS6135200B2 1986-08-12 UIRIAMU JEI GOTSUTOSUTEIN; MUUREI EI KAPURAN; ARUFUONSU PII GURANATETSUKU
28 Manufacture of 7-aminocephem compound JP4669985 1985-03-11 JPS60222489A 1985-11-07 UIRIAMU JIEI GOTSUTOSUTEIN; MUUREI EI KAPURAN; ARUFUONSU PII GURANATETSUKU
29 Neopentylisocyanates and manufacture JP14977984 1984-07-20 JPS6042360A 1985-03-06 HERUMAN HAAGEMAN
30 Fatty diisocyanate, manufacture and manufacture of polyurethane therefrom JP7520284 1984-04-16 JPS6041651A 1985-03-05 YOHANESU AANORUDOUSU FUUBERUTO; DANIERU MARIA YOZEFU TSUNMAASU; YOZEFU ANTONIUSU YOHANESU MARI
31 Oligomer of diisocyanate JP17896082 1982-10-12 JPS5883017A 1983-05-18 ARUBERUTO AANORUDO FUAN HEEENE; YOZEFU ANTONIASU MARIA BINSENT
32 JPS5822026B2 - JP3946976 1976-04-09 JPS5822026B2 1983-05-06 MANFURETSUTO BOTSUKUMU; BARUTERU UERUDEINGEN; YOZEFU PEDAIN
33 JPS588412B2 - JP7498575 1975-06-19 JPS588412B2 1983-02-16 MARINASU YOHANESU ADORIANASU MARIA DEN OTSUTAA; AN TE NIJENFUISU; ARUBERUTO AANORUDO BAN JIINEN
34 JPS5761352B2 - JP7319678 1978-06-19 JPS5761352B2 1982-12-23 NISHINO MASAKI; YASUHARA YUTAKA
35 New aliphatic triisocyanate, its preparation and nonyellowing polyurethane resin hardener composed thereof JP2975180 1980-03-11 JPS56127341A 1981-10-06 DOI TSUNESUKE; IDE TERU; KISHIMOTO YASUSHI
NEW MATERIAL:4-Isocyanatemethyl-1,8-octamethylene diisocyanate of formula I. USE: Hardener for nonyellowing polyurethane resins. It has low toxicity and low viscosity. it is free from irritating odor and can be handled easily and safely, because its vapor pressure is extremely low at about normal temperature. The compound itself is stable to light and heat, and also it can be used as a raw material of e.g. polyurethane resins having high resistance to light and weather. PROCESS: The compound of formula I is obtained by the reaction of a compound of formula II or its salt with phosgene in a solvent, e.g. monochlorobenzene, at 80W 220°C. COPYRIGHT: (C)1981,JPO&Japio
36 66fluorodihydroxyphenylalanine JP14701980 1980-10-22 JPS5665850A 1981-06-03 JIYANOSU KORONITSUSHIYU
37 Polyurethane resin and paint composition JP16180478 1978-12-29 JPS5590526A 1980-07-09 FUKUDA TADANORI; SAKAMOTO SADAYUKI; NISHINO MASAKI; YASUHARA YUTAKA
PURPOSE: To provide polyurethane resin useful for a paint composition not containing volatile monomer with high toxity and having no stimulating odor by reacting polyol and 1,6,11-undecane triisocyanate. CONSTITUTION: Polyol and 1,6,11-undecane triisocyanate represented by a formula. The above-described 1,6,11-undecane triisocyanete is a novel compound having good symmetric structure, having b,p, of 166W167°C/0.2mmHg, being colorless and odorless liquid substance with good flowability in the vicinity of a room temperature, having low vapor pressure at about room temperature, having no stimulating odor to human body, being handled safely as well as containing isocyanate in a high concentration of above 45%. As polyol to be used, diol, polyol, polyetherpolyol, polyesterpolyol, polymerpolyol are included. COPYRIGHT: (C)1980,JPO&Japio
38 Novel resin family triisocyanate and its preparation JP7319678 1978-06-19 JPS55327A 1980-01-05 NISHINO MASAKI; YASUHARA YUTAKA
NEW MATERIAL:1,6,11-Undecane triisocyanate of formula I. USE: A raw material for polyurethane and polyurea usable for coating materials, films and adhesives, capable of imparting improved properties, e.g. light stability, weatherability, and solvent resistance, and good quick drying property and excellent surface hardness to films. PROCESS: 1,6,11-Undecanetriamine hydrochloride of formula II is suspended in an insert solvent, e.g. a chlorinated hydrocarbon, and reacted with phosgene at 100W170°C to give the compound of formula I. The starting compound of formula II is obtained by heating ε-caprolactam, ε-amino caproic acid, or their polymer in the presence of a strong base, e.g. an alkali metal oxide, at 300°C or above, and by reducing the resulting compound of formula III with hydrogen in aqueous ammonia. COPYRIGHT: (C)1980,JPO&Japio
39 New diisocyanate* process for manufacture and use thereof JP1124777 1977-02-05 JPS5295634A 1977-08-11 EEBERUHARUTO KEENITSUHI; YOZEFU PEDAIN
40 33furuoroollaraninoyobi22juuteroo33furuoroollaraninosoreranoddiseitainifuseihenkansuruhoho JP1858076 1976-02-24 JPS51110513A 1976-09-30 DONARUDO EFU REINHOORUDO
2-Deutero-3-fluoro-L-alanine is converted into its D-isomer in an asymmetrical manner. In this process, the L-isomer is reacted with sodium nitrite to give the corresponding L-2-deutero-2-halo-3-fluoro-propionic acid in solution in an aqueous hydrohalic acid. This L-2-deutero-2-halo-3-fluoropropionic acid is then reacted either with ammonia or with sodium azide with replacement of the 2-halogen substituent by a 2-azido group and subsequent catalytic hydrogenation to give 2-deutero-3-fluoro-D-alanine. 2-Deutero-3-fluoro-L-alanine can be converted into pharmaceutically acceptable salts. The resulting compound can be used for inhibition of the growth of Gram-positive and Gram-negative pathogenic bacteria.
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