序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 一种负载型催化剂及其制备方法 CN201210277334.4 2012-08-06 CN103566976B 2016-04-20 戴伟; 蒋海斌; 鲁树亮; 张晓红; 王国清; 乔金樑; 彭晖
发明公开了一种负载型催化剂,其包括:有机高分子材料、负载在有机高分子材料载体表面的雷尼合金粒子,其中所述的雷尼合金粒子部分嵌入有机高分子材料载体中。该负载型催化剂具有易成型、催化活性高和选择性好等优点,可应用于固定床催化反应装置中。
2 一种负载型催化剂及其制备方法 CN201210277334.4 2012-08-06 CN103566976A 2014-02-12 戴伟; 蒋海斌; 鲁树亮; 张晓红; 王国清; 乔金樑; 彭晖
发明公开了一种负载型催化剂,其包括:有机高分子材料、负载在有机高分子材料载体表面的雷尼合金粒子,其中所述的雷尼合金粒子部分嵌入有机高分子材料载体中。该负载型催化剂具有易成型、催化活性高和选择性好等优点,可应用于固定床催化反应装置中。
3 通过卤代的催化脱卤化氢制备氟化烯烃 CN200880023701.X 2008-07-03 CN101687737B 2013-10-30 H·王; 童雪松
发明涉及一种制备氟化烯的方法,所述方法具有使具有至少一个氢原子和至少一个在相邻原子上的氯原子的氢氯氟烃脱氯化氢的步骤,所述步骤优选在催化剂存在下进行,所述催化剂选自(i)一种或多种金属卤化物、(ii)一种或多种卤化金属化物、(iii)一种或多种零价金属/金属合金和(iv)两种或更多种上述催化剂的组合。
4 从二化合物和多氧化合物产生芳香族化合物 CN201710094884.5 2014-03-14 CN107011936A 2017-08-04 泰勒·贝克; 布莱恩·布兰克; 凯西·琼斯; 伊丽莎白·伍兹; 兰迪·柯特莱特
申请涉及从二化合物和多氧化合物产生芳香族化合物。披露了用于从包含二氧化合物和多氧化合物的含氧化合物混合物以高产率产生芳香族化学品和液体燃料的方法、催化剂、以及反应器系统。还披露了用于从氧合化合物、糖、糖醇、糖降解产物等产生芳香族化学品和液体燃料的方法、催化剂、以及反应器系统;以及用于从氧合烃如碳水化合物、糖、糖醇、糖降解产物等产生含氧化合物混合物的方法、催化剂、以及反应器系统。所披露的用于制备该含氧化合物混合物的催化剂包含第VIII族金属和结晶氧化载体。
5 从二化合物和多氧化合物产生芳香族化合物 CN201480014871.7 2014-03-14 CN105143406A 2015-12-09 泰勒·贝克; 布莱恩·布兰克; 凯西·琼斯; 伊丽莎白·伍兹; 兰迪·柯特莱特
披露了用于从包含二化合物和多氧化合物的含氧化合物混合物以高产率产生芳香族化学品和液体燃料的方法、催化剂、以及反应器系统。还披露了用于从氧合化合物、糖、糖醇、糖降解产物等产生芳香族化学品和液体燃料的方法、催化剂、以及反应器系统;以及用于从氧合烃如碳水化合物、糖、糖醇、糖降解产物等产生含氧化合物混合物的方法、催化剂、以及反应器系统。所披露的用于制备该含氧化合物混合物的催化剂包含第VIII族金属和结晶氧化载体。
6 通过卤代的催化脱卤化氢制备氟化烯烃 CN200880023701.X 2008-07-03 CN101687737A 2010-03-31 H·王; 童雪松
发明涉及一种制备氟化烯的方法,所述方法具有使具有至少一个氢原子和至少一个在相邻原子上的氯原子的氢氯氟烃脱氯化氢的步骤,所述步骤优选在催化剂存在下进行,所述催化剂选自(i)一种或多种金属卤化物、(ii)一种或多种卤化金属化物、(iii)一种或多种零价金属/金属合金和(iv)两种或更多种上述催化剂的组合。
7 乙炔衍生物的制备方法 CN99106006.7 1999-04-07 CN1234380A 1999-11-10 园田宽; 冈田一成; 后藤谦一; 福村考纪; 成濑纯子; 林秀俊; 永田辉幸; 高桥章
公开了一种制备乙炔衍生物的方法,包括将分子式中具有式(1)所示骨架的化合物与式(2)所示化合物反应,或与式(3)表示的化合物反应:其中R1、R2、R3、R4和X1如说明书中所述。
8 CATALYTIC HYDROLYSIS AND DEHYDRATION OF SACCHARIDES US15568672 2016-04-22 US20180155305A1 2018-06-07 Xianghong QIAN; Ranil WICKRAMASINGHE
In one aspect, methods of HMF production are described herein. A method of HMF production, in some embodiments, comprises providing a saccharide feedstock including glucose and bringing the saccharide feedstock into contact with a solid state catalytic structure at a temperature sufficient to effectuate dehydration of the glucose to provide HMF. The solid state catalytic structure comprises a substrate having one or more surfaces functionalized with saccharide solubilization functionalities and acid functionalities, wherein the saccharide solubilization functionalities comprise one or more imidazolium salts pendant along chains of a first polymeric species attached to the substrate surface.
9 Production of aromatics from di- and polyoxygenates US14210925 2014-03-14 US09440892B2 2016-09-13 Taylor Beck; Brian Blank; Casey Jones; Elizabeth Woods; Randy Cortright
Methods, catalysts, and reactor systems for producing in high yield aromatic chemicals and liquid fuels from a mixture of oxygenates comprising di- and polyoxygenates are disclosed. Also disclosed are methods, catalysts, and reactor systems for producing aromatic chemicals and liquid fuels from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like; and methods, catalysts, and reactor systems for producing the mixture of oxygenates from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like. The disclosed catalysts for preparing the mixture of oxygenates comprise a Group VIII metal and a crystalline alumina support.
10 METHOD FOR HYDRODEHALOGENATION OF ORGANIC HALOGEN COMPOUND US12089211 2006-10-05 US20100130768A1 2010-05-27 Koji Sato; Makoto Imai
The present invention relates to a hydrodehalogenation method in which a halogen atom on a carbon atom of an organic compound is removed by substituting the halogen atom with a hydrogen atom, and to a method for producing a dehalogenated compound. The hydrodehalogenation method is characterized by including treating an organic compound having a halogen atom on a carbon atom thereof in a solvent with a compound represented by formula (2-1): M2BHpR1q  (2-1) or formula (2-2): M3(BHpR1q)2  (2-2) (wherein M2 represents an alkali metal atom; M3 represents an alkaline earth metal atom or a zinc atom; R1 represents a hydrogen atom, a cyano group, a C2-C13 acyloxy group, or a C1-C6 alkoxy group; p is an integer of 1 to 4; q is an integer of 0 to 3; and the sum of p and q is 4) in the presence of a Group VIII metal complex represented by formula (1): M1XmLn  (1) (wherein M1 represents a Group VIII metal; X represents a halogen atom; L represents a neutral ligand; m is an integer of 1 or 2; n is an integer of 2 or 3; and the sum of m and n is 4).
11 Gas-phase dehydration reaction process US09769442 2001-01-26 US20010014760A1 2001-08-16 Hideyuki Kambe; Shukichi Ugamura; Yuuji Shimasaki; Shinji Takasaki
Here is provided a process capable of efficiently carrying out a gas-phase dehydration reaction comprising contacting a raw material gas with a solid oxide catalyst containing an alkali metal element to allow reaction to progress by inhibiting decomposition of the raw material and the objective product. This process comprises using a sintered oxide comprising an alkali metal element and silica and/or alumina as a loading material for preheating of the raw material gas and/or as a supporting material for fixation of the position of the catalyst.
12 Preparation of nitriles US30245263 1963-08-15 US3317585A 1967-05-02 CHARLES HERSCHMANN
13 Process for producing hydration products from unsaturated hydrocarbons and water US39969329 1929-10-14 US1907317A 1933-05-02 BROWN RALPH L; ODELL WILLIAM W
14 Process for producing reaction products from hydrocarbons and water US19820227 1927-06-11 US1873536A 1932-08-23 BROWN RALPH L; ODELL WILLIAM W
15 PREPARATION OF FLUORINATED OLEFINS VIA CATALYTIC DEHYDROHALOGENATION OF HALOGENATED HYDROCARBONS EP08772398 2008-07-03 EP2164824A4 2011-11-16 WANG HAIYOU; TUNG HSUEH SUNG
A process for making a fluorinated olefin having the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms, preferably carried out in the presence of a catalyst selected from the group consisting of (i) one or more metal halides, (ii) one or more halogenated metal oxides, (iii) one or more zero-valent metals/metal alloys, (iv) a combination of two or more of the foregoing.
16 METHOD FOR DECOMPOSING WATER-SOLUBLE FLUORINE-CONTAINING ORGANIC COMPOUND EP09717332 2009-02-18 EP2248791A4 2011-05-18 NOMURA JUMPEI; MATSUOKA YASUHIKO
17 VERFAHREN ZUR HERSTELLUNG VON SUBSTITUIERTEN TRIFLUORETHYLENEN EP03740131.2 2003-05-08 EP1506150A1 2005-02-16 WOLFRUM, Peter; MARHOLD, Albrecht
The invention relates to a method for the production of substituted trifluoroethylenes, wherein a compound of formula (II), wherein R represents optionally carboxy, halogen, C1-C6-alkoxy, C1-C6-alkoxycarbonyl or C1-C4-alkylcarbonyloxy substituted C1-C6-Alkyl, or a group (III) wherein R' and R'', independently from each other, represent hydrogen or C1-C6-alkyl, or both, together with the nitrogen atom to which they are bonded, jointly represent cycloalkyl with 3-5 carbon atoms, wherein optionally one ring member is replaced with oxygen or sulphur and which is optionally substituted one to four times by C1-C4-alkyl, trifluoromethyl or C1-C4-alkoxy, and Hal represents chlorine, bromium or iodine, preferably chlorine or bromide, are brought into contact in a polar medium, containing water, with a dehalogenating agent.
18 Preparation of aryl-substituted olefins EP92116848.0 1992-10-01 EP0535682A1 1993-04-07 Laurenzo, Kathleen Susan; Stahly, Glenn Patrick; Orihuela, Felix Manuel

A process for dehydrohalogenation of aryl-substituted aliphatic halohydrocarbons is disclosed. The process employs a catalytically effective amount of palladium(0) and a phosphorus-containing ligand. An inorganic or organic base is also required to effect this reaction.

19 Method of manufacturing hydrogen or deuterium, and hydrogenation or deuteration of organic compound using the method JP2013124465 2013-06-13 JP2013176773A 2013-09-09 SAJIKI HIRONAO; KADOGUCHI HIROYA; SAWAMA YOSHINARI; KONDO SHINICHI
PROBLEM TO BE SOLVED: To provide a method of obtaining hydrogen or deuterium easily without requiring a large-scale device, and provide a method which can easily carry out hydrogenation or deuteration reaction without utilizing an expensive reactive reagent or a special catalyst.SOLUTION: A method of manufacturing hydrogen or deuterium is characterized by mechanochemically reacting water or heavy water in the presence of catalytic metal. A method of manufacturing a hydrogenated or deuterated organic compound is characterized by mechanochemically reacting an organic compound and the water or heavy water in the presence of the catalytic metal.
20 有機ハロゲン化合物のヒドロ脱ハロゲン化方法 JP2007538796 2006-10-05 JPWO2007040259A1 2009-04-16 佐藤 耕司; 耕司 佐藤; 今井 誠; 誠 今井
本発明は、有機化合物の炭素原子上のハロゲン原子を、素原子で置換して脱離させるヒドロ脱ハロゲン化方法、及び脱ハロゲン化化合物の製造方法に関する。炭素原子上にハロゲン原子を有する有機化合物を溶媒中、下記式(1)M1XmLn(1)(式中、M1は第VIII族金属を示し、Xはハロゲン原子を示し、Lは中性配位子を示し、mは1〜2の整数を示し、nは2〜3の整数を示し、かつ、mとnとの和は4である。)で表される第VIII族金属錯体の存在下に、式(2−1)M2BHpR1q(2−1)または式(2−2)M3(BHpR1q)2(2−2)(式中、M2はアルカリ金属原子を示し、M3はアルカリ土類金属原子または亜鉛原子を示し、R1は水素原子、シアノ基、炭素数2〜13のアシルオキシ基または炭素数1〜6のアルコキシ基を示し、pは1〜4の整数を示し、qは0〜3の整数を示し、かつ、pとqとの和は4である。)で表される化合物で処理することを特徴とするヒドロ脱ハロゲン化方法。
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