| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 161 | SYNTHESIS OF HIGH CALORIC FUELS AND CHEMICALS | US13943661 | 2013-07-16 | US20150025266A1 | 2015-01-22 | John Henri; Jan Zygmunt; Mark Berggren; Robert Zubrin |
| In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. | ||||||
| 162 | METHOD FOR PRODUCING HYDROGEN OR HEAVY HYDROGENS, METHOD FOR PRODUCING HYDROGENATED (PROTIATED, DEUTERATED OR TRITIATED) ORGANIC COMPOUND, METHOD FOR HYDROGENATING (PROTIATING, DEUTERATING OR TRITIATING) ORGANIC COMPOUND, METHOD FOR DEHALOGENATING ORGANIC COMPOUND HAVING HALOGEN, AND BALL FOR USE IN MECHANOCHEMICAL REACTION | US14378877 | 2013-02-08 | US20150025264A1 | 2015-01-22 | Hironao Sajiki; Yasunari Monguchi; Yoshinari Sawama; Shinichi Kondo; Yasushi Sasai |
| Objects are to provide efficient methods for producing hydrogen or heavy hydrogens and for hydrogenating (protiating, deuterating or tritiating) an organic compound, and to provide an equipment and the like used therefor. A method for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, in which an energy density of a rotational acceleration of 75 G or more is applied to water or heavy water for 25 minutes or more, a method for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, a method for hydrogenating (protiating, deuterating or tritiating) an organic compound, a method for dehalogenating an organic compound having halogen, and a ball for mechanochemical reaction are provided. | ||||||
| 163 | PROCESS FOR PRODUCING HYDROGEN OR HEAVY HYDROGENS, AND HYDROGENATION (PROTIATION, DEUTERATION OR TRITIATION) OF ORGANIC COMPOUNDS USING SAME | US14459673 | 2014-08-14 | US20140363369A1 | 2014-12-11 | Hironao SAJIKI; Yasunari MONGUCHI; Yoshinari SAWAMA; Shinichi KONDO |
| An object is to provide a process for providing hydrogen or heavy hydrogens conveniently without the necessity of large-scale equipment and a process capable of performing hydrogenation (protiation, deuteration or tritiation) reaction conveniently without the use of an expensive reagent and a special catalyst. The production process includes a process for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, and a process for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, containing subjecting an organic compound and water or heavy water to mechanochemical reaction in the presence of a catalyst metal. | ||||||
| 164 | TRANSITION METAL CATALYSTS FOR C-O HYDROGENOLYSIS AND HYDRODEOXYGENATION | US13725595 | 2012-12-21 | US20140179954A1 | 2014-06-26 | Jeffrey Camacho Bunquin; Jeffrey Mark Stryker |
| Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation. | ||||||
| 165 | CATALYSTS AND PROCESSES FOR THE HYDROGENATION OF AMIDES | US14234344 | 2012-07-18 | US20140163225A1 | 2014-06-12 | Steven Bergens; Jeremy M. John |
| There is provided a process for the reduction of one or more amide moieties in a compound comprising contacting the compound with hydrogen gas and a transition metal catalyst in the presence or absence of a base under conditions for the reduction an amide bond. The presently described processes can be performed at low catalyst loading using relatively mild temperature and pressures, and optionally, in the presence or absence of a base or high catalyst loadings using low temperatures and pressures and high loadings of base to effect dynamic kinetic resolution of achiral amides. | ||||||
| 166 | REDUCTION OF C-0 BONDS BY CATALYTIC TRANSFER HYDROGENOLYSIS | US14003971 | 2012-03-08 | US20130345445A1 | 2013-12-26 | Joseph Samec; Anna Lundstedt; Supaporn Sawadjoon |
| The present invention relates to a method of reducing a C—O bond to the corresponding C—H bond in a substrate which could be a benzylic alcohol, allylic alcohol, ester, or ether or an ether bond beta to a hydroxyl group or alpha to a carbonyl group. | ||||||
| 167 | Production method of halogen-substituted phthalide | US13265699 | 2010-05-19 | US08604221B2 | 2013-12-10 | Koji Hagiya; Yasutaka Aoyagi |
| Disclosed is a method for producing a halogen-substituted phthalide, which includes a reaction step of reacting a halogen-substituted phthalic anhydride with sodium borohydride. | ||||||
| 168 | Alcohol production method by reducing ester or lactone with hydrogen | US13611381 | 2012-09-12 | US08524953B2 | 2013-09-03 | Wataru Kuriyama; Yasunori Ino; Osamu Ogata |
| Provided is an alcohol production method comprising the step of reducing an ester or a lactone with hydrogen to produce a corresponding alcohol without addition of a base compound by using, as a catalyst, a ruthenium complex represented by the following general formula (1): RuH(X)(L1)(L2)n (1) wherein X represents a monovalent anionic ligand, L1 represents a tetradentate ligand having at least one coordinating phosphino group and at least one coordinating amino group or a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group, and L2 represents a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group, provided that n is 0 when L1 is the tetradentate ligand, and n is 1 when L1 is the bidentate aminophosphine ligand. | ||||||
| 169 | CONTINUOUS PROCESS FOR CONVERSION OF LIGNIN TO USEFUL COMPOUNDS | US13775242 | 2013-02-24 | US20130224816A1 | 2013-08-29 | Guliz Arf Elliott; Dan Gastaldo; Aaron Murray; Steven Ryba |
| This specification discloses an operational continuous process to convert lignin as found in ligno-cellulosic biomass before or after converting at least some of the carbohydrates. The continuous process has been demonstrated to create a slurry comprised of lignin, raise the slurry comprised of lignin to ultra-high pressure, deoxygenate the lignin in a lignin conversion reactor over a catalyst which is not a fixed bed without producing char. The conversion products of the carbohydrates or lignin can be further processed into polyester intermediates for use in polyester preforms and bottles. | ||||||
| 170 | PROCESS FOR PRODUCING HYDROGEN OR HEAVY HYDROGENS, AND HYDROGENATION (PROTIATION, DEUTERATION OR TRITIATION) OF ORGANIC COMPOUNDS USING SAME | US13817637 | 2011-08-16 | US20130150623A1 | 2013-06-13 | Hironao Sajiki; Yasunari Monguchi; Yoshinari Sawama; Shinichi Kondo |
| An object is to provide a process for providing hydrogen or heavy hydrogens conveniently without the necessity of large-scale equipment and a process capable of performing hydrogenation (protiation, deuteration or tritiation) reaction conveniently without the use of an expensive reagent and a special catalyst. The production process includes a process for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, and a process for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, containing subjecting an organic compound and water or heavy water to mechanochemical reaction in the presence of a catalyst metal. | ||||||
| 171 | Alcohol production method by reducing ester of lactone with hydrogen | US12553544 | 2009-09-03 | US08288575B2 | 2012-10-16 | Wataru Kuriyama; Yasunori Ino; Osamu Ogata |
| Provided is an alcohol production method comprising the step of reducing an ester or a lactone with hydrogen to produce a corresponding alcohol without addition of a base compound by using, as a catalyst, a ruthenium complex represented by the following general formula (1): RuH(X)(L1)(L2)n (1) wherein X represents a monovalent anionic ligand, L1 represents a tetradentate ligand having at least one coordinating phosphino group and at least one coordinating amino group or a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group, and L2 represents a bidentate aminophosphine ligand having one coordinating phosphino group and one coordinating amino group, provided that n is 0 when L1 is the tetradentate ligand, and n is 1 when L1 is the bidentate aminophosphine ligand. | ||||||
| 172 | REDUCTION OF ORGANIC COMPOUNDS WITH LOW AMOUNTS OF HYDROGEN | US13501253 | 2010-11-26 | US20120232266A1 | 2012-09-13 | Martin Decristoforo |
| The present invention relates to a process for the reaction of a compound with hydrogen wherein the reaction is conducted using a hydrogen-containing gas comprising up to about 10 vol. % hydrogen and at least about 90 vol. % of an inert gas and wherein the compound to be reacted with hydrogen is provided in a liquid phase. The process of the present invention is particularly suitable for hydrogenation and hydrogenolysis reactions. | ||||||
| 173 | PRODUCTION METHOD OF HALOGEN-SUBSTITUTED PHTHALIDE | US13265699 | 2010-05-19 | US20120142946A1 | 2012-06-07 | Koji Hagiya; Yasutaka Aoyagi |
| Disclosed is a method for producing a halogen-substituted phthalide, which includes a reaction step of reacting a halogen-substituted phthalic anhydride with sodium borohydride. | ||||||
| 174 | SYNTHETIC METHODS AND COMPOSITIONS | US12823937 | 2010-06-25 | US20100331566A1 | 2010-12-30 | Leslie S. Jimenez; Ahalya Ramanathan |
| The invention provides synthetic methods that utilize bromo or chloro substituents as blocking groups during the functionalization of aromatic rings, as well as compounds that are prepared from such methods. | ||||||
| 175 | PROCESS FOR THE PREPARATION OF ALDEHYDES | US12666576 | 2008-06-30 | US20100174119A1 | 2010-07-08 | Laurent Ducry; Dominique Roberge; Meinrad Mathier; Michael Gottsponer |
| The present invention is related to a method for the production of an aldehyde by reducing an ester of a carboxylic acid with H-DIBAL (diisobutylaluminium hydride). | ||||||
| 176 | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions | US10856014 | 2004-05-28 | US07169953B2 | 2007-01-30 | Xumu Zhang; Wenjun Tang |
| Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described. | ||||||
| 177 | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions | US11031159 | 2005-01-07 | US07153809B2 | 2006-12-26 | Xumu Zhang; Wenjun Tang |
| Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described. | ||||||
| 178 | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions | US10291232 | 2002-11-08 | US07105702B2 | 2006-09-12 | Xumu Zhang; Wenjun Tang |
| Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described. | ||||||
| 179 | Method for the liquid-phase hydrogenation of organic materials | US10121728 | 2002-04-15 | US06653509B2 | 2003-11-25 | Robert Schlögl; Michael Wohlers; Thilo Belz; Thomas Braun |
| A catalyst which consists of amorphous carbon with molecular planes that have curved surfaces and contain six-membered and non-six-membered carbon rings, optionally having at least one catalytically active, low-valency metal covalently bound thereto. Methods of producing the catalyst and applications thereof are included. | ||||||
| 180 | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions | US10291232 | 2002-11-08 | US20030144137A1 | 2003-07-31 | Xumu Zhang; Wenjun Tang |
| Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and nullmnullnnull cycloaddition. Processes for the preparation of the ligands are also described. | ||||||
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