| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 具有硅烷添加剂的可自由基聚合的加固灰浆 | CN201080057798.3 | 2010-11-16 | CN102947243A | 2013-02-27 | J.格吕恩; M.福格尔; C.施密特; C.施伦克; C.魏内尔特 |
| 用于将锚定装置嵌入到孔或缝隙中的灰浆中、基于自由基固化的不饱和反应性树脂的双组分或多组分加固灰浆，该加固灰浆包括硅烷和与硅烷在空间上隔离的固化剂，所述硅烷可以具有或不具有能参与和基于自由基固化的不饱和反应性树脂的合成树脂聚合的反应性基团，且在任何情形下具有Si键接的可水解基团。 | ||||||
| 2 | 丙烯酸类树脂组合物,丙烯酸类预混体,丙烯酸人工大理石的制造方法和增稠剂 | CN97193882.2 | 1997-04-09 | CN1119378C | 2003-08-27 | 池上幸弘; 小柳精也; 岸本祐一郎; 中原祯仁 |
| 公开一种丙烯酸类树脂组合物，它是将一种非交联聚合物粉末(其堆积密度在0.1-0.7g/ml范围内、基于亚麻子油的油吸收范围是60-200ml/100g并且有16倍或以上甲基丙烯酸甲酯溶涨度)作为增稠剂加入到丙烯酸浆料中得到的；用这种组合物和一种无机填料混和而得到的一种丙烯酸类预混体；将结构成分通过捏合挤出机(9)连续形成混和物而得到的一种丙烯酸类预混体；和丙烯酸人工大理石的制备方法，其中将这些丙烯酸类预混体进行固化。丙烯酸类树脂组合物与这种增稠剂混和可在短时间固化，适合高温模塑，并可改良人工大理石和预混体的产率。 | ||||||
| 3 | 人造石壁板 | CN03816818.9 | 2003-07-15 | CN1668548A | 2005-09-14 | 酒井三枝子; 斋藤研一郎 |
| 新型人造石壁板及其制造方法，其中人造石将大小为9.5mm～180μm范围的无机质细粒成分和大小不足180μm的无机质微粒成分以及全体量的7～30重量％范围的树脂成分配合，具有上述无机质细粒成分：无机质微粒成分的重量比为1∶1～5∶1的范围的组成；其在人造石的背面侧和端面侧的至少一侧埋设其一部分露出的壁面安装用的支持体，用人造石实现了对比明显、具有自然感、外观性优异的外壁材料，并且使用于安装到外壁面的准备和施工变得简便，通过将人造石和用于安装到其外壁面的部件一体成型，提供在生产性、施工性以及成本方面有利的新型的人造石壁板。 | ||||||
| 4 | (甲基)丙烯酸系预混料、(甲基)丙烯酸系SMC或BMC,和生产(甲基)丙烯酸系人造大理石的方法 | CN98805471.X | 1998-04-13 | CN1257527A | 2000-06-21 | 小柳精也; 米仓克实; 佐伯慎二; 林健太郎; 岩本祐一郎 |
| 提供了一种(甲基)丙烯酸系预混料,包括(甲基)丙烯酸系树脂组合物(A)、无机填料(B)和固化剂(C),所述组合物(A)含(甲基)丙烯酸系单体(a)和(甲基)丙烯酸系聚合物(b),其中组分(a)包括至少一种选自含具有双环、氟原子、环醚、环己烷环或三环的酯基的(甲基)丙烯酸酯,组分(c)是具有半衰期在温度75℃或更高时为10小时的自由基聚合引发剂;包括这种(甲基)丙烯酸系预混料和增稠剂的(甲基)丙烯酸系SMC或BMC,和生产(甲基)丙烯酸系人造大理石的方法,其中该甲基丙烯酸系SMC或BMC通过在温度105至150℃下加压加热固化。这些可用于制备具有各种优良物理性能如外观、尺寸稳定性、耐热水性和耐气候性的人造大理石。 | ||||||
| 5 | 合成树脂粉末 | CN96113379.1 | 1996-09-25 | CN1150592A | 1997-05-28 | 仲前昌人; 佐藤寿昭 |
| 公开了一种合成树脂粉末，它含有由乙烯属不饱和单体或二烯烃单体制得的聚合物和通过其末端的硫化物键化学键联到所述聚合物的颗粒表面的聚乙烯醇。虽然本发明的合成树脂粉末在运输过程中可为粉末形式，但它在搅拌下通过将水加入其中很容易分散在水中，因为它在水中有极好的分散性和防粘连性。该合成树脂还有极好的成膜性，因此可优选用作砂浆混合物等。 | ||||||
| 6 | 具有硅烷添加剂的可自由基聚合的加固灰浆 | CN201080057798.3 | 2010-11-16 | CN102947243B | 2017-09-05 | J.格吕恩; M.福格尔; C.施密特; C.施伦克; C.魏内尔特 |
| 用于将锚定装置嵌入到孔或缝隙中的灰浆中、基于自由基固化的不饱和反应性树脂的双组分或多组分加固灰浆，该加固灰浆包括硅烷和与硅烷在空间上隔离的固化剂，所述硅烷可以具有或不具有能参与和基于自由基固化的不饱和反应性树脂的合成树脂聚合的反应性基团，且在任何情形下具有Si键接的可水解基团。 | ||||||
| 7 | 可通过前端聚合固化的反应树脂灰浆和固定锚杆的方法 | CN201480051433.8 | 2014-09-19 | CN105579416A | 2016-05-11 | T·布尔格; A·普费尔 |
| 描述了一种可通过前端聚合固化的反应树脂灰浆，其包括至少一种可自由基聚合的化合物(a)、至少一种硫醇官能化的化合物(b)和至少一种聚合引发剂(c)，其中所述至少一种可自由基聚合的化合物(a)与所述至少一种硫醇官能化的化合物(b)的重量比在10:1至2:1的范围内，并且其中所述聚合引发剂(c)选自在高于30℃下可热活化和/或可热释放的化合物，和/或在原位由至少一种有机取代的铵盐和至少一种无机过硫酸盐形成的过硫酸铵，以及一种使用所述反应树脂灰浆在不同基底的钻孔中固定锚杆、钢筋或类似物的方法。 | ||||||
| 8 | 合成树脂粉末 | CN96113379.1 | 1996-09-25 | CN1125838C | 2003-10-29 | 仲前昌人; 佐藤寿昭 |
| 公开了一种合成树脂粉末，它含有由乙烯属不饱和单体或二烯烃单体制得的聚合物和通过其末端的硫化物键化学键联到所述聚合物的颗粒表面的聚乙烯醇。虽然本发明的合成树脂粉末在运输过程中可为粉末形式，但它在搅拌下通过将水加入其中很容易分散在水中，因为它在水中有极好的分散性和防粘连性。该合成树脂还有极好的成膜性，因此可优选用作砂浆混合物等。 | ||||||
| 9 | 丙烯酸类树脂组合物,丙烯酸类预混体,丙烯酸人工大理石的制造方法和增稠剂 | CN97193882.2 | 1997-04-09 | CN1216561A | 1999-05-12 | 池上幸弘; 小柳精也; 岸本祐一郎; 中原祯仁 |
| 公开一种丙烯酸类树脂组合物,它是将一种非交联聚合物粉末(其堆积密度在0.1－0.7g/ml范围内、基于亚麻子油的油吸收范围是60－200ml/100g并且有16倍或以上甲基丙烯酸甲酯溶涨度)作为增稠剂加入到丙烯酸浆料中得到的;用这种组合物和一种无机填料混和而得到的一种丙烯酸类预混体;将结构成分通过捏合挤出机(9)连续形成混和物而得到的一种丙烯酸类预混体;和丙烯酸人工大理石的制备方法,其中将这些丙烯酸类预混体进行固化。丙烯酸类树脂组合物与这种增稠剂混和可在短时间固化,适合高温模塑,并可改良人工大理石和预混体的产率。 | ||||||
| 10 | Macro defect free cement with improved moisture resistance | US15347856 | 2016-11-10 | US09850164B2 | 2017-12-26 | Aaron K. Amstutz |
| A cementitious composition may include polyvinyl alcohol, high alumina cement, water, a metallic coagent, a peroxide crosslinking initiator, and an organic acid retardant. A molded article may be manufactured from the cementitious composition by preparing a hydrogel pre-polymer blend of saponified polyvinyl alcohol acetate (PVAA) with greater than or equal to approximately 85% saponified PVAA, and water, mixing the hydrogel pre-polymer blend with high alumina cement (HAC) using a high shear mixing process, mixing in a metallic coagent and a peroxide crosslinking initiator, mixing in an organic acid retardant, and hot press molding the mixture. | ||||||
| 11 | Macro defect free cement with improved moisture resistance | US14610469 | 2015-01-30 | US09593043B2 | 2017-03-14 | Aaron K. Amstutz |
| A cementitious composition may include polyvinyl alcohol, high alumina cement, water, a metallic coagent, a peroxide crosslinking initiator, and an organic acid retardant. A molded article may be manufactured from the cementitious composition by preparing a hydrogel pre-polymer blend of saponified polyvinyl alcohol acetate (PVAA) with greater than or equal to approximately 85% saponified PVAA, and water, mixing the hydrogel pre-polymer blend with high alumina cement (HAC) using a high shear mixing process, mixing in a metallic coagent and a peroxide crosslinking initiator, mixing in an organic acid retardant, and hot press molding the mixture. | ||||||
| 12 | Free-radical-polymerisable fixing mortar having silane additives | US13515636 | 2010-11-16 | US08828289B2 | 2014-09-09 | Jurgen Grun; Martin Vogel; Clemens Schmidt; Christian Schlenk; Christian Weinelt |
| Two-component or multi-component fixing mortar, based on a free-radical-hardening unsaturated reactive resin, for embedding anchoring means in mortar in holes or crevices, which fixing mortar includes silanes which may or may not have reactive groups capable of participating in the polymerization with a synthetic resin based on free-radical-hardening unsaturated reactive resins but do in any case have Si-bonded hydrolysable groups, and, physically separate therefrom, a hardener. | ||||||
| 13 | Artificial stone wall panel | US10521190 | 2003-07-15 | US07371441B2 | 2008-05-13 | Mieko Sakai; Kenichiro Saito |
| An artificial stone wall panel comprises: an artificial stone, composition of which comprises an inorganic fine powder component with a size of from 9.5 mm to 180 μm, an inorganic finely divided component with a size of less than 180 μm, and a resin component in an amount of from 7 to 30% by weight based on a total artificial stone composition, with a weight ratio of the inorganic fine powder component to the inorganic finely divided component (inorganic fine powder component:inorganic finely divided component) being in a range of from 1:1 to 5:1; and a support for installing the artificial stone onto a wall surface, embedded in the artificial stone, wherein part of the support is exposed at a back surface or edge surface of the artificial stone. This artificial stone wall panel is realized by mold-integrating an artificial stone and structure for installing such artificial stone to an external wall surface, and may be used as an external wall material with excellent design having clear contrast and natural texture. | ||||||
| 14 | Flyash coating | US10454771 | 2003-06-04 | US20040247913A1 | 2004-12-09 | James Stewart |
| The present invention includes a coating. The coating includes flyash in a concentration of 25 to 70 percent by weight; Portland cement; silica; and a curing agent. The coating optionally includes one or more of chopped nylon fiber; styrene; and, rubber. | ||||||
| 15 | Method for making polymer surfaced composites | US10097845 | 2002-03-15 | US06709717B2 | 2004-03-23 | John N. Mushovic |
| To produce a composite building unit having a polymer-cladded surface, a polymerizable resin binder and a blend of filler particles are combined to provide a resin binder/filler mixture which is deposited in a mold. A concrete substrate is then positioned in the mold with a face surface contacting a transition layer comprising a lightly filled resin binder/filler layer portion of the deposited mixture overlying a highly filled resin binder/filler layer portion of the deposited mixture. The resin binder in the transition layer migrates into pockets and pores in the substrate face surface to create mechanical locks when the resin binder is cured. These locks, in addition to chemical bonding, serve to permanently affix the cured resin binder as a surface cladding to the substrate. Initiators may be added to the resin binder to promote thermal and/or UV radiation cures thereof. | ||||||
| 16 | Reaction Resin Mortar Curable by Frontal Polymerization and Method for Fixing Anchor Rods | US15023317 | 2014-09-19 | US20160236983A1 | 2016-08-18 | Thomas BUERGEL; Armin PFEIL |
| A reaction resin mortar curable by frontal polymerization is described, comprising at least one radically polymerizable compound (a), at least one thiol-functionalized compound (b) and at least one polymerization initiator (c), wherein the weight ratio of the at least one radically polymerizable compound (a) and the at least one thiol-functionalized compound (b) is in the range of 10:1 to 2:1 and wherein the polymerization initiator (c) is selected from compounds which can be thermally activated and/or thermally released at a temperature of above 30° C. and/or ammonium persulfates which are formed in-situ from at least one organically substituted ammonium salt and at least one inorganic persulfate as well as a method for fixing anchor rods, rebars or the like in bore holes using the reaction resin mortar. | ||||||
| 17 | MACRO DEFECT FREE CEMENT WITH IMPROVED MOISTURE RESISTANCE | US14610469 | 2015-01-30 | US20160221871A1 | 2016-08-04 | Aaron K Amstutz |
| A cementitious composition may include polyvinyl alcohol, high alumina cement, water, a metallic coagent, a peroxide crosslinking initiator, and an organic acid retardant. A molded article may be manufactured from the cementitious composition by preparing a hydrogel pre-polymer blend of saponified polyvinyl alcohol acetate (PVAA) with greater than or equal to approximately 85% saponified PVAA, and water, mixing the hydrogel pre-polymer blend with high alumina cement (HAC) using a high shear mixing process, mixing in a metallic coagent and a peroxide crosslinking initiator, mixing in an organic acid retardant, and hot press molding the mixture. | ||||||
| 18 | REINFORCEMENT FIBER COATING COMPOSITIONS, METHODS OF MAKING AND TREATING, AND USES FOR IMPROVED ADHESION TO ASPHALT AND PORTLAND CEMENT CONCRETE | US14209247 | 2014-03-13 | US20140275350A1 | 2014-09-18 | Jeffrey B. Lovett; Clifford Norman MacDonald; Daniel T. Biddle |
| The invention relates to coating compositions, treated reinforced fibers, reinforced asphalt and portland cement concrete and methods for producing the same. The coating compositions include monomer, prepolymer or mixtures thereof, and graft initiator. The monomer and/or prepolymer include at least one functional group selected from the group consisting of hydroxyl, carboxyl, amino and ester. The graft initiator includes metallic salt. | ||||||
| 19 | Flyash coating | US10454771 | 2003-06-04 | US07056583B2 | 2006-06-06 | James Stewart |
| The present invention includes a coating. The coating includes flyash in a concentration of 25 to 70 percent by weight; Portland cement; silica; and a curing agent. The coating optionally includes one or more of chopped nylon fiber; styrene; and, rubber. | ||||||
| 20 | Process for coating a concrete surface | US10120657 | 2002-04-12 | US20030194502A1 | 2003-10-16 | Gerald W. Sadleir |
| A process for covering a concrete surface with a cementitious coating. Portland cement is mixed with a polymer containing ethylene-vinyl acetate co-polymer and vinyl acetate monomer with water to form a cementitious mixture with a paint-like viscosity. This paint-like product is placed in a paint spray pressure pot and sprayed using a paint gun with a special spray tip to coat concrete and other substrate surfaces with a natural or integrally colored thin layered cement finish surface to be coated. The result is a surface that is free of stains, spots and discolorations, but with a concrete rather than a paint-like appearance. | ||||||
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