序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
81 High refractive index glass beads JP23608695 1995-08-21 JP3075507B2 2000-08-14 弘和 青島
82 Glass microspheres coated article and a method of manufacturing a smooth surface JP51748697 1996-10-28 JPH11514943A 1999-12-21 ラペレ,ジェイムズ・ディ
This invention relates to glass microsphere (bead) coated articles having an upper surface comprising a layer of low refractive index transparent glass microspheres such as those made from recycled ordinary glass. The articles of the invention have an extremely smooth tactile feel and a low friction surface even though they can be prepared from glass microspheres intermixed with abrasive irregularly shaped glass particles. The invention also relates to the method making the bead coated articles of the invention and transfer articles that can be used to make the bead coated articles of the invention.
83 Horizontal position automatic welding method JP14703694 1994-06-07 JPH07328766A 1995-12-19 OE KIYOTAKA; WATANABE SEIJI; WATANABE KAZUYOSHI; OTA KOJI; OTSUKI HARUHITO
PURPOSE:To dispense with manual control adjustment for welding conditions even in the occurrence of a shell surface difference due to field installation precision, to merely require adjustment by a welder for an aimed position at the beginning of a welding of each pass and, while the progress of welding in the entire welding line is controlled by the welder and to perform multilayer horizontal automatic welding without requiring skillfulness until most of the welding execution is complete. CONSTITUTION:In the case of horizontal position welding while a groove shape is profiled by a welding torch in a groove, the groove depth distance is calculated over an entire welding seam before welding by means of a groove depth detection sensor 3 and a base plate surface detection sensor 5. Welding is performed for a first pass by varying welding current and welding speed based on the calculated data; and individual data are stored for the profiling position of the welding torch, welding current and welding speed. For a second pass and on, welding is performed by correcting the individual data in accordance with the bead thickness that varies based on the fluctuation of the welding current and welding speed of the previous pass, and welding inside the groove is thereby performed with the same number of layers and passes over the entire welding seam.
84 Glass microball JP14992379 1979-11-19 JPS5575938A 1980-06-07 CHI FUANGU TSUNGU; JIEEMUSU AREN REIAADO
85 High refractive index glass for glass bead JP7588678 1978-06-22 JPS553352A 1980-01-11 NAKAGAWA ISAMU; IMAMURA YUKINOBU
PURPOSE: To provide the title glass contg. TiO 2, BaO, ZnO, ZrO 2, SiO 2, CaO, SrO, etc. in a specified ratio, having such a high refractive index as above 2.1 and strong reflective action, and fit for long-term use as a traffic-control sign without being blackened by SO 2 esp. in exhaust gas. CONSTITUTION: The high refractive index glass for glass heads consists of, by wt., TiO 2; 42W50%, BaO; 20W40%, ZnO; 2.5W30%, ZrO 2; 2.5W25%, SiO 2; 0.2W 1.5%, CaO≤2%, SrO≤6%, Al 2O 3≤2%, Na 2O≤1.5%, K 2O≤1.5% and Li 2O ≤1.5% and contains no B 2O 3. The addn. of a little SiO 2 stabilizes the glass structure to enable the ZrO 2 content to be raised. The heterogeneity of glass in a melt- forming process is thus improved, and glass beads of high transparency are obtd. COPYRIGHT: (C)1980,JPO&Japio
86 Production of high refractive index glass beads JP1332378 1978-02-07 JPS54106523A 1979-08-21 INADA KATSUMI
87 Transparent glass element JP9353378 1978-07-31 JPS5434314A 1979-03-13 CHI FUANGU TANGU; BENJIYAMIN TOOMASU FUEROUZU
88 JPS4975651A - JP9935873 1973-09-05 JPS4975651A 1974-07-22
A method for coating glass spheres or other discrete particles in which a silane coupling agent and an anti-caking agent are successively applied to the particles as they are continuously advanced along a feed path. After the application of the coupling agent, but prior to the introduction of the anti-caking agent, the mass of particles is agitated and its rate of movement is slowed to increase the depth of the mass. The curing of the coupling agent is initiated by the application of heat prior to the addition of the anti-caking agent, and the curing is continued during and subsequent to the agitation of the particles to provide a uniform multi-layer coating on each particle.
89 道路標示用の再帰反射材料として使用されるガラスビーズにおける天然粘土コーティングによる表面特性の改善 JP2017517049 2015-09-30 JP2018501170A 2018-01-18 アリカン ヴァタンサーバー; ツレー イナン; ハセー ドガン; ムラト コーラル; ヌラン コカー
【課題】本発明は、ガラスビーズを天然モンモリロナイトおよび有機的に改質されたモンモリロナイトでコーティングすることで、市販製品と競争可能で、使用しやすく、環境に優しい性道路標示用塗料との相溶性が高く、耐摩耗性および再帰反射性に優れたガラスビーズを提供する。【解決手段】10cm×50cmの練炭上に塗布した水性塗料上にコーティングガラスビーズを直ちに展着させる。ガラスビーズの塗料に対する比率は、33重量%とする。塗料が乾燥した後、道路をシミュレーションするために塗料上にて圧6バールのホイールを往復させる。この工程の終了時に夜間視認性を測定する。水性モンモリロナイトコーティングガラスビーズを含む塗料は、10,000サイクルの往復後も、市販のシランコーティングガラスビーズ、未コーティングガラスビーズ、改質モンモリロナイトコーティングガラスビーズを含む各種塗料よりも高い夜間視認性を示す。改質モンモリロナイトコーティングガラスビーズは、市販のシラン系ガラスビーズと同等の夜間視認性を示し、未コーティングガラスビーズよりも高い夜間視認性を示す。【選択図】図4
90 複合粒子、その製造方法、当該粒子を含有する樹脂組成物、当該組成物で形成されたリフレクター、及び該リフレクターを用いた発光半導体装置 JP2014162371 2014-08-08 JP6179483B2 2017-08-16 塩原 利夫; 堤 吉弘
91 再帰反射性に優れた高屈折率のガラスビード及びその製造方法 JP2015552577 2014-01-09 JP2016509566A 2016-03-31 リュ・ヘヨン; チョ・ソンジェ
本発明は、再帰反射性ガラスビードに関し、TiO2、BaO、La2O及びBi2O3からなる群から選択された1種以上の高屈折酸化物;及び、MgO、CaO、ZnO、ZrO2、Al2O3、K2O、Na2O、Li2O及びSrOからなる群から選択された1種以上の添加剤;を含むことを特徴とし、本発明によると、光学特性による再帰反射性に優れながらも、単純な構造によって耐久性及び生産性に優れ、化学的安定性が高くて様々な色にも製造され得るガラスビードを利用することができ、従って、本発明に係るガラスビードを含む再帰反射性集合体は、雨天や乾燥等の様々な状況でも視認性が非常に高い。また、前記ガラスビードの製造方法は、生産原価を減らすことができ、かつ生産性に顕著に優れている。【選択図】図3
92 Transparent microspheres JP2011171078 2011-08-04 JP5197810B2 2013-05-15 ディー. バド ケントン; トシヒロ カサイ; ビー. ロスコー スティーブン; チカフミ ヨコヤマ; イー. ベイリー ジョン
93 Self-cleaning coating composition JP2011541408 2009-12-16 JP2012512019A 2012-05-31 スベリール・グルイムール・グナールション; セーレン・ヒレブラント・ポールセン; ペル・モーラー
The present invention relates to compositions with self-cleaning properties. More particularly, the invention concerns coatings or paints comprising particles coated with a catalytically active composition. In particular, a self-cleaning coating composition (paint) is provided, comprising micro-sized particles coated with a functional layer, wherein the micro-sized particles are hollow or solid beads, or any combination/ratio of hollow and solid beads, wherein the beads comprise one or more material(s) selected from ceramic material(s); polymeric material(s); cermet material(s); metallic material(s); pigmented material(s); light-absorbing and/or light reflecting material(s); including any combination thereof, wherein said layer is covalently bound to said particles, wherein the photocatalytic layer comprises TiO2 in the crystal form of anatase; and wherein the coating composition (paint) comprises less than 0.1 anatase particles derived/released from the micro-sized beads, determined as weight/weight of released anatase/total amount of anatase. The invention provides paint essentially without presence of unbound anatase crystals which is highly undesired, as it is believed that their presence has a negative influence on essential components of the paint, such as binder, pigment and/or additives and furthermore, anatase may cause eye, skin, and respiratory tract irritation.
94 Glass microspheres coated article and a method of manufacturing a smooth surface JP51748697 1996-10-28 JP3905129B2 2007-04-18 ラペレ,ジェイムズ・ディ
This invention relates to glass microsphere (bead) coated articles having an upper surface comprising a layer of low refractive index transparent glass microspheres such as those made from recycled ordinary glass. The articles of the invention have an extremely smooth tactile feel and a low friction surface even though they can be prepared from glass microspheres intermixed with abrasive irregularly shaped glass particles. The invention also relates to the method making the bead coated articles of the invention and transfer articles that can be used to make the bead coated articles of the invention.
95 Multilayer film-coated powder JP14741996 1996-06-10 JP3686167B2 2005-08-24 勝人 中塚; 貴史 新子
A powder comprising a base particle which has been colored desirably and vividly and having a high light transmittance in the visible region. The powder is a multilayer-coated powder comprising a base particle having thereon a multilayered film comprising at least one thin layer comprising a metal sulfide, a metal fluoride, a metal carbonate or a metal phosphate. This multilayered film reflects or absorbs the light having a specific wavelength according to the thickness thereof, the sequence of layer superposition, etc.
96 Optical element including a polyfluoropolyether surface treatment agent JP2002567875 2001-10-24 JP2004519715A 2004-07-02 エル.エス. エルスバーンド,シェリル; シー. クリア,スザンナ; ジン,ナイヨン; ブイ. タイアーズ,ジョージ; エム. フライン,リチャード; ジェイ. ペレライト,マーク
本発明は、フルオロケミカル表面処理剤を含む光学素子に関する。 本発明はさらに、バインダーと表面処理された光学素子とを含む再帰反射シート、路面表示材およびビーズプロジェクションスクリーンのような材料に関する。 フルオロケミカル表面処理剤は、4より多い炭素原子を有するペルフルオロアルキル基を実質的に含まない。 表面処理剤が、少なくとも1つの極性基または極性基含有有機基を含むポリフルオロポリエーテルをベースとする化合物であることが好ましい。
97 Fluorochemical sulfonamide surfactant JP2001533869 2000-10-27 JP2003513123A 2003-04-08 エー. エティエンヌ,サンドラ; エム. サブ,パトリシア
Described are fluorochemical surfactants derived from nonafluorobutanesulfonyl fluoride that contain polyalkyleneoxy side chains and may be copolymerized with acrylic acid or methacrylic acid to form polyacrylates or polymethacrylates. The surfactants surprisingly lower the surface tension of water and other liquids in the same or similar low values achieved by premier surfactants such as those derived from perfluorooctane sulfonyl fluoride.
98 High refractive index glass beads JP13517794 1994-05-26 JP2988831B2 1999-12-13 HAGIWARA SATORU
99 Multilayered film-coated powder JP14741996 1996-06-10 JPH101701A 1998-01-06 SHINKO TAKASHI; NAKATSUKA KATSUTO
PROBLEM TO BE SOLVED: To obtain functional powder colored into desired ones or transparent one by forming multilayered film on substrate particles by specified substances. SOLUTION: This powder is composed in such a manner that substrate powder 1 is used as the core, and on the surface, films 2, 3 and 4 selected from metallic sulfides, metallic fluorides, metallic carbonates and metallic phosphates and whose film thicknesses are regulated to prescribed ones are successively laminated. The substrate particles can be selected from various materials in accordance with the purpose. Namely, the powder coated with the above multi- layered film has functions of which the substrate particles have and is formed into functional powder colored into desired ones or transparent one. For example, by forming the substrate particles into a magnetic body, a color magnetic toner which has been clearly colored can be obtd., furthermore, by forming the substrate into glass or the like, a spherical lens suitable for a spherical spacer for displaying liq. phases high in transparency or the like can be obtd. Moreover, by forming the substrate particles into pigment, cosmetic having a reflective function for ultraviolet rays or the like can be obtd.
100 Glass bead having high refractive index JP23608695 1995-08-21 JPH0959039A 1997-03-04 AOSHIMA HIROKAZU
PROBLEM TO BE SOLVED: To obtain a glass bead having high whiteness (transparency) and high refractive index by preventing coloring of a glass bead even when mixed with colored impurities. SOLUTION: This glass bead is composed of, by mass, 30-55% TiO2 , 20-55% BaO, 0-17% ZnO, 0-6% CaO, 1-15% (ZnO+CaO) and 2-50ppm cobalt oxide. Preferably, the based has >=1.85 refractive index.
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