序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 METHOD FOR FORMING METAL FLUORIDE MATERIAL US14221957 2014-03-21 US20140284526A1 2014-09-25 Jon Shan
The present invention is directed to processing techniques and systems of metal fluoride based material, including but not limited to nickel difluoride, copper difluoride, manganese fluoride, chromium fluoride, bismuth fluoride, iron trifluoride, iron difluoride, iron oxyfluoride, metal doped iron fluorides, e.g., FexM1-xFy (M=metals, which can be Co, Ni, Cu, Cr, Mn, Bi and Ti) materials. An exemplary implementation involves mixing a first compound comprising a metal material, nitrogen, and oxygen to a second compound comprising hydrogen fluoride. The mixed compound is milled to form metal fluoride precursor and a certain byproduct. The byproduct is removed, and the metal fluoride precursor is treated to form iron trifluoride product. There are other embodiments as well.
22 PROCESS FOR THE EXTRACTION OF SPECIFIC TRANSITION METALS US13621750 2012-09-17 US20130064742A1 2013-03-14 JOSEPH L. THOMAS
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCl to form volatile chloride-bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCl pressurized with gaseous HCl.
23 Process for the extraction of specific transition metals US12581778 2009-10-19 US08268267B2 2012-09-18 Joseph L. Thomas
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCl to form volatile chloride-bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCl pressurized with gaseous HCl.
24 PROCESS FOR THE EXTRACTION OF SPECIFIC TRANSITION METALS US12581778 2009-10-19 US20100098606A1 2010-04-22 JOSEPH L. THOMAS
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCl to form volatile chloride-bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCl pressurized with gaseous HCl.
25 Telescoped multiwall nanotube and manufacture thereof US11080010 2005-03-14 US20060057383A1 2006-03-16 John Cumings; Alex Zettl; Steven Louie; Marvin Cohen
The invention relates to a method for forming a telescoped multiwall nanotube. Such a telescoped multiwall nanotube may find use as a linear or rotational bearing in microelectromechanical systems or may find use as a constant force nanospring. In the method of the invention, a multiwall nanotube is affixed to a solid, conducting substrate at one end. The tip of the free end of the multiwall nanotube is then removed, revealing the intact end of the inner wall. A nanomanipulator is then attached to the intact end, and the intact, core segments of the multiwall nanotube are partially extracted, thereby telescoping out a segment of nanotube.
26 Method of determining the extent to which a nickel structure has been attached by a fluorine-containing gas US02618355 1945-09-24 US06761862B1 2004-07-13 James P. Brusie
The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.
27 Telescoped multiwall nanotube and manufacture thereof US09915196 2001-07-24 US20020070426A1 2002-06-13 John P. Cumings; Alex K. Zettl; Steven G. Louie; Marvin L. Cohen
The invention relates to a method for forming a telescoped multiwall nanotube. Such a telescoped multiwall nanotube may find use as a linear or rotational bearing in microelectromechanical systems or may find use as a constant force nanospring. In the method of the invention, a multiwall nanotube is affixed to a solid, conducting substrate at one end. The tip of the free end of the multiwall nanotube is then removed, revealing the intact end of the inner wall. A nanomanipulator is then attached to the intact end, and the intact, core segments of the multiwall nanotube are partially extracted, thereby telescoping out a segment of nanotube.
28 Recovery of metal values from ocean floor nodule ores by halidation in molten salt bath US30973872 1972-11-27 US3894927A 1975-07-15 KANE WILLIAM S; MCCUTCHEN HUGH L; CARDWELL PAUL H
This invention provides a process for removing metal values from ocean floor nodule ores comprising contacting the nodule ore with a molten bath of an alkali metal halide and/or an alkaline earth metal halide to form the halides of the manganese, copper, cobalt and nickel present in the ore, and separating the thus formed halides from the reaction mixture, as by vaporization. The mixture of halides can then be separated into the individual halides, e.g. by dissolving in water and separating by extraction. Preferably the ore is first dehydrated and the ore can be contacted with a reducing agent to reduce the manganese present to the divalent state.
29 PROCESS FOR THE EXTRACTION OF SPECIFIC TRANSITION METALS EP06785032.1 2006-06-16 EP1899271A2 2008-03-19 THOMAS, Joseph, L.,
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCI to form volatile chloride- bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCI pressurized with gaseous HCI.
30 EINSATZ VON AZEOTROP-GETROCKNETEN NICKEL(II)-HALOGENIDEN EP04790947.8 2004-10-28 EP1682561A1 2006-07-26 HADERLEIN, Gerd; BAUMANN, Robert; BARTSCH, Michael; JUNGKAMP, Tim; LUYKEN, Hermann; SCHEIDEL, Jens; SCHÄFER, Heinz; SIEGEL, Wolfgang
The invention relates to a method for the production of nickel(0) phosphorous ligand complexes containing at least one nickel(0) central atom and at least one ligand containing phosphorus. One nickel (II) halognenide dried by azeotropic distillation is reduced in the presence of at least one ligand containing phosphorous.
31 EXTRACTION OF METALS FROM ORES. EP84901943 1984-05-25 EP0145728A4 1985-09-25 LLOYD ROBERT; TURNER MAXWELL JAMES
Metals are extracted from ores which exist in the form of oxides or sulphides, by treating the ore with hydrogen fluoride and/or fluorosilicic acid. There are two preferred forms. When hydrogen fluoride is used, the ore is initially crushed, dried and then contacted with HF gas at temperatures above 105<o>C to produce metal fluorides. The metal fluorides are then contacted with aqueous HF solution and the resulting insoluble metal fluorides and iron oxides are separated from the solution, and metal fluorides preferably including nickel and cobalt fluorides are recovered. When fluorosilicic acid is used, the crushed and dried ore is directly contacted with an aqueous solution of fluorosilicic acid at temperatures above 70<o>C and the resulting insoluble metal fluorides and iron oxides are separated and metal fluorides preferably including nickel and cobalt fluorides are recovered. Preferred ores are cobalt-nickel lateritic ores.
32 페로브스카이트 광흡수층 제조방법 및 이를 적용한 태양전지 제조방법 KR1020160052038 2016-04-28 KR101794988B1 2017-11-08 조효정; 김세윤; 양기정; 성시준; 김대환; 강진규
본발명은금속할로겐화합물층 상에유기할로겐화합물을도포하여페로브스카이트층을형성하는단계(단계 1); 및상기단계 1에서형성된페로브스카이트층에유기할로겐화합물을접촉시키는단계(단계 2);를포함하는, 페로브스카이트광흡수층제조방법을제공한다. 본발명에따른광흡수층제조방법및 상기광흡수층제조방법이적용된태양전지제조방법은페로브스카이트내 불순물로작용하는금속할로겐화합물을반응시켜제거하여, 단락전류의값이향상되고그에따라광전환효율이향상된태양전지를제조할수 있는장점이있다.
33 공비 건조된 니켈(ⅠⅠ) 할로겐화물의 용도 KR1020067008276 2004-10-28 KR101296565B1 2013-08-13 하데르라인,게르트; 바우만,로베르트; 바르트쉬,미하엘; 융캄프,팀; 루이켄,헤르만; 샤이델,옌스; 섀퍼,하인츠; 지겔,볼프강
본 발명은 하나 이상의 니켈(0) 중심 원자 및 인을 함유하는 하나 이상의 리간드를 함유하는 니켈(0) 인 리간드 착물의 제조 방법에 관한 것이다. 공비 증류에 의해 건조된 니켈(II) 할로겐화물은 인을 함유하는 하나 이상의 리간드의 존재 하에서 환원된다. 니켈(II) 할로겐화물, 공비 건조, 니켈(0) 인 리간드 착물
34 공비 건조된 니켈(ⅠⅠ) 할로겐화물의 용도 KR1020067008276 2004-10-28 KR1020070052686A 2007-05-22 하데르라인,게르트; 바우만,로베르트; 바르트쉬,미하엘; 융캄프,팀; 루이켄,헤르만; 샤이델,옌스; 섀퍼,하인츠; 지겔,볼프강
본 발명은 하나 이상의 니켈(0) 중심 원자 및 인을 함유하는 하나 이상의 리간드를 함유하는 니켈(0) 인 리간드 착물의 제조 방법에 관한 것이다. 공비 증류에 의해 건조된 니켈(II) 할로겐화물은 인을 함유하는 하나 이상의 리간드의 존재 하에서 환원된다. 니켈(II) 할로겐화물, 공비 건조, 니켈(0) 인 리간드 착물
35 PROCESS FOR THE EXTRACTION OF SPECIFIC TRANSITION METALS PCT/US2006023589 2006-06-16 WO2007001921A3 2009-08-20 THOMAS JOSEPH L
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCI to form volatile chloride- bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCI pressurized with gaseous HCI.
36 TELESCOPED MULTIWALL NANOTUBE AND MANUFACTURE THEREOF PCT/US0123354 2001-07-24 WO0208120A3 2002-05-02 CUMINGS JOHN P; ZETTL ALEX K; LOUIE STEVEN G; COHEN MARVIN L
The invention relates to a method for forming a telescoped multiwall nanotube. Such a telescoped multiwall nanotube may find use as a linear or rotational bearing in microelectromechanical systems or may find use as a constant force nanospring. In the method of the invention, a multiwall nanotube is affixed to a solid, conducting substrate at one end. The tip of the free end of the multiwall nanotube is then removed, revealing the intact end of the inner wall. A nanomanipulator is then attached to the intact end, and the intact, core segments of the multiwall nanotube are partially extracted, thereby telescoping out a segment of nanotube.
37 PROCESS FOR THE EXTRACTION OF SPECIFIC TRANSITION METALS PCT/US2006023589 2006-06-16 WO2007001921A4 2009-11-05 THOMAS JOSEPH L
A process is disclosed for separation and recovery of vanadium, molybdenum, iron, tungsten, cobalt and nickel from alumina-based materials, mattes, ores, manufacturing by-products and waste. These elements are oxidized. The oxides are reacted with gaseous HCI to form volatile chloride- bearing compounds that subsequently sublimate. The volatile compounds are condensed in a downward-stepped thermal gradient that allows collection of moderate to high purity compounds of individual elements with exception of a nickel-cobalt co-condensate. Nickel is separated from cobalt by precipitation of nickel chloride from concentrated HCI pressurized with gaseous HCI.
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