序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 MULTI-LAYER STRUCTURED LITHIUM METAL ELECTRODE AND METHOD FOR MANUFACTURING SAME US15507641 2015-10-21 US20170309899A1 2017-10-26 Byoung Kuk SON; Min Chul JANG; Eun Kyung PARK; Doo Kyung YANG; Jung Hun CHOI
The present invention relates to a multi-layer structured lithium metal electrode and a method for manufacturing the same and, specifically, to a multi-layer structured lithium metal electrode comprising: a buffer layer of lithium nitride (Li3N) formed on a lithium metal plate; and a protective layer of LiBON formed on the buffer layer, and to a method for manufacturing a multi-layer structured lithium metal electrode by continuously forming a lithium nitride buffer layer and a LiBON protective layer on a lithium metal plate through continuous reactive sputtering multi-layer structured lithium metal electrode multi-layer structured lithium metal electrode lithium metal plate multi-layer structured lithium metal electrode lithium metal plate. The multi-layer structured lithium metal electrode of the present invention can protect the reactivity of the lithium metal from moisture or an environment within a battery, and prevent the formation of dendrites, by forming the protective layer.
102 PRECURSOR OF TRANSITION METAL OXIDE, PREPARATION METHOD THEREOF, LITHIUM COMPOSITE TRANSITION METAL OXIDE, AND POSITIVE ELECTRODE AND SECONDARY BATTERY INCLUDING THE SAME US15516803 2015-11-02 US20170301916A1 2017-10-19 Ho-Suk Shin; Byung-Chun Park; Sang-Min Park; Joo-Hong Jin
Provided herein is a precursor of a transition metal oxide, including a core unit and a shell unit, wherein the core unit includes a compound of chemical formula 1 below, and the shell unit includes a compound of chemical formula 2 below. NiaMnbCo1−(a+b+c)Mc[OH(1−x)2−y]A(y/n)   [Chemical formula 1] Nia′Mnb′Co1−(a′+b′+c′)M′c′[OH(1−x′)2−y′]A(y′/n)   [Chemical formula 2]
103 ALKALI METAL SALT OF FLUOROSULFONYL IMIDE, AND PRODUCTION METHOD THEREFOR US15409708 2017-01-19 US20170133715A1 2017-05-11 Yuichi SATO; Shimpei SATO; Yasunori OKUMURA
The present invention provides an alkali metal salt of fluorosulfonyl imide having favorable heat resistance and a reduced content of specific impurities and a water content, and provides a method for producing an alkali metal salt of fluorosulfonyl imide, which is capable of easily removing a solvent from a reaction solution. An alkali metal salt of fluorosulfonyl imide of the present invention is represented by the following general formula (I) and has a mass loss rate of 2% or less when the alkali metal salt of fuluorosulufonyl imide is kept at 100° C. for 8 hours under an air current. A method for producing an alkali metal salt of fluorosulfonyl imide of the present invention comprises a step of concentrating a solution of the alkali metal salt of fulorosulfonyl imide by bubbling a gas into a reaction solution containing the alkali metal salt of fulorosulfonyl imide, and/or concentrating a solution of the alkali metal salt of fulorosulfonyl imide by thin layer distillation.
104 Alkali metal salt of fluorosulfonyl imide, and production method therefor US14560315 2014-12-04 US09586833B2 2017-03-07 Yuichi Sato; Shimpei Sato; Yasunori Okumura
The present invention provides an alkali metal salt of fluorosulfonyl imide having favorable heat resistance and a reduced content of specific impurities and a water content, and provides a method for producing an alkali metal salt of fluorosulfonyl imide, which is capable of easily removing a solvent from a reaction solution. An alkali metal salt of fluorosulfonyl imide of the present invention is represented by the following general formula (I) and has a mass loss rate of 2% or less when the alkali metal salt of fluorosulfonyl imide is kept at 100° C. for 8 hours under an air current. A method for producing an alkali metal salt of fluorosulfonyl imide of the present invention comprises a step of concentrating a solution of the alkali metal salt of fluorosulfonyl imide by bubbling a gas into a reaction solution containing the alkali metal salt of fluorosulfonyl imide, and/or concentrating a solution of the alkali metal salt of fluorosulfonyl imide by thin layer distillation.
105 SOLID ELECTROLYTE MATERIAL AND ALL SOLID LITHIUM BATTERY US15202627 2016-07-06 US20170040636A1 2017-02-09 Erika OKI; Naoki OSADA
A main object of the present invention is to provide a solid electrolyte material with high Li ion conductivity and heat stability. To achieve the above object, the present invention provides a solid electrolyte material comprising a composition of Li3PS4-xOx (1≦x≦3), a crystal phase A having a peak at a position of 2θ=17.80°±0.50°, 25.80°±0.50° in X-ray diffraction measurement using a CuKα ray, and a crystal phase B having a peak at a position of 2θ=22.30°±0.50°, 23.14°±0.50°, 24.80°±0.50°, 33.88°±0.50°, 36.48°±0.50° in X-ray diffraction measurement using a CuKα ray.
106 METHOD FOR PRODUCING PARTICLES US15205070 2016-07-08 US20170008808A1 2017-01-12 Takuo Yanagi
A method for efficiently producing fine particles in a complex state from a plurality of raw material components is provided. The method includes spraying a good solvent solution made from a good solvent and the plurality of raw material components dissolved in the good solvent into a poor solvent having a temperature of at least 165° C. higher than the boiling point of the good solvent and evaporating off the good solvent and precipitating a plurality of fine particles.
107 Method And Apparatus For Separation Of Offgas In The Combustion Of Particular Metals US15119523 2015-02-11 US20170008765A1 2017-01-12 Manfred Baldauf; Walter Preidel; Guenter Schmid; Dan Taroata
A method is provided for separating offgas from solid and/or liquid reaction products in the combustion of a metal M selected from alkali metals, alkaline earth metals, Al and Zn, and mixtures thereof, with a combustion gas. In a reaction step, the combustion gas is combusted with the metal M, forming offgas and further solid and/or liquid reaction products, and, in a separation step, the offgas is separated from the solid and/or liquid reaction products. In the separation step, a carrier gas is additionally added and the carrier gas is removed as a mixture with the offgas.
108 Galvanic elements containing oxygen-containing conversion electrodes US13510209 2010-11-18 US09490482B2 2016-11-08 Ulrich Wietelmann
A galvanic element containing a substantially transition metal-free oxygen-containing conversion electrode, a transition metal-containing cathode, and an aprotic lithium electrolyte. The substantially transition metal-free oxygen-containing conversion electrode materials contain lithium hydroxide and/or lithium peroxide and/or lithium oxide, and in the charged state additionally contain lithium hydride, and are contained in a galvanic element, for example a lithium battery, as the anode. Methods for producing substantially transition metal-free oxygen-containing conversion electrode materials and galvanic elements made of substantially transition metal-free oxygen-containing conversion electrode materials are also provided.
109 LITHIUM COMPOSITE OXIDE AND MANUFACTURING METHOD THEREFOR US14909034 2014-07-31 US20160190573A1 2016-06-30 Yang-Kook SUN; Sung-June YOUN
The present invention relates to a lithium composite oxide and a manufacturing method therefor and, more specifically, to: a lithium composite oxide in which the concentration of manganese forming the lithium composite oxide exhibits a concentration gradient in the entirety of the particles from the center to the surface, and comprising secondary particles formed from the condensing of stick-shaped primary particles; and a manufacturing method thereof.
110 HIGH CAPACITY HYDROGEN STORAGE NANOCOMPOSITE MATERIALS US14532045 2014-11-04 US20160159645A1 2016-06-09 Ragaiy Zidan; Matthew S. Wellons
A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270° C.
111 STABILIZED LITHIUM METAL FORMATIONS COATED WITH A SHELL CONTAINING NITROGEN, AND A METHOD FOR THE PRODUCTION OF SAME US14785237 2014-04-17 US20160121396A1 2016-05-05 Ulrich WIETELMANN; Christoph HARTNIG; Ute EMMEL; Vera NICKEL
The invention relates to particulate lithium metal formations having a substantially spherical geometry and a core composed of metallic lithium, which are enclosed with an outer passivating but ionically conductive layer containing nitrogen. The invention further relates to a method for producing lithium metal formations by reacting lithium metal with one or more passivating agent(s) containing nitrogen, selected from the groups N2, NxHy with x=1 or 2 and y=3 or 4, or a compound containing only the elements C, H, and N, and optionally Li, at temperatures in the range between 60 and 300° C., preferably between 100 and 280° C., and particularly preferably above the melting temperature of lithium of 180.5° C., in an inert organic solvent under dispersion conditions or in an atmosphere that contains a gaseous coating agent containing nitrogen.
112 PRODUCTION OF HIGH-PURITY LITHIUM DIFLUOROPHOSPHATE US14430642 2013-09-27 US20150263384A1 2015-09-17 Matthias Boll; Wolfgang Ebenbeck
The present invention relates to a process for preparing high-purity, especially low-sodium, lithium difluorophosphate, especially in the form of solutions thereof in organic solvents, proceeding from lithium fluoride and phosphorus pentafluoride.
113 Method for separation of monovalent metals from multivalent metals US13469826 2012-05-11 US09126843B2 2015-09-08 Areski Rezkallah
The present invention is directed to a new more environmentally friendly method for the separation of metals from concentrated solution or more specifically to separate monovalent metals from a solutions that comprise high levels of multivalent metals by using a sulfonic functionalized resin.
114 High capacity hydrogen storage nanocomposite materials US12932242 2011-02-22 US08945500B1 2015-02-03 Ragaiy Zidan; Matthew S. Wellons
A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270° C.
115 STABILIZED LITHIUM COMPOSITE PARTICLES US13673019 2012-11-09 US20140134438A1 2014-05-15 Kishor Purushottam Gadkaree; Xiaorong Liu
Stabilized lithium particles include a lithium-containing core and a coating of a complex lithium salt that surrounds and encapsulates the core. The coating, which is a barrier to oxygen and water, enables the particles to be handled in the open air and incorporated directly into electrochemical devices. The coating material is compatible, for example, with electrolytic materials that are used in electrochemical cells. The average coated particle size is less than 500 microns.
116 PROCESS FOR PREPARING LITHIUM SULFIDE US14119980 2012-05-29 US20140084224A1 2014-03-27 Peter Rittmeyer; Ulrich Wietelmann; Uwe Lischka; Dieter Hauk; Bernhard Füger; Armin Stoll; Dirk Dawidowski
The invention relates to a novel process for preparing lithium sulfide and to the use thereof, wherein a reaction of lithium-containing strong bases with hydrogen sulfide is undertaken in an aprotic organic solvent within the temperature range from −20 to 120° C. under inert conditions. The lithium sulfide obtained by the process is used as a positive material in a galvanic element or for the synthesis of Li ion-conductive solids, especially for the synthesis of glasses, glass ceramics or crystalline products.
117 METHOD FOR SEPARATION OF MONOVALENT METALS FROM MULTIVALENT METALS US13469826 2012-05-11 US20120288426A1 2012-11-15 Areski Rezkallah
The present invention is directed to a new more environmentally friendly method for the separation of metals from concentrated solution or more specifically to separate monovalent metals from a solutions that comprise high levels of multivalent metals by using a sulfonic functionalized resin.
118 Spray Pyrolysis Synthesis of Mesoporous Positive Electrode Materials for High Energy Lithium-Ion Batteries US13462563 2012-05-02 US20120282522A1 2012-11-08 Richard L. Axelbaum; Xiaofeng Zhang
A lithium metal oxide positive electrode material useful in making lithium-ion batteries that is produced using spray pyrolysis. The material comprises a plurality of metal oxide secondary particles that comprise metal oxide primary particles, wherein the primary particles have a size that is in the range of about 1 nm to about 10 μm, and the secondary particles have a size that is in the range of about 10 nm to about 100 μm and are uniformly mesoporous.
119 LITHIUM-POROUS METAL OXIDE COMPOSITIONS AND LITHIUM REAGENT-POROUS METAL COMPOSITIONS US13469299 2012-05-11 US20120235084A1 2012-09-20 Michael LEFENFELD; James L. DYE; Partha NANDI; James JACKSON
The invention relates to lithium metal/porous metal oxide compositions. These lithium metal compositions are prepared by mixing liquid lithium metal with a porous metal oxide in an inert atmosphere under exothermic conditions sufficient to absorb the liquid lithium metal into the porous metal oxide pores. The lithium metal/porous metal oxide compositions of the invention are preferably loaded with lithium metal up to about 40% by weight, with about 20% to 40% by weight being the most preferred loading. The invention also relates to lithium reagent-porous metal oxide compositions having RLi absorbed into a porous oxide. In formula RLi, R is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group, or an NR1R2 group; R1 is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group; and R2 is hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, and an alkaryl group. The preparation and use of these compositions are also described.
120 GALVANIC ELEMENTS CONTAINING OXYGEN-CONTAINING CONVERSION ELECTRODES US13510209 2010-11-18 US20120225356A1 2012-09-06 Ulrich Wietelmann
A galvanic element containing a substantially transition metal-free oxygen-containing conversion electrode, a transition metal-containing cathode, and an aprotic lithium electrolyte. The substantially transition metal-free oxygen-containing conversion. electrode materials contain lithium hydroxide and/or lithium peroxide and/or lithium oxide, and in the charged state additionally contain lithium hydride, and are contained in a galvanic element, for example a lithium battery, as the anode. Methods for producing substantially transition metal-free oxygen-containing conversion electrode materials and galvanic elements made of substantially transition metal-free oxygen-containing conversion electrode materials are also provided.
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