| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 161 | Solid polymer electrolyte membrane and fuel cell | EP04254731.5 | 2004-08-06 | EP1513212A3 | 2006-05-31 | Suzuki, Kenji, Japan Gore-Tex, Inc. |
A solid polymer electrolyte film is composed of at least an ion exchange resin. The solid polymer electrolyte film of the present invention is also characterized in having beaded silica dispersed therein. The ratio of the ion exchange resin and the beaded silica (beaded silica/ion exchange resin) is about 1 to 50 wt%, for example. The preferred beaded silica has a primary particle size of 50 nm or less as measured with the help of the BET method, and has a particle size of 60 nm or more as measured with the help of dynamic light scattering.
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| 162 | MATERIAU HYBRIDE ORGANIQUE-INORGANIQUE COMPRENANT UNE PHASE MINERALE MESOPOREUSE ET UNE PHASE ORGANIQUE, MEMBRANE ET PILE A COMBUSTIBLE | EP04704264.3 | 2004-01-22 | EP1585783A1 | 2005-10-19 | VALLE, Karine; BELLEVILLE, Philippe; SANCHEZ, Clément |
| The inventive organic-inorganic hybrid material comprises two phases: a first mineral phase containing a mesoporous structures open porosity array and a second organic phase containing an organic polymer. The inventive membrane and electrode contain said material. The inventive fuel cell comprises at least on said membrane and/or at least one said electrode. A method for producing said material is also disclosed. | ||||||
| 163 | Solid polymer electrolyte membrane and fuel cell | EP04254731.5 | 2004-08-06 | EP1513212A2 | 2005-03-09 | Suzuki, Kenji, Japan Gore-Tex, Inc. |
A solid polymer electrolyte film is composed of at least an ion exchange resin. The solid polymer electrolyte film of the present invention is also characterized in having beaded silica dispersed therein. The ratio of the ion exchange resin and the beaded silica (beaded silica/ion exchange resin) is about 1 to 50 wt%, for example. The preferred beaded silica has a primary particle size of 50 nm or less as measured with the help of the BET method, and has a particle size of 60 nm or more as measured with the help of dynamic light scattering. |
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| 164 | KOMPOSITE UND KOMPOSITMEMBRANEN | EP00934975.4 | 2000-05-02 | EP1177247A2 | 2002-02-06 | KERRES, Jochen; HÄRING, Thomas; HÄRING, Rima |
| The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchanger polymer; (b) an anion exchanger polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100 % (a) to 100 % (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group of the phyllosilicates or tectosilicates. The use of bentonites and zeolites are generally preferred in special montomorillonite. The mixture ratio isomer:bentonite ranges from 99:1 to 30:70. The invention also relates to the application of the composites/composite membranes: as proton conductors in membrane fuel cells (H2 fuel cells PEFC, direct methanol fuel cells DMFC) at temperatures greater than 100 °C; in (electro)membrane separation methods such as dialysis, diffusion dialysis, gas separation, pervaporation, perstraction and in microfiltration and ultrafiltration, particularly due to their antifouling properties, and; as catalytic membranes in catalytic membrane reactors. | ||||||
| 165 | ALKOXYSILANE/ORGANIC POLYMER COMPOSITION FOR THIN INSULATING FILM PRODUCTION AND USE THEREOF | EP98932538 | 1998-07-15 | EP0997497A4 | 2001-07-11 | IOKA TAKAAKI; TANABE TSUNEAKI |
| Disclosed is an alkoxysilane/organic polymer composition for use in producing an insulating thin film, comprising (A) a specific alkoxysilane; (B) a specific organic polymer; and (C) a solvent for alkoxysilane (A) and organic polymer (B), wherein solvent (C) comprises at least one organic solvent selected from the group consisting of amide linkage-containing organic solvents and ester linkage-containing organic solvents. Also disclosed are a silica-organic polymer composits thin film which is produced by a process comprising: forming a thin film of the composition of the present invention; subjecting the thin film to a hydrolysis and dehydration-condensation reaction with respect to the alkoxysilane thereof, to thereby cause the alkoxysilane to be gelled in the thin film; and removing the solvent remaining in the thin film by drying, and a porous silica thin film which is obtained by removing the organic polymer from the silica-organic polymer composite thin film. Both of the silica-organic polymer composite thin film and the porous silica thin film have advantages not only in that these thin films have a low dielectric constant suitable for insulating layers for a multilevel interconnect for a semiconductor device, but also in that these thin films can be produced by a method which can be easily performed in the current process for producing a semiconductor device. | ||||||
| 166 | POLYURETHANE/POLYUREA COMPOSITIONS CONTAINING SILICONE FOR BIOSENSOR MEMBRANES | EP96911389 | 1996-03-25 | EP0817809A4 | 1998-07-08 | VAN ANTWERP WILLIAM P |
| A homogenous polymer composition useful as a membrane for biosensors is disclosed. The polymer composition comprises the reaction products of a diisocyanate, a hydrophilic diol or diamine, and a silicone material. An aliphatic diol or diamine may also be included. Membranes prepared from the composition allow for increasing oxygen permeability and decreased analyte permeability (e.g. glucose). They also possess the necessary physical properties of an outer polymeric biosensor membrane. | ||||||
| 167 | HYDROPHILIZED SILICONE PARTICLES AND MAKING METHOD | EP13709535.2 | 2013-01-03 | EP2941453A1 | 2015-11-11 | INOKUCHI, Yoshinori; HAGIWARA, Mamoru; OMURA, Naoki |
| Surfaces of silicone particles are hydrophilized by plasma treatment. The hydrophilized silicone particles are readily dispersible in aqueous materials without a need for dispersants, typically surfactants. In aqueous cosmetic applications externally applied to the skin such as skin care cosmetics, make-up cosmetics, antiperspirant cosmetics, and UV care cosmetics, for example, products free of skin irritation concern can be formulated because formulation is possible without a need for surfactants. | ||||||
| 168 | ORGANOSILICIUMVERBINDUNGEN UND DEREN VERWENDUNG ZUR HERSTELLUNG VON HYDROPHILEN OBERFLÄCHEN | EP13705819.4 | 2013-02-26 | EP2820024B1 | 2015-08-12 | SCHEIM, Uwe; BROOK, Michael, A.; CHEN, Yang |
| 169 | GAS-BARRIER FILM AND ELECTRONIC DEVICE | EP11852550 | 2011-12-01 | EP2660041A4 | 2014-06-25 | MORI TAKAHIRO |
| 170 | PROTECTIVE SHEET FOR SOLAR CELL MODULE | EP10797183.0 | 2010-07-08 | EP2453485A1 | 2012-05-16 | TAKANASHI Yasunari; OKAWARA Chiharu; YOSHIDA Shigenobu |
Provided is a protective sheet for a solar cell module having a resin sheet, a vapor deposited layer containing an inorganic oxide provided on at least one side thereof, and a fluorine resin layer containing a silane coupling agent laminated on the vapor deposited layer. |
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| 171 | COMPOSITE NANOGRANULES FROM POLYMER/INORGANIC NANOPARTICLES, PREPARATION METHOD THEREOF AND USE OF THE SAME | EP10774547.3 | 2010-05-12 | EP2431413A1 | 2012-03-21 | QIAN, Suping; XU, Yuhong; FAN, Zhentian; HOU, Yongtai |
Composite nanogranules from polymer/inorganic nanoparticle, especially first composite nanogranules which are formed from first polymer and inorganic nanoparticles, second composite nanogranules which are obtained by forming second polymer on the first composite nanogranules, third composite nanogranules which is obtained by forming third polymer on the second composite nanogranules, and Nth composite nanogranules which is obtained by forming Nth polymer on the (N-1)th composite nanogranules with the similar method, are disclosed. A composition comprising anyone of the composite nanogranules described above is disclosed. The preparation method thereof and use of the same are also disclosed. |
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| 172 | Verfahren zur Herstellung von Kompositmembranen | EP03003310.4 | 2003-02-13 | EP1348478B2 | 2011-12-28 | Goedel, Werner A., Dr.; Jaumann, Manfred, Dipl.-Ing.; Möller, Martin, Prof. Dr.; Muzzafarow, Assiz, Prof. |
| 173 | PROTON CONDUCTIVE MATERIAL, METHOD FOR MANUFACTURING PROTON CONDUCTIVE MATERIAL, AND MEMBRANE-ELECTRODE ASSEMBLY CONTAINING PROTON CONDUCTIVE MATERIAL | EP08807109.7 | 2008-09-18 | EP2206188A1 | 2010-07-14 | FUJINAMI, Tatsuo; MASE, Takuya; TAKAMI, Masayoshi |
| A proton conductive material (100) in which hollow inorganic fine particles (2) that have through holes on a surface of the hollow inorganic fine particles (2), that are filled with an electrolyte resin (1). In addition, a membrane-electrode assembly which has an anode electrode provided on one surface side of a solid polymer electrolyte membrane and including an anode catalyst layer, and a cathode electrode provided on the other surface side of the solid polymer electrolyte membrane and including a cathode catalyst layer, wherein at least the anode catalyst layer from among the pair of catalyst layers includes the proton conductive material (100). | ||||||
| 174 | Komposite und Kompositmembranen | EP07015005.7 | 2000-05-02 | EP1870429A3 | 2008-04-02 | Kerres, Jochen; Häring, Thomas; Häring, Rima |
Zusammenfassung: Gegenstand der Erfindung ist ein Komposit oder ein Komposimembran aus einem Ionomeren und einem anorganischen gegebenenfalls funktionalisierten Schichtsilikat. Dabei kann das Ionomer sein: (a) ein Kationenaustauscherpolymer; (b) ein Anionenaustauscherpolymer; (c) ein Polymer, das auf der Polymerkette sowohl Anionenaustauschergrupplerungen als auch Kakionenaustauschergruppierungen enthält: (d) ein Blend aus (a) und (b), wobei das Mischungsverhältnis von 100 % (a) zu 100 % (b) reichen kann. Der Blend kann ionisch und noch kovalent vernetzt sein. Dabei kann die anorganische Komponente aus der Gruppe der Schicht- oder Gerüstsilikate sein. Allgemein sind die Bentonite und Zeolithe, im Speziellen Montmorillonit bevorzugt. Das Mischungsverhältnis Ionomer/Bentonit reicht dabei von 99/1 zu 30/70. Desweiteren ist Gegenstand dieser Erfindung die Anwendung der Komposites/Kompositmembranen: als Protoncnleitor in Membranbrennstoffzellen (H2-Bronnstoffzellen PEFC, Direktmethanolbrennstoffzellen DMFC) im Temperaturbereich über 100°C; in (Elektro)membrantrennverfahren wie Dialyse, Diffusiondialyac, Gastrennung, Fervaporation, Perstraktion und in Mikro- und Ultrafiltration insbesondere wegen ihrer Antifoulingeigenschaften: als katalytische Membranen in Katalysator-Membran-Reaktoren. |
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| 175 | Komposite und Kompositmembranen | EP07015005.7 | 2000-05-02 | EP1870429A2 | 2007-12-26 | Die Erfindernennung liegt noch nicht vor |
Zusammenfassung: Gegenstand der Erfindung ist ein Komposit oder ein Komposimembran aus einem Ionomeren und einem anorganischen gegebenenfalls funktionalisierten Schichtsilikat. Dabei kann das Ionomer sein: (a) ein Kationenaustauscherpolymer; (b) ein Anionenaustauscherpolymer; (c) ein Polymer, das auf der Polymerkette sowohl Anionenaustauschergrupplerungen als auch Kakionenaustauschergruppierungen enthält: (d) ein Blend aus (a) und (b), wobei das Mischungsverhältnis von 100 % (a) zu 100 % (b) reichen kann. Der Blend kann ionisch und noch kovalent vernetzt sein. Dabei kann die anorganische Komponente aus der Gruppe der Schicht- oder Gerüstsilikate sein. Allgemein sind die Bentonite und Zeolithe, im Speziellen Montmorillonit bevorzugt. Das Mischungsverhältnis Ionomer/Bentonit reicht dabei von 99/1 zu 30/70. Desweiteren ist Gegenstand dieser Erfindung die Anwendung der Komposites/Kompositmembranen: als Protoncnleitor in Membranbrennstoffzellen (H2-Bronnstoffzellen PEFC, Direktmethanolbrennstoffzellen DMFC) im Temperaturbereich über 100°C; in (Elektro)membrantrennverfahren wie Dialyse, Diffusiondialyac, Gastrennung, Fervaporation, Perstraktion und in Mikro- und Ultrafiltration insbesondere wegen ihrer Antifoulingeigenschaften: als katalytische Membranen in Katalysator-Membran-Reaktoren. |
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| 176 | REINFORCING MATERIAL FOR PROTON CONDUCTIVE MEMBRANE, PROTON CONDUCTIVE MEMBRANE USING SAME AND FUEL CELL | EP05719953 | 2005-03-03 | EP1727225A4 | 2007-10-31 | ASADA ATSUSHI; INO JUICHI; SATO NORIAKI |
| Disclosed is a reinforcing material for proton conductive membranes which contains a nonwoven fabric mainly composed of glass fibers having the C-glass composition and a binder for strengthening bonding between fibers. The glass fibers have an average fiber diameter of 0.1-20 μm, and an average fiber length of 0.5-20 mm. This reinforcing material is excellent in heat resistance, acid resistance and dimensional stability. | ||||||
| 177 | SUBSTRATE WITH AN ANTI-SOILING COATING | EP05802877.0 | 2005-10-21 | EP1809706A1 | 2007-07-25 | DANG, Hoa Thien; MOYSAN, Yannick |
| A substrate having at least one main surface comprising a first coating deposited on said main surface and a second coating having anti-soiling properties deposited and adhering on the surface of said first coating, the first coating being a (meth)acrylate based coating and being obtained by polymerizing a polymerizable composition comprising: i) at least one (meth)acrylate compound and ii) at least one compound I having at least one —M—Z′ bond with M representing Si or a Metal atom, Z′ representing OH or a hydrolysable group, and at least one ethylenic unsaturated group or epoxy group, and/or iii) at least one silica or metal oxide colloid having free ethylenically unsaturated groups; and the second coating, having anti-soiling properties, being obtained by depositing on said first coating an anti-soiling coating composition comprising at least one compound II, or a hydrolyzate thereof, having at least one —Si—Z″ group with Z″ representing OH or a hydrolysable group. | ||||||
| 178 | Verfahren zur Herstellung von Kompositmembranen | EP03003310.4 | 2003-02-13 | EP1348478A3 | 2005-06-22 | Goedel, Werner A., Dr.; Jaumann, Manfred, Dipl.-Ing.; Möller, Martin, Prof. Dr.; Muzzafarow, Assiz, Prof. |
Ein Verfahren zur Herstellung von Kompositmembranen, das folgende Schritte aufweist:
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| 179 | ALKOXYSILANE/ORGANIC POLYMER COMPOSITION FOR THIN INSULATING FILM PRODUCTION AND USE THEREOF | EP98932538.6 | 1998-07-15 | EP0997497B1 | 2004-10-27 | IOKA, Takaaki; TANABE, Tsuneaki |
| 180 | FLUOROSULFONIC ACID ORGANIC POLYMERS | EP01935501.5 | 2001-05-14 | EP1397398A1 | 2004-03-17 | YANG, Zhen-Yu |
| The present invention provides for a composition and a process for forming the composition. The composition comprises an organic polymer and 0.5-40 % by weight of the composition of a siloxane, the organic polymer having a fluorinated backbone and 3-20 mol-% of pendant groups represented by the formula (I): -Op-[CF(Rf1)CF-Om]n-CF2CF2SO3X; wherein Rf is F or a perfluoroalkyl radical having 1-10 carbon atoms either unsubstituted or substituted by one or more ether oxygen atoms, m=0 or 1, n=0 to 3, p=0 or 1, and X is H or an alkali metal; the siloxane comprising two or more groups which need not be the same represented by the formula (II): -OaSi(OH)b-aR13-bR2Rf2SO3; wherein a=1; 1 to b, b=1 to 3, R1 is a non-hydrolyzable group independently selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl, X is is an alkali metal or hydrogen, R2 is a bidentate alkylene radical either unsubstituted or substituted by at least one ether oxygen atom with the proviso that R2 has at least two carbon atoms linearly disposed between Si and R¿f?2, and R¿f?2 is a perfluoroalkylene ether radical either unsubstituted or substituted by at least one ether oxygen atom. | ||||||
