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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 Foam-generating, hardening compositions for forming impressions of surfaces and impression trays for use therewith US12062065 2008-04-03 US20090098503A1 2009-04-16 GOTTFRIED KNISPEL; Martin Grunwald; Andreas Grundler
Foam-generating, hardening composition for making impressions of biological surfaces include A at least one impression material based on i isocyanates, which react with mono- and multi-functional amines and/or compounds having hydroxyl groups, to form urethane or urea, or ii A-silicones, or iii C-silicones, or iv Polyethers, or v alpha-silanes, or vi mixtures of two or more materials i to v, and optionally B at least one foaming agent. Impressions of biological surfaces made from this compound have a foam with closed pores.
102 Functional addition polymers and a method for their preparation US10957568 2004-10-01 US07232863B2 2007-06-19 Walter H. Ohrbom; Donald H. Campbell; Donald L. St. Aubin; Swaminathan Ramesh; Paul J. Harris; Ulrike Röckrath
Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C═C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.
103 Thermoplastic polyurethane molding and manufacturing method thereof US10559343 2004-04-19 US20070093631A1 2007-04-26 Koji Nishida; Toshiji Kanaya; Takehiko Sugimoto; Wei Ji; Toshiaki Kasazaki
The thermoplastic polyurethane molding of the present invention is obtained by melting, molding, cooling and solidifying, subsequently heating to a temperature T1 (specifically, 180 to 190° C) that is not more than flow starting temperature Tm and not less than glass transition point Tg and cooling down quickly to a temperature T2 (Tm>T1>T2>Tg, specifically, 160 to 165° C.). In dynamic viscoelasticity measurement, the difference between the temperature at which LogE′ turns 4.5 MPa and the peak temperature of tan δ is 190 to 225° C.
104 Process for copolymerization of bicyclic amide acetals and polyisocyanates US4738 1987-01-20 US4721767A 1988-01-26 Anil B. Goel
An improved process for the copolymerization of a mixture of a bicyclic amide acetal and a polyisocyanate comprising carrying out the copolymerization reaction at a temperature in the range of from about ambient temperature up to about 200.degree. C. in the presence of a catalytic amount of a salt of a metal selected from the group consisting of bismuth, lead, mercury, copper, vanadium, cobalt, nickel, potassium, zinc and antimony is described.
105 Reaction injection molding process and reaction injection molded products US592081 1984-03-22 US4582879A 1986-04-15 Kurt C. Frisch; Kaneyoshi Ashida; Jozef L. M. van der Loos; Albert A. van Geenen
A reaction injection molding process is disclosed comprising:introducing a mixture of substantially stable reactant streams into a mold, said mixture, in the aggregate, containing polyamide polymer forming compounds and polyurethane polymer forming compounds, said polyamide polymer forming compounds including lactam, an anionic polymerization catalyst and a polymerization activator, said polyurethane polymer forming compounds including a polyol, a polyisocyanate, a chain extender if desired, and a polyurethane polymerization catalyst, said polyamide polymer forming compounds and said polyurethane forming compounds reacting to respectively form polyamide and polyurethane polymers in said mold to thereby yielding a reaction injection molded product composed of said polymers; andrecovering said product from said mold.
106 Polymers derived from polyisocyanates, bicyclic amide acetals and oxazolines US693953 1985-01-23 US4558114A 1985-12-10 Anil B. Goel
A process for preparing novel interpolymers from mixtures of a bicyclic amide acetal, an oxazoline and a polyisocyanate and the novel polymers produced are described.
107 Process for the production of foamed poly(epoxy-polyisocyanate)silicate polymers US405414 1982-08-05 US4377646A 1983-03-22 David H. Blount
Poly(epoxy-polyisocyanate) silicate foamed products are produced by mixing and reactng an epoxide compound, an oxidated silicon compound and a polyisocyanate in the presence of a Lewis acid. The foam produced by this process may be utilized for thermal and sound insulation.
108 Coating compositions containing polymers with isocyano groups and nickel oligomerization catalysts US108842 1979-12-31 US4251421A 1981-02-17 Walter R. Hertler
This invention relates to cross-linkable film-forming compositions which contain a polymer with pendant isocyano groups and a nickel oligomerization catalyst and to the use of the compositions in ambient temperature-cure finishes.
109 Furan-modified isocyanurate foams US534559 1974-12-19 US4232127A 1980-11-04 Moses Cenker; Thirumurti L. Narayan
Furan-modified rigid isocyanurate foams are taught herein. The foams herein are prepared by either (1) the in situ polymerization of furfuryl alcohol and/or furfural during the foam formation reaction, or (2) the catalytic condensation of a furfuryl alcohol-blocked organic polyisocyanate.
110 Thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate stabilized by incorporating an organic electron acceptor US797429 1977-05-16 US4129554A 1978-12-12 Yoshiharu Karasawa; Tohru Koyama; Toshikazu Narahara
A thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate which is normally catalyzed by a basic curing catalyst for forming oxazolidone rings and isocyanurate rings or uredione rings is remarkably stabilized at low temperatures by incorporating a small amount of an organic electron acceptor, such as, picric acid, quinone, chloranil, or cyanoacetate ester into the composition. Since the specific electron acceptors effectively inhibit the polymerization of the reactive components in the composition at low temperatures, a shelf life of the composition is remarkably prolonged.
111 Polyurethane-protein composition and process for making same US38350173 1973-07-30 US3873478A 1975-03-25 COMTE PHILIPPE; FISCHER WILHELM
Proteinic substances are degreased (defatted), dried and pulverized and combined with polyurethane precursors (i.e. polyols and di, tri or polyisocyanates) to form a leatherlike composition.
112 Novel bisamides containing fluorine US3786093D 1969-10-17 US3786093A 1974-01-15 LICHSTEIN B; DU BOIS R
NOVEL COMPOUNDS USEFUL IN IMPARTING OIL REPELLENCY TO FABRICS HAVE THE FORMULA (RFCONH)2CHR WHEREIN RF IS A RADICAL CONTAINING AT LEAST ONE FLUORINE ATOM AND FROM 1 TO 20 CARBON ATOMS, THE RADICAL BEING SELECTED FROM THE GROUP CONSISTING OF ALKYL, PHENYL, ALKYLPHENYL, PHENYLALKYL; AND ANY OF THESE RADICALS CONTAINING AN ETHER LINKAGE, AND R IS HYDROGEN, TRICHLOROMETHYL, OR PHENYL. THE COMPOUNDS ARE PREPARED BY REACTING A NITRILE OF THE FORMULA RFCN WITH FORMALDEHYDE, CHLORAL, CHLORAL HYDRATE OR BENZADEHYDE IN THE PRESENCE OF A CATATLYTIC AMOUNT OF A STRONG ACID AND PREFERABLY ALSO IN THE PRESENCE OF A SOLVENT SUCH AS CARBON TETRACHLORIDE.
113 Process for the preparation of mono-and polyimines with electrophilic double-bond systems US3742033D 1969-11-20 US3742033A 1973-06-26 HAJEK M; WAGNER K
Imines substituted in the Alpha -position are obtained by reacting mono- or polyimines (ket- and aldimines) with an electrophilic olefin (i.e., acrylic and metacrylic acid derivatives) at a temperature between 10* and 150* C, optionally under pressure and optionally in the presence of an inert solvent. The imines modified by the process of the invention have many possible uses and represent valuable intermediates for many organic syntheses. The new compounds obtainable according to the process can be used in the preparation of elastic moulding masses.
114 Glutamic acid polymer adherents US3729366D 1971-01-15 US3729366A 1973-04-24 FUJIMOTO Y; NAGAOKA K; TATSUKAWA K
A LEATHER-LIKE COMPOSITE COMPRISING A COATING ADHESIVELY SECURED TO A SUBSTRATE, SAID COATING COMPRISING A MAJOR AMOUNT OF A POLYGLUTAMIC ACID AND AN ADHESIVE CONTAINING A DIISOCYANATO-SUBSTITUTED ALIPHATIC CARBOXYLIC ACID ESTER AS HE PRINCIPAL CONSTITUENT. THE ADHESIVE USED IN THE PRESENT INVENTION PROVIDES A GOOD BOND BETWEEN THE POLYMERIC FILM AND THE SUBSTRATE SURFACE, FOR EXAMPLE, A COTTON CLOTH. THE COMPOSITE EXHIBITS AN IMPROVED LUSTER AND EXCELLENT RESISTANCE TO LIGHT, AS WELL AS AN ENHANCED ELONGATION.
115 High energy curable liquid polyene polythiol polymer composition US3725229D 1971-06-25 US3725229A 1973-04-03 KEHR C; WSZOLEK W
THE INVENTION DISCLOSED IS FOR A NEW ENERGY CURABLE LIQUID POLYMER COMPOSITION WHICH INCLUDES A LIQUID POLYENE COMPPNENT HAVING A MOLECULE CONTAININGS AT LEAST TWO UNSATURATED CARBON/TO-CARBON BONDS DISPOSED AT TERMINAL POSITIONS ON A MAIN CHAIN BACKBONE OF THE MOLECULE, AND A POLYTHIOL COMPONENT HAVING A MOLECULE CONTAINING A MULTIPLICITY OF PENDANT OR TERMINALLY POSITIONED -SH FUNCTIONAL GROUPS PER AVERAGE MOLECULE. THE HIGH ENERGY CURABLE LIQUID POLYMER COMPOSITION UPON CURING IN THE PRESENCE OF HIGH ENERGY IRRADIATION FORMS ODORLESS, SOLID, ELASTOMERIC PRODUCTS WHICH MAY SERVE AS SEALANTS, COATINGS, ADHESIVES, AND MOLDED ARTICLES.
116 Carpets having a back-coating of in situ-formed polyurethane US3664863D 1969-05-19 US3664863A 1972-05-23 DIJKHUIZEN WILLEM; BEERSMA PIETER JOHANNES ADRIAN
Carpets are back-coated with essentially non-cellular elastomeric polyurethanes, formed and cured in situ at ambient temperature from a mixture of selected polyether-polyols, selected polyisocyanates and catalyst.
117 Photocurable liquid polyene-polythiol polymer compositions US3661744D 1970-06-08 US3661744A 1972-05-09 KEHR CLIFTON L; WSZOLEK WALTER R
The invention disclosed is for a new photocurable liquid polymer composition which includes a liquid polyene component having a molecule containing at least two unsaturated carbon-to-carbon bonds disposed at terminal positions on a main chain of the molecule, a polythiol component having a molecule containing a multiplicity of pendant or terminally positioned -SH functional groups per average molecule, and a photocuring rate accelerator. The photocurable liquid polymer composition upon curing in the presence of actinic light forms odorless, solid, elastomeric or resinous products which may serve as sealants, coatings, adhesives and molded articles.
118 Alkoxylated mannich base urethane prepolymer composition and method of preparation US3655619D 1969-01-24 US3655619A 1972-04-11 SELLET LUCIEN
TREATING AGENTS WHICH ARE THE REACTION PRODUCT OF AN HYDROXYL CONTAINING NITROGEN COMPOUND, AN ISOCYANATE TERMINATED URETHANE PREPOLYMER AND AN ACID OR QUATERNIZING AGENT, SAID REACTION PRODUCTS BEING USEFUL IN THE TREATMENT OF FIBROUS, POROUS AND NONPOROUS SUBSTRATES.
119 Method of preparing solid polyurethane elastomers US3645975D 1968-04-08 US3645975A 1972-02-29 BERNSTEIN CARL
UNVULCANIZED, SOLID POLYURETHANE ELASTOMERS ARE PREPARED BY REACTING AN ADMIXTURE OF ACTIVE-HYDROGEN-CONTAINING LINEAR POLYETHER OR POLYESTER POLYMERS OR BRANCHED-CHAIN DERIVATIVES THEREOF, ORGANIC DIISOCYANATES, AND SUCH OTHER INGREDIENTS AS MAY BE REQUIRED, SUCH AS CHAIN-EXTENDERS, IN A THIN-WALLED, PREFORMED POLYETHYLENE REACTION CONTAINER AT A TEMPERATURE FROM ABOUT 125 TO 300 DEGREES F., THE REACTION MIXTURE ADVANTAGEOUSLY BEING PROTECTED FROM CONTACT WITH THE ATMOSPHERE UNTIL A SOLID POLYMER IS FORMED. THE PLASTIC REACTION VESSEL CAN BE READILY CUTY AND STRIPPED FROM THE SURFACE OF THE SOLID ELASTOMER OR THE SOLID ELASTOMER CAN BE STORED OR SHIPPED WHILE STILL ENCASED IN THE PLASTIC REACTION VESSEL.
120 Block copolymers comprising an nphenyl maleimide and either a diolefin or cyclic oxide US3632681D 1967-05-04 US3632681A 1972-01-04 POPE GEORGE A; VAUGHAN GEORGE; WILSON PAUL I
A BLOCK COPOLYMER HAVING THE GENERAL FORMULA

A-(B-A)N

IN WHICH A REPRESENTS A CRYSTALLINE POLYMER BLOCK HAVING A MELTING POINT ABOVE 100*C. AND THE TOTAL AMOUNT OF POLYMER BLOCK A IS FROM 3 PERCENT TO 30 PERCENT BY WEIGHT OF THE BLOCK COPOLYMER AND IN WHICH B REPRESENTS AN AMOUPHOUS POLYMER BLOCK HAVING A GLASS TRANSITION TEMPERATURE NOT GREATER THAN 15*C. AND HAS A VISCOSITY AVERAGE MOLECULAR WEIGHT OF 10,000 TO 600,000 AND N IS AN INTEGAR OF FROM 1 TO 5.
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