序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
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101 | Foam-generating, hardening compositions for forming impressions of surfaces and impression trays for use therewith | US12062065 | 2008-04-03 | US20090098503A1 | 2009-04-16 | GOTTFRIED KNISPEL; Martin Grunwald; Andreas Grundler |
Foam-generating, hardening composition for making impressions of biological surfaces include A at least one impression material based on i isocyanates, which react with mono- and multi-functional amines and/or compounds having hydroxyl groups, to form urethane or urea, or ii A-silicones, or iii C-silicones, or iv Polyethers, or v alpha-silanes, or vi mixtures of two or more materials i to v, and optionally B at least one foaming agent. Impressions of biological surfaces made from this compound have a foam with closed pores. | ||||||
102 | Functional addition polymers and a method for their preparation | US10957568 | 2004-10-01 | US07232863B2 | 2007-06-19 | Walter H. Ohrbom; Donald H. Campbell; Donald L. St. Aubin; Swaminathan Ramesh; Paul J. Harris; Ulrike Röckrath |
Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C═C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate. | ||||||
103 | Thermoplastic polyurethane molding and manufacturing method thereof | US10559343 | 2004-04-19 | US20070093631A1 | 2007-04-26 | Koji Nishida; Toshiji Kanaya; Takehiko Sugimoto; Wei Ji; Toshiaki Kasazaki |
The thermoplastic polyurethane molding of the present invention is obtained by melting, molding, cooling and solidifying, subsequently heating to a temperature T1 (specifically, 180 to 190° C) that is not more than flow starting temperature Tm and not less than glass transition point Tg and cooling down quickly to a temperature T2 (Tm>T1>T2>Tg, specifically, 160 to 165° C.). In dynamic viscoelasticity measurement, the difference between the temperature at which LogE′ turns 4.5 MPa and the peak temperature of tan δ is 190 to 225° C. | ||||||
104 | Process for copolymerization of bicyclic amide acetals and polyisocyanates | US4738 | 1987-01-20 | US4721767A | 1988-01-26 | Anil B. Goel |
An improved process for the copolymerization of a mixture of a bicyclic amide acetal and a polyisocyanate comprising carrying out the copolymerization reaction at a temperature in the range of from about ambient temperature up to about 200.degree. C. in the presence of a catalytic amount of a salt of a metal selected from the group consisting of bismuth, lead, mercury, copper, vanadium, cobalt, nickel, potassium, zinc and antimony is described. | ||||||
105 | Reaction injection molding process and reaction injection molded products | US592081 | 1984-03-22 | US4582879A | 1986-04-15 | Kurt C. Frisch; Kaneyoshi Ashida; Jozef L. M. van der Loos; Albert A. van Geenen |
A reaction injection molding process is disclosed comprising:introducing a mixture of substantially stable reactant streams into a mold, said mixture, in the aggregate, containing polyamide polymer forming compounds and polyurethane polymer forming compounds, said polyamide polymer forming compounds including lactam, an anionic polymerization catalyst and a polymerization activator, said polyurethane polymer forming compounds including a polyol, a polyisocyanate, a chain extender if desired, and a polyurethane polymerization catalyst, said polyamide polymer forming compounds and said polyurethane forming compounds reacting to respectively form polyamide and polyurethane polymers in said mold to thereby yielding a reaction injection molded product composed of said polymers; andrecovering said product from said mold. | ||||||
106 | Polymers derived from polyisocyanates, bicyclic amide acetals and oxazolines | US693953 | 1985-01-23 | US4558114A | 1985-12-10 | Anil B. Goel |
A process for preparing novel interpolymers from mixtures of a bicyclic amide acetal, an oxazoline and a polyisocyanate and the novel polymers produced are described. | ||||||
107 | Process for the production of foamed poly(epoxy-polyisocyanate)silicate polymers | US405414 | 1982-08-05 | US4377646A | 1983-03-22 | David H. Blount |
Poly(epoxy-polyisocyanate) silicate foamed products are produced by mixing and reactng an epoxide compound, an oxidated silicon compound and a polyisocyanate in the presence of a Lewis acid. The foam produced by this process may be utilized for thermal and sound insulation. | ||||||
108 | Coating compositions containing polymers with isocyano groups and nickel oligomerization catalysts | US108842 | 1979-12-31 | US4251421A | 1981-02-17 | Walter R. Hertler |
This invention relates to cross-linkable film-forming compositions which contain a polymer with pendant isocyano groups and a nickel oligomerization catalyst and to the use of the compositions in ambient temperature-cure finishes. | ||||||
109 | Furan-modified isocyanurate foams | US534559 | 1974-12-19 | US4232127A | 1980-11-04 | Moses Cenker; Thirumurti L. Narayan |
Furan-modified rigid isocyanurate foams are taught herein. The foams herein are prepared by either (1) the in situ polymerization of furfuryl alcohol and/or furfural during the foam formation reaction, or (2) the catalytic condensation of a furfuryl alcohol-blocked organic polyisocyanate. | ||||||
110 | Thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate stabilized by incorporating an organic electron acceptor | US797429 | 1977-05-16 | US4129554A | 1978-12-12 | Yoshiharu Karasawa; Tohru Koyama; Toshikazu Narahara |
A thermosettable, polymerizable resin composition comprising a polyepoxide and a polyisocyanate which is normally catalyzed by a basic curing catalyst for forming oxazolidone rings and isocyanurate rings or uredione rings is remarkably stabilized at low temperatures by incorporating a small amount of an organic electron acceptor, such as, picric acid, quinone, chloranil, or cyanoacetate ester into the composition. Since the specific electron acceptors effectively inhibit the polymerization of the reactive components in the composition at low temperatures, a shelf life of the composition is remarkably prolonged. | ||||||
111 | Polyurethane-protein composition and process for making same | US38350173 | 1973-07-30 | US3873478A | 1975-03-25 | COMTE PHILIPPE; FISCHER WILHELM |
Proteinic substances are degreased (defatted), dried and pulverized and combined with polyurethane precursors (i.e. polyols and di, tri or polyisocyanates) to form a leatherlike composition.
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112 | Novel bisamides containing fluorine | US3786093D | 1969-10-17 | US3786093A | 1974-01-15 | LICHSTEIN B; DU BOIS R |
NOVEL COMPOUNDS USEFUL IN IMPARTING OIL REPELLENCY TO FABRICS HAVE THE FORMULA (RFCONH)2CHR WHEREIN RF IS A RADICAL CONTAINING AT LEAST ONE FLUORINE ATOM AND FROM 1 TO 20 CARBON ATOMS, THE RADICAL BEING SELECTED FROM THE GROUP CONSISTING OF ALKYL, PHENYL, ALKYLPHENYL, PHENYLALKYL; AND ANY OF THESE RADICALS CONTAINING AN ETHER LINKAGE, AND R IS HYDROGEN, TRICHLOROMETHYL, OR PHENYL. THE COMPOUNDS ARE PREPARED BY REACTING A NITRILE OF THE FORMULA RFCN WITH FORMALDEHYDE, CHLORAL, CHLORAL HYDRATE OR BENZADEHYDE IN THE PRESENCE OF A CATATLYTIC AMOUNT OF A STRONG ACID AND PREFERABLY ALSO IN THE PRESENCE OF A SOLVENT SUCH AS CARBON TETRACHLORIDE.
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113 | Process for the preparation of mono-and polyimines with electrophilic double-bond systems | US3742033D | 1969-11-20 | US3742033A | 1973-06-26 | HAJEK M; WAGNER K |
Imines substituted in the Alpha -position are obtained by reacting mono- or polyimines (ket- and aldimines) with an electrophilic olefin (i.e., acrylic and metacrylic acid derivatives) at a temperature between 10* and 150* C, optionally under pressure and optionally in the presence of an inert solvent. The imines modified by the process of the invention have many possible uses and represent valuable intermediates for many organic syntheses. The new compounds obtainable according to the process can be used in the preparation of elastic moulding masses.
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114 | Glutamic acid polymer adherents | US3729366D | 1971-01-15 | US3729366A | 1973-04-24 | FUJIMOTO Y; NAGAOKA K; TATSUKAWA K |
A LEATHER-LIKE COMPOSITE COMPRISING A COATING ADHESIVELY SECURED TO A SUBSTRATE, SAID COATING COMPRISING A MAJOR AMOUNT OF A POLYGLUTAMIC ACID AND AN ADHESIVE CONTAINING A DIISOCYANATO-SUBSTITUTED ALIPHATIC CARBOXYLIC ACID ESTER AS HE PRINCIPAL CONSTITUENT. THE ADHESIVE USED IN THE PRESENT INVENTION PROVIDES A GOOD BOND BETWEEN THE POLYMERIC FILM AND THE SUBSTRATE SURFACE, FOR EXAMPLE, A COTTON CLOTH. THE COMPOSITE EXHIBITS AN IMPROVED LUSTER AND EXCELLENT RESISTANCE TO LIGHT, AS WELL AS AN ENHANCED ELONGATION.
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115 | High energy curable liquid polyene polythiol polymer composition | US3725229D | 1971-06-25 | US3725229A | 1973-04-03 | KEHR C; WSZOLEK W |
THE INVENTION DISCLOSED IS FOR A NEW ENERGY CURABLE LIQUID POLYMER COMPOSITION WHICH INCLUDES A LIQUID POLYENE COMPPNENT HAVING A MOLECULE CONTAININGS AT LEAST TWO UNSATURATED CARBON/TO-CARBON BONDS DISPOSED AT TERMINAL POSITIONS ON A MAIN CHAIN BACKBONE OF THE MOLECULE, AND A POLYTHIOL COMPONENT HAVING A MOLECULE CONTAINING A MULTIPLICITY OF PENDANT OR TERMINALLY POSITIONED -SH FUNCTIONAL GROUPS PER AVERAGE MOLECULE. THE HIGH ENERGY CURABLE LIQUID POLYMER COMPOSITION UPON CURING IN THE PRESENCE OF HIGH ENERGY IRRADIATION FORMS ODORLESS, SOLID, ELASTOMERIC PRODUCTS WHICH MAY SERVE AS SEALANTS, COATINGS, ADHESIVES, AND MOLDED ARTICLES.
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116 | Carpets having a back-coating of in situ-formed polyurethane | US3664863D | 1969-05-19 | US3664863A | 1972-05-23 | DIJKHUIZEN WILLEM; BEERSMA PIETER JOHANNES ADRIAN |
Carpets are back-coated with essentially non-cellular elastomeric polyurethanes, formed and cured in situ at ambient temperature from a mixture of selected polyether-polyols, selected polyisocyanates and catalyst.
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117 | Photocurable liquid polyene-polythiol polymer compositions | US3661744D | 1970-06-08 | US3661744A | 1972-05-09 | KEHR CLIFTON L; WSZOLEK WALTER R |
The invention disclosed is for a new photocurable liquid polymer composition which includes a liquid polyene component having a molecule containing at least two unsaturated carbon-to-carbon bonds disposed at terminal positions on a main chain of the molecule, a polythiol component having a molecule containing a multiplicity of pendant or terminally positioned -SH functional groups per average molecule, and a photocuring rate accelerator. The photocurable liquid polymer composition upon curing in the presence of actinic light forms odorless, solid, elastomeric or resinous products which may serve as sealants, coatings, adhesives and molded articles.
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118 | Alkoxylated mannich base urethane prepolymer composition and method of preparation | US3655619D | 1969-01-24 | US3655619A | 1972-04-11 | SELLET LUCIEN |
TREATING AGENTS WHICH ARE THE REACTION PRODUCT OF AN HYDROXYL CONTAINING NITROGEN COMPOUND, AN ISOCYANATE TERMINATED URETHANE PREPOLYMER AND AN ACID OR QUATERNIZING AGENT, SAID REACTION PRODUCTS BEING USEFUL IN THE TREATMENT OF FIBROUS, POROUS AND NONPOROUS SUBSTRATES.
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119 | Method of preparing solid polyurethane elastomers | US3645975D | 1968-04-08 | US3645975A | 1972-02-29 | BERNSTEIN CARL |
UNVULCANIZED, SOLID POLYURETHANE ELASTOMERS ARE PREPARED BY REACTING AN ADMIXTURE OF ACTIVE-HYDROGEN-CONTAINING LINEAR POLYETHER OR POLYESTER POLYMERS OR BRANCHED-CHAIN DERIVATIVES THEREOF, ORGANIC DIISOCYANATES, AND SUCH OTHER INGREDIENTS AS MAY BE REQUIRED, SUCH AS CHAIN-EXTENDERS, IN A THIN-WALLED, PREFORMED POLYETHYLENE REACTION CONTAINER AT A TEMPERATURE FROM ABOUT 125 TO 300 DEGREES F., THE REACTION MIXTURE ADVANTAGEOUSLY BEING PROTECTED FROM CONTACT WITH THE ATMOSPHERE UNTIL A SOLID POLYMER IS FORMED. THE PLASTIC REACTION VESSEL CAN BE READILY CUTY AND STRIPPED FROM THE SURFACE OF THE SOLID ELASTOMER OR THE SOLID ELASTOMER CAN BE STORED OR SHIPPED WHILE STILL ENCASED IN THE PLASTIC REACTION VESSEL.
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120 | Block copolymers comprising an nphenyl maleimide and either a diolefin or cyclic oxide | US3632681D | 1967-05-04 | US3632681A | 1972-01-04 | POPE GEORGE A; VAUGHAN GEORGE; WILSON PAUL I |
A BLOCK COPOLYMER HAVING THE GENERAL FORMULA
A-(B-A)N IN WHICH A REPRESENTS A CRYSTALLINE POLYMER BLOCK HAVING A MELTING POINT ABOVE 100*C. AND THE TOTAL AMOUNT OF POLYMER BLOCK A IS FROM 3 PERCENT TO 30 PERCENT BY WEIGHT OF THE BLOCK COPOLYMER AND IN WHICH B REPRESENTS AN AMOUPHOUS POLYMER BLOCK HAVING A GLASS TRANSITION TEMPERATURE NOT GREATER THAN 15*C. AND HAS A VISCOSITY AVERAGE MOLECULAR WEIGHT OF 10,000 TO 600,000 AND N IS AN INTEGAR OF FROM 1 TO 5. |