ANTIFOULING MATTED OBJECT |
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申请号 | EP17208235.6 | 申请日 | 2017-12-18 | 公开(公告)号 | EP3339271A1 | 公开(公告)日 | 2018-06-27 |
申请人 | TOTO LTD.; | 发明人 | SATOSHI, Shimizu; YUKIKA, Yamazawa; | ||||
摘要 | An object of the present invention is to provide a matted object capable of achieving both a lower range of glossiness and an antifouling property. A matted object includes a substrate, and a glassy layer provided on the surface of the substrate. The surface of the glassy layer has a 60°-glossiness of 20 or less, a skewness Rsk of -0.5 or more, and a maximum height roughness Rz more than 2.5 µm and less than 5. 7 µm, the skewness Rsk and the maximum height roughness Rz being specified in JIS B0601 (2001). | ||||||
权利要求 | |||||||
说明书全文 | The present invention relates to a matted object having a surface that is matted and also has a good antifouling property. Some bathtubs, lavatory sinks, toilet bowls, and the like have the surfaces of their substrates covered with a glassy layer of glaze, enamel, or the like in order to densify and protect their surfaces. On the other hand, there has been an increasing need for an exterior with a good design that provides a harmony in the space as a whole. Thus, there has been a demand to express a matted, soft exterior besides the glossiness of the glassy layer. As mentioned above, to obtain a matted surface, methods have been employed which involve providing a surface with asperities so that light will be scattered on the surface, for example. A problem, however, is that dirt enters the recessed portions of the asperities and is difficult to be removed depending on the profile of the asperities. Moreover, a matted surface having a 60°-glossiness of 20 or less while ensuring an antifouling property has not yet been developed. An object of the present invention is to provide a matted object capable of achieving both a lower range of glossiness and an antifouling property. The present inventors have discovered that both a matted exterior with a 60°-glossiness of 20 or less and high dirt removability can be achieved when Rsk of the surface of a glassy layer is a predetermined value or more and Rz of the surface of the glassy layer is within a predetermined range. Specifically, the present invention provides a matted object including a substrate and a glassy layer provided on a surface of the substrate, in which a surface of the glassy layer has a 60°-glossiness of 20 or less, a skewness Rsk of -0.5 or more, and a maximum height roughness Rz more than 2.5 µm and less than 5.7 µm, the skewness Rsk and the maximum height roughness Rz being specified in JIS B0601 (2001). According to the present invention, a matted object having both a matted exterior with a 60°-glossiness of 20 or less and high dirt removability can be provided. [ A matted object of the present invention includes a substrate and a glassy layer provided on the surface of the substrate. The substrate used in the present invention is not particularly limited but includes ceramic, metal, and the like. The 60°-glossiness of the surface of the glassy layer provided on the surface of the substrate is 20 or less. Also, skewness Rsk of the surface of the glassy layer provided on the surface of the substrate is -0.5 or more and preferably 0.1 or less, the skewness Rsk being specified in JIS B0601 (2001). Also, maximum height roughness Rz of the surface of the glassy layer provided on the surface of the substrate is more than 2.5 µm and less than 5.7 µm, preferably 3.0 µm or more, preferably 4.8 µm or less, and more preferably 3.0 µm to 4.8 µm, the maximum height roughness Rz being specified in JIS B0601 (2001). With a surface having such properties, it is possible to provide an object that is matted but is resistant to adhesion of stains and/or contaminants and also capable of letting adhering stains and/or contaminants be easily removed. Also, the ratio (RC/RSm) of the mean height of roughness profile elements (Rc) to the mean length of roughness profile elements (RSm) of the surface of the glassy layer provided on the surface of the substrate is preferably at least 20 × 10-3 and not more than 33 × 10-3, the mean height of roughness profile elements (Rc) and the mean length of roughness profile elements (RSm) each being specified in JIS B0601 (2001). The glassy layer is provided by coating the surface of the substrate with glaze. A glaze layer as an intermediate layer may be further provided on the surface of the substrate. The composition of the glaze, used to form the glassy layer, is not particularly limited. A mixture of particles of natural minerals such as silica sand, feldspar, and limestone, a pigment such as a cobalt compound or an iron compound, an opalizer such as zirconium silicate or tin oxide, and the like are typically used as the materials of the glaze. The glassy layer can be obtained by melting the materials of the glaze at high temperature and then quenching the melt to vitrify it. In the present invention, a preferable composition of the glaze is, for example, 10wt% to 30wt% of feldspar, 15wt% to 40wt% of silica sand, 10wt% to 25wt% of calcium carbonate, 10wt% or less of corundum, talc, dolomite, and zinc oxide individually, and 15wt% or less of the opalizer and the pigment together. The matted object of the present invention can be manufactured by the following method, for example. Specifically, first, a substrate is prepared. In a case where the substrate is ceramic, for example, ceramic body slip containing materials such as silica sand, feldspar, and clay is molded into a desired shape by slip casting utilizing water-absorbing molds to obtain a ceramic green body. Then, the surface of the dried green body is coated with the materials of the glaze by a common method such as spray coating, dip coating, spin coating, or roll coating. Thereafter, the green body coated with the materials of the glaze is sintered. The sintering temperature is preferably at least 1,000°C and not more than 1,300°C, at which the ceramic body is sintered and the glaze is softened. Further, the surface of the glassy layer on the resultant green body is subjected to wet blasting or the like, so that the surface profile defined earlier is obtained. In the wet blasting, the surface of the glassy layer can be adjusted into a predetermined surface profile by jetting a mixture of water, an abrasive material, and compressed air together onto the surface of the glassy layer. In a case where the substrate is metal, for example, a metallic surface that has been subjected to pretreatment such as degreasing or washing is coated with the materials of the glaze by a common method such as spray coating, dip coating, spin coating, or roll coating and then sintered. The sintering temperature is preferably at least 750°C and not more than 850°C, for example. The matted object of the present invention may have a part which is not subjected to the treatment for obtaining the above-defined surface profile in some areas such as areas where dirt does not adhere so much. The matted object of the present invention may also have a pattern formed by glossy portions and matted portions. The present invention will be described more specifically with reference to the following examples. Note that the present invention is not limited to these examples. 2 kg of natural mineral particles with the composition in Table 1, 1 kg of water, and 4 kg of spherical stones were placed in a ceramic pot having a capacity of 6 liters and pulverized using a ball mill (ball diameter: 50 mm) for approximately 24 hours to obtain a glaze slurry. Thereafter, a 70×70-mm plate-shaped test piece was prepared using a sanitary ceramic ware body slip prepared using silica sand, feldspar, clay and the like as materials. This plate-shaped test piece was coated with the glaze to a thickness of 0.5 mm by spray coating using a wet-spray method and was then sintered at 1100 to 1200°C to obtain a substrate. A commercially available wet blasting apparatus was used on the above substrate to adjust the surface profile of the substrate. In the wet blasting, the surface of the substrate can be adjusted into a predetermined surface profile by jetting a mixture of water, an abrasive material, and compressed air together onto the surface of the substrate. The surface of the substrate was adjusted into the desired surface profile by using aspherical alumina particles as the abrasive material and appropriately selecting an abrasive-material average particle diameter (particle diameter range: 10 µm to 100 µm), compressed-air supply pressure, jetting distance, jetting angle, and jetting duration. 2 kg of natural mineral particles with a composition in Table 2, 1 kg of water, and 4 kg of spherical stones were placed in a ceramic pot having a capacity of 6 liters and pulverized using a ball mill (ball diameter: 50 mm) for approximately 24 hours to obtain a glaze slurry. Thereafter, a 70×70-mm plate-shaped test piece was prepared using a sanitary ceramic ware body slip prepared using silica sand, feldspar, clay and the like as materials. This plate-shaped test piece was coated with the glaze to a thickness of 0.5 mm by spray coating using a wet-spray method and was then sintered at 1100 to 1200°C to obtain a sample. Examples 7, 8, 11, 12, 14, 15, and 20 to 23 of sanitary ceramic wares were obtained in this manner. A commercially available wet blasting apparatus was used on two kinds of commercially available sanitary ceramic wares to adjust the surface profile of the substrate. In the wet blasting, the surface of the substrate can be adjusted into a predetermined surface profile by jetting a mixture of water, an abrasive material, and compressed air together onto the surface of the substrate. The surface of the substrate was adjusted into the desired surface profile by using aspherical alumina particles as the abrasive material and appropriately selecting an abrasive-material average particle diameter (particle diameter range: 10 µm to 100 µm), compressed-air supply pressure, jetting distance, jetting angle, and jetting duration. The surface profile of the samples of examples 1 to 25 was measured using a stylus surface roughness measurement apparatus (SV-624 manufactured by Mitsutoyo Corporation) complying with JIS B0601 (1996) or a laser microscope LEXT OLS4000 (manufactured by Olympus Corporation) complying with JIS B0601 (2001) based on definitions and representation in JIS B0601 (2001). Regarding the measurement conditions of the stylus surface roughness measurement apparatus, an evaluation length of 4 mm and a cutoff value λc of 0.8 mm were selected, line roughness was measured in a total of 10 spots, and the average of these values were employed as the value of a roughness parameter of the sample. Regarding the observation conditions of the laser microscope, a high accuracy mode with 430x magnification (pitch: 0.2 µm) was selected, seven images were captured each of which was a 640×640-µm image captured from a single field of view, and an image obtained by combining them by using an image joining function was evaluated. Regarding the conditions of the evaluation, an evaluation length of 4 mm and a cutoff value λc of 0.8 mm were selected, line roughness was measured in a total of 10 spots on the combined image, and the average of these values were employed as the value of a roughness parameter of the sample. The 60°-glossiness of the samples of examples 1 to 25 was measured using a glossmeter (GM-268plus manufactured by KONICA MINOLTA, INC.) based on JIS Z8741. As an index of mat feeling, a 60°-glossiness of 20 or less was defined as acceptable. The antifouling property of the surfaces of the samples of examples 1 to 25 was evaluated by the following method. A color difference meter SPECTROPHOTOMETER CM-2600d (manufactured by KONICA MINOLTA, INC.) was used. The conditions of the measurement were set to use the following: the color system: L*a*b*, mask/gloss: S/I + E, the UV setting: UV 100%, the light source: D65, the angle of view for observation: 10 degrees, and representation: absolute color difference value. The value of a* (the average of the values of three measurements on the same spot) presented by the specular component include (SCI) method, which is a method of measuring light including specularly reflected light, was used.
A dirt removability of 80% or higher can be considered a good removability. |