序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
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61 | NITRO DYES | PCT/EP1995002745 | 1995-07-13 | WO1996003463A1 | 1996-02-08 | BASF AKTIENGESELLSCHAFT |
Nitro dyes of formula (I), in which X<1> and X<2> are hydrogen, C1-C6 alkyl, C1-C6 alkoxy or pyrrolidine-2-one-1-yl, X<3> is hydrogen or C1-C6 alkyl and X<4> is a radical of formula (a), (b) or (c), in which R<1> is hydrogen, possibly substituted C1-C12 alkyl, possibly substituted C3-C7 cycloalkyl or possibly substituted phenyl, R<2> and R<3> are hydrogen, C1-C6 alkyl or C1-C6 alkoxy, R<4> is hydrogen, methyl, ethyl, methoxy or ethoxy and R<5> is hydrogen or C1-C6 alkyl and process for their production and their use in dyeing or printing textiles. | ||||||
62 | NITROSULFIDE DYES | EP06763695.1 | 2006-06-14 | EP1893697A2 | 2008-03-05 | CREMER, Christian; WALLQUIST, Olof |
Disclosed are nitro-sulfide dyes of formula (1) , their salts, isomers, hydrates and other solvates, wherein R1, R2, R3, independently from each other are hydrogen; C1-C20alkyl or C1-C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, -NO2 or hydroxy; C3-C6cycloalkyl; -C(O)H; -C(O)-C1-C5alkyl; -C(O)OH; -C(O)O-C1-C5alkyl; halogen; NO2; OH; SH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1- C5alkylamino, -NO2 or hydroxy; or a radical of formula (1a) -NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or -(CO)-H; -(CO)-C1- C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, -NO2, carboxy or hydroxy; or a radical of formula (2); wherein at least one of the radicals R1, R2 or R3 is NO2; Y1 is C1-C10alkylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-(C1-C10alkylene); Z1 is the direct bond; formula (3) ; or a cationic biradical of a saturated, aromatic or heteroaromatic group; Q1 is -C(O)-; --C(O)O-; -OCO-; -N(R6)-X2-; -CON(R6)-; -(R6)NC(O)-; -O-; -S-; -S(O)-; or -S(O)2-; X1 and X2 independently from each other are the direct bond; C1-C10alkylene; C5- C10cycloalkylene; C5-C10arylene; or C5-C10arylene-(C1-C10alkylene); and R6, R7 and R8 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6- C10aryl; C6-C10aryl-C1-C10alkyl; or C1-C10alkyl(C5-C10aryl); m is 1; or 2; U is hydrogen, if m is 1; or the direct bond, if m is 2; with the proviso that the method does not comprise contacting hair with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation. | ||||||
63 | Procédé de préparation de dérives de 1- (4-nitrophényl)-3-pyrrolidinols optiquement actifs, et paraphénylenediamines à groupement pyrrolidinyle chirales | EP04106111.0 | 2004-11-26 | EP1535904A3 | 2005-07-13 | Bordier, Thierry; Xu, Jinzhu |
Procédé de préparation d'un dérivé de 1-(4-nitrophényl)-3-pyrrolidinol optiquement actif répondant à la formule (I) suivante : Dérivés de paraphénylènediamine substitués par un groupement pyrrolidinyle chiral, de formule (II) et leurs sels d'addition : Composition tinctoriale contenant un dérivé de paraphénylènediamine de formule (II). Procédé de teinture d'oxydation des fibres kératiniques mettant en oeuvre ladite composition. Dispositifs à plusieurs compartiments dans lequel un premier compartiment contient ladite composition tinctoriale et un deuxième compartiment contient un agent oxydant. |
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64 | NEUE FARBSTOFFE UND FÄRBEMITTEL | EP00949238.0 | 2000-07-01 | EP1189993B1 | 2004-02-18 | HOLLENBERG, Detlef; HÖFFKES, Horst; FOITZIK, Joachim-Kurt; ROSE, David; NAUMANN, Frank; WOLFRAM, Leszek, J. |
65 | NITROFARBSTOFFE | EP95925868.2 | 1995-07-13 | EP0772651B1 | 1998-09-30 | LAMM, Gunther; REICHELT, Helmut; GRUND, Clemens |
66 | FÄRBEMITTEL FÜR NATÜRLICHE UND SYNTHETISCHE FASERN | EP93904005.1 | 1993-02-22 | EP0629221B1 | 1998-04-15 | ROSE, David; HÖFFKES, Horst; LIESKE, Edgar; MATZIK, Iduna |
New compounds have formula (I), in which one of the groups R?1 and R2¿ is a nitro group, whereas the other is hydrogen, an alkyl group with 1 to 4 atoms or an alkoxy group with 1 to 4 atoms, R?3 and R4¿ represent independently from each other a group -(CH¿2?-CHR?7-O)¿nH where R7 stands for hydrogen, methyl or ethyl and n = 0 or an integer from 1 to 4, provided that in at least one of the groups R?3 and R4¿ n be different from zero and R?5 and R6¿ represent independently from each other hydrogen or an alkyl group with 1 to 4 C atoms. Also disclosed are the salts of these compounds, as well as their use for dyeing natural and synthetic fibres, preferably polyacrylnitril fibres and keratinic fibres, most preferably for dyeing human hair. | ||||||
67 | 2-Nitro métaphénylènediamines substituées, leur procédé de préparation et leur utilisation en teinture des fibres kératiniques et en particulier des cheveux humains | EP88111198.3 | 1988-07-13 | EP0303826B1 | 1991-02-27 | Junino, Alex; Jehanno, Nicole; Lang, Gérard |
68 | Verfahren zur Herstellung von 2-Nitro-4-sulfamyl-diphenylamin-Farbstoffen | EP87107657.6 | 1987-05-26 | EP0248334A3 | 1990-09-26 | Brodt, Werner, Dr.; Papenfuhs, Theodor, Dr. |
Verfahren zur Herstellung von 2-Nitro-4-sulfamyl-diphenylamin-Farbstoffen der Formel (1)
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69 | Verwendung von 2,6-Dinitro-phenol-derivaten in Haarfärbemitteln | EP89111641.0 | 1989-06-27 | EP0352489A2 | 1990-01-31 | Clausen, Thomas, Dr.; Balzer, Wolfgang, Dr.; Lang, Günther, Dr. |
Verwendung eines 2,6-Dinitro-phenolderivats der allgemeinen Formel (I),
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70 | 2-Nitro métaphénylènediamines substituées, leur procédé de préparation et leur utilisation en teinture des fibres kératiniques et en particulier des cheveux humains | EP88111198.3 | 1988-07-13 | EP0303826A1 | 1989-02-22 | Junino, Alex; Jehanno, Nicole; Lang, Gérard |
L'invention concerne une 2-nitro métaphénylènediamine de formule :
Ce composé est utilisé en teinture des cheveux. |
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71 | Verfahren zur Herstellung von sauren Nitrofarbstoffen | EP85106114.3 | 1985-05-18 | EP0165483B1 | 1988-11-30 | Hertel, Hasso, Dr. |
72 | Process for the manufacture of acid nitro dyes | EP84109921 | 1984-08-21 | EP0137243A3 | 1986-12-17 | Hertel, Hasso, Dr. |
73 | 고견뢰도 분산 흑색염료 조성물 | KR1020180017090 | 2018-02-12 | KR102065838B1 | 2020-01-13 | |
74 | 고견뢰도 분산 흑색염료 조성물 | KR20180017090 | 2018-02-12 | KR20180021752A | 2018-03-05 | LI BAICHUN |
본발명은식(I)에도시된화합물에서의적어도하나가선택되는성분A, 식(II)에도시된화합물에서의적어도하나가선택되는성분B, 식(III) 및/또는식(IV)에도시된화합물에서의적어도하나가선택되는성분C, 식(V)에도시된화합물에서의적어도하나가선택되는성분D를포함하는고견뢰도분산흑색염료조성물을개시한다. 본발명이제공하는고견뢰도분산흑색염료조성물은응용될경우친환경적이고공법청결과제품견뢰도가높은특점을갖는다. | ||||||
75 | 브릴리언트 블루 아조염료 및 이 제조방법과 응용 | KR20180016342 | 2018-02-09 | KR20180021022A | 2018-02-28 | LI BAICHUN |
본발명은브릴리언트블루아조염료및 이제조방법과응용을개시하는바, 구조식식(Ⅰ)에도시된바와같이본 발명은브릴리언트블루아조염료가폴리에스터섬유의염색또는프린팅에서의응용을개시한다. 브릴리언트블루아조염료를구조통식(Ⅰ)에서선택된적어도한 화합물과혼합하여분산염료조성물을제작하되상기분산염료조성물은폴리에스터섬유의염색또는프린팅에응용될수 있다. 본발명은염색을진행할경우내세척견뢰도, 내마찰견뢰도, 땀견뢰도, 내일광견뢰도및 염색율이모두훌륭하고본 발명의분산염료조성물의염색강도가높으며색상이화려하고염색성능이우수한바, 특히우수한워싱견뢰도를가지고색상이안정되며쉽게퇴색되지않고원가가비교적낮다. | ||||||
76 | 착색 하전 실세스퀴옥산 | KR1020147030359 | 2013-04-02 | KR1020140138348A | 2014-12-03 | 외를라인,라인홀트; 바이쉬,가브리엘레 |
본 발명은 하기 화학식 II가 하기 화학식 III인 하기 화학식 1A의 화합물 및 하기 화학식 IV가 하기 화학식 V인 하기 화학식 1B의 화합물, 및 이러한 화학식 1A 또는 1B의 화합물을 포함하는 전기영동 장치를 제공한다.
<화학식 1A> <화학식 II> <화학식 III> <화학식 1B> <화학식 IV> <화학식 V> |
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77 | 신규한 화합물, 이를 포함하는 형광 염료, 표시 장치 및 에스터 교환 반응 촉매 | KR1020120017885 | 2012-02-22 | KR101451144B1 | 2014-10-20 | 김철; 배정미; 김진훈; 정광덕 |
본 발명은 신규한 화합물, 이를 포함하는 형광 염료, 표시 장치 및 에스터 교환 반응 촉매에 관한 것으로, 구체적으로 수은 및 디피리딜아민에 의한 착화합물로서 [Hg(Hdpa)X
2 ]
2 , [Hg(Hdpa)(O
2 CC
6 H
5 )
2 ], [Hg
2 (dpa)
2 (NO
3 )
2 ] 및 [Hg
2 (dpa)
2 ]·(ClO
4 )
2 에서 선택되는 화합물과 이를 포함하는 형광 염료, 표시 장치 및 에스터 교환 반응 촉매에 관한 것이다.
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78 | 니트로 염료 | KR1019970700399 | 1995-07-13 | KR1019970704835A | 1997-09-06 | 람,군터; 라이헬트,헬무트; 그룬트,크레멘스 |
하기 화학식 Ⅰ의 니트로 염료 및 그의 제조 방법 및 직물을 염색하거나 인쇄하기 위한 그의 용도에 관한 것이다. 식 중, X 1 및 X 2 수소는, C 1 -C 6 -알킬, C 1 -C 6 -알콕시 또는 피롤리딘-2-온-I-일이고, X 3 은 수소 또는 C 1 -C 6 -알킬이며, X 4 은 화학식 (a), (b) 또는(c) R 1 은 수소, 치환되거나 치환되지 않은 C 1 -C 12 -알킬, 치환되거나 치환되지 않은 C 3 -C 7 -시클로알킬, 또는 치환되거나 치환되지 않은 페닐이며, R 2 및 R 3 은 수소, C 1 -C 6 -알킬 또는 C 1 -C 6 -알콕시이고, R 4 은 수소, 메틸, 에틸, 메톡시 또는 에톡시이며, 및 R 5 은 수소 또는 C 1 -C 6 -알킬이다. | ||||||
79 | FLUORESCENT PROBES FOR MONOACYLGLYCEROL LIPASE (MAGL) | EP20780979.9 | 2020-09-22 | EP4034602A1 | 2022-08-03 | BENZ, Joerg; GAZZI, Thais; GOBBI, Luca; GRETHER, Uwe; HORNSPERGER, Benoit; KROLL, Carsten; KUHN, Bernd; MOSTINSKI, Yelena; NAZARE, Marc; O'HARA, Fionn; RICHTER, Hans |
The invention provides fluorescent probes having the general formula (I)wherein X, Y, L and R1 to R4 are as described herein, compositions including the compounds, processes of manufacturing the compounds and methods of using the compounds. | ||||||
80 | SPIRO[CHROMAN-2,2'-INDOLE]DERIVATIVES AS CYANIDE ION CHEMOSENSORS | EP13726311.7 | 2013-07-29 | EP2999704B1 | 2018-10-10 | SACKUS, Algirdas; MARTYNAITIS, Vytas; DAGILIENE, Migle; KRIKSTOLAITYTE, Sonata; RAGAITE, Greta |
The invention describes new spiro[chroman-2,2'-indole] derivatives of formula (I). When compounds of the invention, 1',3',3,4-tetrahydrospiro[chromen-2,2'-indoles], are treated with solution containing cyanide ions, 3,4-dihydropyrane ring opening occurs, resulting in formation of colored 4-nitrophenolate ion, which is detectable colorimetrically. |