| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 三价阳离子染料 | CN200780022263.0 | 2007-06-04 | CN101466797A | 2009-06-24 | 克里斯琴·克里默; 奥洛夫·沃尔奎斯特; 维克托·P·埃利厄; 基肖尔·R·尼瓦尔卡 |
| 本发明披露了式(1)的化合物，其中D是芳族基团或阳离子杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、羟基－C1－C14烷基、C3－C8环烷基、－CN，NO2、－NR3R4、卤素、任选被C1－C14烷基取代的C6－C10芳基，或一个或多个基团Z；E1和E2各自独立地为＝CH；或＝N－；K为芳族基团或杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、C3－C8环烷基、C6－C10芳基、卤素、羟基、NO2、－NR3R4、－N(R3)(CO)R4、－SO2NR1R2、－SONR1R2或一个或多个Z；或式－NR1R2的基团；R1和R2各自独立地为氢；C1－C14烷基；C1－C14环烷基；C6－C10芳基；芳族基团或杂芳族基团，所述基团任选被以下基团取代：C1－C14烷基、C1－C14烷氧基、C3－C8环烷基、C6－C10芳基、卤素、羟基、－NR5R6、－N(R5)－(CO)R5或Z；Z是式(1a)*－X1－Y1－W1的基团，其中X1是直接键；－NR7－；－O－；－NR7(C＝O)－；－(CO)NR7－；－O(C＝O)－；－(CO)O－；或－(C＝O)－；Y1是直接键；C1－C12亚烷基，所述C1－C12亚烷基可任选被－O－、－NR8、－S－、－(C＝O)－、－O(C＝O)－、(C＝O)O－、－NR7(C＝O)－、－(C＝O)NR7－隔断，并且其可被C1－C14烷基、羟基－C1－C14烷基、羟基、－NR9R10或卤素取代；或C6－C10亚芳基，所述C6－C10亚芳基可被C1－C14烷基、羟基－C1－C14烷基、羟基、氨基或卤素取代；W1是阳离子基团；和R3、R4、R5、R6、R7、R8、R9和R10各自独立地为氢；C1－C14烷基；或Z；和An1－、An2－和An3－各自独立地为阴离子。所述化合物可用于对有机物质进行染色，所述有机物质例如是角蛋白纤维、羊毛、皮革、丝、纤维素或聚酰胺，特别是含角蛋白的纤维、棉或尼龙、优选为毛发，更优选为人类毛发。 | ||||||
| 2 | 深度着色的偶氮染料 | CN200780039413.9 | 2007-10-23 | CN101883554A | 2010-11-10 | 马库斯·斯佩克巴彻; 杰西卡·查索特; 汉斯-于尔根·布朗 |
| 本发明涉及a)用于角蛋白纤维，具体为人的毛发的非氧化性着色剂，该非氧化性着色剂包含至少一种式(I)或(II)的染料，b)用于角蛋白纤维，具体为人的毛发的氧化性着色剂，该氧化性着色剂包含至少一种氧化剂(例如过氧化氢)、至少一种氧化染料前体和至少一种式(I)或(II)的染料，和c)用于淡色角蛋白纤维，具体为人的毛发的试剂，该试剂包含至少一种氧化剂(例如过氧化氢)和至少一种式(I)或(II)的染料，其中R4为阳离子基团。 | ||||||
| 3 | 深度着色的偶氮染料 | CN200780039413.9 | 2007-10-23 | CN101883554B | 2012-09-26 | 马库斯·斯佩克巴彻; 杰西卡·查索特; 汉斯-于尔根·布朗 |
| 本发明涉及a)用于角蛋白纤维，具体为人的毛发的非氧化性着色剂，该非氧化性着色剂包含至少一种式(I)或(II)的染料，b)用于角蛋白纤维，具体为人的毛发的氧化性着色剂，该氧化性着色剂包含至少一种氧化剂(例如过氧化氢)、至少一种氧化染料前体和至少一种式(I)或(II)的染料，和c)用于淡色角蛋白纤维，具体为人的毛发的试剂，该试剂包含至少一种氧化剂(例如过氧化氢)和至少一种式(I)或(II)的染料，其中R4为阳离子基团。 | ||||||
| 4 | 用封端的重氮化合物和偶联组分染色的方法 | CN200480041906.2 | 2004-12-08 | CN1918132A | 2007-02-21 | 维克托·P·伊利厄; 比特·弗罗林; 多米尼克·考夫曼 |
| 本发明涉及多孔材料染色的方法，其包括使要染色的材料与a)式(1)封端的重氮化合物，和b)任选的偶联组分接触，式(1)封端的重氮化合物中A+为有机化合物的阳离子基团，B为未取代或取代的脂肪胺或芳香胺基团，An为阴离子。此外，本发明还涉及新化合物及其组合物。 | ||||||
| 5 | METHOD OF COLORING WITH CAPPED DIAZOTIZED COMPOUND AND COUPLING COMPONENT | PCT/EP2004053335 | 2004-12-08 | WO2005058840A3 | 2005-08-11 | ELIU VICTOR PAUL; FROEHLING BEATE; KAUFFMANN DOMINIQUE |
| The present invention relates to a method of coloring porous material, which comprises contacting the material being colored, with a) a capped diazonium compound of formula (1) wherein A<+> is a cationic radical of an organic compound, B is a radical of an unsubstituted or substituted, aliphatic or aromatic amine, An is an anion,and b) optionally a coupling component. Further, the present invention relates to novel compounds and compositions thereof. | ||||||
| 6 | TRICATIONIC DYES | PCT/EP2007/055442 | 2007-06-04 | WO2007144280A3 | 2007-12-21 | CREMER, Christian; WALLQUIST, Olof; ELIU, Victor Paul; NIVALKAR, Kishor Ramachandra |
Disclosed are compounds of formula (I); wherein D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, -CN, NO2, -NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are =CH; or =N-; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, -NR3R4, -N(R3)(CO)R4, -SO2NR1R2, -SONR1R2 or by one or more Z; or a radical of formula -NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6- C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1- C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, -NR5R6, -N(R5)-(CO)R5 or by Z; Z is a group of the formula (1 a) *- X1-Y1-W1, wherein X1 is the direct bond; -NR7-; -0-; -NR7(C=O)-; -(CO)NR7-; -0(C=O)-; -(CO)O-; or -(C=O)-; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by -0-, -NR8, -S-, -(C=O)-, -0(C=O)-, (C=O)O-, -NR7(C=O)-, -(C=O)NR7-, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, -NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1-, An2- and An3- independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair. |
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| 7 | IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS | PCT/EP1981000041 | 1981-05-06 | WO1981003179A1 | 1981-11-12 | SANDOZ AG; DOSWALD P; MOSER H; MORICONI E; SCHMID H |
| Sulpho-free azo compound in metal free, 1:1 complex or 1:2 complex form having at least an average of 1.3 water solubilising basic groups of the formula I (FORMULA) in which Ra is an aromatic or acetoacyl group including a metallisable group, x is a metallisable group, R |
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| 8 | DARK COLOURED AZO DYES | PCT/IB2007054308 | 2007-10-23 | WO2008050295A3 | 2010-01-21 | SPECKBACHER MARKUS; CHASSOT JESSICA; BRAUN HANS-JUERGEN |
| The present invention relates to a) a non-oxidative colouring agent for keratin fibres, in particular human hair, comprising at least one dye according to formula (I) or (II), b) an oxidative colouring agent for keratin fibres, in particular human hair, which comprises at least one oxidizing agent (e.g. hydrogen peroxide), at least one oxidative dye precursor and at least one dye according to formula (I) or (II), and c) a lightening agent for keratin fibres, in particular human hair, which comprises at least one oxidizing agent (e.g. hydrogen peroxide) and at least one dye according to formula (I) or (II), with R4 being a cationic group. | ||||||
| 9 | CATIONIC IMIDAZOLAZO DYES CONTAINING A 2, 5-DIAMINOPHENYL MOIETY | PCT/EP2005051323 | 2005-03-23 | WO2005095522A3 | 2005-11-10 | ELIU VICTOR PAUL; SAUDER THOMAS; KAUFFMANN DOMINIQUE; FROEHLING BEATE |
| Disclosed are azo dyes of formula (1) , wherein R1 is hydrogen; C1-C14alkyl; hydroxy- C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a) -(CH2)n1-O-(CH2)n2-CH3; a radical of formula (1b) C10aryl; or C6-C10aryl-C1-C6alkyl; R3 is hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C6alkyl; or CO-R6; R4 is CO-R6; R5 is C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; R6 is hydrogen; C1-C14alkyl; C2-C14alkenyl; or C6-C10aryl; R7, R8, R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; m is 1; or 2; An<-> is an anion; If m = 1, R2 is hydrogen; C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a); a radical of formula (1b) ; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; If m = 2, R2 is the direct bond; or C1-C14alkylene, which is optionally substituted by one or more C1-C4alkyl, or which is optionally interrupted by C5-C10arylene, -O- or -NR9R10-; R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair. | ||||||
| 10 | MODULAR DESIGN AND SYNTHESIS OF AMINIMIDE CONTAINING MOLECULES | PCT/US1993012612 | 1993-12-28 | WO1995018186A1 | 1995-07-06 | ARQULE PARTNERS, L.P. |
| The design and synthesis of novel aminimide-derived molecular modules and the use of the modules in the construction of new molecules and fabricated materials is disclosed. The new molecules and fabricated materials are molecular recognition agents useful in the design and synthesis of drugs, and have applications in separations and materials science. | ||||||
| 11 | TRICATIONIC DYES | EP07729830.5 | 2007-06-04 | EP2029674A2 | 2009-03-04 | CREMER, Christian; WALLQUIST, Olof; ELIU, Victor Paul; NIVALKAR, Kishor Ramachandra |
| Disclosed are compounds of formula (I); wherein D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, hydroxy-C1-C14alkyl, C3-C8cycloalkyl, -CN, NO2, -NR3R4, halogen, C6-C10aryl, which is optionally substituted or C1-C14alkyl, or by one or more groups Z; E1 and E2 independently from each other are =CH; or =N-; K is an aromatic or heteroaromatic group which is optionally substituted by C1-C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, NO2, -NR3R4, -N(R3)(CO)R4, -SO2NR1R2, -SONR1R2 or by one or more Z; or a radical of formula -NR1R2; R1 and R2 independently from each other are hydrogen; C1-C14alkyl; cyclo-C1-C14alkyl; C6- C10aryl; an aromatic or heteroaromatic group which is optionally substituted by C1- C14alkyl, C1-C14alkoxy, C3-C8cycloalkyl, C6-C10aryl, halogen, hydroxy, -NR5R6, -N(R5)-(CO)R5 or by Z; Z is a group of the formula (1 a) *- X1-Y1-W1, wherein X1 is the direct bond; -NR7-; -0-; -NR7(C=O)-; -(CO)NR7-; -0(C=O)-; -(CO)O-; or -(C=O)-; Y1 is the direct bond; C1-C12alkylene, which is optionally interrupted by -0-, -NR8, -S-, -(C=O)-, -0(C=O)-, (C=O)O-, -NR7(C=O)-, -(C=O)NR7-, and which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, -NR9R10 or halogen; or C6-C10arylene, which may substituted by C1-C14alkyl, hydroxy-C1-C14alkyl, hydroxy, amino or halogen; W1 is a cationic group; and R3, R4, R5, R6, R7, R8, R9 and R10 independently from each other are hydrogen; C1-C14alkyl; or Z; and An1-, An2- and An3- independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair. | ||||||
| 12 | LANTHANOIDCHELATE UND IHRE ANWENDUNG IN DER BIOANALYTIK | EP05746647.6 | 2005-04-30 | EP1732935A2 | 2006-12-20 | MARX, Jörg; SCHUMER, Frank; LISCHEWSKI, Regina; ZECKERT, Kornelia; BÖHME, Hans-Joachim; HENNING, Horst |
| The invention relates to novel chemical compounds, of application in fluorometric analytical methods, for qualitative and quantitative determination of biomolecules. The aim of the invention is to identify and prove the suitability of such compounds. Said aim is achieved with compounds of formula (I), where R1 is an antenna function, R2 is a chelate forming agent, containing a coordinated lanthanide (III) ion, X is -OH or a group with affinity for the biomolecule, bonded to a carboxyl group of the chelate forming agent by means of an amide bond and Y is -H or a group with affinity for the biomolecule, coupled to the antenna function. | ||||||
| 13 | Sulpho-free basic azo compounds in metal-free or 1:1 or 1:2 metal complex form | EP83100106.0 | 1981-05-06 | EP0093828B1 | 1987-11-19 | Doswald, Paul; Moriconi, Emil; Moser, Helmut; Schmid, Horst |
| 14 | Verfahren zur Herstellung kationischer Farbstoffe | EP81102164.1 | 1981-03-23 | EP0037506A1 | 1981-10-14 | Gleinig, Harald, Dr.; Berger-Lohr, Bernd, Dr.; Breig, Kurt, Dr. |
Die Herstellung von kationischen Farbstoffen der allgemeinen Formel
in Abwesenheit von organischen Lösungsmitteln in Gegenwart von Wasser, wobei das Gewichtsverhältnis von Azobase : Wasser 100 : 15 - 100 und das Molverhältnis Azobase : Dialkylsulfat 1 : 1,5 - 2,5 betragen, und gegebenenfalls durch Austausch desAlkylsulfat-Anions gegen ein anderesAnion. |
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| 15 | Verfahren zur Herstellung kationischer Farbstoffe | EP80104239.1 | 1980-07-18 | EP0023652A1 | 1981-02-11 | Raue, Roderich, Dr.; Giesecke, Heinz, Dr. |
Zur Herstellung von Farbstoffen der allgemeinen Formel
|
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| 16 | Basische Farbstoffe auf Basis von Amiden der 1-Hydroxy-6-aminonaphtalin-3-sulfonsäure sowie deren Zwischenprodukte | EP95101121.2 | 1995-01-27 | EP0666287A3 | 1997-01-08 | Schlösser, Ulrike, Dr.; Mayer, Udo, Dr. |
Die vorliegende Erfindung betrifft neue Farbstoffe der Formel
|
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| 17 | Basische Farbstoffe auf Basis von Amiden der 1-Hydroxy-6-aminonaphtalin-3-sulfonsäure sowie deren Zwischenprodukte | EP95101121.2 | 1995-01-27 | EP0666287A2 | 1995-08-09 | Schlösser, Ulrike, Dr.; Mayer, Udo, Dr. |
Die vorliegende Erfindung betrifft neue Farbstoffe der Formel
|
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| 18 | Verfahren zur Herstellung kationischer Farbstoffe | EP80104239.1 | 1980-07-18 | EP0023652B1 | 1984-05-09 | Raue, Roderich, Dr.; Giesecke, Heinz, Dr. |
| 19 | Sulphofree basic azo compounds in metal-free 1:1 or 1:2 metal complex form | EP83100107.8 | 1981-05-06 | EP0093829A1 | 1983-11-16 | Doswald, Paul; Moriconi, Emil; Moser, Helmut; Schmid, Horst |
Sulpho-free azo compound in metal-free 1:1 complex or 1:2 complex form having at least an average of 1.3 water solubilising basic groups of the formula
The compounds are useful as dyes for leather an paper. |
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| 20 | Sulpho-free basic azo compounds in metal-free or 1:1 or 1:2 metal complex form | EP83100106.0 | 1981-05-06 | EP0093828A1 | 1983-11-16 | Doswald, Paul; Moriconi, Emil; Moser, Helmut; Schmid, Horst |
Sulpho-free mono and disazo compounds in their metal-free 1:1 metal complex or 1:2 metal complex form having an average of at least 2 water solubilizing basic groups per dyestuff unit, of the general formula
These compounds are useful as dyes for leather and paper. |
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