81 |
염 및 염료 |
KR1020120004787 |
2012-01-16 |
KR101940107B1 |
2019-01-18 |
|
|
82 |
양이온성 직접 염료 및 증점 중합체를 갖는 케라틴 섬유 염색용 조성물 |
KR1019990027067 |
1999-07-06 |
KR100355642B1 |
2002-10-09 |
랑제라르; 꼬뜨레쟝 |
본 발명은, 염색에 적합한 매질 중에 주어진 화학식의 양이온성 직접 염료 하나 이상을 포함하는 케라틴 섬유, 특히 모발과 같은 인간 케라틴 섬유의 염색용 조성물에 관한 것으로, 이 조성물은 하기로 구성되는 군으로부터 선택된 증점 중합체 하나 이상을 추가로 함유하는 것을 특징으로 한다 :
- 하나 이상의 친수성 단위 및 지방 사슬을 함유하는 단위 하나 이상을 포함하는 비이온성 양쪽친화성 중합체,
- 하나 이상의 친수성 단위 및 지방 사슬을 함유하는 단위 하나 이상을 포함하는 음이온성 양쪽친화성 중합체,
- 하나 이상의 친수성 단위 및 지방 사슬을 함유하는 단위 하나 이상을 포함하는 양이온성 양쪽친화성 중합체.
본 발명은 또한 이를 사용한 염색 방법 및 염색 장치에 관한 것이다. |
83 |
양이온성 직접 염료 및 증점 중합체를 갖는 케라틴 섬유 염색용 조성물 |
KR1019990027052 |
1999-07-06 |
KR100355641B1 |
2002-10-09 |
롱도크리스띤; 랑제라르; 꼬떼레쟝 |
A dye composition for keratinic fibers, especially hair, comprises at least one compound (I), (II), (III), (III') or (IV), and at least one polymeric thickener. A dye composition for keratinic fibers, especially hair, comprises at least one compound of formula (I), (II), (III), (III') or (IV), and at least one polymeric thickener. D, D1, D2 = N or -CH; R1, R2 = H, 1-4C alkyl, (optionally substituted), 4'-aminophenyl or forms with a carbon of the benzene a heterocycle (optionally containing O or N and optionally substituted); R3, R'3 = H, halo, cyano, 1-4C alkyl, 1-4C alkoxy or acetyloxy; X<->, X'<-> = anion; A = a group of formula (A1); R4 = 1-4C alkyl (optionally substituted); R5 = 1-4C alkoxy; R6, R11, R12, R16, R17 = H or 1-4C alkyl; R7 = H, alkyl (optionally substituted) or 4'-aminophenyl; NR6R7 = heterocycle (optionally containing O or N, and optionally substituted); R8, R9 = H, halo, 1-4C alkyl, 1-4C alkoxy or cyano; B' = a group of formula (B'3); R, R', R10 = 1-4C alkyl; R13 = H, halo, 1-4C alkoxy or amino; R14 = H, 1-4C alkyl or forms with a carbon of the benzene a heterocycle (optionally containing O or N, and optionally substituted); R15 = H or halo; m, r = 0 or 1; E = a group of formula (E1); G = a group of formula (G1)-(G3); R18 = 1-4C alkyl, phenyl (optionally substituted by halo or 1-4C alkyl); R19, R21 = 1-4C alkyl or phenyl; R20, R31, R32 = H, 1-4C alkyl or phenyl; R20 + R21 = in (G1) a substituted benzene or in (G2) an optionally substituted benzene; Z = O, S or -NR19; M, K', P' = -CH, -CR or -NR22(X'<->)r; R22 = O-, 1-4C alkyl or 1-4C alkoxy; R23, R24 = H, halo, 1-4C alkyl, 1-4C alkoxy or nitro; J = a group of formula (J1) or 5- or 6-membered nitrogen and/or carbonyl containing heterocycle (optionally substituted), preferably a group of formula (J2); R25 = H, halo, 1-4C alkyl, 1-4C alkoxy, hydroxy, nitro, -NHR28, -NR29R30, -NHCO(1-4C alkyl); R26 = H, halo, 1-4C alkyl, 1-4C alkoxy; R27 = H, hydroxy, -NHR28 or -NR29R30; R28 = H, 1-4C alkyl, 1-4C monohydroxyalkyl, 2-4C polyhydroxyalkyl or phenyl; R25 + R26, R26 + R27, R26 + R28 = 5- or 6-membered heterocycle containing at least one N, S or O; R29, R30 = 1-4C alkyl, 1-4C monohydroxyalkyl or 2-4C polyhydroxyalkyl; Y' = -CO- or -C(CH3)=; U' = not defined; n = 0 or 1; and with provisos. The full definition is given in the Definition (Full Definition) Field. Independent claims are also included for: (1) a method of dyeing hair by applying the composition and optionally rinsing and washing; (2) a kit comprising two compartments to be mixed before application, one comprising a cationic direct colorant and optionally at least one oxidation base and the other comprising at least one oxidizing agent. One of the compartments comprises the polymeric thickener. |
84 |
양이온성 직접 염료 및 증점 중합체를 갖는 케라틴 섬유 염색용 조성물 |
KR1019990027052 |
1999-07-06 |
KR1020000011515A |
2000-02-25 |
롱도크리스띤; 랑제라르; 꼬떼레쟝 |
PURPOSE: A keratin fiber coloring compound consisting of positive ionic direct dyeing compound and more than one of specific viscosity-increasing polymer is provided, which colors human hair keratin strongly and non-selectively. Also provided are coloring methods and equipment. CONSTITUTION: A specific viscosity-increasing polymer is selected from group consisting of bridged acrylic acid monomer, partially or totally neutralized 2-acrylamido-2-methyl propane sulfonic acid monomer and polymer, monomer of ammonium acrylate and polymer of ammonium acrylate and acrylamide, bridged polymer of acrylic acid and C1-C6 alkyl acrylate, and nonionic monomer and polymer containing monomer with an ethylene unsaturated part of ester and/or amide type A positive ionic direct dyeing compound is desirably 0.001-10wt%(more desirably 0.005-5wt%) and viscosity-increasing polymer is desirably 0.01-10wt%, especially 0.1-5wt% to total weight of coloring compound. |
85 |
양이온성 직접 염료 및 증점 중합체를 갖는 케라틴 섬유 염색용조성물 |
KR1019990026861 |
1999-07-05 |
KR1020000011486A |
2000-02-25 |
롱도크리스띤 |
PURPOSE: A keratin fiber coloring compound consisting of positive ionic direct dyeing compound and more than one of viscosity-increasing polymer(which containing more than one of sugar unit) in adequate medium for coloring is provided, which colors human hair keratin strongly and non-selectively. Also provided are coloring methods and equipment. CONSTITUTION: A keratin fiber coloring compound contains more than one of positive ionic direct dyeing compound(chemical formula 1, 2, 3, or 3a) and more than one of viscosity-increasing polymer(which containing more than one of sugar unit). Positive ionic direct dyeing compound is desirably 0.001-10wt%(more desirably 0.005-5wt%) and viscosity-increasing polymer is desirably 0.01-10wt%, especially 0.1-5wt% to total weight of coloring compound. |
86 |
반응성 염료, 이의 제조방법 및 이의 용도 |
KR1020087005713 |
2006-08-02 |
KR101326561B1 |
2013-11-08 |
크리스트나쉐위베르쟝뤽; 치카스아타나씨오스; 뢴트겐게오르그 |
화학식 1의 반응성 염료는 면을 염색하기에 특히 적합하며 우수한 다용도 견뢰도 특성을 갖는 염색물을 제공하며, 화학식 1에서,
B는 지방족 브릿지 구성원이고,
R
1 은 C
1 -C
4 알킬, 할로겐 또는 -SO
2 -Z 라디칼이고,
R
2 및 R
3 은 각각 서로 독립적으로 C
1 -C
4 알콕시이고,
R
4 , R
5 및 R
6 은 각각 서로 독립적으로 수소 또는 치환되지 않거나 치환된 C
1 -C
4 알킬이고,
k 및 q는 각각 서로 독립적으로 0 또는 1이고,
p는 0, 1 또는 2이고,
X
1 및 X
2 는 각각 서로 독립적으로 할로겐이고,
T는 할로겐, 섬유 비반응성 치환체 또는 다음 화학식 2a, 화학식 2b, 화학식 2c, 화학식 2d, 화학식 2e 또는 화학식 2f의 섬유 반응성 라디칼이거나, T는 화학식 3의 라디칼이고, 화학식 2a 내지 화학식 2f 및 화학식 3에서,
(R
7 )
0-2 는 할로겐, C
1 -C
4 알킬, C
1 -C
4 알콕시 및 설포 그룹으로부터의 0 내지 2개의 동일하거나 상이한 치환체이고,
Z는 비닐 또는 -CH
2 -CH
2 -U 라디칼이고,
U는 알칼리성 조건하에 제거할 수 있는 그룹이고,
Q는 -CH(Hal)-CH
2 -Hal 또는 -C(Hal)=CH
2 그룹이고,
Hal은 할로겐이고,
R
1 , R
2 , R
3 , R
4 , k, p 및 q는 각각 위에서 언급한 정의를 갖는다.
반응성 염료, 염색, 날염, 견뢰도, 염착 농도(colour yield), 고착율, 소핑 손실(soaping loss) |
87 |
염 및 염료 |
KR1020120004787 |
2012-01-16 |
KR1020120084262A |
2012-07-27 |
아카사카,테츠오; 오용호; 김상동 |
PURPOSE: Salt having organic metal anionic Mn- and onium cation is provided to enhance solubility in an organic solvent. CONSTITUTION: Salt which is useful as a dye is n valent organic metal anion Mn- containing metal atoms and salt with onium cations. An organic metal anion is denoted by chemical formula 1(M^n- nz^+). In chemical formula, Mn- is an organic metal cation. Z+ is an hydrone or alkali metal cation. A dye contains the salt with the organic metal anion Mn- and onium cation as an active ingredient. |
88 |
양이온성 직접 염료 |
KR1020067000502 |
2004-07-14 |
KR101087158B1 |
2011-11-25 |
엘리우빅토르파울; 프뢰링베아테 |
본 발명은 하기 화학식(1)의 양이온성 염료에 관한 것이다:
상기 식에서,
R
1 은 비치환 또는 치환된 C
1 -C
14 알킬 또는 아릴 라디칼이고,
X
- 는 음이온이고,
R
3 은 비치환 또는 치환된 C
1 -C
14 알킬, 아릴 라디칼, C
1 -C
6 알콕시, 시아니드, 니트로 또는 할라이드이며,
n은 1 또는 2이며,
n이 1인 경우, R
2 는 수소, 비치환 또는 치환된 C
1 -C
14 알킬이거나, 또는
n이 2인 경우, R
2 는 비치환 또는 치환된 C
1 -C
14 알킬렌이다.
본 발명은 또한 특히 기타 염료를 포함하는 그의 조성물, 그의 제조방법 및 케라틴, 모, 가죽, 실크, 종이, 셀룰로오스 또는 폴리아미드와 같은 유기 물질, 바 람직하게는 인간 모발을 염색하기 위한 그의 용도에 관한 것이다.
모발, 염색, 양이온성 직접 염료 |
89 |
2,5-디아미노 치환 아조 염료 |
KR1020067021341 |
2005-03-23 |
KR101074726B1 |
2011-10-19 |
엘리우,빅토르파울; 사우더,토마스; 카우프만,오미니크; 프뢸링,베아테 |
본 발명은 하기 화학식(1)의 아조 염료에 관한 것이다:
(1)
상기 식에서,
R
1 은 수소, C
1 -C
14 알킬, 히드록시-C
1 -C
14 알킬, C
2 -C
14 알케닐, -(CH
2 )
n1 -O-(CH
2 )
n2 -(CH
3 )(화학식1a의 라디칼); (화학식1b의 라디칼), C
6 -C
10 아릴, 또는 C
6 -C
10 아릴-C
1 -C
6 알킬이고;
R
3 는 수소, C
1 -C
14 알킬, C
2 -C
14 알케닐, C
6 -C
10 아릴, C
6 -C
10 아릴-C
1 -C
6 알킬, 또는 CO-R
6 이고;
R
4 는 CO-R
6 이고;
R
5 는 C
1 -C
14 알킬, C
2 -C
14 알케닐, C
6 -C
10 아릴, 또는 C
6 -C
10 아릴-C
1 -C
6 알킬이고;
R
6 는 수소, C
1 -C
14 알킬, C
2 -C
14 알케닐 또는 C
6 -C
10 아릴이고;
R
7 , R
8 , R
9
및
R
10 은 서로 독립적으로 수소 또는 C
1 -C
5 알킬이고;
m은 1 또는 2이고;
An
- 은 음이온이고;
m이 1인 경우,
R
2 는 수소, C
1 -C
14 알킬, C
2 -C
14 알케닐, 화학식(1a)의 라디칼, 화학식(1b)의 라디칼, C
6 -C
10 아릴, 또는 C
6 -C
10 아릴-C
1 -C
6 알킬이고;
m이 2인 경우,
R
2 는 직접 결합, 또는 1 이상의 C
1 -C
4 알킬에 의해 임의로 치환되거나 사슬 중간에 C
5 -C
10 아릴렌, -O- 또는 -NR
9 R
10 -을 임의로 갖는 C
1 -C
14 알킬렌이고;
R
9
및
R
10 은 서로 독립적으로 수소 또는 C
1 -C
5 알킬이고; 그리고
n1, n2, n3 및 n4는 서로 독립적으로 0∼5이다.
이들 화합물은 유기 물질, 바람직하게는 인간 모발의 염색에 유용하다.
아조 염료 |
90 |
양이온성 직접 염료 및 독립 중합체를 함유하는 케라틴 섬유용염료 조성물 |
KR1019990011879 |
1999-04-06 |
KR100293004B1 |
2001-06-15 |
롱도크리스띤 |
본 발명은 염색에 적합한 매질내에, 주어진 화학식의 하나 이상의 양이온성 직접 염료를 포함하고, 또한 하나 이상의 특정한 양이온성 또는 양쪽성 독립 중합체를 함유하는 것을 특징으로 하는, 케라틴 섬유, 구체적으로는 모발과 같은 사람의 케라틴 섬유용 염료 조성물에 관한 것이다.
본 발명은 또한 상기 조성물을 이용한 염색 방법 및 장치에 관한 것이다. |
91 |
양이온성 직접 염료 및 증점 중합체를 갖는 케라틴 섬유 염색용 조성물 |
KR1019990027067 |
1999-07-06 |
KR1020000011517A |
2000-02-25 |
랑제라르; 꼬뜨레쟝 |
PURPOSE: A composition for dyeing keratin fibers is provided, which can exhibit excellent resistance to many factors against hairs including light, bed weather and shampoo, and provide deeper and more non-selective coloring with hairs. Also, a process and an apparatus for dyeing using the composition are provided. CONSTITUTION: The composition comprises in a suitable medium for dyeing, 0.001-10wt% of one or more cationic direct dye selected from the compounds of formula 1, 2, 3a, 3b and 4, based on a total weight of the composition, and additionally 0.01-10wt% of one or more thickening polymer selected from the following, based on a total weight of the composition:(1) a nonionic amphoteric polymer that comprises one or more hydrophilic unit and one or more an aliphatic chain-containing unit, (2) an anionic amphoteric polymer that comprises one or more hydrophilic unit and one or more an aliphatic chain-containing unit and (3) a cationic amphoteric polymer that comprises one or more hydrophilic unit and one or more an aliphatic chain-containing unit. |
92 |
Pyridone - Mechidoazo dye |
JP27148796 |
1996-09-20 |
JP4257872B2 |
2009-04-22 |
ライナー・ハンプレヒト |
|
93 |
Dye composition for keratin fiber, containing cationic direct dye and substantive polymer |
JP2006060143 |
2006-03-06 |
JP2006169262A |
2006-06-29 |
RONDEAU CHRISTINE |
PROBLEM TO BE SOLVED: To provide a dye composition having uniform dyeability and excellent durability, and to provide a method for dyeing.
SOLUTION: The composition for dyeing keratin fiber is obtained by containing a cationic direct dye in a medium suitable for dyeing, wherein a cationic or amphoteric substantive polymer is included, and the obtained is coated on the keratin fiber. The cationic direct dye is represented by formula (I) or the like and the substantive polymer is a cationic cellulose derivative, copolymer of dimethyl diallyl ammonium halide with (meth)acrylic acid, homopolymer and copolymer of methacryloyloxyethyltrimethyl ammonium halide, quaternary ammonium polymer having a prescribed structure, and vinylpyrrolidone copolymer containing a cationic unit.
COPYRIGHT: (C)2006,JPO&NCIPI |
94 |
Keratin fiber dye composition containing cationic direct dye and thickening polymer |
JP2004233178 |
2004-08-10 |
JP2004339236A |
2004-12-02 |
LANG GERARD; COTTERET JEAN |
PROBLEM TO BE SOLVED: To provide a dye composition having uniformly dyeing properties and excellent fastness.
SOLUTION: The keratin fiber dye composition contains a cationic direct dye of a prescribed chemical formula in a medium suitable for dyeing, wherein the composition also contains at least one specified thickening polymer and the obtained is coated on the keratin fiber.
COPYRIGHT: (C)2005,JPO&NCIPI |
95 |
Recording sheet |
JP7179699 |
1999-03-17 |
JP2000263922A |
2000-09-26 |
IGUCHI YUJI |
PROBLEM TO BE SOLVED: To provide an ink jet recording sheet of color metallic luster having little or no failure in the color registering of an ink receiving layer surface. SOLUTION: The ink jet recording sheet of color metallic luster includes an adhesive resin layer, metal foil, and an ink receiving layer laminated by turns on one surface of a supporting body, and a coloring pigment or coloring dye is contained in the in receiving layer. Furthermore, such a coloring pigment or a coloring dye has a cationic property. |
96 |
Composition for dyeing keratinous fiber containing cationic direct dye and thickening polymer |
JP19681599 |
1999-07-09 |
JP2000086472A |
2000-03-28 |
LANG GERARD; COTTERET JEAN |
PROBLEM TO BE SOLVED: To obtain a composition capable of applying stronger coloration with scarcely any selectivity and useful for dyeing karatinous fibers such as human hair by including a specific direct dye and a specified thickening polymer in a medium. SOLUTION: This composition is obtained by including (B) a cationic direct dye selected from a compound represented by formula I D is N or the like; R1 and R2 are each H or the like; R3 and R3' are each cyano or the like; X- is an anion such as a chloride; A is a structure represented by formula II [R4 is an (OH-substituted) 1-4C alkyl or the like] or the like, with the proviso that R1 and R2 are not simultaneously H when D is CH; A is formula II or the like; R3 is other than an alkoxy}, a compound represented by formula III [R6 is a 1-4C alkyl or the like; R7 is H or the like; R8 and R9 are each a halogen or the like such as F; B is a structure represented by formula IV (R10 is a 1-4C alkyl) or the like] or the like and (C) a thickening polymer selected from a nonionic amphiphilic polymer containing a unit having an aliphatic chain and a hydrophilic unit, an anionic amphiphilic polymer containing a unit having an aliphatic chain and a hydrophilic unit or the like in (A) a medium. |
97 |
Dyeing composition for keratin fiber, containing cationic direct dye and thickening polymer |
JP19681799 |
1999-07-09 |
JP2000063246A |
2000-02-29 |
RONDEAU CHRISTINE |
PROBLEM TO BE SOLVED: To obtain a composition for dyeing a keratin fiber such as human hair, showing a good resistance to attacking factors to the hair, not having selectivity and capable of dyeing more potently by including a specific cationic direct dye and a thickening polymer in a medium suitable for the dyeing.
SOLUTION: This dyeing composition for a keratin fiber containing a cationic direct dye and a thickening polymer is obtained by including, in a medium suitable for the dyeing, (A) 0.001-10 wt.% cationic direct dye based preferably on the total weight of the composition and selected from compounds of (i) a compound of formula I [D is N or CH group; R1, R2 are each H, a heterocyclic ring or the like; R3, R'3 are each H, Cl or the like; X- is chloride or the like; A is a group of formula II (R4 is a 1-4C alkyl) or the like] and (ii) a compound of formula III (R6 is H or a 1-4C alkyl; R7 is a heterocyclic ring or the like; R8, R9 are each H, bromine or the like; B is a group of formula IV (R10 is a 1-4C alkyl) or the like] and (B) at least one kind of a thickening polymer having at least one sugar unit (preferably a nonionic guar gum, etc.).
COPYRIGHT: (C)2000,JPO |
98 |
Basic dye |
JP31140390 |
1990-11-19 |
JPH04183755A |
1992-06-30 |
INOUE KANAME |
NEW MATERIAL:A compound shown by formula I (R
1 is H or 1-4C alkyl; R
2 to R
4 are H, 1-4C alkenyl quaternized residue, etc.; F is monoazo dye, disazo dye, etc.; X
- is anion; a is 1-4; b is 1-3; c is 0-2).
EXAMPLE: A compound shown by formula II.
USE: Basic dye having extremely high dyeing rate, dyeing ratio and dyeing concentration and excellent light resistance and fastness to wetting. Dyed waste water is colorless.
PREPARATION: First, a compound shown by the formula F(SO
3H)
d (d is 0-3) is reacted in chlorosulfonic acid to give sulfonic acid chloride shown by formula III. Then this compound is condensed with an amine shown by formula VI or formula V preferably at 20-80°C at pH 4-10 additionally in the presence of an acid binder.
COPYRIGHT: (C)1992,JPO&Japio |
99 |
JPH0356595B2 - |
JP6574383 |
1983-04-15 |
JPH0356595B2 |
1991-08-28 |
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100 |
JPS6141940B2 - |
JP8738176 |
1976-07-23 |
JPS6141940B2 |
1986-09-18 |
GYUNTAA BEEMUKE; UDO BINFURIITO HENDORITSUKUSU |
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