序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
61 DISULFIDE DYES EP12779423.8 2012-05-02 EP2705094A4 2015-09-23 MARQUAIS-BIENEWALD, Sophie; CREMER, Christian; FRÖHLING, Beate
62 AZOXYFARBSTOFFE UND DEREN CU-KOMPLEXE EP00912518.8 2000-02-28 EP1161499B1 2003-12-03 TRESCH, Rainer; ETZBACH, Karl-Heinz; SENS, Rüdiger; KRÄH, Claudia
The invention relates to azoxy dyes of general formula (I) in their free acid form, in which n is 0 or 1, R<1> is methoxy, hydroxyl and carboxyl, R<2> is carboxyl, amine, C1-C4 alkylamine, allylamine, benzylamine and methoxycarbonylmethylamine and the phenyl rings A can be substituted with C1-C8 alkyl, phenyl that can be substituted with methyl or halogen, hydroxyl, amine, nitro, halogen, carboxyl, N-benzylcarbamoyl, phenylcarbamoyl and naphthylcarbamoyl that can be unsubstituted or substituted with nitro, halogen, C1-C4 alkoxy, acetoxy, or they can be benzo-anellated. The invention also relates to their Cu complexes, to a method for producing the Cu complex dyes, to azoxy dyes of formula (I) in their partially or completely deacylated form, to their Cu complexes, to dyes containing said azoxy dyes and/or to their Cu complexes and to their use for dyeing and printing natural or synthetic substrates.
63 Verfahren zur Herstelung von Aminourethanen EP93101291.8 1993-01-28 EP0555699B1 1998-01-07 Jäger, Horst, Dr.; Henk, Hermann, Dr.
64 Verfahren zur Herstellung von Disazofarbstoffen EP81810244.4 1981-06-15 EP0043796B1 1985-05-08 Seitz, Karl, Dr.
65 DYE COMPOUNDS AND METHODS OF USING PCT/GB2024051181 2024-05-03 WO2024228036A2 2024-11-07 BLACKBURN RICHARD SIMON; RAYNER CHRISTOPHER MARK; CROMPTON NATHANIEL BEAUMONT; OATES HARRISON GEORGE
The present invention relates to compounds of formula (I): (I) wherein R1 is a dye, and L1, R2 and R3 are as defined herein. The compounds of the invention reversibly convert from a hydrophobic form to a hydrophilic form upon contact with water and carbon dioxide. The present invention also relates to methods of dyeing fibres, and methods of decolouring dyed fibres. The method is particularly useful for dyeing polyester fibres.
66 DISAZO DYESTUFFS FOR INK JET PRINTING PCT/GB2000/004082 2000-10-23 WO01030916A1 2001-05-03
A compound of Formula (1) and salts thereof, wherein: A is a substituted phenyl group carrying a group of the formula -NR<3>R<4> and an ortho carboxy group; n is 0 or 1; L<1> and L<2> are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L<1> and L<2> together with the N atom to which they are attached form an optionally substituted 5- or 6- membered ring; R<1> and R<2> are each independently optionally substituted alkyl or optionally substituted alkoxy; and R<3> and R<4> are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R<3> and R<4> together with the N atom to which they are attached form an optionally substituted 5- or 6- membered ring; or R<3> is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl; and R<4> is an acyl group. The use of these compounds in inks and the use of inks comprising these compounds in ink jet printing.
67 AZOXY DYES AND THEIR CU COMPLEXES PCT/EP2000/001636 2000-02-28 WO00055259A1 2000-09-21
The invention relates to azoxy dyes of general formula (I) in their free acid form, in which n is 0 or 1, R<1> is methoxy, hydroxyl and carboxyl, R<2> is carboxyl, amine, C1-C4 alkylamine, allylamine, benzylamine and methoxycarbonylmethylamine and the phenyl rings A can be substituted with C1-C8 alkyl, phenyl that can be substituted with methyl or halogen, hydroxyl, amine, nitro, halogen, carboxyl, N-benzylcarbamoyl, phenylcarbamoyl and naphthylcarbamoyl that can be unsubstituted or substituted with nitro, halogen, C1-C4 alkoxy, acetoxy, or they can be benzo-anellated. The invention also relates to their Cu complexes, to a method for producing the Cu complex dyes, to azoxy dyes of formula (I) in their partially or completely deacylated form, to their Cu complexes, to dyes containing said azoxy dyes and/or to their Cu complexes and to their use for dyeing and printing natural or synthetic substrates.
68 PROCESS FOR PREPARING REACTIVE AZO DYES PCT/EP1996000296 1996-01-25 WO1996024637A1 1996-08-15 BAYER AKTIENGESELLSCHAFT
Reactive azo dyes having the formula (I), in which A stands for the residue of a diazo component and X is a fibre-reactive heterocyclic residue, are prepared by saponifying maleinylated azo dyes having the formula (IV), then by reacting them with reactive components having the formula X-hal without previously isolating them. The remaining substituents have the meanings given in the description.
69 DISULFIDE DYES EP12779423.8 2012-05-02 EP2705094B1 2021-12-15 MARQUAIS-BIENEWALD, Sophie; CREMER, Christian; FRÖHLING, Beate
70 AZOXYFARBSTOFFE UND DEREN CU-KOMPLEXE EP00912518.8 2000-02-28 EP1161499A1 2001-12-12 TRESCH, Rainer; ETZBACH, Karl-Heinz; SENS, Rüdiger; KRÄH, Claudia
The invention relates to azoxy dyes of general formula (I) in their free acid form, in which n is 0 or 1, R1 is methoxy, hydroxyl and carboxyl, R2 is carboxyl, amine, C¿1?-C4 alkylamine, allylamine, benzylamine and methoxycarbonylmethylamine and the phenyl rings A can be substituted with C1-C8 alkyl, phenyl that can be substituted with methyl or halogen, hydroxyl, amine, nitro, halogen, carboxyl, N-benzylcarbamoyl, phenylcarbamoyl and naphthylcarbamoyl that can be unsubstituted or substituted with nitro, halogen, C1-C4 alkoxy, acetoxy, or they can be benzo-anellated. The invention also relates to their Cu complexes, to a method for producing the Cu complex dyes, to azoxy dyes of formula (I) in their partially or completely deacylated form, to their Cu complexes, to dyes containing said azoxy dyes and/or to their Cu complexes and to their use for dyeing and printing natural or synthetic substrates.
71 VERFAHREN ZUR HERSTELLUNG VON REAKTIVAZOFARBSTOFFEN EP96902250.8 1996-01-25 EP0808343B1 1999-05-26 KUNDE, Klaus
72 Mit einer Urethane und einer Aminogruppe substituierte aromatische Verbindungen EP93101291.8 1993-01-28 EP0555699A3 1994-05-25 Jäger, Horst, Dr.; Henk, Hermann, Dr.

Verbindungen der Formel worin die Substituenten die in der Beschreibung angegebene Bedeutung haben, sind interessante Farbstoffe und wertvolle Zwischenprodukte zur Herstellung von Reaktiv- und Substantivfarbstoffen.

73 Mit einer Urethane und einer Aminogruppe substituierte aromatische Verbindungen EP93101291.8 1993-01-28 EP0555699A2 1993-08-18 Jäger, Horst, Dr.; Henk, Hermann, Dr.

Verbindungen der Formel worin die Substituenten die in der Beschreibung angegebene Bedeutung haben, sind interessante Farbstoffe und wertvolle Zwischenprodukte zur Herstellung von Reaktiv- und Substantivfarbstoffen.

74 Verfahren zur Herstellung von Azofarbstoffen EP90111802.6 1990-06-22 EP0406629A2 1991-01-09 Jäger, Horst, Dr.; Arlt, Dieter, Prof.Dr.

Ein neues Verfahren zur Herstellung von Aminoazofarbstoffen der Formel

worin

D den Rest einer Diazokomponente und

K einen Sulfonaphthylenrest bedeutet und

R für Wasserstoff oder Methyl steht,

ist dadurch gekennzeichnet, daß man die Diazoverbindung eines Amins der Formel

D-NH₂      (2)

mit einer Kupplungskomponente der Formel

worin

R₁ für gegebenenfalls substituiertes C₁-C₄-Alkyl oder Phenyl steht,

zu einem Farbstoff der Formel

vereinigt und daraus durch Verseifen im alkalischen Medium Farbstoffe (1) herstellt.

75 Verfahren zur Herstellung von Azofarbstoffen EP87103381.7 1987-03-10 EP0237910A2 1987-09-23 Leverenz, Klaus, Dr.

Azofarbstoffe der Formel I worin

D = Diazokomponente

R₁ und R₂ = Alkyl oder Aralkyl

R₃ = H, R oder OR₁

R₄ = KW-Rest oder Acyl

erhält man auf einfache Weise durch Aminolyse von Azover­bindungen der genannten Formel, worin anstelle des Restes -NR₁R₂ eine Ethergruppe enthalten ist.

76 Method of preparing disazo dyestuffs EP81810244 1981-06-15 EP0043796A3 1982-01-20 Seitz, Karl, Dr.
77 Verfahren zur Herstellung von Disazofarbstoffen EP81810244.4 1981-06-15 EP0043796A2 1982-01-13 Seitz, Karl, Dr.

Ein Verfahren zur Herstellung von Disazofarbstoffen der Formel dadurch gekennzeichnet, daß man 1-Amino-8-hydroxynaphthalin-3,6-disulfonsäure mit einem Äquivalent einer diazotierten Monoacetyl-m- oder -p-diaminobenzol-sulfonsäure der Formel in stark saurer, Naphthalinsulfonsäure enthaltender Lösung kuppelt, die erhaltene Monoazoverbindung mit einem weiteren Äquivalent der gleichen Diazokomponente der Formel (5) in schwach alkalischer Lösung kuppelt, und den erhaltenen Disazofarbstoff, zwecks Abspaltung der beiden Acetylgruppen, verseift, gibt Disazofarbstoffe der Formel (4) rein und in hoher Ausbeute; die Disazofarbstoffe der Formel (4) eignen sich als Zwischenprodukte zur Herstellung von Reaktivfarbstoffen.

78 BR0008951 2000-02-28 BR0008951B1 2010-06-15
79 AT01983540 2001-10-10 ATE337049T1 2006-09-15 MOECKLI PETER
80 AT00971556 2000-10-23 ATE264374T1 2004-04-15 MISTRY PRAHALAD MANIBHAI
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