序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 Deaminated trisazo dye US26299951 1951-12-22 US2676957A 1954-04-27 ARMENTO WILLIAM H
42 Diphenyl disazo dyes containing deaminated amine coupling components US5337348 1948-10-07 US2607769A 1952-08-19 ARMENTO WILLIAM H
43 Process of producing fast dyeings and the dyed fiber obtained thereby US36737640 1940-11-27 US2352701A 1944-07-04 ERICH FISCHER; WERNER KIRST; WALTER GMELIN
44 Method of replacing one amino group in phenyl-azo-alpha-alpha-diamino pyridine with alpha hydroxyl group US37760029 1929-07-11 US1856601A 1932-05-03 TISZA EDMOND T; BERNARD JOOS
45 DISPERSE DYES FOR DYEING POLYESTER FIBRES PCT/GB2024051181 2024-05-03 WO2024228036A3 2024-12-12 BLACKBURN RICHARD SIMON; RAYNER CHRISTOPHER MARK; CROMPTON NATHANIEL BEAUMONT; OATES HARRISON GEORGE
The present invention relates to compounds of formula (I): wherein R1 is a dye, and L', R2 and R3 are as defined herein. The compounds of the invention reversibly convert from a hydrophobic form to a hydrophilic form upon contact with water and carbon dioxide. The present invention also relates to methods of dyeing fibres, and methods of decolouring dyed fibres. The method is particularly useful for dyeing polyester fibres.
46 CATIONIC IMIDAZOLE AZO DYES PCT/EP2001/011708 2001-10-10 WO02031056A1 2002-04-18
Dyes of formula (1) or (2) wherein R1, R1', R2 and R2' are each independently of the others hydrogen, C1-C4alkyl, halogen or nitro, R3, R3', R4 and R4' are each independently of the others C1-C4alkyl unsubstituted or substituted by OH, C1-C4alkoxy, halogen, CN or phenyl, R5 is hydrogen or C1-C4alkyl, R6 is unsubstituted or amino-substituted C5-C12alkyl; or unsubstituted or amino-substituted C5-C8cycloalkyl; or phenyl-substituted C1-C4alkyl; or wherein R5 and R6 together with the nitrogen atom linking them from a piperazine ring, which is substituted, at the nitrogen atom that is not bonded to the phenyl group, by C1-C4-alkyl or phenyl, the alkyl and phenyl radicals mentioned as substituents of the nitrogen atom of the piperazine ring being unsubstituted or substituted by amino, X1, X2, X3 and X4 are each independently of the others hydrogen, C1-C4alkyl, C1-C4alkoxy or halogen, Y1 is a bridging member of formula (I) or -NH-(CH2)6-NH-, and X<-> is an anion, as wels as methods of dyeing or printing textile materials, leather, paper or glass fibres with those dyes, are described.
47 DISAZODYESTUFFS FOR INK JET PRINTING PCT/GB2000/004083 2000-10-23 WO01030917A1 2001-05-03
A compound of Formula (1) and salts thereof, wherein: A is a substituted phenyl group carrying a group of the formula -NR<3>R<4> and an ortho group selected from sulpho, phosphonato and phosphinato; n is 0 or 1; L<1> and L<2> are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L<1> and L<2> together with the N atom to which they are attached form an optionally substituted 5- or 6- membered ring; R<1> and R<2> are each independently optionally substituted alkyl or optionally substituted alkoxy; and R<3> and R<4> are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R<3> and R<4> together with the nitrogen atom to which they are attached form an optionally substituted 5- or 6- membered ring; or R<3> is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl and R<4> is an acyl group. The use of these compounds in inks and the use of inks comprising these compounds in ink jet printing.
48 Process for the preparation of reactive azo dyes US875812 1997-08-05 US5872228A 1999-02-16 Klaus Kunde
Reactive dyestuffs of the formula (I) ##STR1## wherein A denotes the radical of a diazo component andX is a fibre-reactive heterocyclic radicalare obtained by hydrolysis of maleylated azo dyestuffs of the formula (IV) ##STR2## and subsequent reaction with reactive components of the formula X-Hal without intermediate isolation, the other substituents having the meaning given in the description.
49 Process for preparing phenyl- and naphthylazo-aminonaphthol sulphonic acids US700063 1985-02-11 US4841027A 1989-06-20 Yutaka Kayane; Takashi Omura; Yasuo Tezuka; Hideharu Sone
Improvement in a process for producing an arylazo-aminonaphtholsulfonic acid represented by a free acid of the formula, ##STR1## wherein A is a phenyl or naphthyl group unsubstituted or substituted by one to four members selected from alkyl, alkoxy, phenoxy, sulfonic acid, carboxylic acid, arylamino, amino, nitro and hydroxyl groups and halogen atoms, and m is 0 or 1, which comprises reacting an aminonaphtholsulfonic acid represented by a free acid of the formula, ##STR2## wherein m is as defined above, with a dibasic acid anhydride to obtain an acylaminonaphtholsulfonic acid, coupling a diazonium compound of amine of the formula,A'--NH.sub.2wherein A' is a phenyl or naphthyl group unsubstituted or substituted by one to four members selected from alkyl, alkoxy, phenoxy, sulfonic acid, carboxylic acid, arylamino, acrylamino, nitro and hydroxyl groups and halogen atoms, with the acylaminonaphtholsulfonic acid, and then subjecting the resulting coupling product to hydrolysis in the presence of an acid or an alkali. The arylazo-aminonaphtholsulfonic acid is useful as acid dyes or acid mordant dyes in itself as well as an important intermediate for the production of reactive dyes or direct dyes.
50 1-(4'-Diazoniumphenyl)-pyridinium salts and the process of preparation US514664 1974-10-15 US3985724A 1976-10-12 Hermann Hoffmann; Byron G. Held; Harry E. Green; Harold E. Van Essen
Novel diazonium compounds and methods for their preparation are disclosed. Specifically, 1-(4'-diazoniumphenyl)-1,2-dihydro pyrid-2-imino-sulfinate is prepared by rearrangement of 2-(4'-diazobenzene-sulfonylamino)-pyridine, and 1-(4'-diazoniumphenyl)-2-amino-pyridinium salts are obtained by reaction of 1-(4'-diazoniumphenyl)-1,2-dihydro-pyrid-2-imino-sulfinate with aqueous acids. The novel compounds are useful as precursors for azo dyestuffs.
51 Basic indazole containing monoazo dyestuffs US3524843D 1965-08-06 US3524843A 1970-08-18 KREMER GILBERT VICTOR HENRI; SUREAU ROBERT FREDERIC MICHEL
52 Anthraquinone azo barbituric acid derivative dyes US3428620D 1966-02-18 US3428620A 1969-02-18 BRAUN WILLY; PAETZKE INGO
53 Process for the manufacture of 4-amino-3-nitroazobenzenes US39376164 1964-09-01 US3352847A 1967-11-14 WILHELM LIECHTI HANS
54 Process and apparatus for the production of parts from synthetic materials of any kind reinforced with fibres US61045756 1956-09-18 US3107057A 1963-10-15 HUGO HANUSCH
55 Solid, stable diazonium compounds US76221158 1958-09-22 US2961436A 1960-11-22 HERBERT KRACKER; HANS ALBERT
56 Azo dyestuffs US2735845D US2735845A 1956-02-21
57 Verfahren zur Herstellung von Azofarbstoffen EP90111802.6 1990-06-22 EP0406629B1 1995-02-22 Jäger, Horst, Dr.; Arlt, Dieter, Prof.Dr.
58 Verfahren zur Herstellung von Azofarbstoffen EP90111802.6 1990-06-22 EP0406629A3 1993-02-17 Jäger, Horst, Dr.; Arlt, Dieter, Prof.Dr.

Ein neues Verfahren zur Herstellung von Aminoazofarbstoffen der Formel

worin

D den Rest einer Diazokomponente und

K einen Sulfonaphthylenrest bedeutet und

R für Wasserstoff oder Methyl steht,

ist dadurch gekennzeichnet, daß man die Diazoverbindung eines Amins der Formel

D-NH₂      (2)

mit einer Kupplungskomponente der Formel

worin

R₁ für gegebenenfalls substituiertes C₁-C₄-Alkyl oder Phenyl steht,

zu einem Farbstoff der Formel

vereinigt und daraus durch Verseifen im alkalischen Medium Farbstoffe (1) herstellt.

59 Verfahren zur Herstellung von Azofarbstoffen EP87103381.7 1987-03-10 EP0237910B1 1990-05-30 Leverenz, Klaus, Dr.
60 Process for producing azo dyestuffs EP87103381 1987-03-10 EP0237910A3 1988-07-13 Leverenz, Klaus, Dr.
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