序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 FR2189472B1 - FR7319178 1973-05-25 FR2189472B1 1977-02-11
102 IT2454873 1973-05-24 IT987881B 1975-03-20
103 SU1662484 1971-05-27 SU425408A3 1974-04-25
104 FR2197048A1 - FR7326982 1973-07-24 FR2197048A1 1974-03-22
105 FR2189472A1 - FR7319178 1973-05-25 FR2189472A1 1974-01-25
106 PROCEDIMIENTO PARA LA PREPARACION DE NUEVOS COMPUESTOS DE FENAZONIO POLIMEROS. ES391131 1971-05-13 ES391131A1 1973-07-16
107 Verfahren zur Herstellung von Azofarbstoffen CH1017565 1965-07-20 CH455088A 1968-04-30 NICKEL HORST DR; SUCKFUELL FRITZ DR; SCHUENDEHUETTE KARL-HEINZ DR
108 A process for the preparation of azo dyestuffs DEF0043957 1964-09-11 DE1264645B 1968-03-28 NICKEL DR HORST; SUCKFUELL DR FRITZ; SCHUENDEHUETTE DR KARL-HEINZ
109 Verfahren zur Herstellung von neuen Diareno-triazocinen CH550461 1961-05-10 CH402228A 1965-11-15 BOSSARD WERNER DR; HANS BOSSHARD; WEGMUELLER HANS DR
110 Verfahren zur Herstellung von o-Oxy-azo-verbindungen CH1049760 1960-09-16 CH400413A 1965-10-15 SUCKFUELL FRITZ DR; DITTMER HELMUT DR; MESSMER ERNST DR
111 Verfahren zur Herstellung von neuen 2,3 : 6,7-Diareno-1-oxa-4,5-diazepinen CH651960 1960-06-08 CH384750A 1965-02-26 BOSSARD WERNER DR; HANS BOSSHARD; WEGMUELLER HANS DR
112 Process for the production of ú´-hydroxy-azo-naphthalenic compounds GB3647160 1960-10-24 GB929052A 1963-06-19
o-Hydroxy azo compounds are made by treating a diazotate, in solution or suspension, with a diazonium compound, at least one of the starting components being of the naphthalene series. It is stated that some of the products are new. Reaction is usually effected in a distinctly alkaline solution, e.g. pH 9-12, but may, with some diazotates, occur at pH's of 5-9. Stoichiometrical proportions of reactants are normally used. From a diazotate R-N=N-O(-), and a 1-diazonaphthalene compound, a 2-naphthol dye of formula is obtained, a 2-diazonaphthalene compound yielding a 1-naphthol of formula By-products may be obtained from the action of the alkali on the diazo compound, e.g. and The by-products may be isolated or redissolved and their production controlled by varying the proportions of diazotate and diazonium compound. From a diazonium compound and a diazotate of the naphthalene series, similar dyes are obtained. With some of the 1-naphthol azo dyes thus obtained a second azo group may, by a secondary reaction, enter the molecule in a para position to the resulting hydroxy group. The second coupling may be counteracted by varying the proportions of diazotate and diazonium compound. The diazotates may be derived from carbo- and heterocyclic diazo compounds. Derivatives of benzene, naphthalene, anthracene and dehydrothiotoluidine disulphonic acid are mentioned. Substituents, e.g. sulphonic and carboxylic acid, benzenesulphonate, alkyl, nitro, acylamino, halogen and azo groups, may be present in the diazotates. Advantageously syn-diazotates are used. Specified diazotates include 4-sulphophenyl-syn-and anti and 4-nitro-, 2,5-dichloro-and 2-methoxy-4-nitro-phenyl-anti-diazotates. The diazotates need not be used in the isolated form. Thus the diazonium compounds, from which they are derived, may be converted, in situ, to diazotates by treatment with sodium carbonate or hydroxide. Illustrative of diazo compounds, to be so treated, are those derived from aniline, 4-benzoylamino-aniline, 4-aminoazobenzene-41-sulphonic acid, dehydrothiotoluidine-disulphonic acid, 6-nitro-2-naphthylamine-4,8-disulphonic acid and 1-aminoanthraquinone. Diazonium compounds specified include aniline, 4-nitroaniline, 2-naphthylamine-4-sulphonic and 3-carboxylic acids, 1-naphthylamine-3,6,8-trisulphonic acid, 1-aminoanthraquinone, 4-aminoazobenzene-41-sulphonic acid and 8-aminoquinoline-5-sulphonic acid. Numerous examples are provided of the preparation of the dyes, a variety of colours being obtained, and their use in dyeing wool.
113 FR1292492A - FR864182 1961-06-07 FR1292492A 1962-03-26
114 Colorants azoïques et leur procédé de préparation BE576038 1959-02-24 BE576038A 1959-06-15 SUCKFULL FRITZ; NICKEL HORST; SCHMIDT KARL HEINZ; SCHUNDEHUTTE KARL HEINZ
115 Способ получения оптически отбеливающих соединений SU588046 1957-12-19 SU117995A3 1958-11-30 AZIM KOMAR SARKAR; VILYAM ADAMS; DENNIS ARTUR
116 A process for producing metal-containing polyazo DEF0018240 1955-08-20 DE1044316B 1958-11-20 SUCKFUELL DR FRITZ; PUETTER DR ROLF; NICKEL DR HORST
117 A process for producing copper-o, o'-Dioxyazoverbindungen DEF0018236 1955-08-19 DE1017717B 1957-10-17 PUETTER DR ROLF; SUCKFUELL DR FRITZ; NICKEL DR HORST
118 Improvements relating to dyestuffs and processes of dyeing and printing GB2927049 1949-11-15 GB666462A 1952-02-13
Textiles are dyed or printed by applying, from a vat or sulphur dyebath or in an alkaline discharge paste, a compound containing two aromatic nuclei, one nucleus containing a diazotizable amino group or a nitro group reducible in an alkaline bath to a diazotizable amino group and the other nucleus containing a hydroxyl group capable of directing coupling with a diazo compound, and the colour is subsequently developed by treatment with nitrous acid. In examples: (1) the textile material is dyed from a bath containing meta-nitranilide of beta-oxynaphthoic acid and sodium sulphide, with or without the addition of a sulphur brown dyestuff, and the colour is developed by passing the material into a bath containing sodium nitrite and acetic acid; (2) the material is dyed from a bath containing meta-nitranilide of beta-oxynaphthoic acid, caustic soda and sodium hydrosulphite, with or without Caledon Yellow G, and then developed as in (1); and (3) cotton is dyed with Direct Fast Yellow 4GL, printed with a paste containing meta-nitranilide of beta-oxynaphthoic acid, potash, gum tragacanth and sodium formaldehyde sulphoxylate, dried, steamed and then developed in a bath containing sodium nitrite and acetic acid to give a red discharge effect on the yellow ground.
119 Способ получения черных азокрасителей, пригодных для изготовления копировальных бумаг SU385485 1949-08-10 SU90327A1 1949-11-30 VOLFGANG RIKHTER
120 Способ получения моноазокрасителей SU341348 1945-10-29 SU66875A1 1945-11-30 GERSHZON G I; MITELMAN S I; NUSBAUMER S A
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