101 |
FR2189472B1 - |
FR7319178 |
1973-05-25 |
FR2189472B1 |
1977-02-11 |
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102 |
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IT2454873 |
1973-05-24 |
IT987881B |
1975-03-20 |
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103 |
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SU1662484 |
1971-05-27 |
SU425408A3 |
1974-04-25 |
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104 |
FR2197048A1 - |
FR7326982 |
1973-07-24 |
FR2197048A1 |
1974-03-22 |
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105 |
FR2189472A1 - |
FR7319178 |
1973-05-25 |
FR2189472A1 |
1974-01-25 |
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106 |
PROCEDIMIENTO PARA LA PREPARACION DE NUEVOS COMPUESTOS DE FENAZONIO POLIMEROS. |
ES391131 |
1971-05-13 |
ES391131A1 |
1973-07-16 |
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107 |
Verfahren zur Herstellung von Azofarbstoffen |
CH1017565 |
1965-07-20 |
CH455088A |
1968-04-30 |
NICKEL HORST DR; SUCKFUELL FRITZ DR; SCHUENDEHUETTE KARL-HEINZ DR |
|
108 |
A process for the preparation of azo dyestuffs |
DEF0043957 |
1964-09-11 |
DE1264645B |
1968-03-28 |
NICKEL DR HORST; SUCKFUELL DR FRITZ; SCHUENDEHUETTE DR KARL-HEINZ |
|
109 |
Verfahren zur Herstellung von neuen Diareno-triazocinen |
CH550461 |
1961-05-10 |
CH402228A |
1965-11-15 |
BOSSARD WERNER DR; HANS BOSSHARD; WEGMUELLER HANS DR |
|
110 |
Verfahren zur Herstellung von o-Oxy-azo-verbindungen |
CH1049760 |
1960-09-16 |
CH400413A |
1965-10-15 |
SUCKFUELL FRITZ DR; DITTMER HELMUT DR; MESSMER ERNST DR |
|
111 |
Verfahren zur Herstellung von neuen 2,3 : 6,7-Diareno-1-oxa-4,5-diazepinen |
CH651960 |
1960-06-08 |
CH384750A |
1965-02-26 |
BOSSARD WERNER DR; HANS BOSSHARD; WEGMUELLER HANS DR |
|
112 |
Process for the production of ú´-hydroxy-azo-naphthalenic compounds |
GB3647160 |
1960-10-24 |
GB929052A |
1963-06-19 |
|
o-Hydroxy azo compounds are made by treating a diazotate, in solution or suspension, with a diazonium compound, at least one of the starting components being of the naphthalene series. It is stated that some of the products are new. Reaction is usually effected in a distinctly alkaline solution, e.g. pH 9-12, but may, with some diazotates, occur at pH's of 5-9. Stoichiometrical proportions of reactants are normally used. From a diazotate R-N=N-O(-), and a 1-diazonaphthalene compound, a 2-naphthol dye of formula is obtained, a 2-diazonaphthalene compound yielding a 1-naphthol of formula By-products may be obtained from the action of the alkali on the diazo compound, e.g. and The by-products may be isolated or redissolved and their production controlled by varying the proportions of diazotate and diazonium compound. From a diazonium compound and a diazotate of the naphthalene series, similar dyes are obtained. With some of the 1-naphthol azo dyes thus obtained a second azo group may, by a secondary reaction, enter the molecule in a para position to the resulting hydroxy group. The second coupling may be counteracted by varying the proportions of diazotate and diazonium compound. The diazotates may be derived from carbo- and heterocyclic diazo compounds. Derivatives of benzene, naphthalene, anthracene and dehydrothiotoluidine disulphonic acid are mentioned. Substituents, e.g. sulphonic and carboxylic acid, benzenesulphonate, alkyl, nitro, acylamino, halogen and azo groups, may be present in the diazotates. Advantageously syn-diazotates are used. Specified diazotates include 4-sulphophenyl-syn-and anti and 4-nitro-, 2,5-dichloro-and 2-methoxy-4-nitro-phenyl-anti-diazotates. The diazotates need not be used in the isolated form. Thus the diazonium compounds, from which they are derived, may be converted, in situ, to diazotates by treatment with sodium carbonate or hydroxide. Illustrative of diazo compounds, to be so treated, are those derived from aniline, 4-benzoylamino-aniline, 4-aminoazobenzene-41-sulphonic acid, dehydrothiotoluidine-disulphonic acid, 6-nitro-2-naphthylamine-4,8-disulphonic acid and 1-aminoanthraquinone. Diazonium compounds specified include aniline, 4-nitroaniline, 2-naphthylamine-4-sulphonic and 3-carboxylic acids, 1-naphthylamine-3,6,8-trisulphonic acid, 1-aminoanthraquinone, 4-aminoazobenzene-41-sulphonic acid and 8-aminoquinoline-5-sulphonic acid. Numerous examples are provided of the preparation of the dyes, a variety of colours being obtained, and their use in dyeing wool. |
113 |
FR1292492A - |
FR864182 |
1961-06-07 |
FR1292492A |
1962-03-26 |
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114 |
Colorants azoïques et leur procédé de préparation |
BE576038 |
1959-02-24 |
BE576038A |
1959-06-15 |
SUCKFULL FRITZ; NICKEL HORST; SCHMIDT KARL HEINZ; SCHUNDEHUTTE KARL HEINZ |
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115 |
Способ получения оптически отбеливающих соединений |
SU588046 |
1957-12-19 |
SU117995A3 |
1958-11-30 |
AZIM KOMAR SARKAR; VILYAM ADAMS; DENNIS ARTUR |
|
116 |
A process for producing metal-containing polyazo |
DEF0018240 |
1955-08-20 |
DE1044316B |
1958-11-20 |
SUCKFUELL DR FRITZ; PUETTER DR ROLF; NICKEL DR HORST |
|
117 |
A process for producing copper-o, o'-Dioxyazoverbindungen |
DEF0018236 |
1955-08-19 |
DE1017717B |
1957-10-17 |
PUETTER DR ROLF; SUCKFUELL DR FRITZ; NICKEL DR HORST |
|
118 |
Improvements relating to dyestuffs and processes of dyeing and printing |
GB2927049 |
1949-11-15 |
GB666462A |
1952-02-13 |
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Textiles are dyed or printed by applying, from a vat or sulphur dyebath or in an alkaline discharge paste, a compound containing two aromatic nuclei, one nucleus containing a diazotizable amino group or a nitro group reducible in an alkaline bath to a diazotizable amino group and the other nucleus containing a hydroxyl group capable of directing coupling with a diazo compound, and the colour is subsequently developed by treatment with nitrous acid. In examples: (1) the textile material is dyed from a bath containing meta-nitranilide of beta-oxynaphthoic acid and sodium sulphide, with or without the addition of a sulphur brown dyestuff, and the colour is developed by passing the material into a bath containing sodium nitrite and acetic acid; (2) the material is dyed from a bath containing meta-nitranilide of beta-oxynaphthoic acid, caustic soda and sodium hydrosulphite, with or without Caledon Yellow G, and then developed as in (1); and (3) cotton is dyed with Direct Fast Yellow 4GL, printed with a paste containing meta-nitranilide of beta-oxynaphthoic acid, potash, gum tragacanth and sodium formaldehyde sulphoxylate, dried, steamed and then developed in a bath containing sodium nitrite and acetic acid to give a red discharge effect on the yellow ground. |
119 |
Способ получения черных азокрасителей, пригодных для изготовления копировальных бумаг |
SU385485 |
1949-08-10 |
SU90327A1 |
1949-11-30 |
VOLFGANG RIKHTER |
|
120 |
Способ получения моноазокрасителей |
SU341348 |
1945-10-29 |
SU66875A1 |
1945-11-30 |
GERSHZON G I; MITELMAN S I; NUSBAUMER S A |
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