序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
121 JET REACTOR WITH FLOW DUCTS AND PROCESS FOR PREPARING ISOCYANATES USING IT EP07800746.5 2007-08-21 EP2179985A4 2010-07-28 SHANG, Yonghua; SUN, Zhongping; LI, Jianfeng; WANG, Yong; HUA, Weiqi; MA, Deqiang; WANG, Yongsheng; DING, Jiansheng
122 Verfahren zur Herstellung von Isocyanaten in der Gasphase EP09015171.3 2009-12-08 EP2199277A1 2010-06-23 Bruns, Rainer, Dr.; Pohl, Fritz, Dr.; Steffens, Friedhelm; Michele, Volker, Dr.

Die Erfindung betrifft ein Verfahren zur Herstellung primärer Isocyanate durch Umsetzung der entsprechenden primären Amine mit Phosgen, dadurch gekennzeichnet, dass die primären Amine oberhalb der Siedetemperatur der Amine mit Phosgen in einem Rohrreaktor, der einen Reaktionsraum enthält, umgesetzt werden, bei dem

a) mindestens ein Phosgen enthaltender Eduktstrom P und mindestens ein die Amine enthaltenden Eduktstrom A dem Reaktionsraum über eine Düsenanordnung zugeführt werden, wobei die Düsenanordnung eine Anzahl von n ≥1 von parallel zur Rotationsachse des Rohrreaktors ausgerichteten Düsen und einen die Düsen umgebenden freien Raum umfasst, und

b) einer der Eduktströme A oder P über die Düsen und der andere Eduktstrom über den die Düsen umgebenden freien Raum dem Reaktionsraum zugeführt werden, und

c) der Reaktionsraum zumindest ein bewegliches Mischorgan enthält.

123 Ammoniumchloridabtrennung aus der Gasphase EP08009992.2 2008-05-31 EP2128127A1 2009-12-02 Hansen, Sven Michael, Dr.; Schneider, Ralf, Dr.; Schwethelm, Bernd; Schiefer, Rolf; Dreher, Jürgen

Die vorliegende Erfindung betrifft ein neues Verfahren zur Herstellung von Isocyanaten in der Gasphase, wobei die Standzeiten der Anlage durch selektive Abtrennung von Nebenprodukten wie Ammoniumchlorid durch Desublimation aus der Gasphase erreicht werden können.

124 POLYMERIC ACETOACETANILIDE AZO COLORANTS EP01984933.0 2001-11-26 EP1337509A4 2004-05-19 XIA, Jusong; MASON, Mary, G.; MILEY, John, W.; STEPHENS, Eric, B.; STARKS, Leonard, J.; STEPHENSON, Kyle, E.
This invention related to colorans comprising a chromophore having a single azo acetoacetanilide moiety, wherein said moiety each have at least one poly(oxyalkylene) chain. Such colorants exhibit extremely good base stability and lighfastness, particularly when incorporate within certain media and/or on the surface of certain substrates. These poly(oxyalkylene) chains provide sulubility in different solvents or resins thereby permitting the introduction of such excellent coloring chromophores within diverse media and/or or diverse substrates. Compositions and articles comprising such colorants are provided as are methods for producing such inventive colorants.
125 POLYMERIC ACETOACETANILIDE AZO COLORANTS EP01984933.0 2001-11-26 EP1337509A1 2003-08-27 XIA, Jusong; MASON, Mary, G.; MILEY, John, W.; STEPHENS, Eric, B.; STARKS, Leonard, J.; STEPHENSON, Kyle, E.
This invention related to colorans comprising a chromophore having a single azo acetoacetanilide moiety, wherein said moiety each have at least one poly(oxyalkylene) chain. Such colorants exhibit extremely good base stability and lighfastness, particularly when incorporate within certain media and/or on the surface of certain substrates. These poly(oxyalkylene) chains provide sulubility in different solvents or resins thereby permitting the introduction of such excellent coloring chromophores within diverse media and/or or diverse substrates. Compositions and articles comprising such colorants are provided as are methods for producing such inventive colorants.
126 METHOD OF UTILIZING ISOCYANATE LINKAGES FOR FORMING MULTI-TIER CASCADE POLYMERS EP97917126.1 1997-03-31 EP1005450A4 2000-10-25 NEWKOME, George, R.; WEIS, Claus
A method of synthesizing multi-tier cascade polymers and the polymers made thereby are formed by reacting at least one tier of a polymer with a functionalized isocyanate having the following formula: O = C = N - C(CH2-R)3 with R being selected from the group including: a) - (CH2)n - CH2 - COOR' with R' being selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl-polycycloalkyl, adamantyl, n = 0-10; - O - (CH2)n - CH2 - COOR'; b) - O - (CH2)n - CH2 - CN with R' being selected from the group consisting of alkyl (C-1 to C-20), cycloalkyl (C-3 to C-10), aryl heteroaryl, polycycloalkyl, adamantyl, n = 0-10; and c) - CH2 - (CH2)n - O - R'' with n = 0-10, R'' being selected from the group consisting of alkyl, cycloalkyl, aryl heteroaryl ester functionality, and a sulphur or a silicon atom bearing substituents selected from the group including: (I), (II), -SO2-R''', - SiR3 - CH2 - CH2 - CN, -CH2 - CH2 - COOR''' wherein R''' is alkyl (C-1 to C-20), cycloalkyl (C3-C-10), aryl, heteroaryl, polycycloalkyyl, adamantyl.
127 Fluorierte Bis-aryloxy-substituierte Alkene, Verfahren zu deren Herstellung und deren Verwendung EP89108533.4 1989-05-12 EP0343441B1 1993-03-24 Negele, Michael, Dr.; Bielefeldt, Dietmar, Dr.; Himmler, Thomas, Dr.; Marhold, Albrecht, Dr.
128 Verfahren zur Herstellung stabiler Dispersionen feinteiliger Polyisocyanate und deren Verwendung EP86106318.8 1986-05-09 EP0204970B1 1990-12-27 Blum, Rainer; Belde, Horst; Osterloh, Rolf, Dr.; Uhl, Guenter
129 Process for the production of poly-isocyanates containing allophanate groups EP88112492.9 1988-08-01 EP0303150A2 1989-02-15 Slack, William E.; Potter, Terry A.; Dunlap, Kenneth L.

Aliphatic and/or cycloaliphatic polyisocyanates containing allophanate groups are produced by reacting (a) a di- and/or polyisocyanate with aliphatic and/or cycloaliphatic isocyanate groups with (b) a hydroxy compound at a temperature of at least 150°C for no more than 90 minutes and then rapidly cooling the reaction mixture to a temperature of less than 100°C. It is preferred that the reaction be carried out in the absence of oxygen. The products thus obtained are virtually colorless and have a relatively low viscosity and excellent storage stability.

130 Preparation of cyclohexyl mono- and diurethanes and isocyanates derived therefrom by addition of methylcarbamates to limonene, process and compositions EP87115750.9 1987-10-27 EP0266661A2 1988-05-11 Nummy, Laurence John

A process is disclosed whereby mono- and diurethane cyclohexyl derivatives are obtained corresponding to the Lewis acid-catalyzed addition reaction of dipentene and methyl carbamate at a temperature of from about 40° to about 150°C. The mono- and diurethane cyclohexyl derivatives are pyrolytically converted to other corresponding mono- and diisocyanate cyclohexyl derivatives. Novel vinyl unsaturated monoisocyanate cyclohexyl derivatives useful as reactants for polyfunctional compounds to produce cured compositions are disclosed.

131 Isocyanate compounds and their production EP86303601.8 1986-05-12 EP0202840A2 1986-11-26 Urano, Satoshi; Tsuboniwa, Noriyuki; Aoki, Kei; Matsumura, Akira; Suzuki, Yuji; Mizuguchi, Ryuzo

A process for preparing alkenoyl isocyanates of the formula: wherein R is a hydrogen atom or a lower alkyl group which comprises subjecting an oxazolinedione hydrohalide of the formula: wherein X is a halogen atom and R is as defined above to decomposition under an ordinary pressure, in the presence of a hydrogen halide-eliminating agent and/or in a liquid medium having a dielectric constant of not more than 4.

132 URETHANE COMPOUND EP21789359.3 2021-04-12 EP4137479A1 2023-02-22 YAMAMOTO, Ikuo; MINAMI, Shinichi; ZHOU, Bin

Provided is a urethane compound giving crosslinking agents which give high water-and-oil repellency. The urethane compound is (A) a urethane compound formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO-Z(Y-R)n [wherein the R moieties are each independently -O-, -NH-, -O-C(=O)-, - NH-C(=O)-, -C(=O)-NH-, -O-C(=O)-NH-, -NH-C(=O)-O-, -NH-C(=O)-NH-, -NH-S(=O)2-, -S(=O)2-NH-, -NH-(CH2)m-NH-S(=O)2-, -NH-(CH2)m-S(=O)2-NH-, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2].

133 METHOD FOR PREPARING ISOCYANATE IN GASEOUS PHASE EP18944569.5 2018-12-26 EP3904336A4 2022-08-10 HUA, Weiqi; LI, Tonghe; SHANG, Yonghua; SUN, Shuchang; WANG, Jingxu; HAN, Jinping; LI, Qiang; LI, Wenbin; LI, Jing; WANG, Pengfei; LI, Yuan
Disclosed is a method for preparing an isocyanate in a gaseous phase, comprising feeding, in the presence or absence of an inert gas, an amine-containing gas stream and a phosgene-containing gas stream into a reaction region, allowing the amine and the phosgene to contact in gaseous forms and undergo a phosgenation reaction in the reaction region, thus preparing the target isocyanate in a gaseous form in the reaction region. The phosgene-containing stream is subjected to preheating and warming before being fed into the reaction region, and the phosgene-containing stream comprises a substance A at a mass fraction of < 1% before being subjected to the preheating and warming up, the substance A being a NCO group-containing substance and/or an olefinic double bond-containing substance. The method of the present invention can reduce the formation of clogging matter in a heat exchanger and a vessel during the preheating and warming of the phosgene and during the reaction process. Accordingly, clogging can be effectively ameliorated, a longer run cycle can be achieved, the frequency of overhaul of the phosgene-containing system can be reduced, and the safety in apparatus operation can be enhanced.
134 ZUR HERSTELLUNG EINER ORGANISCHEN ELEKTRONISCHEN VORRICHTUNG EINSETZBARE VERBINDUNGEN EP19805570.9 2019-11-12 EP3880657A1 2021-09-22 STOESSEL, Philipp
135 METHOD FOR PREPARING ALIPHATIC ISOCYANATES EP19822219.2 2019-06-03 EP3808732A1 2021-04-21 RYU, Hyun Cheol; HAN, Kee Do

The present invention relates to a method for preparing aliphatic isocyanate. More specifically, the present invention relates to a high purity isocyanate preparation method that can effectively recover unreacted materials and recycle them to a reaction step, and reduce energy consumed when separating reactants.

136 VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN EP10715181.3 2010-04-07 EP2417100B1 2017-07-12 LEHR, Vanessa Simone; KNOESCHE, Carsten; MATTKE, Torsten
137 POLYISOCYANURATES EP09735777.6 2009-04-09 EP2265656B1 2016-10-26 ZHANG, Yugen; YING, Jackie Y.; BINTE RIDUAN, Siti Nurhanna
138 VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN EP12710512.0 2012-03-26 EP2691364A1 2014-02-05 LEHR, Vanessa, Simone; MATTKE, Torsten; KNÖSCHE, Carsten; SCHELLING, Heiner; OLBERT, Gerhard
The invention relates to a method for producing isocyanates by phosgenating the corresponding amines in the gas phase, characterized in that a reaction mixture containing phosgene from the gas-phase synthesis of carbon monoxide and chlorine to form phosgene, the gas-phase synthesis being driven at a stoichiometric excess of carbon monoxide with respect to chlorine, is divided into two streams by means of a thermal separating method and/or a membrane separating method, specifically into a first flow low in carbon monoxide, containing at most 1 wt% of carbon monoxide with respect to the total weight of the first flow low in carbon monoxide, and into a second flow high in carbon monoxide, containing more than 10 wt% of carbon monoxide with respect to the total weight of the second flow high in carbon monoxide, and that the first flow low in carbon monoxide is used as a reactant flow in the phosgenation of amines to form isocyanates in the gas phase.
139 CARBAMATE PRODUCTION METHOD, ISOCYANATE PRODUCTION METHOD, CARBAMATE PRODUCTION DEVICE AND ISOCYANATE PRODUCTION DEVICE EP11795506.2 2011-05-19 EP2583961A1 2013-04-24 TAKAMATSU, Koji; KATO, Satoshi; FUKUDA, Takeshi; NAKANO, Tetsuya; SASAKI, Masaaki

A method for producing carbamate including a urea production step; a carbamate-forming step; an ammonia separation step of absorbing the gas with water in the presence of carbonate to produce a gas absorption water, and separating ammonia; an aqueous alcohol solution separation step of separating an aqueous alcohol solution from the gas absorption water; an ammonia/carbon dioxide separation step of separating carbon dioxide gas from the aqueous ammonia solution in the gas absorption water from which the aqueous alcohol solution is separated; an aqueous ammonia solution reusing step of mixing the aqueous ammonia solution and carbonate with the water to be used for production of the gas absorption water.

140 VERFAHREN ZUR HERSTELLUNG VON ISOCYANATEN EP10715181.3 2010-04-07 EP2417100A2 2012-02-15 LEHR, Vanessa Simone; KNOESCHE, Carsten; MATTKE, Torsten
The invention relates to a method for producing isocyanates by reacting the corresponding amines with phosgene, optionally in the presence of an inert medium, wherein phosgene and amine are first mixed and are converted in a reactor to form isocyanate, wherein a reaction gas containing isocyanate and hydrogen chloride leaving the reactor is cooled in a quench by adding a liquid quenching medium, wherein a mixture of reaction gas and quenching medium results as a product stream. The walls of the quench are wetted with a liquid substantially completely.
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