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Silver halide photographic element

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专利汇可以提供Silver halide photographic element专利检索,专利查询,专利分析的服务。并且PURPOSE: To form a positive image of high sensitivity free of occurrence of an unfavorable negative image, by adding specified core shell type silver halide grains and a specified heterocyclic mercapto compound to an emulsion layer.
CONSTITUTION: A heterocyclic mercapto compound represented by the formula shown is added to a sliver halide emulsion containing core shell type silver halide grains with the cores chemically sensitized. Variaous preparation conditions of the above grains are studied or the surfaces of the grains are chemically sensitized so as to produce 0.4 or more in density by the sensitivity of the grains when the emulsion is coated in an amount of 300 to 400 mg Ag/ft
2 , and after imagewise exposure, this is 5 minutes developed at 27°C in a surface developing solution-A. Such an emulsion coated on a support permits a positive type image high in maximum density and low in minimum density to be formed. In the formula, X is O, S, or NR
2 ; Q is a nonmetallic atomic group needed to form a 5- or 6-membered heterocyclic ring including that further having a 5- or 6-membered unsaturated ring; R
1 ,R
2 , and R
3 are H, halogen, SH, OH, COOH, SO
3 H, or from this optionally substituted alkyl, aryl, or alkoxy; and at least one of R
1 ,R
2 , and R
3 contains at least one of OH, COOH, or SO
3 H. The surface developing solution-A contains Na
2 SO
3 30.0 g; N-methyl-p- aminophenol sulfate 2.5 g; hydroquinone 2.5 g; NaBO
2 10.0 g; KBr 0.5 g; water to give a total volume of 1 liter.
COPYRIGHT: (C)1980,JPO&Japio,下面是Silver halide photographic element专利的具体信息内容。

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