GREEN OXIDATION CATALYTIC SYSTEM

申请号 US15537746 申请日 2015-12-18 公开(公告)号 US20180297976A1 公开(公告)日 2018-10-18
申请人 TRUSTEES OF BOSTON UNIVERSITY; 发明人 John Philip CARADONNA; Paul C. TARVES; Joshua MCNALLY; Lauren GREGOR;
摘要 Disclosed herein are reaction compositions comprising an oxidation catalyst, a solvent, and a substrate that is dissolved in the solvent. The oxidation catalyst comprises a metal ion complexed with an α-keto acid and a tridentate N,N,O-ligand. Also disclosed herein are methods for oxidizing a C—H bond of a molecule, the methods comprising contacting the molecule with a metal complex comprising a metal ion complexed with a tridentate N,N,O-ligand in the presence of an α-keto acid and a solvent. In some embodiments, the oxidation catalyst or metal complex is linked to a solid support.
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