Refractory oxides

申请号 EP97107432.3 申请日 1994-06-14 公开(公告)号 EP0791560A3 公开(公告)日 1997-11-05
申请人 ALCAN INTERNATIONAL LIMITED; 发明人 Emblem, Harold; Davies, Thomas James, Materials Science Centre;
摘要 A mixture suitable for firing to an oxide of the formula (II), Ba0.m(A1 2x Cr 2y 0 3 ), where 4.6 ≤ m ≤ 6.6; (x + y) = 1 ; and 0 ≤ y ≤ 0.5, said mixture comprising at least one of:
(a) barium oxide; (b) a clean thermal precursor (as hereinbefore defined) of barium oxide, such as barium carbonate or barium hydroxide; and (c) barium mono-aluminate, Ba0.A1 2 0 3 ; with at least one of:
(A) alumina, A1 2 0 3 ; (B) hydrated forms of alumina, such as boehmite, A1 2 0 3 .H 2 0; and (C) a clean thermal precursor (as hereinbefore defined) of aluminium oxide;
and, where y is not zero, with at least one of (D) chromium (III) oxide, Cr 2 0 3 ; (E) hydrous chromium (III) oxide; and (F) a clean thermal precursor (as hereinbefore defined) of chromium (III) oxide, the relative amounts of the components of the mixture being adjusted to give the desired values of m and y when the mixture is heated. Also disclosed is a grain mix suitable for forming refractory and/or ceramic articles prepared by comminuting either or both of:
(a) The above mixture and (b) an oxide of the formula (II), Ba0.m(A1 2x Cr 2y 0 3 ), where 4.6 ≤ m ≤ 6.6; (x + y) = 1 ; and 0 ≤ y ≤ 0.5.
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