1 |
JPS4867209A - |
JP12536872 |
1972-12-15 |
JPS4867209A |
1973-09-13 |
|
|
2 |
JPS5346807B2 - |
JP6697973 |
1973-06-15 |
JPS5346807B2 |
1978-12-16 |
|
|
3 |
JPS504006A - |
JP6697973 |
1973-06-15 |
JPS504006A |
1975-01-16 |
|
|
4 |
Method for inhibiting the formation of acetaldehyde in the solution containing vinyl acetate and alcohol |
US11035361 |
1961-05-16 |
US3296299A |
1967-01-03 |
MASAO MORI; YASUO KOTANI; YUKIO FUJITA |
|
5 |
Method for charging fluorocarbon gases |
US1652460 |
1960-03-21 |
US3018633A |
1962-01-30 |
HALLIWELL RONALD H |
|
6 |
Preparation of 1,1,2,3-tetrachloropropene from 1,2,3-trichloropropane |
US21274271 |
1971-12-27 |
US3823195A |
1974-07-09 |
SMITH L |
THIS PROCESS PREPARED 1,1,2,3-TETRACHLOROPROPENE FROM 1,2,3-TRICHLOROPROPANE. 1,2,2,3-TETRACHLOROPROPANE IS OBTAINED AS A BY-PRODUCT. THE PRODUCT AND BY-PRODUCT OF THIS PROCESS ARE USEFUL AS INTERN.EDIATES IN THE PREPARATION OF PESTICIDES.
|
7 |
Butadienes and chlorinated derivatives thereof |
US57015231 |
1931-10-21 |
US2038593A |
1936-04-28 |
ELKIN MUSKAT IRVING |
|
8 |
활성탄에 담지된 팔라듐 촉매 및 그의 제조 방법과, 이를 이용한 염화불화탄소로부터 불화탄화수소의 제법 |
KR1019990032851 |
1999-08-11 |
KR1020010017372A |
2001-03-05 |
문동주; 안병성; 정문조; 박건유 |
PURPOSE: Disclosed are a palladium catalyst supported on active carbon, a preparation method thereof and a hydrogenation reaction of chlorofluorocarbon to hydrofluorocarbon using the prepared catalyst. CONSTITUTION: The active carbon used as catalyst support is pretreated with a basic solution of 0.2-1M NaOH at 60-80deg.C for 1-5hours two or five times. And the acid treatment of a hydrochloric acid may be also conducted whenever after the base treatment or the hydrogen fluorine treatment or before loading of palladium species. The palladium species is impregnated by the adsorption precipitation method or the co-precipitation method. The hydrogenation reaction, dehalogenation, of chlorofluorocarbon to hydrofluorocarbon is selectively preformed to increase the yield of HFC-32. |