| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | Compositions for the sulphation-removing cleaning of carbonatic lithoidal surfaces | US439808 | 1989-11-21 | US5069811A | 1991-12-03 | Giuseppe Pizzigoni; Paolo Parrini |
| Improved compositions for the sulphation-removing cleaning of lithoidal surfaces of prevailingly carbonatic nature, or of layers of such nature on different materials, comprising a mixture of an anion-exchange material (e.g., an anion-exchange resin) with an aqueous solution of ammonium carbonate and/or bicarbonate, and a filler selected from the group consisting of powders and/or fibrils of hydrophilic materials. | ||||||
| 2 | Composition for the desulphatizing cleaning of carbonatic stone surfaces | US822104 | 1986-01-24 | US4686064A | 1987-08-11 | Giuseppe Pizzigoni; Paolo Parrini |
| Compositions for the desulphatizing cleaning of stone surfaces of prevailingly carbonatic nature or of layers of such nature on different materials, consisting of a mixture of an anion exchange material (for instance an anionic exchange resin) with an aqueous solution of ammonium carbonate and optionally with additives. | ||||||
| 3 | Restoration of stone objects | US514896 | 1983-07-18 | US4479503A | 1984-10-30 | Maurizio Pouchain; Ludovico Medolago Albani |
| The restoration of monuments and other objects made of stone is described. The process is carried out by immersing the stone object in deionized water in order to dissolve the calcium sulfate contamination present on the deteriorated stone which is caused by the pollutants present in air, then circulating the water containing the dissolved calcium sulfate through an ion exchange resin which can selectively trap the sulfate and release calcium hydroxide into the solution, followed by exposure to carbon dioxide under controlled conditions in order to thereby reprecipitate the calcium ions on the stone object as the carbonate in the calcite crystalline form. | ||||||
| 4 | Composition for the desulphatizing cleaning of carbonatic stone surfaces | EP86100955.3 | 1986-01-24 | EP0189866A1 | 1986-08-06 | Pizzigoni, Giuseppe; Parrini, Paolo |
Compositions for the desulphatizing cleaning of stone surfaces of prevailingly carbonatic nature or of layers of such nature on different materials, consisting of a mixture of an anion exchange material (for instance an anionic exchange resin) with an aqueous solution of ammonium carbonate and optionally with additives. |
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| 5 | A process for the decontamination and cleaning of monumental marble works | EP85830039 | 1985-02-19 | EP0174281A3 | 1986-08-13 | Pouchain, Maurizio |
57 A process for the decontamination and cleaning of monumental marble works, consisting in the immersion into deionized water of said works, said water being pushed by a pump for the circulation in a column containing ionic exchange resins which separate the SO4- ione as quickly as possible from said solution, said ione deriving from the dissolving of the calcium sulphate so that the calcium bicarbonate formed following to the dissolving of the sulphate contained in the work immediately precipitates at values of PH = 7 ÷ 7.5 in the form un undissolvable carbonate, determining the formation of a superficial crust that can be easily removed with a distilled water jet so as to leave the clean marble underneath. |
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| 6 | A process for the decontamination and cleaning of monumental marble works | EP85830039.5 | 1985-02-19 | EP0174281A2 | 1986-03-12 | Pouchain, Maurizio; Medolago Albani, Ludovico, Prof. |
57 A process for the decontamination and cleaning of monumental marble works, consisting in the immersion into deionized water of said works, said water being pushed by a pump for the circulation in a column containing ionic exchange resins which separate the SO4- ione as quickly as possible from said solution, said ione deriving from the dissolving of the calcium sulphate so that the calcium bicarbonate formed following to the dissolving of the sulphate contained in the work immediately precipitates at values of PH = 7 ÷ 7.5 in the form un undissolvable carbonate, determining the formation of a superficial crust that can be easily removed with a distilled water jet so as to leave the clean marble underneath. |
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| 7 | Procedure for reforming calcium carbonate in the restoration of stone monuments or the like | EP83830113.3 | 1983-06-07 | EP0127721A2 | 1984-12-12 | Pouchain, Maurizio; Medolago Albani, Ludovico, Prof. |
Procedure for restoring monuments made of stone or similar materials consisting of the removal of the sulfate present in the deteriorated stone caused by the pollutant urban air, releasing the calcium ion in the original stc followed by re-exposuretothe action of carbon dioxide ur controlled conditions, in orderto reprecipitate the calcium as the carbonate, in the calcite form. |
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| 8 | Improved compositions for the sulphation-removing cleaning of carbonatic lithoidal surfaces | EP87114580.1 | 1987-10-06 | EP0263486B1 | 1991-12-18 | Pizzigoni, Guiseppe; Parrini, Paolo |
| 9 | Composition for the desulphatizing cleaning of carbonatic stone surfaces | EP86100955.3 | 1986-01-24 | EP0189866B1 | 1989-12-13 | Pizzigoni, Giuseppe; Parrini, Paolo |
| 10 | Improved compositions for the sulphation-removing cleaning of carbonatic lithoidal surfaces | EP87114580.1 | 1987-10-06 | EP0263486A3 | 1989-05-03 | Pizzigoni, Guiseppe; Parrini, Paolo |
Improved compositions for the sulphation-removing cleaning of lithoidal surfaces of prevailingly carbonatic nature, or of layers of such nature on different materials, comprising a mixture of an anion-exchange material (e.g., an anion-exchange resin) with an aqueous solution of ammonium carbonate and/or bicarbonate, and a filler selected from the group consisting of powders and/or fibrils of hydrophilic materials. |
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| 11 | Improved compositions for the sulphation-removing cleaning of carbonatic lithoidal surfaces | EP87114580.1 | 1987-10-06 | EP0263486A2 | 1988-04-13 | Pizzigoni, Guiseppe; Parrini, Paolo |
Improved compositions for the sulphation-removing cleaning of lithoidal surfaces of prevailingly carbonatic nature, or of layers of such nature on different materials, comprising a mixture of an anion-exchange material (e.g., an anion-exchange resin) with an aqueous solution of ammonium carbonate and/or bicarbonate, and a filler selected from the group consisting of powders and/or fibrils of hydrophilic materials. |
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| 12 | 콘크리트 보수보강재 | KR1020070020070 | 2007-02-28 | KR100843309B1 | 2008-07-03 | 박승호; 이한승; 채성태 |
| A concrete reinforcement material is provided to be cured without causing any freezing at low temperature when the reinforcement material is applied onto a concrete structure, and to improve workability and economic effect of repair and reinforcement construction. A concrete reinforcement material comprises a reinforcement material powder and a liquid phase in a weight ratio of 100:30. The reinforcement material powder includes 8.9-20wt% of light burned magnesia, 5-10wt% of magnesium chloride, 5-6wt% of calcium sulfoaluminate, 5-6wt% of anhydrite, 5-7wt% of general portland cement, 0.01-0.1wt% of aluminum metal powder, 1-6wt% of sodium nitrite, 1-6wt% of calcium nitrite, and 38.9-50wt% of sand. The liquid phase includes 25-35wt% of a resin emulsion, 21-26wt% of a resin emulsion which is urethane copolymer, 30-40wt% of purified water, 1-5wt% of ethylene glycol as an antifreezing liquid, 0.05-2.5wt% of an antiseptic, and 0.1-1.5wt% of texanol as a coalescent agent. | ||||||
