| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 101 | 플루오르화탄소-그래프트 폴리실록산 | KR1020077020120 | 2006-01-31 | KR101273757B1 | 2013-06-12 | 빠봉,마르띠알,장-자끄; 세베라,로망; 뷔슈와,엠마누엘,아벨; 뻬르돈,매튜 |
| 폴리플루오로알킬 술포닐 할라이드를 하기 화학식 II, III 또는 IV의 화합물과 접촉시킴으로써 제조되고, 20℃의 온도 및 0.1 s -1 의 전단 속도 하에서 점도가 10000 mPa.s 이하인 중합체를 포함하는, 기재에 발유성, 발수성 및 내오염성을 제공하는데 유용한 조성물을 제공한다. <화학식 II> <화학식 III> <화학식 IV> 상기 식 중, 각각의 R 2 는 독립적으로 C 1 내지 C 8 알킬이고, 각각의 R 3 는 독립적으로 탄소, 산소, 및 임의로 질소, 산소 및 황 중 적어도 하나를 함유하는 2가의 기이고, 각각의 R 4 는 독립적으로 H 또는 C 1 내지 C 8 알킬이고, 각각의 E는 독립적으로 C 1 내지 C 8 분지형 또는 선형 알킬이고, 각각의 q는 독립적으로 0 또는 1이고, m은 양의 정수이고, n은 독립적으로 0 또는 양의 정수이되, n/(m+n)은 0 또는 약 0.7 이하의 양의 분수이다. 발유성, 발수성, 내오염성, 퍼플루오로알킬술폰아미드-그래프트 폴리(알킬실록산) 중합체, 폴리플루오로알킬 술포닐 할라이드 | ||||||
| 102 | 용제 용해성이 양호한 발수 발유 방오제 | KR1020097026004 | 2008-05-14 | KR1020100019514A | 2010-02-18 | 우에다아끼히꼬; 마에다마사히꼬; 마스따니데쯔야 |
| Disclosed is a water-repellent oil-repellent antifouling agent containing a fluorine-containing polymer for a treatment for providing water repellency, oil repellency and antifouling property. The fluorine-containing polymer has a repeating unit (A) derived from a fluorine-containing acrylate monomer, and a repeating unit (B) derived from at least one non-fluorine acrylate monomer selected from the group consisting of a monomer (B1) having a cyclic hydrocarbon group and a monomer (B2) having a short chain hydrocarbon group. This water-repellent oil-repellent antifouling agent has good solubility in solvents, and exhibits excellent effects on various bases, especially on masonries. | ||||||
| 103 | FLUOROCARBON-GRAFTED POLYSILOXANES | PCT/US2006003330 | 2006-01-31 | WO2006083818A8 | 2007-04-26 | PABON MARTIAL JEAN-JACQUES; SEVERAC ROMAIN; PUCHOIS EMMANUEL ABEL; PERDON MATTHIEU |
| A composition useful to provide oil repellency, water repellency, and stain resistance to substrates comprising a polymer prepared by contacting a polytluoroalkyl sulfonyl halide with a compound of Formula II: (E-(O)q)3Si-O-(Si(R2)2-O)m [Si(R3-NHR4)(R2)O]n-Si-((O)q-E)3, Formula III: HR4N-R3-Si(R2)2-O-[Si(R2)2-O]m [Si(R3-NHR4)(R2)O]n-Si-(R2)2-R3-NHR4 or Formula IV: HR4N-R3-Si(R2)2-O-[Si(R2)2-O]mSi-((O)q-E)3 , wherein each R2 is independently a C1 to C8 alkyl, each R3 is independently a divalent group containing carbon, oxygen, and optionally at least one of nitrogen oxygen and sulfur, each R4 is independently H or C1 to C8 alkyl, each E is independently a C1 to C8 branched or linear alkyl, each q is independently zero or 1, m is a positive integer, and n is independently zero or a positive integer, such that n/(m+n) is zero or a positive fraction having a value up to about 0.7, and the polymer viscosity is less than or equal to 10000 mPa.s under a shear rate of 0.1 s-1 at a temperature of 20° C. | ||||||
| 104 | (メタ)アクリレートおよび(メタ)アクリレートと(メタ)アクリル酸アミン複合体のフッ素化コポリマーの製造方法 | JP2013544868 | 2011-12-19 | JP5989662B2 | 2016-09-07 | シッダールタ シェノイ; ジョエル エム.ポリーノ; アニルクマル ラガバンピライ; ブラッド エム.ローゼン; アーネスト バイロン ワイソン |
| 105 | フッ素化コポリマーのコーティングコポリマー | JP2013544866 | 2011-12-19 | JP5952298B2 | 2016-07-13 | シッダールタ シェノイ; ジョエル エム.ポリーノ; アニルクマル ラガバンピライ; ブラッド エム.ローゼン; ジョン ラッセル クロンプトン ジュニア |
| 106 | 溶剤溶解性の良好な撥水撥油防汚剤 | JP2015116923 | 2015-06-09 | JP2015187280A | 2015-10-29 | 上田 晶彦; 前田 昌彦; 桝谷 哲也 |
| 【課題】溶剤溶解性が良好であり、種々の基材、特にメーソンリーに優れた効果を示す撥水撥油防汚処理剤を提供する。 【解決手段】(A)含フッ素アクリレート単量体から誘導された繰り返し単位、ならびに(B)環状炭化水素基を有する単量体(B1)および短鎖炭化水素基を有する単量体(B2)からなる群から選択された少なくとも1種の非フッ素アクリレート単量体から誘導された繰り返し単位を有してなる撥水撥油防汚処理用含フッ素重合体を含む撥水撥油防汚処理剤。 【選択図】なし |
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| 107 | 溶剤溶解性の良好な撥水撥油防汚剤 | JP2009515172 | 2008-05-14 | JP5625352B2 | 2014-11-19 | 晶彦 上田; 前田 昌彦; 昌彦 前田; 哲也 桝谷 |
| 108 | (Meth) acrylates and (meth) acrylate and (meth) method for producing a fluorinated copolymer of acrylic acid amine complex | JP2013544868 | 2011-12-19 | JP2013545882A | 2013-12-26 | シェノイ シッダールタ; エム．ポリーノ ジョエル; ラガバンピライ アニルクマル; エム．ローゼン ブラッド; バイロン ワイソン アーネスト |
| 汚れ抵抗性、撥油性および撥水性の向上した性能を有する硬質表面に有用な（メタ）アクリレート：（メタ）アクリル酸アミン複合体のコポリマーの製造方法。 | ||||||
| 109 | Hydraulic mixture for the material with "Easy-to-clean" properties | JP2013501834 | 2011-03-30 | JP2013523580A | 2013-06-17 | フリーデル マヌエル; リェジッチ スポメンコ; アルベアト フィリップ; シュタントケ ブルクハルト |
| The present invention relates to a hydraulically setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.01% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulically setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as facing concrete, where the surface of the materials exhibits only relatively low soiling tendency (easy-to-clean property) even on abrasion. | ||||||
| 110 | A method of forming a removable anti-fouling water-repellent surface coating | JP2004124694 | 2004-04-20 | JP4499469B2 | 2010-07-07 | ヌン エドウィン; ウィンター パトリック; ミュラー フェリックス |
| Detachable dirt- and water-repellent surface coatings on articles are produced by suspending hydrophobic particles in a solution of a silicone wax in a highly volatile siloxane; applying the suspension to surface(s) of an article; and removing the highly volatile siloxane. Independent claims are also included for the following: (1) a method of treating surfaces of an article to make the surfaces water- and dirt repellent, comprising applying a suspension comprising hydrophobic particles in a solution of a silicone wax in a highly volatile siloxane to surface(s) of the article; and removing the highly volatile siloxane; and (2) an impregnating composition for producing detachable dirt- and water-repellant surface coatings, comprising the above suspension. | ||||||
| 111 | Aqueous fluorochemical polymer composition for the water and oil repellency treatment of Mesonri and well within the pit | JP2003523174 | 2002-05-16 | JP2005501138A | 2005-01-13 | ダブリュ． ファン，ウェイン; ジェイ． マーティン，スティーブン |
| 本発明は、多孔質基材を処理して多孔質基材に水性汚れおよび油性汚れを通さなくさせるために有用な水溶性保存安定性水性フルオロケミカルポリマー処理剤を提供する。 この処理剤は、（ａ）フルオロ脂肪族基、（ｂ）カルボキシル含有基、（ｃ）シリル基および任意に（ｄ）他の非親水基の各基が複数主鎖から垂れ下がっていて、その主鎖中に炭素原子のみを含む水溶性または水分散性フルオロケミカルポリマーを含む。 本発明の水溶性ポリマー処理剤およびその処理剤の保存安定性水溶液は、水溶液で多孔質基材に被着させることができるので、環境に有害で毒性の共溶媒の必要性をなくす。 これらのポリマー処理剤は、特にメーソンリおよび他の珪質材料に被着させた時、ポリマー処理剤が上に被着される基材と反応して、撥水撥油し、汚れに耐え、そして基材の表面から容易に洗い流され得ない非可視水不溶性被膜を形成することが可能である。 これらのポリマーで処理された基材は雨および通常の風化から永続的に保護される。 | ||||||
| 112 | Compositions and methods for protecting the calcite and / or silicic acid surface | JP2000561140 | 1999-07-21 | JP2002521299A | 2002-07-16 | ニール オルンスタイン，イアン; チャールズ クライスト，ジェフリー |
| (57)【要約】 水、油、グリース及び天候からの損傷に対する耐性が増大した、方解石性及び／又はケイ酸性の建築用及び建造用材料が、（Ａ）１００％固体に基づき約０．１〜４重量％の、フッ素化基、カチオン性基及び非イオン性基を含むモノマーの反応生成物であるコポリマーの、水性溶液又は自己分散性乳液若しくは分散液、（Ｂ）有効量の浸透助剤、並びに（Ｃ）１００％にするための水を含む水性組成物で該材料を処理することを特徴とする方法により提供される。 | ||||||
| 113 | Anti-adhesive coating of scratch resistance of a heat-resistant | JP50810699 | 1998-07-03 | JP2001500928A | 2001-01-23 | マンゲン ヴァルター; ジルメン ウルリッヒ; クリュムペルマン トーマス; カウプ フリーデル; ベルケンケター ヘルベルト |
| (57)【要約】 本発明は、無機分子構造及び物質の塗布及び熱処理により得られた表面被膜を有する支持体材料に関する。 更に本発明は、表面被膜の製法及び適当な使用に関する。 ガラス、金属又はセラミック製の支持体材料は、水−及び／又は油性有機物質または水−油−エマルジヨンに対する耐付着性を示し、同時に慣用のＰＴＦＥ−又はシリコン被覆よりも著しく耐熱性で耐引掻性である表面被膜を有すべきである。 この要件は、本発明により、その最上の分子層中での支持体材料の無機分子と塗布された物質の有機分子とが結合している表面被膜によって満たされる。 このような表面の製造のために無機支持体材料上に、まず、シリコン様ネットワークを有する有機物質を塗布し、引き続き熱処理を行い、その際、温度及び時間を、塗布された純粋な有機層が充分に分解され及び／又は除去されるが、最上の分子層中には、支持体材料の無機分子と塗布された物質の有機分子との結合が生じることができるように選択する。 本発明の表面被膜を有する好適な支持体材料は、殊に、家事用−及び台所用器具に有利に使用できる。 | ||||||
| 114 | Functional building material | JP26573898 | 1998-09-02 | JP2000072569A | 2000-03-07 | MAYUMI SADATAKA; MORIKAWA TOMOAKI; NAKANISHI YOSHIYUKI |
| PROBLEM TO BE SOLVED: To facilitate the removal of foulings due to a sticking only component in a member to which the foulings easily stick due to the oily component inside and outside the house by forming minute uneven films of an oxide capable of increasing the contact angle with an oil from that with water by the photoexcitation in a surface layer part. SOLUTION: Minute uneven films of an oxide having a suitable surface roughness are formed on the surface of a member to thereby reduce the contact angle with water from that with an oil without reducing the contact angle with the oil on the surface of the member. The surface roughness of the minute uneven films is preferably ≤500 nm Ra. The contact angle with water is preferably ≤25°. Furthermore, the half-life of electrification is preferably ≤10 s. An oxide having photocatalytic functions is preferred as the oxide. The substrate surface 1 is coated with a coating liquid containing the oxide 3 having the photocatalytic functions and, as necessary, an oxide such as SiO2 or Al2O3 compounded therein through a binder 2 by spraying, printing, etc., many times and then heated to form the minute uneven films of the oxide 3. COPYRIGHT: (C)2000,JPO | ||||||
| 115 | Water-based organopolysiloxane-containing composition, its production and use | JP22924697 | 1997-08-26 | JPH10158522A | 1998-06-16 | STANDKE BURKHARD DR; EDELMANN ROLAND; FRINGS ALBERT-JOHANNES DR; HORN MICHAEL DR; JENKNER PETER DR; LAVEN RALF DR; MACK HELMUT DR; MONKIEWICZ JAROSLAW DR |
| PROBLEM TO BE SOLVED: To obtain the subject composition that contains a specific organopolysiloxane, essentially contains no organic solvent and essentially liberates no alcohol by its hydrolysis, when it is diluted with water. SOLUTION: This composition contains an organopolysiloxane of formula I [A is an aminoalkyl derived from formula II (0<=f<=6, when f is 0, g is 0, if f>0, g is 1; 0<=h<=b, 0<=z<=1); B is a fluoroalkyl derived from formula III (R<1> is a 1-9C monofluorinated alkyl, an oligo-fluorinated alkyl, a perfluyorinated alkyl, an aryl; 0<=y<=1) and C is an alkyl derived from formula IV; D is an alkyl derived from formula V (R<3> is a 1-8C alkyl); HX is an acid and X is an inorganic or organic acid radical; 0<=y<=1; a>0 and b>0, c>=0, d>=0, e>=0; a+b+c+d>=2]. | ||||||
| 116 | Composition for floor finishing | JP29447496 | 1996-10-14 | JPH10120455A | 1998-05-12 | MURAYAMA NAOKI |
| PROBLEM TO BE SOLVED: To obtain a composition for floor finishing excellent in oil resistance, solvent resistance and high-early-strength. SOLUTION: This composition for floor finishing consists essentially of cement, aggregate, a synthetic resin emulsion based on anionic copolymer obtained by copolymerization of ethylenic unsaturated monomers and a superplasticizer. In the composition, a weight ratio of cement to aggregate is (1:0.5) to (1:4) and solid content weight of synthetic resin emulsion to 100 pts.wt. mixture of cement with aggregate is 10-35 pts.wt. and an amount of the superplasticizer to 100 pts.wt. cement is 0.05-2 pts.wt. The anionic copolymer contains at least one monomer unit selected from a group comprising an ethylenic unsaturated carboxylic acid, ethylenic unsaturated sulfonic acid and ethylenic unsaturated phosphonic acid and the copolymer contains the ethylenic unsaturated monomer having at least one organosilicon group or the synthetic resin emulsion contains epoxysilane. COPYRIGHT: (C)1998,JPO | ||||||
| 117 | Composition comprising organosilicon compound and organofluorosiloxane compound, and water repelling treatment and oil repelling treatment of water-absorbing material | JP5675497 | 1997-03-12 | JPH1025297A | 1998-01-27 | HAGER RUDOLF; GUENTER KOLLERITSCH; WOLFGANG KNAUP |
| PROBLEM TO BE SOLVED: To obtain the subject composition useful for water-repelling and oil- repelling treatment of mineral construction materials, wood, etc., comprising an organosilicon compound bearing hydrocarbon, hydroxyl and alkoxy groups or the like and an organofluorosiloxane compound bearing fluoroalkyl groups. SOLUTION: This composition comprises (A) an organosilicon compound composed of unit of formula I (R is a monovalent 1-20C hydrocarbon group bound to SiC; R<1> is H or a 1-6C alkyl; (a) is 0, 1, 2 or 3; (b) is 1, 2, 3 or 4; (a+b)<=4) and (B) an organofluorosiloxane compound composed of at least one unit of formula II (R<2> represents a single group R; E is a group having at least one 4-20C fluoroalkyl group and 3-200atoms such as C, H, O, N and Cl; (x) is 0, 1 or 2), at least 5 units of formula III ((y) is 0, 1 or 2) and unit of formula IV (E<1> is a group having a single group E and 3-200atoms such as C, H, O, N and Cl; (z) is 0 or 1-3). | ||||||
| 118 | JPH06509146A - | JP50230093 | 1992-06-29 | JPH06509146A | 1994-10-13 | |
| This invention relates to a treating composition containing 0.3 to 30% by weight of a fluoroaliphatic radical containing poly(oxyalkylene) compound, 0.3 to 30% by weight of an anti-soiling agent and 0 to 60% by weight of an environmentally acceptable water-miscible organic solvent and water for the use for imparting excellent water- and oil repellency, stain resistance and dry soil resistance to textiles, carpets, concrete, paper, leather and wool. | ||||||
| 119 | Production of high oil-resistant cement hardened body | JP18844992 | 1992-07-15 | JPH06107479A | 1994-04-19 | SUZUKI YASUHIRO; SAKAKIBARA HIROYUKI; ONO AKIRA; SATO MASAO; UCHIDA KIYOHIKO |
| PURPOSE: To obtain a high oil-resistant cement hardened body without necessitating a large-sized equipment or a special device by aging and hardening a cement molded material having a specific compressive strength in carbon dioxide gas at a specific temp. CONSTITUTION: A cement composition containing 10-70 pts.wt. portland cement, 90-30 pts.wt. aggregate and mixed with water so as to be 0.30-0.70 water/cement ratio is molded into a desired shape, and the molded body hardened so as to become 300kg/cm 2 in compression strength at the body just after molding is aged in carbon dioxide gas. Carbon dioxide is usually used as a gaseous mixture in which the carbon dioxide is mixed with air. The carbon dioxide may be used at low concn., but preferably used at ≥3%. The temp. i.e., aging temp of the gaseous mixture containing carbon dioxide is not restricted but preferably 30-900°C. As a result, the cured body is surely neutralized to the inside thereof without necessitating the excess time for neutralizing. COPYRIGHT: (C)1994,JPO&Japio | ||||||
| 120 | メーソンリー処理組成物 | JP2016523449 | 2015-05-21 | JP6233510B2 | 2017-11-22 | 高橋 可奈子; 福森 正樹; 山本 育男 |
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