序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US10866948 2004-06-14 US07060128B2 2006-06-13 Paul Brown
In some embodiments, alternate sources of aluminum or calcium are provided in various ways including the desired compounds. The further object of the present invention contemplate in situ creation of the compound in interest in fresh concrete and as a slurry which can be employed in remediation of existing concrete structures. A method of resisting corrosion in concrete containing metal elements is provided. It includes introducing into fresh concrete, containing metal elements, at least one compound capable of sequestering chloride ions. The method may also involve employing a compound which is capable of establishing a corrosion resistant oxide layer on the metal reinforcing elements. The invention also includes certain compounds which may be employed in the method as well as concrete structures containing the compounds. In another embodiment of the invention, concrete structures may be rehabilitated by providing an overlay containing a compound of the type which will contribute to corrosion resistance either through chloride ion sequestering or creating barriers around metal structural elements with the overlay being provided in situ or as a preformed member and with possible use of a slurry in combination with an overlay segment. In another embodiment, a source of alumina is combined in solution with Ca(NO2)2 and/or NaNO2 with the resultant solution being introduced into the pores of a concrete structure, preferably under pressure to cause them to react with each other and with Ca(OH)2 contained within the concrete to produce the desired corrosion inhibiting compound.
22 In situ formation of chloride sequestering compounds US11078814 2005-03-11 US20050235881A1 2005-10-27 Eric Stevens; Paul Brown
The present invention provides methods and compounds for the in situ formation in concrete of chloride sequestering compounds that resist corrosion of metals contained within the concrete. These chloride sequestering compounds may include, but are not limited to, compounds having the formula 3CaO.Fe(2-x)AlxO3.Ca(NO2)2.nH2O and 3CaO.Fe(2-x)AlxO3.Ca(NO3)2.nH2O, where x ranges from about 0 to 1.4 and n ranges from about 8 to 24. In one embodiment, at least one Fe-containing additive is introduced into cement, and at least one anion-containing additive is introduced into mixing water. When the cement and mixing water are combined to create fresh concrete, the additives react to form chloride sequestering compounds. In another embodiment, the additives are introduced or mixed directly into fresh concrete that has already been formed, where they react to create chloride-sequestering compounds. “In situ” formation refers to the creation of a chloride sequestering compound within concrete.
23 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US11039101 2005-01-20 US20050121651A1 2005-06-09 Paul Brown
The present invention provides methods for resisting corrosion of metal elements in concrete, and associated compounds and structures. Acid mine drainage sludge is used as a source of a precursor compound that reacts with a source of anion to form a chloride-sequestering compound. The precursor compound may have the formula 2Me′(II)O·(Y(2−x),Y′x)O3+qMe′(II)O, where at least one of Y and Y′ is present; Y and Y′ are different and are independently selected from the group consisting of Al, Fe, Cr, and not present; Me′ is a cation and is selected from the group consisting of Ca, Ba, Sr, Mn, and Zn; x is a number ranging from 0 to 2; and q is a number ranging from 0 to 2; and combinations thereof. In a preferred embodiment, the precursor compound has the formula 2CaO(Fe(2−x),Alx)O3+CaO.
24 Construction material US10311744 2003-02-03 US06800130B2 2004-10-05 Peter Greenwood; Hans Bergqvist; Ulf Skarp
The invention relates to a construction material comprising a hydraulic binder, water, and an aluminum-modified colloidal silica. The invention also relates to a method for preparing such materials and the use thereof.
25 Construction material US10311744 2003-02-03 US20040039088A1 2004-02-26 Peter Greenwood; Hans Bergqvist; Ulf Skarp
The invention relates to a construction material comprising a hydraulic binder, water, and an aluminium-modified colloidal silica. The invention also relates to a method for preparing such material and the use thereof.
26 Mixture of silica sols US09882108 2001-06-15 US06596250B2 2003-07-22 Peter Greenwood; Hans Bergqvist; Ulf Skarp
The invention concerns a silica sol mixture comprising a first silica sol having a broad particle size distribution, the relative standard deviation being at least about 30% by numbers, and a second silica sol having a narrow particle size distribution having a relative standard deviation lower than about 15% by numbers. The invention also concerns a method for preparing a silica sol mixture and use thereof. The invention further concerns a concrete composition comprising a silica sol mixture and a method for preparing such composition.
27 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US10289702 2002-11-07 US20030093962A1 2003-05-22 Paul W. Brown
A method of resisting corrosion in concrete containing metal elements is provided. It includes introducing into fresh concrete, containing metal elements, at least one compound capable of sequestering chloride ions. The method may also involve employing a compound which is capable of establishing a corrosion resistant oxide layer on the metal reinforcing elements. The invention also includes certain compounds which may be employed in the method as well as concrete structures containing the compounds. In another embodiment of the invention, concrete structures may be rehabilitated by providing an overlay containing a compound of the type which will contribute to corrosion resistance either through chloride ion sequestering or creating barriers around metal structural elements with the overlay being provided in situ or as a preformed member and with possible use of a slurry in combination with an overlay segment.
28 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US10289808 2002-11-07 US20030089065A1 2003-05-15 Paul W. Brown
A method of resisting corrosion in concrete containing metal elements is provided. It includes introducing into fresh concrete, containing metal elements, at least one compound capable of sequestering chloride ions. The method may also involve employing a compound which is capable of establishing a corrosion resistant oxide layer on the metal reinforcing elements. The invention also includes certain compounds which may be employed in the method as well as concrete structures containing the compounds.
29 Method and apparatus for surfacing inner wall of swimming pool US10032902 2001-10-19 US20030077389A1 2003-04-24 John C. Jones
A surfacing method and apparatus produce a smooth surface on the wall of a swimming pool. The smooth surface minimizes both algae growth on the pool wall and skin abrasions caused by the surface. The method and apparatus utilize a cement slurry composition which includes a liquid bonding agent and fibers to increase the strength of the surface so the surface can be polished by a water cooled diamond impregnated surfacing wheel.
30 Mixture of silica sols US09882108 2001-06-15 US20020011191A1 2002-01-31 Peter Greenwood; Hans Bergqvist; Ulf Skarp
The invention concerns a silica sol mixture comprising a first silica sol having a broad particle size distribution, the relative standard deviation being at least about 30% by numbers, and a second silica sol having a narrow particle size distribution having a relative standard deviation lower than about 15% by numbers. The invention also concerns a method for preparing a silica sol mixture and use thereof. The invention further concerns a concrete composition comprising a silica sol mixture and a method for preparing such composition.
31 Pozzolan cement compositions and admixtures therefor US552635 1995-11-03 US5588990A 1996-12-31 Jonathan E. Dongell
Blended cement compositions for mixture with aggregate and water to prepare cementitious products. Such blended cement compositions contain cement, calcined diatomaceous earth, calcined kaolin, and about 0.5% to about 4% (w/w) of potassium, with or without talc and/or bentonite or their functional equivalents. Admixtures for blending into cement to create such blended cements or their read-mix equivalents contain calcined kaolin, calcined diatomaceous earth, and potassium, with or without talc and/or bentonite or their functional equivalents.
32 Manufacture of light concrete US76001834 1934-12-31 US2081802A 1937-05-25 ANDERS EKLUND KARL IVAR
33 A method for the treatment of metals US15021596 2014-09-12 US20160229721A1 2016-08-11 Vesa Rissanen
A method for precipitating metal waste is characterized in that the waste which contains one or more dissolved metal salts, is mixed with a boron compound, and the pH is adjusted to a value at which precipitation takes place in the presence of precipitation nuclei necessary for the formation of metal borates.
34 Low pH colloidal silica compositions for application to concrete US14678959 2015-04-04 US09272951B1 2016-03-01 Dal N. Hills; Kent Barrus
A composition for hardening concrete that has a pH of less than 10, and may have a pH of 8 or less. Thus, the hardening composition may be free of or substantially free of alkaline materials. The hardening composition is water-based and includes silica particles and stabilizer, which may be present on portions of the surfaces of the silica particles. The stabilizer may be aluminum-based (e.g., it may comprise alumina, etc.). In use, the hardening composition is applied to the surface of concrete, either alone, with curing compounds, or as part of a polishing process. Any residue that remains on the treated surface may simply be swept, blown, or sprayed away.
35 Low pH compositions for hardening concrete US14508710 2014-10-07 US08999056B1 2015-04-07 Dal N. Hills; Kent Barrus
A composition for hardening concrete that has a pH of less than 10, and may have a pH of 8 or less. Thus, the hardening composition may be free of or substantially free of alkaline materials. The hardening composition is water-based and includes silica particles and an aluminum-based (e.g., alumina, etc.) stabilizer, which may be present on portions of the surfaces of the silica particles. In use, the hardening composition is applied to the surface of concrete, either alone, with curing compounds, or as part of a polishing process. Any residue that remains on the treated surface may simply be swept, blown, or sprayed away.
36 Method of fabrication of construction materials from industrial solid waste US13506210 2012-04-04 US20120255463A1 2012-10-11 Magdi M. Nasrallah; Raouf O. Loutfy
A low-pressure method for producing construction materials, such as blocks, bricks or slabs, utilizing high percentages of waste cement dust in admixture with additive material capable of effectively neutralizing the high lime content and agglomerating the extremely fine particles of the cement dust upon blending of the admixture with water. The resulting blend may simply be cast in molds of various shapes and sizes and cured under normal atmospheric pressure conditions into a hardened construction material exhibiting high strength, light weight and high thermal insulation.
37 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US11039101 2005-01-20 US07101429B2 2006-09-05 Paul W. Brown
The present invention provides methods for resisting corrosion of metal elements in concrete, and associated compounds and structures. Acid mine drainage sludge is used as a source of a precursor compound that reacts with a source of anion to form a chloride-sequestering compound. The precursor compound may have the formula 2Me′(II)O·(Y(2−x),Y′x)O3+qMe′(II)O, where at least one of Y and Y′ is present; Y and Y′ are different and are independently selected from the group consisting of Al, Fe, Cr, and not present; Me′ is a cation and is selected from the group consisting of Ca, Ba, Sr, Mn, and Zn; x is a number ranging from 0 to 2; and q is a number ranging from 0 to 2; and combinations thereof. In a preferred embodiment, the precursor compound has the formula 2CaO(Fe(2−x),Alx)O3+CaO.
38 Method of improving material comprising a pozzolanic component US10507869 2003-03-19 US20050223950A1 2005-10-13 Joseph Jan Biermann; Nicolaas Voogt
The invention relates to a method of improving a material comprising a pozzolanic component. According to the invention the material is treated with an aqueous liquid resulting in treated, calcium-depleted material and a calcium-enriched aqueous solution, which are subsequently separated. This provides a material having an increased pozzolanity and/or increased specific surface area
39 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US10817605 2004-04-02 US20040261341A1 2004-12-30 Paul W. Brown
A method of resisting corrosion of metal elements in concrete is provided. It includes introducing into concrete containing metal elements, at least one combination compound capable of sequestering chloride ions having the formula 3Me(II)O.(R, Rnull)2O3.Me(II)(anion)2.nH2O, where R and Rnull are different and are independently selected from the group consisting of Al, Fe and Cr; anion is selected from the group consisting of NO2, NO3 and OH, n is 0 to 24, and Me(II) is a cation and is selected from the group consisting of Ca, Ba, Sr, Mn, Zn and combinations thereof. In one embodiment of the invention, concrete structures may be rehabilitated by providing an overlay containing the combination compound, with the overlay being provided in situ or as a preformed member and with possible use of a slurry in combination with an overlay segment.
40 Method of resisting corrosion in metal reinforcing elements contained in concrete and related compounds and structures US10289808 2002-11-07 US06732482B2 2004-05-11 Paul W. Brown
A method of resisting corrosion in concrete containing metal elements is provided. It includes introducing into fresh concrete, containing metal elements, at least one compound capable of sequestering chloride ions. The method may also involve employing a compound which is capable of establishing a corrosion resistant oxide layer on the metal reinforcing elements. The invention also includes certain compounds which may be employed in the method as well as concrete structures containing the compounds.
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