序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
61 Concrete admixture additive US11979601 2007-11-06 US20080071040A1 2008-03-20 Theresa Tsai
A new family of concrete admixture additives can be derived from reacting a mixture of olefins/cyclic olefins-maleic anhydride copolymers and methoxy polyethylene glycol amines and/or polyethylene glycol monoalkyl ethers, or a mixture of styrene-maleic anhydride copolymers and methoxy polyethylene glycol amines and/or polyethylene glycol monoalkyl ethers, or a mixture of styrene-olefins/cyclic olefins-maleic anhydride terpolymers and methoxy polyethylene glycol amines and/or polyethylene glycol monoalkyl ethers. These reactions lead to formation of a kind of carboxylic salt containing polymer, which can be used alone in concrete. Only a small amount of this substance is needed to provide excellent water reduction, high concrete flowability and high early strength.
62 Dispersant compositions for cement compositions and related methods US10698293 2003-10-31 US07240732B2 2007-07-10 Samuel J. Lewis; Michael J. Szymanski
The present invention relates to cementing operations, and more particularly to improved cement dispersants for cement compositions and methods of cementing. In one embodiment, the present invention provides a method of cementing comprising the steps of: providing a cement composition comprising a cement, and a dispersant composition, the dispersant composition comprising a surfactant and a hydrolyzed protein; placing the cement composition in a desired location; and allowing the cement composition to set.
63 Dispersant compositions for cement compositions and related methods US10698293 2003-10-31 US20050092211A1 2005-05-05 Samuel Lewis; Michael Szymanski
The present invention relates to cementing operations, and more particularly to improved cement dispersants for cement compositions and methods of cementing. In one embodiment, the present invention provides a method of cementing comprising the steps of: providing a cement composition comprising a cement, and a dispersant composition, the dispersant composition comprising a surfactant and a hydrolyzed protein; placing the cement composition in a desired location; and allowing the cement composition to set.
64 Methods of preparing particulate flow enhancing additives US10256858 2002-09-27 US20030110987A1 2003-06-19 Baireddy R. Reddy; Ronald E. Sweatman; James F. Heathman; Russell M. Fitzgerald; Ronald J. Crook
Methods of preparing a particulate flow enhancing additive are provided. The methods are basically comprised of preparing a particulate flow enhancing additive for improving the flow properties of particulate cementitious materials comprising adsorbing a flow inducing chemical on a particulate solid adsorbent material.
65 Method for producing a cement admixture, concrete and fluorine-containing oxyalkylene compounds US09793700 2001-02-27 US06395083B2 2002-05-28 Genichirou Enna; Hiroki Fukuda; Yoshihiro Ohtsuka
The present invention is the following invention which provides a cement admixture which satisfies fluidity of fresh concrete and high strength of the hardened product of concrete simultaneously. Namely, the present invention resides in a cement admixture which is a mixture of fluorine-containing compounds represented by the formula (1): Rf13 Q1—O—(A1—O)k—R1   (1) wherein Rf is a C1-22 polyfluoroaliphatic hydrocarbon group which may contain ethereal oxygen atoms or thioethereal sulfur atoms, Q1 is a C1-5 linear or branched alkylene group, k is an integer of from 1 to 100, A1 is a C2-4 linear alkylene group or a group having at least one hydrogen atom of said alkylene group substituted by a hydrocarbon group which may contain ethereal oxygen atoms, provided that when k is from 2 to 100, the plurality of A1 may be the same or different, and R1 is a hydrogen atom, a C1-18 hydrocarbon group or a C1-18 acyl group, said mixture having a ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn) (i.e. Mw/Mn) of at least 1.1, and concrete which contains said cement admixture.
66 Flow properties of dry cementitious materials US09815903 2001-03-23 US20010014651A1 2001-08-16 Baireddy R. Reddy; Ronald E. Sweatman; James F. Heathman; Russell M. Fitzgerald; Ronald J. Crook
Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.
67 Admixtures for cementitous compositions US983069 1998-05-22 US6063184A 2000-05-16 Bernhard Leikauf; Max Oppliger; Salvatore Valenti
The invention relates to a random styrene-maleic anhydride (SMA) copolymer in free acid or salt form wherein the copolymer has the following types and numbers of monomer units ##STR1## in which M is selected from hydrogen, a cation and a residue of a hydrophobic polyalkylene glycol or polysiloxane, R is the residue of methylpoly(ethylene)glycol of molecular weight (weight-average) 900-2000, x=0.35-0.75 and y=0.25-0.65. These copolymers are particularly useful as superplasticizers in cementitious compositions such as concretes and mortars.
68 Flowability additive US905284 1997-08-01 US5716447A 1998-02-10 Shigemi Matsuo; Akira Ohta; Tadashi Tsuchitani; Minoru Ueda
A cement pumpability-enhancing additive which comprises polyethylene glycol and diethylene glycol monobutyl ether and/or a derivative thereof, and optionally polysaccharide. The additive is especially useful for high-strength, high-flow concretes for use in construction.
69 Non-slumping, pumpable castable and method of applying the same US549018 1995-10-27 US5549745A 1996-08-27 Mark C. Langenohl; Gustav G. Hughes
An essentially non-slumping, high density, low moisture and low cement castable composition, consisting of a tempered, pumpable first component containing the castable solids and consisting essentially of a refractory aggregate, a calcium-aluminate cement, a flow aid, a deflocculating agent, and water, the water being present in the lowest amount sufficient to achieve a pumpable consistency of the tempered first component, and a flocculating agent as a second component to be added to said first component at time of installation in an amount sufficient to give the castable a dried bulk density of at least about 120 pcf.
70 Dry application papercrete US15293921 2016-10-14 US10150705B2 2018-12-11 James R. Brock
A dry papercrete mix is formed by preparing a wet pulp of fiber material such as newsprint and sharp sand by mixing sand, fiber material and water in a batch or continuous mixer, drying the pulp to a moisture content below that which will cause a reaction with Portland cement and adding additional sands and/or pumice and Portland cement. The resulting dry, granular mix can then be handled stored and used in the manner which is conventional for concrete. The dry papercrete mix can also be applied by pouring the dry papercrete mix into a desired volume such as a form in a dry state and injecting water into the dry papercrete mix until the mix is sufficiently wetted without a requirement for mixing in the manner common for concrete. Structural modules and a technique for joining them into a structure are particularly appropriate to the use of dry application papercrete.
71 ROOFING TILE AND METHOD FOR PRODUCING SUCH A ROOFING TILE US15896625 2018-02-14 US20180170809A1 2018-06-21 Andreas DRECHSLER; Michael FRIEDRICH; Michael HEISE; Jürgen KLEIN; Stephan WESTPHAL; Ben CRANFIELD
A roofing tile composed of concrete material and a method for producing such a roofing tile. The concrete material contains a binder, a gravel, a light-weight aggregate, and added water. The roofing tile has at least one watercourse and a lateral interlocking joint having a covering fold and a water fold. The ratio of water to binder is less than 0.3, the light-weight aggregate is composed of a material that is hydrophobic and/or not hygroscopic, and the roofing tile has a density in the range of 1.6 g/cm3 to 1.9 g/cm3 after the hardening. The roofing tile has a thickness of 5 mm to 9 mm, preferably 7 mm to 8 mm, in the highly loaded regions, preferably in the region of the watercourse.
72 Thermally enhanced HDD grout US13546830 2012-07-11 US09758433B2 2017-09-12 Joshuah S. Hathcox; Ryan P. Collins
A grout used in horizontal directional drilling including a silica material present in an amount of from about 50% to about 70%, bentonite present in an amount of from about 20% to about 30%, a carbon source present in an amount of from about 5% to about 15%, an inorganic alkaline material present in an amount of from about 0% to about 3%, a fluid loss additive present in an amount of from about 0% to about 1%, a polymeric dispersant present in an amount of from about 0% to about 1%, and a polymeric flow enhancer present in an amount of from about 0% to about 0.5%, all by weight of the grout composition. Methods utilizing the grout include placing conduit in a hole, forming the grout slurry, and placing the grout slurry adjacent to the conduct.
73 Dry application papercrete and block design using basalt US14574905 2014-12-18 US09725906B2 2017-08-08 James Robert Brock
A dry papercrete mix containing a pulp of fiber material such as newsprint and sharp sand, Portland cement and adding additional sand and/or pumice. The resulting dry, granular mix can then be handled stored and used in the manner which is conventional for concrete. The dry papercrete mix can be fortified with a fiber form of basalt which can be added to or substituted for all or a portion of the cellulose fiber content of the dry papercrete mix to provide a stronger structure when hydrated and cast into a desired shape with only a small increase in weight. Basalt reinforcing bars and meshes may be included in shapes cast from the hydrated mix in combination with or substitution for steel reinforcing structures. Including basalt in the mix and in reinforcing systems allows the design of joints between structural modules to provide exceptional strength in a unitary structure so formed.
74 Continuous process for preparing copolymers US14648591 2013-12-09 US09284395B2 2016-03-15 Christian Schwede; Günter Kaiser; Andreas Brodhagen; Mario Vierle
The present invention relates to a process for the continuous preparation of polymers in a polymerization apparatus, where the starting materials comprise at least one olefinically unsaturated polyether macromonomer and at least one olefinically unsaturated acid monomer and at least one free-radical initiator and the polymerization is carried out at temperatures in the range from −20 to +120° C., wherein the polymerization apparatus comprises at least one loop reactor which has at least one feed line for the starting materials and at least one outlet, where the loop reactor comprises at least one reaction zone which comprises internal cooling and mixing elements and which has a volume-based heat removal power of at least 10 kW/m3·K. Furthermore, the use of the polymer of the invention as dispersant for hydraulic binders is disclosed.
75 CEMENTITIOUS COMPOSITION AND ADMIXTURE US14819704 2015-08-06 US20150336847A1 2015-11-26 Samy M. SHENDY; Daniel CONSTANTINER
A cementitious composition including at least one cementitious and/or pozzolanic material and at least one desugared molasses. A method of preparing a cementitious composition including forming a mixture of water, at least one cementitious and/or pozzolanic material and at least one desugared molasses. An admixture for cementitious compositions including: (i) at least one desugared molasses; and (ii) at least one additional active admixture component.
76 PARTICULATE FLOW ENHANCING ADDITIVES AND ASSOCIATED METHODS US14748353 2015-06-24 US20150321961A1 2015-11-12 Sam Lewis; Rita McKinley; Russell Fitzgerald
A dry, free-flowing cement composition that comprises dry cement particles and flow inducing particulates that comprise solid adsorbent particulates having adsorbed thereon a flow inducing chemical, ethylene glycol, and water. The water is present in an amount from 5% to 30.3% by weight of the solid adsorbent particulates, the ethylene glycol is present in an amount from 3.25 to 20% by weight of the solid adsorbent particulates, and the flow inducing particulate is present in an amount from 0.005% to 5% by weight of the cement. The dry, free-flowing cement composition is free-flowing at temperatures at least as low as 10° F.
77 CONTINUOUS PROCESS FOR PREPARING COPOLYMERS US14648591 2013-12-09 US20150315318A1 2015-11-05 Christian SCHWEDE; Günter KAISER; Andreas BRODHAGEN; Mario VIERLE
The present invention relates to a process for the continuous preparation of polymers in a polymerization apparatus, where the starting materials comprise at least one olefinically unsaturated polyether macromonomer and at least one olefinically unsaturated acid monomer and at least one free-radical initiator and the polymerization is carried out at temperatures in the range from −20 to +120° C., wherein the polymerization apparatus comprises at least one loop reactor which has at least one feed line for the starting materials and at least one outlet, where the loop reactor comprises at least one reaction zone which comprises internal cooling and mixing elements and which has a volume-based heat removal power of at least 10 kW/m3·K. Furthermore, the use of the polymer of the invention as dispersant for hydraulic binders is disclosed.
78 HIGH FLOW NOZZLE FOR FIBER-REINFORCED CONCRETE US14740001 2015-06-15 US20150273409A1 2015-10-01 David L. Nicolson
Glass-fiber-reinforced concrete compositions that may be sprayed, and methods of preparing and applying such compositions. Such compositions may include cement, reinforcing glass fibers randomly oriented and homogenously distributed throughout the concrete composition, and a particle packing aggregate. At least a portion of the particle packing aggregate may be rounded rather than crushed and include a first aggregate portion having a first particle size and a second aggregate portion having a second particle size that is smaller than the first particle size so that the aggregate is capable of particle packing. The uncured compositions can be delivered through a spray nozzle with the glass fibers already mixed into the composition. The compositions can provide uniform, non-directional strength characteristics, e.g., modulus of rupture of at least 16 MPa and a limit of proportionality of at least 7 MPa with a glass-fiber content of no more than 4% by weight.
79 Glass-fiber-reinforced concrete compositions and related methods US14466604 2014-08-22 US09139473B2 2015-09-22 David L. Nicolson
Glass-fiber-reinforced concrete compositions that may be sprayed, and methods of preparing and applying such compositions. Such compositions may include cement, reinforcing glass fibers randomly oriented and homogenously distributed throughout the concrete composition, and a particle packing aggregate. At least a portion of the particle packing aggregate may be rounded rather than crushed and include a first aggregate portion having a first particle size and a second aggregate portion having a second particle size that is smaller than the first particle size so that the aggregate is capable of particle packing. The uncured compositions can be delivered through a spray nozzle with the glass fibers already mixed into the composition. The compositions can provide uniform, non-directional strength characteristics, e.g., modulus of rupture of at least 16 MPa and a limit of proportionality of at least 7 MPa with a glass-fiber content of no more than 4% by weight.
80 Cementitious composition and admixture US14548415 2014-11-20 US09133059B2 2015-09-15 Samy M. Shendy; Daniel Constantiner
A cementitious composition including at least one cementitious and/or pozzolanic material and at least one desugared molasses. A method of preparing a cementitious composition including forming a mixture of water, at least one cementitious and/or pozzolanic material and at least one desugared molasses. An admixture for cementitious compositions including: (i) at least one desugared molasses; and (ii) at least one alkanolamine and/or at least one polyhydroxyalkylamine.
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