序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 Styrene-butadiene based redispersible polymer powders with improved stability in cement applications EP11178240.5 2011-08-22 EP2433984B1 2014-06-18 Kuehn, Hartnut; Lohmuller, Gerold Adolf; Dombrowski, Juergen; Perello, Margarita; Lazarus, Etienne; Scharlemann, Sonja
42 Redispersible polymer powders prepared from low carboxylation styrene butadiene-based latex EP11161357.6 2011-04-06 EP2380927A1 2011-10-26 Kim-Habermehl, Linda H.; Ladika, Mladen; Hong, Liang

A water redispersible polymer powder is produced by drying an aqueous mixture of a low carboxylation, low Tg, large average particle size water insoluble film-forming polymer latex or emulsion and a colloidal stabilizer. The latex polymer may have an average particle size of 2000Å to 5,000Å, and an amount of carboxylation of 0.1% to 2.75% by weight of at least one ethylenically unsaturated dicarboxylic acid, salts or mixtures thereof, based upon the weight of the polymer. Dispersions containing the polymer and a polyvinyl alcohol as a colloidal stabilizer exhibit an unexpectedly low viscosity which facilitates spray drying and permits use of high solids content dispersions with low pressure spray drying to increase production efficiency. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly lower rates of viscosity buildup for better workability or troweling, faster set time, and superior heat flow characteristics.

43 NOUVEL AGENT HYDROFUGEANT HYDRODISPERSABLE, SA PREPARATION ET SON UTILISATION DANS LE DOMAINE DE LA CONSTRUCTION ET PLUS PARTICULIEREMENT DANS LES COMPOSITIONS DE LIANTS MINERAUX EP05773070.7 2005-05-24 EP1751218A2 2007-02-14 MERCIER, Jean-Michel; JOUBERT, Daniel; TAQUET, Pascal; DERUELLE, Martial
The invention relates to a novel hydrodispersible waterproofing agent based on at least one water-insoluble and water-immiscible waterproofing agent which has previously been emulsified in a hydrosoluble amphiphilic copolymer composition. The invention also relates to the solid forms of said composition obtained by drying, and to the use thereof in a water-insoluble film-forming polymer composition or in a mineral binding agent composition for applications in the field of construction.
44 IMPROVED WORKABILITY AND BOARD LIFE IN MASONRY MORTAR AND METHOD FOR OBTAINING SAME EP99956667 1999-10-26 EP1194482A4 2003-09-17 JARDINE LESLIE A
Improved workability and board life in masonry mortar is achieved through the use of an alkali soluble emulsion polymer and a low molecular weight, water-soluble humectant comprising a polymer haivng oxyalkylene groups, polyhydric groups, or a mixture thereof. The humectant in combination with a pH-sensitive polymer which provides significant advantages over the polymer alone. Preferably, the molecular weight of the humectant is approximately 2500 or lower. Exemplary masonry mortar compositions and methods for modifying them are also disclosed.
45 Poudres redispersables de polymères vinyliques EP91403354.3 1991-12-11 EP0493168B2 2001-01-17 Colombet, Jean-François; Thiebaut, Bruno
46 Poudres redispersables de polymères vinyliques EP91403354.3 1991-12-11 EP0493168B1 1995-06-14 Colombet, Jean-François; Thiebaut, Bruno
47 Poudres redispersables de polymères vinyliques EP91403354.3 1991-12-11 EP0493168A1 1992-07-01 Colombet, Jean-François; Thiebaut, Bruno

Les poudres redispersables dans l'eau de polymères filmogènes vinyliques et/ou acrylique insolubles dans l'eau sont caractérisées en ce qu'elles contiennent au moins une silicone.

Utilisation notamment comme additifs à des mélanges de liants hydrauliques dans l'industrie du batiment.

48 VERFAHREN ZUR HERSTELLUNG VON GRANULATEN AUS ZEMENTZUSAMMENSETZUNGEN EP15788414.9 2015-11-03 EP3215474A1 2017-09-13 KURZ, Christoph; BÜRGE, Christian; WOMBACHER, Franz
The invention relates to a method for producing aggregates from non-hardened cement compositions, in particular from concrete or residual concrete, which method comprises adding a) a water-absorbing agent and b) a crystallization deactivator to a non-hardened cement composition and mixing until a granular material has formed. The method allows unneeded residues of still liquid concrete to be converted into a practical product, which can then be reused to produce new concrete compositions. The invention further relates to a granulated cement material that can be obtained according to a corresponding method, to the use of said granulated cement material as an additive for cement compositions, and to additive combinations for cement compositions, which additive combinations comprise a water-absorbing agent and a crystallization activator.
49 Styrene-butadiene based redispersible polymer powders with improved stability in cement applications EP11178240.5 2011-08-22 EP2433984A1 2012-03-28 Kuehn, Hartnut; Lohmuller, Gerold Adolf; Dombrowski, Juergen; Perello, Margarita; Lazarus, Etienne; Scharlemann, Sonja

A water redispersible polymer powder is produced by drying an aqueous mixture of a carboxylated styrene butadiene polymer and a colloidal stabilizer which includes a polyvinyl alcohol modified with an alkyl end chain. The alkyl modified polyvinyl alcohol provides excellent redispersibility of the redispersible polymer powder without adversely affecting spray drying. Cement compositions such as mortars, which contain the redispersible polymer powder with the alkyl modified polyvinyl alcohol exhibit unexpectedly superior stability and an unexpectedly lower rate of mortar viscosity buildup which is advantageous for workability or troweling.

50 IMPROVED WORKABILITY AND BOARD LIFE IN MASONRY MORTAR AND METHOD FOR OBTAINING SAME EP99956667.2 1999-10-26 EP1194482B1 2011-04-20 JARDINE, Leslie, A.
Improved workability and board life in masonry mortar is achieved through the use of an alkali soluble emulsion polymer and a low molecular weight, water-soluble humectant comprising a polymer haivng oxyalkylene groups, polyhydric groups, or a mixture thereof. The humectant in combination with a pH-sensitive polymer which provides significant advantages over the polymer alone. Preferably, the molecular weight of the humectant is approximately 2500 or lower. Exemplary masonry mortar compositions and methods for modifying them are also disclosed.
51 HYDRAULISCH ABBINDENDE BAUSTOFFMISCHUNGEN ENTHALTEND MIKROVERKAPSELTE LIPOPHILE SUBSTANZEN EP08804629.7 2008-09-24 EP2203397A1 2010-07-07 MORARU, Bogdan; JUNG, Marc Rudolf; BECKER, Stefan; MANGEL, Timo; PAKUSCH, Joachim; RUPANER, Robert
The invention relates to a novel use of microcapsules comprising a polymer capsule wall and a lipophilic substance as a capsule core, said lipophilic substance having a melting point of ≤120°C and a boiling point of ≥100 °C, as additives providing stability in freeze-thaw conditions in hydraulically setting construction material mixtures.
52 SILAN-MODIFIZIERTE ADDITIVE UND SILAN-MODIFIZIERTE POLYMERZUSAMMENSETZUNGEN EP08787076.2 2008-08-11 EP2178971A1 2010-04-28 HASHEMZADEH, Abdulmajid; KILLAT, Marion
The invention relates to silane modified additives obtained by condensation of one or a plurality of silanes of the general formula (RO)3-nR1nSi(R2X)(1), wherein R is an optionally substituted alkyle, aryle or alkoxyalkyl radical with 1 to 10 carbon atoms or hydrogen, R1 an optionally substituted hydrocarbon radical with 1 to 12 carbon atoms or hydrogen,R2 an optionally substituted alkylene radical with 1 to 20 carbon atoms, wherein methylene units that are not adjacent to one another can be substituted by groups -O-, and X is bound to R2 via a covalent bond and stands for an amino radical NHR3, an epoxy radical CR4(O) CR5R6, an urethane radical NR3-C (=O)OR3, an urea radical NR3-C (=O) NR3R4, a phosphorous acid radical P(=O) (OH)2, an anhydride radical C (=O) O (O=) CR3 or a carbon acid radical, wherein R3 is hydrogen or an optionally substituted alkyle, aryle or amino alkyle radical with 1 to 10 carbon atoms, R4, R5, R6 hydrogen or an optionally substituted alkyle or aryle radical with 1 to 10 carbon atoms, wherein the respective radicals R1, R2, R3, R4, R5 and R6 each obtain their values independently from each other, and n takes on the value 0, 1, 2, or 3, in an aqueous solvent by mixing with one or a plurality of water solvent polymers, wherein the content of water soluble polymers is ≥ 15 wt.%, based on the dry weight of the silane modified additives, and optionally drying of the thus obtained aqueous mixture.
53 REDISPERGIERBARE DISPERSIONSPULVER-ZUSAMMENSETZUNG, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG EP01974307.9 2001-09-27 EP1325068B8 2006-07-05 FIEDLER, Wolfgang; GEISSLER, Ulrich; SCHMITZ, Ludwig
The invention relates to a dispersion powder composition which is redispersible in water and based on water insoluble polymers. The invention is characterised in that the composition contains 0.1 - 30 wt. %, in relation to the total weight of the polymer, of at least one carboxylic acid ester whose alcohol component comes from the group of polyhydroxy compounds. The invention also relates to a method for the production and use thereof, particularly in building materials in order to reduce the water absorption thereof.
54 REDISPERGIERBARE DISPERSIONSPULVER-ZUSAMMENSETZUNG, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG EP01974307.9 2001-09-27 EP1325068B1 2006-02-22 FIEDLER, Wolfgang; GEISSLER, Ulrich; SCHMITZ, Ludwig
The invention relates to a dispersion powder composition which is redispersible in water and based on water insoluble polymers. The invention is characterised in that the composition contains 0.1 - 30 wt. %, in relation to the total weight of the polymer, of at least one carboxylic acid ester whose alcohol component comes from the group of polyhydroxy compounds. The invention also relates to a method for the production and use thereof, particularly in building materials in order to reduce the water absorption thereof.
55 REDISPERGIERBARE DISPERSIONSPULVER-ZUSAMMENSETZUNG, VERFAHREN ZU DEREN HERSTELLUNG SOWIE DEREN VERWENDUNG EP01974307.9 2001-09-27 EP1325068A1 2003-07-09 FIEDLER, Wolfgang; GEISSLER, Ulrich; SCHMITZ, Ludwig
The invention relates to a dispersion powder composition which is redispersible in water and based on water insoluble polymers. The invention is characterised in that the composition contains 0.1 - 30 wt. %, in relation to the total weight of the polymer, of at least one carboxylic acid ester whose alcohol component comes from the group of polyhydroxy compounds. The invention also relates to a method for the production and use thereof, particularly in building materials in order to reduce the water absorption thereof.
56 Vernetzbare in Wasser redispergierbare Pulverzusammensetzung EP98112702.0 1998-07-09 EP0896029A1 1999-02-10 Eck, Herbert, Dr.; Figge, Reiner, Dr.; Barthel, Herbert, Dr.

Gegenstand der Erfindung der Erfindung ist eine vernetzbare, in Wasser redispergierbare Pulverzusammensetzung enthaltend

  • a) 30 bis 95 Gewichtsteile von einem oder mehreren in Wasser unlöslichen, filmbildenden Polymerisaten aus einem oder mehreren radikalisch polymerisierbaren, ethylenisch ungesättigten Monomeren,
  • b) 5 bis 70 Gewichtsteile von einem oder mehreren in Wasser löslichen Polymeren,

    wobei zumindest einer der Polymeranteile a) und b) ein oder mehrere Comonomereinheiten mit vernetzbaren Gruppen enthält, und sich die Gewichtsteile von a) und b) auf 100 Gewichtsteile aufaddieren, und
  • c) 0.5 bis 30 Gew%, bezogen auf das Gesamtgewicht von a) und b), von in Wasser und in organischen Lösungsmitteln unlöslichen, anorganischen oder organischen Feststoffen mit einer mittleren Teilchengröße von 5 nm bis 100 µm, an deren Oberfläche funktionelle Gruppen chemisch gebunden sind, welche mit den vernetzbaren Gruppen der Polymerisate a) und b) kovalente Bindungen ausbilden können.

57 ビニルアルコール系重合体及びその製造方法、掘削泥用添加剤、掘削泥水、掘削セメントスラリー用添加剤、並びに掘削セメントスラリー JP2015536628 2014-09-11 JPWO2015037672A1 2017-03-02 洋介 熊木; 靖知 齋藤
本発明は、下記式(1)で表される構造及び/又はジスルフィド構造により架橋されたビニルアルコール系重合体であって、4質量%の濃度となるようにに添加し95℃で3時間撹拌した際に完溶しない、ビニルアルコール系重合体である。なお、式(1)中、R1、R2及びR3は、それぞれ独立して、水素原子又は置換基を有してもよい炭素数8以下の炭化水素基を表す。本発明は、当該ビニルアルコール系重合体を含有する掘削泥水用添加剤、当該ビニルアルコール系重合体が添加された掘削泥水、当該ビニルアルコール系重合体を含有する掘削セメントスラリー用添加剤、及び当該ビニルアルコール系重合体が添加された掘削セメントスラリーも含む。
58 Redispersible polymer powder made from a low carboxylated styrene-butadiene-based latex JP2011084140 2011-04-06 JP5379181B2 2013-12-25 リンダ・エイチ.キム−ハーバーメール; ムラデン・レイディカ; リン・ホン
A water redispersible polymer powder is produced by drying an aqueous mixture of a low carboxylation, low Tg, large average particle size water insoluble film-forming polymer latex or emulsion and a colloidal stabilizer. The latex polymer may have an average particle size of 2000Å to 5,000Å, and an amount of carboxylation of 0.1% to 2.75% by weight of at least one ethylenically unsaturated dicarboxylic acid, salts or mixtures thereof, based upon the weight of the polymer. Dispersions containing the polymer and a polyvinyl alcohol as a colloidal stabilizer exhibit an unexpectedly low viscosity which facilitates spray drying and permits use of high solids content dispersions with low pressure spray drying to increase production efficiency. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly lower rates of viscosity buildup for better workability or troweling, faster set time, and superior heat flow characteristics.
59 Styrene-butadiene based redispersible polymer powder with improved stability in cement application JP2011180119 2011-08-22 JP2012072049A 2012-04-12 KUEHN HARTMUT; DOMBROSKI JUERGEN; LAZARUS ETIENNE; LOHMULLER GERALD ADOLF; PERELLO MARGARITA; SCHARLEMANN SONJA
PROBLEM TO BE SOLVED: To provide a water redispersible polymer powder produced by drying an aqueous mixture of a carboxylated styrene butadiene polymer and a colloidal stabilizer which includes a polyvinyl alcohol modified with an alkyl end chain, wherein an alkyl modified polyvinyl alcohol provides excellent redispersibility of the redispersible polymer powder without adversely affecting spray drying.SOLUTION: Cement compositions such as mortars, which contain the redispersible polymer powder with the alkyl modified polyvinyl alcohol exhibit unexpectedly superior stability and an unexpectedly lower rate of mortar viscosity buildup which is advantageous for workability or troweling.
60 Cement composition JP2006092881 2006-03-30 JP2007261920A 2007-10-11 SASAYA TATSUYA; ABE YOSHIHIRO; MATSUO MASATOSHI; UNE FUMIYOSHI
PROBLEM TO BE SOLVED: To provide a cement composition having excellent bleeding resistance, which exhibits good flowability when it is applied with shearing force during pump pressure-feeding or the like, but has high thixotropic property (dripping preventing property) even when the amount of water is increased without using a quick-setting agent, and which is less likely to cause bleeding when it is cured and almost free from volume shrinkage after curing. SOLUTION: In a cement composition comprising cement (a) and water (b), the cement composition contains crosslinked acrylic polymer particles (c) and an alkylether-modified cellulose resin (d). In the cement composition, the weight ratios of the contents of respective components are as follows: (a)/(b)=100/40-100/100, (c)/(b)=1/500-1/100, (d)/(b)=1/1,000-1/100, and (c)/(d)=1/1-10/1, and the crosslinked acrylic polymer particles (c) are water-insoluble powder composed of crosslinked acrylic polymer particles containing sulfonic acid group and/or acrylamide group. COPYRIGHT: (C)2008,JPO&INPIT
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