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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
21	Chemical-free production of graphene-reinforced inorganic matrix composites	US14998729	2016-02-09	US20170225233A1	2017-08-10	Aruna Zhamu; Bor Z. Jang
Provided is a simple, fast, scalable, and environmentally benign method of producing a graphene-reinforced inorganic matrix composite directly from a graphitic material, the method comprising: (a) mixing multiple particles of a graphitic material and multiple particles of an inorganic solid carrier material to form a mixture in an impacting chamber of an energy impacting apparatus; (b) operating the energy impacting apparatus with a frequency and an intensity for a length of time sufficient for peeling off graphene sheets from the graphitic material and transferring the graphene sheets to surfaces of solid inorganic carrier material particles to produce graphene coated or graphene-embedded inorganic particles inside the impacting chamber; and (c) forming graphene-coated or graphene-embedded inorganic particles into the graphene-reinforced inorganic matrix composite. Also provided is a mass of the graphene-coated or graphene-embedded inorganic particles produced by this method.
22	Photochromic substance and method for producing same	US14368389	2012-11-01	US09663398B2	2017-05-30	Morito Akiyama
Provided is a photochromic substance that has lower toxicity, exhibits good sensitivity in a visible light region, changes color deeply, has slow speed of color fading, has chemical and thermal stability, and has good durability. The photochromic substance has a composition represented by the formula: Ba(a-b)CabMgcSidOe:FefMgM′h where 1.8≦a≦2.2, 0≦b≦0.1, 1.4≦c≦3.5, 1.8≦d≦2.2, e=(a+c+2d), 0.0001≦f, 0.0001≦g, 0≦h, M is at least one of Al and Eu, and M′ is at least one element selected from the group consisting of Na, K, Nd, Li, S, C, Ti, V, Mn, Cr, Cu, Ni, Co, Ge, Zn, Ga, Zr, Y, Nb, In, Ag, Mo, Sn, Sb, Bi, Ta, W, La, Ce, Pr, Nd, Sm, Gd, Er, Ho, Tb, Tm, Yb, Lu, P, Cd, and Pb.
23	Hybrid organic-inorganic material constituted by a silica network having photochromic agents and optical power limiting agents as a doping agent in the material	US13638778	2011-04-12	US08901185B2	2014-12-02	Frédéric Chaput; Stéphane Parola; César Lopes; Denis Chateau; Cédric Desroches
The invention concerns a preparation process of a hybrid organic-inorganic material including the following successive steps: a) preparation of a neutral organosilicon sol in at least one organic solvent, b) incorporation of a doping agent into the neutral organosiliconsol, and production of a doped sol, c) incorporation into the doped sol, of an accelerating agent in order to activate the subsequent gelation of the sol, d) condensation of the sol in order to obtain a crosslinked gel, e) drying of the gel and production of a stable doped gel. and the material obtainable by such a method.
24	METHOD FOR PREPARING HYBRID MATERIALS OBTAINED BY FAST CONDENSATION OF AN ORGANOSILICON SOL	US13638778	2011-04-12	US20130131203A1	2013-05-23	Frédéric Chaput; Stéphane Parola; César Lopes; Denis Chateau; Cédric Desroches
The invention concerns a preparation process of a hybrid organic-inorganic material including the following successive steps: a) preparation of a neutral organosilicon sol in at least one organic solvent, b) incorporation of a doping agent into the neutral organosiliconsol, and production of a doped sol, c) incorporation into the doped sol, of an accelerating agent in order to activate the subsequent gelation of the sol, d) condensation of the sol in order to obtain a crosslinked gel, e) drying of the gel and production of a stable doped gel. and the material obtainable by such a method.
25	Pigmented vitreous material	US10335727	2003-01-02	US06737533B2	2004-05-18	Véronique Hall-Goulle; Zhimin Hao
The present application relates to a process for the manufacture of pigmented vitreous materials, as well as to pigmented vitreous materials, characterized by the use of soluble pigment precursors and preferably the absence of significant amounts of dispersants. These pigmented vitreous materials can be used as coloured materials for any known purposes. Soluble pigment precursors comprising a partial structure: are also claimed, wherein X1 is an aromatic or heteroaromatic ring, B is hydrogen or a group of the formula: but at least one group B is not hydrogen, and L is a solubilizing group.
26	Nanocomposite for thermal insulation	US09423782	1999-11-12	US06479156B1	2002-11-12	Helmut Schmidt; Martin Mennig; Gerhard Jonschker
The invention relates to a nanocomposite for thermal insulation especially for fireproofing purposes, which can be obtained by combining (A) at least 35 wt. % of nanoscaled, optionally surface-modified particles of an inorganic compound; (B) 10-60 wt. % of a compound with at least two functional groups which can react and/or interact with the surface groups of nanoscaled particles (A), (C) 1-40 wt. % of water and/or an organic solvent which has no functional groups or only one which is defined in (B), wherein the above-mentioned percentages relate to the sum of components (A), (B) and (C), and (D)=0-10 wt. % (based on the nanocomposite) of additives.
27	Naphthopyran derivatives, compositions and (co) polymer matrices containing same	US09341967	1999-07-20	US06399791B1	2002-06-04	Olivier Breyne; You-Ping Chan
For subject, the present invention has novel naphthopyran derivatives of formula: optionally substituted in position(s) 2, 3, 4, 6, 7, 8, 9 or/and 10; the substituent Z in position 5 being of formula —C(R1)(R2)(OR3). The invention also relates to compositions and (co)polymer matrices containing such derivatives. Said derivatives have interesting photochromic properties.
28	Photochromic spiroxazines, compositions and articles containing them	US370	1998-01-28	US06030555A	2000-02-29	You-Ping Chan
The invention concerns photochromic compounds having a formula (I), where R.sup.1 is a polycyclo group formed by at least one alicyclic group linked to, bridged or condensed, with at least one other aliphatic or aromatic ring. ##STR1##
29	Inorganic-organic composite compositons exhibiting nonlinear optical response	US15759	1987-04-17	US4851270A	1989-07-25	Tessie M. Che; Dagobert E. Stuetz; Alan Buckley; Donald R. Ulrich
This invention provides an optical medium which consists of an inorganic glass monolith with a microporous structure containing an organic component which exhibits nonlinear optical response.In one embodiment this invention provides a sol-gel process for producing a composite of a transparent homogeneous microporous inorganic oxide glass monolith and an organic compound which exhibits nonlinear optical response.
30	Sulfide glass, and method for producing sulfide glass ceramic	US14413893	2013-06-14	US09991554B2	2018-06-05	Ryo Aburatani; Tadanori Junke
A method for producing sulfide-based glass ceramics including crystallizing a glass solid electrolyte, wherein the glass solid electrolyte includes: sulfide-based glass comprising at least a sulfur element and a lithium element; and a nitrile compound incorporated into the sulfide-based glass.
31	Glass-phosphor composite containing rare-earth ion and light-emitting diode including same	US14836876	2015-08-26	US09647180B2	2017-05-09	Jong Heo; Byoung Jin So; Seung Ryeol Lee
A method of manufacturing a glass-phosphor composite is disclosed. The method comprises: preparing rare earth ion-containing parent glass; mixing the rare-earth ion-containing parent glass in a power state with a phosphor in a powder state; and providing a glass-phosphor composite using the powder mixture of the rare earth ion-containing parent glass and the phosphor, wherein the mixing includes mixing the rare earth ion-containing parent glass in the powder state with the phosphor in the powder state so that the phosphor in the glass-phosphor composite is in an amount of 5 wt % to 30 wt %, and the preparing includes using a glass frit having a glass transition point of 300° C. to 800° C. and a sintering temperature of 200° C. to 600° C.
32	SULFIDE GLASS, AND METHOD FOR PRODUCING SULFIDE GLASS CERAMIC	US14413893	2013-06-14	US20150207170A1	2015-07-23	Ryo Aburatani; Tadanori Junke
A method for producing sulfide-based glass ceramics including crystallizing a glass solid electrolyte, wherein the glass solid electrolyte includes: sulfide-based glass comprising at least a sulfur element and a lithium element; and a nitrile compound incorporated into the sulfide-based glass.
33	Polyphosphate glasses as a plasticizer for nylon	US11717934	2007-03-14	US20070290405A1	2007-12-20	Joshua Otaigbe; Kevin Urman
The present invention discloses the miscibility of inorganic phosphate glass and organic polymer prepared by blending both components in the liquid phase using conventional polymer processing methods. By utilizing low Tg phosphate glasses to plasticize nylon, e.g. polyamide 6, a new class of plasticizer is introduced that allows for the creation of unique nylon polymer composites. These materials display tunable morphologies, interesting properties, and significant reduction in flammability, while easing the processing of nylon through a substantial reduction of viscosity. The addition of a low Tg phosphate glass in small amounts (less than 10% by volume) to a nylon matrix results in a drastic reduction in viscosity and a decrease in the nylon glass transition temperature and flammability, with the capability of adding a low Tg phosphate glass up to 60% by volume. The observed mechanical properties of the nylon/phosphate glass hybrid are consistent with that of plasticized polymers.
34	Templated compositions of inorganic liquids and glasses	US10390275	2003-03-17	US06790382B2	2004-09-14	James D. Martin; Todd A. Thornton
An inorganic liquid or glass of hybrid composition including an inorganic component; and a template component, wherein the inorganic component and the template component are present in composition in a ratio that provides an intermediate range structural order to the composition. The intermediate range structural order results in the formation of metallotropic liquid crystals and anisotropic glasses. Methods of preparing the composition are also disclosed.
35	Templated compositions of inorganic liquids and glasses	US10390275	2003-03-17	US20030183804A1	2003-10-02	James D. Martin; Todd A. Thornton
An inorganic liquid or glass of hybrid composition including an inorganic component; and a template component, wherein the inorganic component and the template component are present in composition in a ratio that provides an intermediate range structural order to the composition. The intermediate range structural order results in the formation of metallotropic liquid crystals and anisotropic glasses. Methods of preparing the composition are also disclosed.
36	Templated compositions of inorganic liquids and glasses	US09620823	2000-07-21	US06540939B1	2003-04-01	James D. Martin; Todd A. Thornton
An inorganic liquid or glass of hybrid composition including an inorganic component; and a template component, wherein the inorganic component and the template component are present in composition in a ratio that provides an intermediate range structural order to the composition. The intermediate range structural order results in the formation of metallotropic liquid crystals and anisotropic glasses. Methods of preparing the composition are also disclosed.
37	Pigmented vitreous material	US09686642	2000-10-10	US06524382B1	2003-02-25	Patrice Bujard; Véronique Hall-Goulle; Zhimin Hao; Hitoshi Nagasue; Gerardus De Keyzer
The present application relates to a process for the manufacture of pigmented vitreous materials, as well as to pigmented vitreous materials, characterized by the use of soluble pigment precursors and preferably the absence of significant amounts of dispersants. These pigmented vitreous materials can be used as colored materials for any known purposes. Soluble pigment precursors comprising a partial structure are also claimed, wherein X1 is an aromatic or heteroaromatic ring, B is hydrogen or a group of the formula but at least one group B is not hydrogen, and L is a solubilizing group.
38	Ceramic dielectric compositions	US09226117	1999-01-07	US06174829B1	2001-01-16	Jau-Ho Jean; Shih-Chun Lin
A low-fire, low-dielectric ceramic composition is disclosed. The ceramic composition comprises a mixture of finely divided particles consisting of 30-90% by volume of Ca—Ba—Al—Zn—Si glass and 70-10% by volume of oxides, which can be densified up to 95% at temperatures of 800-1000° C. The sintered body produced thereby exhibits a dielectric constant in the range of 6-10 and a dielectric loss in the range of 0.01%-0.5% at 1 MHz. The ceramic composition can be processed with organic solvent, polymeric binder and plasticizer to produce a green sheet which is co-firable with high electrical conductivity metal such as gold, silver, silver-palladium and copper.
39	Glass/polymer composites and methods of making	US981700	1992-11-25	US5422384A	1995-06-06	W. D. Samuels; Gregory J. Exarhos
The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.
40	Method for producing large silica sol-gels doped with inorganic and organic compounds	US611490	1990-11-06	US5071674A	1991-12-10	Jean-Luc Nogues; Larry L. Hench; Shi-Ho Wang
A method of producing doped, monolithic objects of silica in a wide variety of shapes which comprises impregnating a stabilized silica sol-gel monolith with a doping solution having therein a wide range of inorganic or organic dopants to achieve unique physical properties, such as specific optical absorption bands or scintillation properties.

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