序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
181 Method of producing sodium carbonate and bicarbonate spherules from brine US35045373 1973-04-12 US3855397A 1974-12-17 HOFFMAN R; FOLLOWS A
Free-flowing spherules of sodium bicarbonate are prepared from a sodium carbonate or from salt brine, substantially saturated with ammonia, by carbonating the sodium carbonate solution, or the ammonia-saturated brine with carbon dioxide in the presence of from 200 to 2500 parts per million of a water soluble alkaline phosphate. Spherules of sodium bicarbonate crystallizing from the solutions are separated as a product having a bulk density between about 32 to 48 pounds per cubic foot, and a screen size substantially between 14 and 100 mesh. Sodium carbonate spherules are also readily obtained by calcining the sodium bicarbonate spherules.
182 Production of sodium bicarbonate using baffled cooling tube compartments in a tower US3551097D 1968-12-20 US3551097A 1970-12-29 BROOKS RICHARD; TASIAUX PAUL
Sodium bicarbonate is made by the ammoniasoda process in a column having a plurality of superposed compartments wherein carbon dioxide is contacted with a magma of sodium bicarbonate supported on a horizontal perforated plate and passing from compartment to compartment through a downcomer off set in relation to the downcomers of adjacent compartments, at least one of the lower compartments in the column having an arranging of spaced cooling tubes extending across the compartment and over which the magma of sodium bicarbonate flows, baffles being arranged to direct rising carbon dioxide first upwardly in a central zone of the cooling arrangement, then downwardly in adjacent zones thereof and then upwardly again in the outer zones of the arrangement to the compartment above. In compartments with cooling tubes the perforations of the plates are arranged in rows co-extensive with the cooling tubes while in the other compartments the perforations are arranged in concentric circles. The downcomers project above the perforated plates, are disposed in a peripheral zone thereof and may be inclined to the vertical. A column preferably has a diameter of between 6 and 9 feet and may have between 14 and 20 compartments of which 4 or 5 contain cooling means.
183 Cyclic process for the fabrication of sodium carbonate and of chlorine US3514381D 1967-02-20 US3514381A 1970-05-26 SEGUELA PIERRE
184 Process and apparatus for harvesting crystals US46291465 1965-06-10 US3389974A 1968-06-25 CESARE BARATTINI; PAOLO BORTOLINI; ALBERTO SCARFI
1,099,318. Crystallizing. SOCIETA' EDISON. June 9, 1965 [June 10, 1964], No. 24466/ 65. Heading B1G. [Also in Division F4] Cooling and crystallization of a saturated solution is effected in a vessel by means of water-cooled heat exchange tubing 1 resiliently suspended from a frame 2 which is vibrated by a cam operated by a motor 18. The tubing is in the form of two bundles operating in parallel, each bundle comprising a plurality of tubes, each connected to the next alternately at the top and bottom. The solution is stirred by a propellor 19 between the bundles.
185 Process for producing sodium carbonate from sodium bicarbonate obtained by the ammonia-soda process US46723465 1965-06-28 US3336106A 1967-08-15 MEEDER GERARDUS H W
186 Process for recovering calcium chloride from the ammonium chloride waste liquor of the ammonia soda process US36147364 1964-04-21 US3329479A 1967-07-04 EDMOND HUSTINX
187 Method of recovering ammonium chloride US76228058 1958-09-22 US3014782A 1961-12-26 HIDEO ARITA; HIROYUKI KUSAKA
188 Continuous process for producing sodium bicarbonate slurry US69399357 1957-11-01 US2942942A 1960-06-28 HOFF JEAN M
189 Process for making sodium carbonate and acetylene US67485257 1957-07-29 US2845329A 1958-07-29 NEUBAUER JOSEPH A; THEIS FRANCIS W
190 Conversion of sodium chloride into sodium carbonate and ammonia chloride US44556854 1954-07-26 US2843454A 1958-07-15 ADRIEN DEVAUX; MARCEL JEAN
191 Manufacture of soda ash US24609251 1951-09-11 US2737440A 1956-03-06 ROBERTS EDWARD S; SAMUEL STRELZOFF
192 Production of sodium bicarbonate and ammonium chloride in modified ammonia-soda type process US30943652 1952-09-13 US2666686A 1954-01-19 STANDISH MILLER WARREN; HIRDLER LOUIS C
193 Cyclic process for production of sodium bicarbonate and ammonium chloride US24819051 1951-09-25 US2622004A 1952-12-16 STANDISH MILLER WARREN; HIRDLER LOUIS C
194 Production of potassium bicarbonate US59542332 1932-02-26 US2013977A 1935-09-10 HANS WEISS
195 Process for the manufacture of alkali metal carbonates and hydroxides and recovery of ammonium chloride US62470132 1932-07-26 US1992318A 1935-02-26 MACMULLIN ROBERT B
196 Production of alkali metal carbamates US71933734 1934-04-06 US1969516A 1934-08-07 BURNS MACMULLIN ROBERT
197 Process for the production of potassium carbonate US43926130 1930-03-26 US1794260A 1931-02-24 THEODOR THORSSELL; AUGUST KRISTENSSON
198 Process for the manufacture of sodium carbonate US27972328 1928-05-22 US1789235A 1931-01-13 KIPPER HERMAN B
199 Process for manufacturing sodium bicarbonate and ammonium chloride US162825 1925-01-10 US1710636A 1929-04-23 WILHELM GLUUD; BERNHARD LOPMANN
200 Ammonia soda process US55780122 1922-05-01 US1570299A 1926-01-19 GALT HUGH A
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