序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 一种从锂母精矿提取金属化合物的方法 CN92106977.4 1992-06-23 CN1029112C 1995-06-28 黄际芬; 唐贤柳; 汪锡孝; 张国华
一种锂母精矿混合压煮法制取酸锂,是将精矿通入蒸汽进行焙烧,然后将熔料配入混合碱(如、碳酸钠或氢氧化钠)进行研磨调浆、溶液净化蒸发浓缩、碳酸化提锂,混合碱回收循环使用,、铷、铯综合回收等过程。本发明具有溶出过程压温度低,生产过程简单,生产设备易解决,操作安全可靠,能耗低,碱用量少(每吨碳酸锂仅消耗0.6吨碳酸钠),生产成本低,金属回收率高等特点,在工业生产中值得推广应用。
2 母精矿混合压煮法制取酸锂 CN92106977.4 1992-06-23 CN1067028A 1992-12-16 黄际芬; 唐贤柳; 汪锡孝; 张国华
一种锂母精矿混合压煮法制取酸锂,是将精矿通入蒸汽进行焙烧,然后将焙料配入混合碱(如、碳酸钠或氢氧化钠)进行研磨调浆、溶液净化蒸发浓缩、碳酸化提锂,混合碱回收循环使用,、铷、铯综合回收等过程。本发明具有溶出过程压温度低,生产过程简单,生产设备易解决,操作安全可靠,能耗低,碱用量少(每吨碳酸锂仅消耗0.6吨碳酸钠),生产成本低,金属回收率高等特点,在工业生产中值得推广应用。
3 Cyclic manufacture of potassium carbonate US62826032 1932-08-10 US2020801A 1935-11-12 FRIEDRICH RUSBERG
4 Method of preparing potassium carbonate or potassium hydroxide US56852031 1931-10-12 US2002684A 1935-05-28 HERMANN FRICKE; JENNY BARTLING
5 A METHOD OF RECOVERING METALS FROM SPENT Li-ION BATTERIES US15742511 2016-06-27 US20180205122A1 2018-07-19 NITIN GUPTA; G. PRABAHARAN; Smruti Prakash BARIK; BHUVNESH KUMAR
The present invention relates to an improved process and method of recovering metals of value from used Lithium Ion batteries. More particularly, the invention provides a method for recovering cobalt and lithium along with other metals of value wherein the method majorly includes physical processes for separation, limiting the use of chemical for removing minor impurities. Majority of elements were separated by physical process instead of chemical process which gives the benefit of cost saving in chemical treatment of liquid and solid effluents. Chemicals are used to dissolve only minor impurities from electrolyte which lead to the process economically attractive. This makes the method of recovering metal values is environment friendly. The invention provides for a cost effective, economic and environmental friendly process for recovering metals of value.
6 Decomposition of engel salt US65923933 1933-03-01 US2045203A 1936-06-23 FRIEDRICH RUSBERG
7 Method of making potassium carbonate US10397416 1916-06-16 US1400542A 1921-12-20 HARLOW IVAN F
8 使用済みLiイオン電池から金属を回収する方法 JP2018520039 2016-06-27 JP2018528593A 2018-09-27 グプタ, ニティン; プラバハラン, ジー; バリク, スムルティ パラカシュ; クマル,ブヴネシュ
本発明は、使用済みリチウムイオン電池からの、改善された有価金属回収プロセス及び方法に関する。より具体的には、本発明は、コバルトおよびリチウムを、他の有価金属と共に回収するプロセスを提供し、該プロセスは、物理的な分離プロセスを主に含み、特にスラリーの湿式篩別において、化学薬品の使用を微量不純物の除去に限定する。最大限の元素が化学的プロセスに代えて、物理的プロセスにより分離され、これにより、液体および固体排出物の化学処理におけるコスト削減の利益が得られる。化学薬品は、微量不純物を溶解するためにのみ使用され、これは、プロセスを経済的に魅的なものにする。これにより、環境に優しい有価金属回収方法となる。本発明は、費用対効果が大きく、経済的で環境に優しい有価金属回収プロセスを提供する。
【選択図】図3
9 Process for the extraction of arsenic from aqueous solutions containing alkali metal carbonate, sulfate and hydroxide or hydrogen carbonate and at least on metal including vanadium, uranium and molybdenum US448854 1982-12-07 US4485075A 1984-11-27 Pierre Maurel
A process for extracting arsenic from aqueous solutions containing alkali metal carbonate, sulfate and hydroxide or hydrogen carbonate, at least one metal selected from the group consisting of vanadium, uranium and molybdenum in the form of an alkali metal salt, and inorganic and/or organic impurities, comprising the steps of caustifying the solution with lime to convert the alkali metal carbonates into hydroxides to precipitate the insoluble calcium salts formed, concentrating the solution by evaporation of the effluent liquids originating from the caustification step to obtain a precipitate substantially comprising alkali metal sulfate wherein the caustification is performed in two steps, consisting of (a) treating the solutions with an amount of lime approximately equal to but less than the stoichiometric amount necessary to convert the alkali metal carbonates into hydroxides as a first precipitate, and (b) after separating and washing the first precipitate, treating the resulting liquor with at least the stoichiometric amount of lime necessary to precipitate the arsenic in solution and the carbonate ions still present. The process is well adapted to the treatments of the liquors originating from the alkaline attack of uraniferous ore.
10 Making potassium bicarbonate and magnesium carbonate trihydrate from engel salt US62825932 1932-08-10 US1967630A 1934-07-24 FRIEDRICH RUSBERG
11 Manufacture of potassium carbonate US62825832 1932-08-10 US1933452A 1933-10-31 FRIEDRICH RUSBERG
12 소모된 리튬 이온 배터리로부터 금속을 회수하는 방법 KR20187003656 2016-06-27 KR20180036975A 2018-04-10
본발명은폐 리튬이온배터리로부터유용한금속을회수하는개선된프로세스및 방법에관한것이다. 특히, 본발명은코발트및 리튬을유용한다른금속과함께회수하는방법을제공하는데,이방법은주로분리를위한물리적공정, 특히슬러리의습식스크리닝을포함하고, 경미한불순물을제거하기위한화학물질의사용을제한한다. 요소의대부분은화확공정을대신하여물리적공정으로분리되고, 이는액체및 고체유출물의화학처리비용을절감하는이점을제공한다. 화학물질은전해질의미세한불순물만용해시키는데만이용되고본 프로세스는경제적으로매력이있다. 따라서금속을회수하는방법은친환경적이다. 본발명은유용한금속을회수하기위한비용대비효과적이고경제적이며친환경적인방법을제공한다.
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