序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
121 Electrodeless plasma torch apparatus and methods for the dissociation of hazardous waste US746419 1991-08-16 US5288969A 1994-02-22 Alfred Y. Wong; Andras Kuthi
A system and method are provided for the non-thermal destruction of hazardous waste material using an electrodeless inductively coupled RF plasma torch. The waste material is combined with a controllable source of free electrons, and the RF plasma torch is used to excite the free electrons, raising their temperature to 3000.degree. C. or more. The electrons are maintained at this temperature for a sufficient time to enable the free electrons to dissociate the waste material as a result of collisions and ultraviolet radiation generated in situ by electron-molecule collisions. The source of free electrons is preferably an inert gas such as argon, which may be used as both the waste material carrier gas and the torch gas.
122 Method of immobilizing contaminants in the soil or in materials similar to the soil US787701 1991-11-01 US5234485A 1993-08-10 Friedrich Bolsing
A method of immobilizing a contaminant comprising mixing the contaminant with a reaction partner that is capable of chemically interacting with the contaminant to form a water-insoluble reaction product, the reaction partner being mixed in the form of a hydrophobic solid preparation, which is either obtained by grinding the reaction partner with an inert material and treating it with a hydrophobing agent or which contains the educt or reaction product of a dispersion by chemical reaction preliminarily treated with a hydrophobing agent, the mixing being conducted to form a soil or soil-like material with cohesive constituents of a clay-like structure.
123 Plasma torch furnace processing of spent potliner from aluminum smelters US868024 1992-04-13 US5222448A 1993-06-29 George W. Morgenthaler; Jeffrey L. Struthers; George W. Carter
Spent potliner from aluminum reduction cells includes carbon, inorganic brick and refractory material, and fluoride, sulfur, and cyanide compounds, and is considered hazardous. It is treated by introducing it into a vessel, and exposing it to the heat of a plasma torch at a temperature of at least 1000.degree. C. As a result, carbon is gasified and converted to combustible carbon monoxide or hydrocarbons, or to carbon dioxide; inorganic material is melted form slag; fluoride compounds are melted, vaporized, or reduced to gaseous HF; cyanide compounds are destroyed; and all other materials, including sulfur compounds, are either melted or gasified. As a result, the spent potliner is rendered non-hazardous, and the quantity of remaining slag has both its solid volume and mass substantially reduced by a factor of at least 1.5:1 in mass and at least 3:1 in volume relative to the input spent potliner. The process allows gaseous fluoride compounds to be captured and thermal energy produced in the process to be extracted. The molten slag material produced within the vessel is removed from the vessel, and cooled to form a solid slag which is substantially free of cyanide compounds, resistive to leaching, and safe for disposal. The slag has commercial utility. Combustible carbon compounds can be captured and used. When carried out at an aluminum smelting site, adequate electrical power is readily available, and there is an in situ demand for recovered fluoride compounds, combustible gases, and extracted heat.
124 Waste incineration process US679505 1991-04-01 US5177305A 1993-01-05 Philippe Pichat
The process is the type wherein the solid portions of waste materials of all origins are crushed and ground to a granulometry of under 5 mm and then are heated to between 750.degree. C. and 1,350.degree. C. According to the invention, after the addition, if applicable, of liquid waste to obtain a pasty mass, a reagent is added to the latter, in pulverulent form having granules of under 500 microns based with calcium carbonate, silicium oxide and, possibly, aluminum and iron oxides in quantities to produce the following ratio after incineration: ##EQU1## Application to the treatment of all types of waste by combustion.
125 Method for treating a liquid medium US552427 1990-07-12 US5130032A 1992-07-14 Helfred E. Sartori
A process for enhancement of chemical oxidation of oxidizable materials comprises storing the materials in suspended or dissolved form in a storage tank, pumping the material from the tank through an electrostatic treater, an ultrasonic ozone disperser, an ultrasonic treatment chamber, and a cooling unit. The material is then returned to the storage tank for subsequent treatments until a target oxidation is achieved. The ozone dispersed by the ultrasonic ozone disperser is first produced in an ozone generator and then enhanced magnetically before or at the point of injection into the treatment loop.
126 Composition for solidification or semi-solidification of waste materials US174973 1988-03-29 US4952242A 1990-08-28 Eugene F. Earp
A method and composition for solidification or semicolidification of single or multi-phased waste including mixing the waste with a composition including having as its major component a cement, and, as lesser components, a fixative, an absorbant, and optionally an emulsifier. The composition of the invention is mixed with the waste and dried.
127 Hazardous waste incinerator using cyclotron resonance plasma US282838 1988-12-08 US4909164A 1990-03-20 J. Leon Shohet; David T. Anderson
A hazardou waste incinerator which utilizes a cyclotron resonance plasma. The plasma is generated by introducing vaporized hazardous material and a feed gas into a vacuum chamber. The chamber has a magnetic field source and an electromagnetic radiation source. The cyclotron resonance plasma is produced by the resonance that occurs when the frequency of the electromagnetic radiation is set equal to that of the gyration of electrons or other charged particles in the magnetic field according to the formula: F.sub.res =(1/2.pi.)(qB/m) hertz Where q is the charge of the electron or ion, B is the strength of the magnetic field and m is the mass of the electron or ion. The strength of the electromagnetic radiation is adjusted so that the flowing gases are ionized, forming a plasma. During the reaction, the charged particles collide with neutral particles, providing both ionization and fragmentation (the breaking up of high-mass molecules into lower mass fragments). When electromagnetic radiation is applied at the ion cyclotron resonance frequency for a particular charge-to-mass ratio, ions of this ratio are accelerated outward and colilde with other particles in the plasma. This can result in further fragmenting of these ions or other particles or the ions will be selectively expelled or collected at the outer boundaries of the reactor.
128 Destruction of toxic organic chemicals US669420 1984-11-08 US4602574A 1986-07-29 Robert D. Bach; Christopher J. Nagel
Toxic chemicals such as polychlorinated biphenyls and other organic wastes are destroyed by injecting them, together with oxygen, into a metal or slag bath such as is utilized in a steelmaking facility. The metal bath may be melted initially by induction or an electric arc; the desired temperature greater than 2500.degree. F. may be maintained thereafter by the reaction of the oxygen and the organic waste. Various by-products may be obtained from the gas.
129 Stimulation of biooxidation processes in subterranean formations US669408 1984-11-08 US4588506A 1986-05-13 Richard L. Raymond; Richard A. Brown; Robert D. Norris; Eugene T. O'Neill
The present invention is a process to stimulate the biooxidation of a contaminant in a subterranean formation by introducing an aqueous solution into the formation. The concentration of the hydrogen peroxide is increased thereby acclimating the biota to higher concentrations of hydrogen peroxide. Periodically the concentration of the hydrogen peroxide is increased for a short time sufficiently to be toxic to the biota at or relatively adjacent to the site of introduction, thereby increasing the permeability of the formation at or adjacent to the site of introduction.
130 Treatment of scrap lining material from aluminium reduction cells US584534 1984-02-28 US4576651A 1986-03-18 John E. Deutschman
A process for treating fluoride-contaminated scrap lining material from electrolytic reduction cells comprises mixing the material with 7-30 parts of sulphuric acid and sufficient water to bring liquid content to 60-80 parts per 100 parts of lining material, mixing in sufficient lime to at least neutralize the sulphuric acid and make the slurry slightly alkaline, the slurry then being allowed to set into a solid mass.The slurry should be of a paste-like consistency. The lime may be wholly calcium hydroxide, but a substantial proportion may be in the form of calcium carbonate.The scrap, before or after the above treatment with lime and sulphuric acid, is preferably heated to 150.degree.-500.degree. C. in the presence of water vapor to destroy cyanides.
131 Process for disposal of sodium sludge US851396 1977-11-14 US4154607A 1979-05-15 Andrew O. Wikman; Robert L. Say; Robert H. Jones; James E. Rogers
A process for safely and conveniently disposing of active metal residue, such as a mixture of alkali metal and alkaline earth metal, by introducing the residue into a furnace in which it is completely transformed into harmless metal salts or oxides, which can be disposed of safely and inexpensively.
132 Process for the treatment of carburizing salt wastes US537448 1974-12-30 US3953570A 1976-04-27 Wolfgang Muller; Lothar Witzke
This invention relates to a process for the treatment of the reaction mass produced during the joint elimination of barium-containing nitrite-/nitrate-bearing carburizing salt wastes and cyanide-/cyanate-bearing wastes by ignition of the dry mixture at elevated temperatures, comprising suspending the reaction mass in water and eitherA. neutralizing the alkaline suspension obtained with concentrated nitric acid to a pH value of 6, the feed velocity of the acid and conditions of agitation being so selected that the pH value of the suspension will at no time fall below pH 6, and separating the barium carbonate,OrB. freeing the alkaline suspension obtained from barium carbonate, and neutralizing the filtrate with concentrated nitric acid to a pH value of 7.2, the feed velocity of the acid and conditions of agitation being so selected that the pH value of the suspension will at no time fall below pH 7.2, and separating the precipitated sodium bicarbonate,Concentrating the clear solutions obtained according to (a) or (b) to a water content of 10 - 20% by weight, separating precipitated sodium chloride, and evaporating the residual solution to dryness.
133 IMPROVED PRODUCT FOR TRANSFORMATION OF A TOXIC CORROSIVE OR ENVIRONMENTALLY-NOXIOUS LIQUID PRODUCT INTO A NON-CORROSIVE OR NON-NOXIOUS RESIDUE PCT/FR2005002609 2005-10-20 WO2006048521A3 2007-04-26 MEYER MARIE-CLAUDE; MATHIEU LAURENCE; GODARD CELINE
The invention relates to a product for transformation of a toxic corrosive or environmentally-noxious product into a non-corrosive or non-noxious residue, comprising at least one amphoteric agent, at least one lipophilic absorbent, at least one hydrophilic absorbent and at least one binary coloured indicator, selected from the group of the following mixtures: Nile blue/alizarin red, alizarin yellow/alizarin red, thymolphthalein/methyl red, phenolphthalein/methyl red and tropaeolin OO/thymol blue and optionally an additive selected from the group comprising charge agents, granulation agents, anti-static agents and mixtures thereof.
134 METHOD FOR TREATING SPENT POT LINER PCT/GB2008001037 2008-03-26 WO2008117044A3 2008-11-20 CHAPMAN CHRIS; LY HAO
The present invention relates to a method for treating spent pot liner material (SPL) containing carbon and/or an inorganic material, the method comprising: providing a plasma furnace having first and second electrodes for generating plasma and a crucible having a non-electrically conductive inner surface, heating the SPL material in the crucible in the presence of a flux material and an oxidant by passing an arc between the first and second electrodes via the SPL material to form a molten slag material and convert at least some of the carbon in the SPL material to CO and/or CO2 and/or incorporate at least some of the inorganic material into the molten slag material.
135 폴리염화비페닐을 포함하는 폐절연유의 처리방법 및 처리장치 KR1020090034129 2009-04-20 KR1020100115512A 2010-10-28 전일봉; 김병철
PURPOSE: A method and a device for treatment of polychlorinated biphenyls in wasted insulation oil are provided to reduce energy consumption by providing the energy of the treated insulation oil as the reaction heat for the insulation oil to be treated. CONSTITUTION: A device for treatment of polychlorinated biphenyls in wasted insulation oil comprises: a control device(50) which controls the whole operation of the treatment device; a reactor(15) which chemically reacts the wasted insulation oil including polychlorinated biphenyls; a pre-storage tank(110) which temporally stores the waste insulation oil to be treated; a post-storage tank(140) which temporally stores the wasted insulation oil of high temperature treated in the reactor; a heat exchanger which transfers thermal energy to the pre-storage reactor; and a storage tank(150) which stores the wasted insulation oil which are treated in the post-storage reactor.
136 오염된 퇴적물 및 토양의 열화학적 개질 및 정화 방법 KR1019997005702 1997-12-23 KR100449553B1 2004-09-21 카오리차드엘; 랜드하바사라브예이트에스; 랜드하바수르예이트에스; 멘싱거마이클씨; 레호맷아미레일지; 리안쏘니엘
This invention relates to thermo-chemical remediation and decontamination of sediments and soils contaminated with organic contaminants as well as inorganic materials with subsequent beneficial reuse. Novel environmentally stable products of commercial value are produced when certain additives such as calcium and metal oxides are mixed with the contaminated materials. In the process, the mixture is heated to 1150 DEG C. DIFFERENCE 1500 DEG C. to produce a molten reaction product with at least part of an excess amount of oxygen mixture or air is continuously bubbled through the melt in order to provide mixing and achieve high thermal destruction and removal efficiencies of the organic contaminants. The melt is then quickly quenched in moist air, steam, or water to avoid the transformation of the amorphous material into crystals. The inorganic contaminants such as chromium, nickel, zinc, etc. are incorporated and completely immobilized within the amorphous silicate network. The amorphous material can be pulverized to yield a powder which evinces cementitious properties either by reaction with alkali solution or by blending it with other materials to produce blended cements. The compressive strengths of the concretes made from the powder of the subject invention and blends thereof are comparable to, or greater than the ASTM requirements for general purpose concrete applications. The powder of the subject invention, blended cements, and concrete/mortar derived therefrom also easily pass the EPA TCLP leach test to achieve environmental acceptability.
137 팔라듐-알루미나 촉매와 초음파를 이용한 PCB 독성저감방법 KR1020020019278 2002-04-09 KR1020030080580A 2003-10-17 이희승; 신종헌; 홍기훈; 노정래
PURPOSE: A method for reducing the toxicity of PCBs by reducing all chlorine atoms contained in PCBs (polychlorinated biphenyls) by using hydrogen, thereby converting the polychlorinated biphenyls into biphenyl. CONSTITUTION: The method comprises a step of mixing methanol solution saturated with sodium with a solution into which PCBs (polychlorinated biphenyls) is dissolved; a step of adding palladium-alumina catalyst to a mixed solution in which the PCBs solution is mixed with the methanol solution; and a step of applying ultrasonic waves to the mixed solution to which the palladium-alumina catalyst is added, wherein toxicity of chlorine molecules of PCBs is reduced by increasing activity of the palladium-alumina catalyst using ultrasonic waves, thereby stably conducting chemical reaction in which chlorine atoms of the PCBs are replaced with hydrogen of sodium formate.
138 폐기물처리방법 KR1019940704813 1993-06-29 KR100267206B1 2000-11-01 데이비드스튜워드코노치; 로빈존배터함; 테리알란매튜스
본 발명에 따라서 배스 상부공간과 폐가스 배출구(11)를 가진 용기(3)내에 포함되어 있는 용해된 금속 배스내에서 무기고형의 폐기물을 처리하는 방법이 제공된다. 상기방법은 폐기물과 배스간의 반응이 일어나고 또는 폐기물이 회수되거나 처분되기에 좀 더 용이한 물질로 전환되기 위해서 상변이가 일어나는 제1 반응영역을 형성하기 위해서 배스내로 폐기물을 주입하는 단계를 포함한다. 또한, 상기 방법은 제1 반응영역(13)으로 부터 방출된 산화성 물질이 용기내의 폐가스 배출구(11)로 흐를 때 통과하며 산화성 물질은 산화되고 그러한 산화에 의해 방출된 열은 배스내로 전달되는 배스상부 공간의 일 부분에 제2 반응영역을 형성하기 위해서 배스의 표면을 향해 산소를 함유한 가스를 주입하는 단계를 추가로 포함한다.
139 동식물 유기성 폐기물의 탈염처리 방법과 그 장치 KR1019980063839 1998-12-31 KR1020000047080A 2000-07-25 서영준; 전상진; 문익기
PURPOSE: A method to treat an organic waste of animals and plants and a device thereof are provided which removes salt to be a problem when the by-products of an aquatic products or food dregs are processed to be a feed or compost, suppresses the occurring of the chloride, oxygen, chlorine dioxide, hydrogen by sterilizing the harmful microorganism, and improves the efficacy of the electronic power and removing salt. CONSTITUTION: A method to treat an organic waste of animals and plants comprises: injecting a marine by-product or leftovers of food into the central part(4) of a dechlorination tank(1) having an anion exchange septum(2) to an anode(6) and a cation exchange septum(3) to a cathode(5) ; and applying a direct current to the waste while stirring it to remove the marine by-product or the salt in leftovers of food, wherein low molecular organic materials such as CH3OH, CH3COOH, HCOOH or reducing materials such as H2SO3 are injected into an anode compartment(9), and air is injected into a cathode compartment(8), thereby enhancing the electric power efficiency and the salt removal efficiency.
140 폐기물 소각방법 KR1019910005308 1991-04-02 KR100187307B1 1999-04-01 피샤,필리프
본 발명의 방법은 모든 종류의 폐기물의 고형분을 입경 5mm 이하의 입자로 파쇄 및 분쇄한 다음 이를 750℃ 내지 1,350℃의 온도로 가열시키는 단계를 포함하는 것이다. 본 발명에 따라, 적용가능한 경우 액체 폐기물을 첨가하여 페이스트 물질을 얻은 후, 탄산칼슘, 산화규소 및 가능하게는 산화철과 알루미늄이 풍부한 500 마이크론 이하의 분말 형태의 시약을 소각 후 다음 식의 비율이 만족되는 양으로 첨가한다: 연소에 의한 모든 형태의 폐기물 처리에 적용.
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