子分类:
序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
181 JPH027345B2 - JP50264381 1981-07-06 JPH027345B2 1990-02-16 ROORAN JATSUKU JII
A pressure sensitive adhesive composition comprising the solids deposited from a mixture of solvents, synthetic rubber and tackifiers and also including a polysiloxane additive in about 6 to 10 percent of the resultant composition, which composition has reduced edge ooze or flow when on sheets subjected to a cutting action.
182 Improved acrylate adhesive polymer JP15902488 1988-06-27 JPS6433175A 1989-02-03 ROBAATO DABURIYUU RANSU; ETEIENNU EERU DE A RAZARU
A (meth)acrylate-based adhesive polymer composition is improved by the use of itaconic acid and a hydroxyalkyl (meth)acrylate, such as hydroxyethyl acrylate, polymerized therein. From 1 to 5 weight percent itaconic acid and from 1.5 to 17 weight percent hydroxyalkyl (meth)acrylate are used to improve the combinations of tack and shear strength in these adhesive polymers. With an optional tackifier, these polymers are found especially useful in pressure sensitive adhesive applications.
183 Manufacture of vinylidene fluoride resin laminate JP3807987 1987-02-23 JPS63205217A 1988-08-24 YAMAGUCHI TAKASHI; TSUTSUMI TADAHIKO; WATANABE RIE
PURPOSE:To bond vinylidene fluoride resin to rubber material strongly and obtain a resin laminate, prominent in resistances to chemicals, heat and weather as well as in contamination preventing property, by a method wherein adhesive agent, containing a rubber type polymer, a metallic compound of an element which belongs to groups II-IV of the periodic table and organic solvent, is employed. CONSTITUTION:When the laminate of a vinylidene fluoride series resin layer A and a rubber type polymer layer B is manufactured, an adhesive agent, containing a rubber type polymer, at least one kind of metallic compound, selected from the oxide and the hydroxide of an element which belongs to groups II-IV of the periodic table, and an organic solvent, capable of resolving or swelling the resin layer A and/or the polymer layer B, is spread on the resin layer A and/or the polymer layer B; thereafter, both of them are laminated and bonded within a temperature range not higher than the melting point of the resin layer A. Nitrile rubber is preferable for the rubber type polymer, which is the constituent of the adhesive agent, while silicon dioxide, magnesium oxide, zinc oxide, aluminum hydroxide or calcium hydroxide is preferable for the metallic compound.
184 JPS627209B2 - JP14073881 1981-09-07 JPS627209B2 1987-02-16 MIZUI KIMYA; TAKEDA MASAMI; IWATA TADAO
A hydrocarbon resin consisting essentially of a copolymer of (A) an unsaturated chain hydrocarbon or a cyclic hydrocarbon having a vinylidene group and (B) 9,10-dihydrodicyclopentadiene or its derivative, or a hydrocarbon resin modified by addition reacting an ethylenically unsaturated carboxylic acid or its anhydride, or hydrogen, to the above-mentioned copolymer. The hydrocarbon resin and the modified hydrocarbon resin have a high softening point and a low melt viscosity, and are suitable for use in adhesives and traffic paints.
185 JPS6136035B2 - JP1844177 1977-02-21 JPS6136035B2 1986-08-15 TAKAMATSU HIDEO; KONO NAOTAKE; TERAO KATSUYOSHI; YAMAUCHI JUNNOSUKE
A pressure-sensitive adhesive composition having excellent tackiness and improved thermal resistance comprises (A) a low molecular weight polyisoprene, which may be obtained by polymerizing isoprene monomer with the aid of a lithium-type catalyst, said polyisoprene having a cis-1,4 content of not less than 75%, a viscosity average molecular weight of 8,000 to 77,000 and an Mw/Mn value (Mw: weight average molecular weight; Mn: number average molecular weight) of 1.0 to 2.7 and (B) an elastomer.
186 Aqueous pressure-sensitive adhesive JP23652385 1985-10-24 JPS61101555A 1986-05-20 JIYOO ETSUCHI ESU CHIYAN
Xanthan gum is used as a rheology modifier for pressure sensitive adhesives, improving their cohesive strength. 0.01 to 2 weight per cent of xanthan gum is added to a composition that also comprises a water-based pressure-sensitive adhesive latex.
187 JPS57500985A - JP50264381 1981-07-06 JPS57500985A 1982-06-03
A pressure sensitive adhesive composition comprising the solids deposited from a mixture of solvents, synthetic rubber and tackifiers and also including a polysiloxane additive in about 6 to 10 percent of the resultant composition, which composition has reduced edge ooze or flow when on sheets subjected to a cutting action.
188 Adhesive tape for bundling raw vegetable of flower JP8896379 1979-07-13 JPS5626968A 1981-03-16 ONO KIYOSHI; SAKURAI YASUO; MATSUI TATSUO; NARITA SEIICHI; NAGAO SATORU
PURPOSE: Titled adhesive tape having improved creep resistance, prepared by coating one side of a water-resistant substrate with an adhesive composition based on a styrene-isoprene-styrene block copolymer. CONSTITUTION: Titled adhesive tape is obtained by coating one side of a water- resistant substrate such as polypropylene or polyethylene film with an adhesive composition comprising (a) 100pts.wt. of a styrene-isoprene-styrene block copolymer or an elastomer based on said block copolymer, (b) 20W150pts.wt. of a tackifier, softening point ≥100°C, such as polyterpene, resin ester or a petroleun resin and (c) 0W150pts.wt. of an additive such as calcium carbonate, zinc white, titanium oxide, vegetable oils or modified products thereof. Preferably, this tape has an initial adhesion force of about 300W700g/5mm width and an adhesive force of about 200W700g/20mm width. COPYRIGHT: (C)1981,JPO&Japio
189 JPS5610936B2 - JP2661476 1976-03-11 JPS5610936B2 1981-03-11
190 JPS5523286B2 - JP12654374 1974-11-05 JPS5523286B2 1980-06-21
A process for preparing a hydrocarbon resin which comprises copolymerizing (A) a hydrocarbon fraction boiling within the range of 130 DEG to 300 DEG C. obtained by cracking, reforming and/or refining petroleum with (B) dicyclopentadiene in the presence of a Friedel-Crafts catalyst in a proportion such that the resulting hydrocarbon resin contains, based on the total weight thereof, 20 to 80% of a unit derived from the dicyclopentadiene (B).
191 JPS5516173B2 - JP1834175 1975-02-13 JPS5516173B2 1980-04-30
A pressure sensitive adhesive composition comprising (A) 100 parts by weight of a conjugated diene-type rubber, and (B) 30 to 250 parts by weight of a hydrocarbon resin having a softening point of 60 DEG C to 140 DEG C and comprising (a) 45 to 85% by weight of a unit derived from 1,3-pentadiene, (b) 10 to 45% by weight of a unit derived from alpha -methylstyrene, (c) 3 to 20% by weight of a unit derived from cyclopentene, (d) 0 to 20% by weight of a unit derived from 1,3-butadiene, and (e) 0 to 5% by weight of a unit derived from a copolymerizable monomer selected from isoprene, cyclopentadiene and dicyclopentadiene.
192 Preparation of rosin ester having high softening point and improved stability JP7672578 1978-06-23 JPS559605A 1980-01-23 MATSUO KOUTAROU; TSUCHIDA SEIICHI
PURPOSE: To obtain a rosin ester having a high softening point, a remarkable effect as an pressure-sensitive adhesive tackifier and good stability at low cost, by esterifying a purified disproportionated rosin with a tri- or polyhydric alcohol. CONSTITUTION: High-polymer or unsaponified substances in a disproportionated rosin, obtained by reacting a raw material rosin in the presence of 0.01W5 wt.% of a catalyst, e.g. palladium carbon, nickel, platinum, iodine, or iron sulfide, at 100W300°C, are removed by distillation or recrystallization, to give a purified disproportionated rosin having an acid value ≥177. The resin is then esterified with a tri- or polyhydric alcohol, e.g. glycerol, pentaerythritol to give a rosin ester having a softening point of 65W140°C, preferably 90W140°C, an acid value ≤20, and a weight-average molecular weight of 700W1,100. COPYRIGHT: (C)1980,JPO&Japio
193 JPS533412B2 - JP3085373 1973-03-19 JPS533412B2 1978-02-06
1435661 Hydrocarbon resins MITSUI PETROCHEMICAL INDUSTRIES Ltd 19 March 1974 [19 March 1973] 12188/74 Headings C3P and C3Q Hydrocarbon resins suitable for use as tackifiers in adhesives and comprising a copolymer of (1) 100 parts by weight of unsaturated aromatic hydrocarbons containing at least 80 weight per cent of isopropenyl toluene and (2) 5 to 100 parts by weight of a fraction obtained from cracking or refining of petroleum and comprising mainly C 4 and/or C 5 unsaturated hydrocarbons boiling at - 15‹ to +45‹ C., are prepared by polymerization in the presence of a Friedel-Crafts catalyst and optionally a hydrocarbon solvent. The resins may be compounded with rubbers and optionally plasticizers, fillers, stabilizers and solvents, to provide pressure sensitive adhesives. Examples describe the preparation of hydrocarbon resins by copolymerizing isopropenyl toluene with (1-3) C 4-5 hydrocarbon fractions, (4) C 5 hydrocarbon fraction, (5) cyclopentadiene-free C 5 hydrocarbon fraction, (6) isoprene-free C 5 hydrocarbon fraction, (7) C 4 hydrocarbon fraction and (8) butadiene-free hydrocarbon fraction, and the preparation of adhesives by mixing the resins with natural rubber and toluene.
194 N-acyl amino acid compositions and their use as adhesion promoters US936563 1997-09-24 US6096813A 2000-08-01 Karl F. Schimmel; Dennis W. Jones; Umesh C. Desai
Disclosed are curable compositions such as adhesives and coatings containing as an adhesion promoter N-acyl amino acids having the structure: ##STR1## wherein n is 0 or 1, R.sup.1 is an alkyl or aryl group having from one to 10 carbon atoms optionally including --COOH, R.sup.2 is an alkylene or arylene group having from one to 10 carbon atoms, and R.sup.3 is H, --COOH, alkyl or aryl groups having from one to 10 carbon atoms, or carboxyl-substituted alkyl or aryl groups having from one to 10 carbon atoms.
195 Pressure sensitive adhesives and tape product prepared therefrom US792896 1997-01-31 US5798175A 1998-08-25 John K. Tynan, Jr.; Deborah Anne Chrzanowski
A pressure sensitive adhesive composition comprising a natural or synthetic rubber and a thermoplastic polyolefin blend comprising ethylene-propylene rubber, hydrogenated polyisoprene and polypropylene.
196 Silicone adhesive and organic adhesive composites US5856 1993-01-15 US5747567A 1998-05-05 Frank John Traver; Duane Franklin Merrill
Organic pressure-sensitive adhesive and silicone pressure-sensitive adhesive composites have improved shear strength upon the addition of a silicone cross-linking agent.
197 Thermal polymerization of dicyclopentadiene US626828 1996-04-03 US5691432A 1997-11-25 Theodore Joseph Williams
The specification discloses a method for making DCPD based resins that have relatively narrow molecular weight distributions. The method comprises thermally polymerizing dicyclopentadiene monomer in the presence of one or more strong acids, preferably with an olefinic modifier, to provide a dicyclopentadiene oligomer. Optionally, an organic sulfur species can also be used to further effect molecular weight control. For end-use performance in inks, adhesives, coatings and other related areas, the invention provides dicyclopentadiene oligomer resins having weight average molecular weights less than 1000 and relatively narrow molecular weight distributions, as measured by a polydispersity index, of less than about 2.3. Among the strong acids that are effective for controlling molecular weight, hypophosphorous acid is preferred because it gives light colored resins.
198 Pressure-sensitive adhesives based on preferentially tackified immiscible elastomers US203349 1994-02-28 US5663228A 1997-09-02 Yukihiko Sasaki; Jesse Ercillo
A pressure sensitive adhesive of a mutually immiscible first elastomer (styrene-butadiene block copolymer) exhibiting a first glass transition temperature and a second elastomer (e.g., a styrene-isoprene-styrene block copolymer) exhibiting a second glass transition temperature greater than the first is tackified by a tackifying system comprising tackifier preferentialIy miscible with the second elastomer to provide a dynamic mechanical spectrum plot of tangent delta versus temperature in .degree.C. showing two separate and distinct glass transition temperature peaks. The mixture exhibits excellent processability and ambient and low temperature adhesive properties.
199 Adhesive compositions, wound dressings and methods US469023 1995-06-06 US5633010A 1997-05-27 Yen-Lane Chen
Hydrocolloid adhesive compositions are disclosed comprising a hydrophobic unsaturated aliphatic homopolymer, a compatible tackifier, and at least one hydrocolloid absorbent. The compositions have enhanced resistance to breakdown by body fluids, adjustable absorbency, improved adhesive and cohesive properties, as well as a reduced tendency to leave an adhesive residue after application. Also disclosed are wound dressings, ostomy or prosthesis adhesives, methods of using wound dressings, and methods for forming the hydrocolloid adhesive compositions.
200 Adhesive composition for use as a wound dressing or ostomy/prosthesis adhesive US351890 1994-12-08 US5622711A 1997-04-22 Yen-Lane Chen
Hydrocolloid adhesive compositions for use as wound dressings or ostomy/prosthesis adhesives are disclosed. These adhesive compositions are made of a mixture of a hydrophobic, unsaturated, elastomeric homopolymer, a polyisobutylene tackifier and a hydrocolloid absorbent which is cross-linked by 5-200 kGy gamma radiation to provide a cross-linked matrix having a wet integrity value of at least about eighty percent, a shear hold value of at least about 500 min/500 g and a dry cohesive strength which prevents adhesive composition breakage or delamination. Methods of using such wound dressings or ostomy/prosthesis adhesives and methods of making the hydrocolloid adhesive compositions are also disclosed.
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