101 |
JPH0411591B2 - |
JP11361183 |
1983-06-23 |
JPH0411591B2 |
1992-02-28 |
|
Polymer composition, useful as or in binders, coatings or adhesives, comprises (A) carboxylic acid copolymer emulsion and (B) halohydroxypropyl- and/or glycidylammonium salt polymer wherein the polymer molecules are sufficiently swollen as to readily react with and penetrate interstices amongst emulsion (A) on drying the mixture. Coatings, binders or adhesives employing the composition are activated by base for coating or impregnating substrates, particularly non-woven fabric or fabric laminate, whereupon on drying and curing the mixture the polymer becomes crosslinked and insoluble. |
102 |
JPH045010B2 - |
JP16851583 |
1983-09-14 |
JPH045010B2 |
1992-01-30 |
|
Polymerizable alkyl poly (oxyalkylene) esters of acrylate oligomer are provided as well as copolymers thereof, especially stable, aqueous dispersions of water-insoluble emulsion copolymers of (1) at least 10% by weight of certain acids, especially methacrylic or acrylic acid, (2) about 0.5-30% by weight of the alkyl poly (oxyalkylene) acrylate oligomer ester, and optionally further ethylenically unsaturated monomer, which are useful thickeners. Thickening is effected on at least partial neutralisation of the copolymers and thickening is especially effective in the presence of surfactant. Aqueous compositions utilising this thickening effect are disclosed. |
103 |
Coating composition |
JP1881387 |
1987-01-30 |
JPS62283165A |
1987-12-09 |
JIYONASAN HAAPAA SUMISU; JIOFURII GOODON SAMAAZU |
|
104 |
JPS6221028B2 - |
JP175379 |
1979-01-10 |
JPS6221028B2 |
1987-05-11 |
BIRU BII GUROSU; MAIKERU JEI MATSUKISHIMOBITSUCHI |
|
105 |
Manufacture of aqueous ketone resin or ketone/aldehyde resindispersion |
JP3296385 |
1985-02-22 |
JPS60215026A |
1985-10-28 |
KURUTO FUISHIYAA; HARO PEETERUZEN; HERUMUUTO KASHIYU; EKEHARUTO BUISUTOUBA |
|
106 |
Self-levelling floor brightener |
JP7930884 |
1984-04-19 |
JPS59206476A |
1984-11-22 |
YOSEFU MIKAERU OOENSU; CHIYAARUSU EDOWAADO OFUARERU |
|
107 |
JPS5922722B2 - |
JP11122575 |
1975-09-12 |
JPS5922722B2 |
1984-05-29 |
NAKAYAMA YOSEI; WATANABE TADASHI; YAMASHITA YOSHIO; AIHARA TETSUO; HIMOTO ISAO |
|
108 |
Method of coating base material and coating aqueous solution composition therefor |
JP8335782 |
1982-05-19 |
JPS57195772A |
1982-12-01 |
GERARUTO GIYUNTAA |
A process is provided for coating a substrate by applying to a substrate an aqueous coating composition that comprises (a) an aqueous dispersion of a film forming polymer having a minimum film forming temperature not higher than 45 DEG C.; (b) a solid, particulate polymer having a softening temperature in the range of 45 DEG to 260 DEG C. and an average particle size in the range of 2 to 400 mu m and (c) a solid, rubberlike polymer having an average particule size in the range of 1 to 500 mu m, the resulting coating being cured at a temperature of 70 DEG -260 DEG C. The invention also relates to the liquid aqueous coating composition to be used in said process. |
109 |
JPS5425530B2 - |
JP3496174 |
1974-03-28 |
JPS5425530B2 |
1979-08-29 |
|
|
110 |
JPS542657B2 - |
JP11685474 |
1974-10-12 |
JPS542657B2 |
1979-02-10 |
|
|
111 |
JPS536982B2 - |
JP3217774 |
1974-03-21 |
JPS536982B2 |
1978-03-13 |
|
|
112 |
Emulsion composition |
JP11122575 |
1975-09-12 |
JPS5235238A |
1977-03-17 |
NAKAYAMA YASUHARU; WATANABE TADASHI; YAMASHITA YOSHIO; AIHARA TETSUO; SUGUMOTO ISAO |
PURPOSE: To prepare an emulsion composition having excellent applicability and high rate of curing after coating which results excellent physical properties and weatherability of the coating film, by the emulsion polymerization of a polymerizable vinyl monomer in the presence of a specifcc emulsifier.
COPYRIGHT: (C)1977,JPO&Japio |
113 |
Aqueous coating composite for applying to inner surface of vessels and production thereof |
JP5717875 |
1975-05-13 |
JPS51125118A |
1976-11-01 |
ROJIYAA EMU KURISUTENSON; RUDORUFU MASUKA |
|
114 |
JPS49133424A - |
JP11106673 |
1973-10-04 |
JPS49133424A |
1974-12-21 |
|
1444353 Coating compositions IMPERIAL CHEMICAL INDUSTRIES Ltd 3 Oct 1973 [4 Oct 1972] 45698/72 Headings C3P and C3R Coating compositions comprise (i) a dispersion of particles of a film-forming addition polymer derived from one or more ethylenically unsaturated monomers in an inert organic liquid in which the disperse polymer is insoluble, the dispersion being stabilized by a polymeric stabilizer comprising an anchoring component which associates with the particles of disperse polymer and a component solvated by the organic liquid which provides a stabilizing steric barrier around the particles and (ii) in an amount of 0À1 to 0À6%, calculated as aluminium metal and based on the weight of addition polymer solids, an organo-aluminium complex obtained by reacting an aluminium alkoxide with a #- keto carboxylic acid ester. Component (ii) prevents flocculation of pigments present in the composition which can cause an undesired rise in viscosity of the composition and formation of a thixotropic gel. Component (ii) may be, for example, a reaction product of aluminium isopropoxide, isobutoxide and/or sec.-butoxide with ethyl acetoacetate; unreacted alkoxide groups in the product are suitably condensed with water. In examples the addition polymer used is a styrene/methyl methacrylate/n-butyl methacrylate / 2 - ethylhexyl acrylate / 2- hydroxyethyl acrylate / methacrylic acid copolymer. Optional components which may be included in the compositions include solvents for the disperse polymer, supplementary filmforming polymers, cross-linking resins, e.g. etherified melamine-formaldehyde condensates. In addition to pigments, the compositions may also contain fillers, extenders or plasticizers. In the examples the compositions are coated on to metal panels used for automobiles and on to chromate-treated aluminium panels. |
115 |
JPS49131228A - |
JP3217774 |
1974-03-21 |
JPS49131228A |
1974-12-16 |
|
|
116 |
JPS4947015B1 - |
JP7706568 |
1968-10-24 |
JPS4947015B1 |
1974-12-13 |
|
|
117 |
JPS471058A - |
JP304871 |
1971-01-29 |
JPS471058A |
1972-01-19 |
|
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118 |
COATING ADDITIVE |
US15744156 |
2015-07-20 |
US20180194948A1 |
2018-07-12 |
Liqiang Fan; Rui Wang; Jianming Xu |
The present invention provides a coating additive (co)polymer comprising, as (co)polymerized units, by dry weight based on total dry weight of the (co)polymer, from 20% to 60%, at least one acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer, and from 40% to 80% at least one water soluble ethylenically unsaturated monomer. It further provides a coating formulation comprising higher than 0.04% by dry weight based on total dry weight of the coating formulation, the acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer. |
119 |
Hydrophilic monolayer films |
US15307045 |
2015-05-12 |
US09976049B2 |
2018-05-22 |
Koju Okazaki |
The invention provides monolayer films excellent in hydrophilicity and transparency which include a crosslinked resin having a surface enriched with hydrophilic groups, and materials which exhibit excellent properties such as hydrophilicity, antifogging properties and antifouling properties by virtue of having the above monolayer films. A monolayer film is fabricated which includes a crosslinked resin obtained by polymerizing a composition including a compound (I) having an anionic hydrophilic group and a functional group with a polymerizable carbon-carbon double bond, and a compound (II) having three or more hydroxyl groups and three or more functional groups with a polymerizable carbon-carbon double bond, the monolayer film having a gradient (Sa/Da) of not less than 1.1 wherein Sa is the surface concentration of the anionic hydrophilic groups in the monolayer film, and Da is the deep concentration of the hydrophilic groups at ½ of the thickness of the monolayer film. |
120 |
HYDROPHILIC MONOLAYER FILMS |
US15307045 |
2015-05-12 |
US20170044393A1 |
2017-02-16 |
Koju OKAZAKI |
The invention provides monolayer films excellent in hydrophilicity and transparency which include a crosslinked resin having a surface enriched with hydrophilic groups, and materials which exhibit excellent properties such as hydrophilicity, antifogging properties and antifouling properties by virtue of having the above monolayer films. A monolayer film is fabricated which includes a crosslinked resin obtained by polymerizing a composition including a compound (I) having an anionic hydrophilic group and a functional group with a polymerizable carbon-carbon double bond, and a compound (II) having three or more hydroxyl groups and three or more functional groups with a polymerizable carbon-carbon double bond, the monolayer film having a gradient (Sa/Da) of not less than 1.1 wherein Sa is the surface concentration of the anionic hydrophilic groups in the monolayer film, and Da is the deep concentration of the hydrophilic groups at ½ of the thickness of the monolayer film. |