序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
181 Silane diimidic tetracarboxylic perylene dyes US663166 1984-10-22 US4613667A 1986-09-23 Antonio Marraccini; Filippo M. Carlini; Giorgio Bottaccio; Antonio Pasquale; Giorgio Maranzana
Silane diimidic tetracarboxylic perylene dyes, the composite pigments obtainable therefrom by means of grafting onto an inorganic substrate, and the processes for preparing same.The dyes have the general formula: ##STR1## in which R is the residue of a silane group of formula: ##STR2## in which n is 3, 4 or 5; q is 0 or 1, p and m are such integers than when q is 0, p is 3 and m is 0, 1, 2 or 3, and when q is 1, p is 2 and m is 0, 1 or 2; R.sub.2 is an alkyl C.sub.1 -C.sub.4 or a phenyl; R.sub.3 is an alkoxyl C.sub.1 -C.sub.2 ; R.sub.1 may be the same as R or represent an alkyl C.sub.1 -C.sub.6, a cycloalkyl, a phenyl optionally substituted by one or more alkyl or alkoxyl groups C.sub.1 -C.sub.6 or a halogen.The dyes and the composite pigments obtained from said dyes are utilized in paints, air and stove enamels, in the pigmentation of plastic materials, and in printing inks.
182 Quinophthalonic dyes containing silane groups and process for preparing same US458197 1983-01-17 US4458073A 1984-07-03 Antonio Marraccini; Marcello Pieroni; Antonio Pasquale; Luigi Balducci
There are described a new class of organic dyes containing silane groups, the composite pigments obtainable therefrom by associating them with a substrate (SiO.sub.2, TiO.sub.2, Al.sub.2 O.sub.3), and the processes for preparing same.The silane organic dyes have the formula (I): ##STR1## wherein all substituents are defined later. The silane dyes (I) are utilized per se for dyeing natural fibres, such as wool, and man-made fibres, such as the polyamide, polyester, polyacrylic fibres and the like, while the composite pigments prepared from said dyes by association with an inorganic substrate are employed in paints, air enamels and stoving enamels, in the pigmentation of plastics, in the inks, in the printing of textiles etc.
183 Silicone-compatible azo dyestuffs US501211 1974-08-28 US3981859A 1976-09-21 Carl Mayn Smith; George Van Dyke Tiers
Azo dyestuffs containing the tris(trimethylsilyloxy)silylalkylamino group, ##EQU1## are produced and are found to be compatible with cured silicone polymers.
184 Silicone-compatible indigo dyestuffs US50121274 1974-08-28 US3920695A 1975-11-18 SMITH CARL MAYN; TIERS GEORGE VAN DYKE
Dyestuffs containing the tris(trimethylsilyloxy)silyalkylamino group,

are produced and are found to be compatible with cured silicone polymers.
185 Tert-silyl and tert-alkyl phthalocyanine dyestuffs US3759947D 1970-11-13 US3759947A 1973-09-18 PUGIN A; HOPFE H; GALLEGRA P
Unmetallized and metallized phthalocyanine dyestuffs being substituted in the benzene nuclei of the phthalocyanine system by from one to four organically trisubstituted tertiary silyl or alkyl groups are described, which dyestuffs are useful for the coloring of synthetic macromolecular materials of polymerizates and polycondensation products, in particular by dyeing in the mass especially of synthetic polyamide and polyolefine fibers; those of the new dyestuffs containing three or, preferably, four tertiary silyl or alkyl groups per phthalocyanine nucleus being of particularly good solubility in certain organic solvents and also useful, apart from the above purposes, for the dyeing of lacquer raw materials, while those new dyestuffs having fewer tertiary silyl or alkyl groups and especially those having only one tertiary silyl or alkyl group per phthalocyanine nucleus are useful as pigments and for the coloring, in the mass, of polyolefin fibers.
186 Treatment of inorganic oxide materials with organosilicon compounds containing aminoalkyl groups and articles produced thereby US3455725D 1968-09-05 US3455725A 1969-07-15 JEX VICTOR B; BAILEY DONALD L
882,052. Arylaminoalkyl silanes and siloxanes. UNION CARBIDE CORPORATION. Oct. 3, 1957 (Oct. 12, 1956], No. 30933/57. Class 2(7) The invention comprises arylaminoalkyl silanes and siloxanes, the former having the formula where Ar is a substituted or unsubstituted phenyl or naphthyl group, X is hydrogen or an alkyl group of 1 to 4 carbon atoms, n is 3 to 8, B is an alkyl or aryl group, a is 0 to 3, and Y is an alkyl group of 1 to 5 carbon atoms or a phenyl or phenoxy group or an alkoxy radical of 1 to 4 carbon atoms. They are prepared by reacting an arylamine ArNHX with an aminoalkylsilane H 2 N(CH 2 )nSi(B)aY 3 -a. The siloxanes may be prepared by hydrolysis of the silane products or by reacting the arylamine and silane in the presence of water. In a modification, aryldiaminoalkylsilanes of the formula are prepared by reacting the aminoalkylsilane with an aryl diamine of the formula D(NHX) 2 where D is an arylene radical. The aminoalkyl silane starting materials are disclosed in Specification 882,096. Suitable arylamines are aniline, N-methyl aniline, anisidines, xylidines, 4-aminodiphenyl, 2-methoxy-5-nitroaniline, mono- and di-chloro- and nitro-anilines, toluidines, alphanaphthylamine, 1-aminonaphthalene -4- and 5- sulphonic acid, 1-hydroxy-6-amino-naphthalene - 3-sulphonic acid, p-phenylenediamine, 4,41- diaminostilbene, dianisidine, benzidine and diaminonaphthalenes. When naphthylamine is used, a catalyst such as sulphanilic or p-toluene sulphonic acid, ammonium iodide or iodine may may added. The polysiloxanes may contain SiO 3/2 or SiO units or may be disiloxanes. The arylaminoalkylsilanes may be converted to dyestuffs by coupling with diazonium salts, as described in Specification 882,063. In the Examples: (1) alpha-naphthylamine is heated with gamma-aminopropyltriethoxysilane in the presence of sulphanilic acid to give N-(gammatriethoxysilylpropyl)- alpha-naphthylamine; (2) N - methyl - N - (gamma - triethoxysilylpropyl) - aniline is hydrolyzed with dilute NH 4 OH to give the siloxane Reference has been directed by the Comptroller to Specification 795,894.
187 Thiazine dyestuffs and process of dyeing fibrous material US65550257 1957-04-29 US2955898A 1960-10-11 BAILEY DONALD L; PIKE RONALD M
188 Azoic colors US67582557 1957-08-02 US2934459A 1960-04-26 CANOVAI JR PETER C
Silicon-containing azo dyestuffs, which may be silanes or siloxanes, and are of the formula where R is an aryl or substituted aryl nucleus, Ar is an arylene or substituted arylene radical, X is hydrogen or alkyl, V is alkyl or aryl, a is at least 3, b is 0 to 3, and the nitrogen atom is at least 3 carbon atoms removed from the silicon atom, are prepared in situ on fibrous material by treating the material with an arylaminoalkylsilane of the formula Ar1-N(X)CaH2\-Si(V)bY3-b where Ar1 is aryl and Y is alkoxy, and then contacting the treated fabric with a diazotized primary arylamine. The siloxane dyes of formula (1) are the same as those of the parent Specification. The arylaminoalkylsilanes of formula (2) are disclosed in Specification 882,052. They may be applied to the fabric as suspensions or solutions in water or in mixtures of water and an organic solvent. After drying, it is treated with a solution of the diazo compound. This latter solution may be stabilized. A number of examples are given.ALSO:Silicon-containing azo dyestuffs, which may be silanes or siloxanes, and are of the formula where R is an aryl or substituted aryl nucleus, Ar is an arylene or substituted arylene radical, X is hydrogen or alkyl, V is alkyl or aryl, a is at least 3, b is 0 to 3, and the nitrogen atom is at least 3 carbon atoms removed from the silicon atom, are formed in situ on fibrous material, particularly glass fabric, by treating the material with an arylamino-alkyl silane of the formula: Ar1-N(X)CaH2aSi(V)bY3-b where Ar1 is aryl and Y is alkoxy, and then contacting the treated fabric with a diazotised primary arylamine. The siloxane dyes of formula (1) are the same as those of the parent specification. The silanes of formula (2) are disclosed in Specification 882,052. They may be applied to the fabric as suspensions or solutions in water or in mixtures of water and an organic solvent, which may contain wetting agents. After drying, the fabric is treated with a solution of the diazo compound, which may be stabilised with the usual amine compounds.
189 Siloxane azo dyestuffs US65550857 1957-04-29 US2925313A 1960-02-16 BAILEY DONALD L; PIKE RONALD M
190 Metal complexes, comprising carbene ligands having an o-substituted non-cyclometalated aryl group and their use in organic light emitting diodes US15862933 2018-01-05 US10118939B2 2018-11-06 Stefan Metz; Korinna Dormann; Glauco Battagliarin; Christian Eickhoff; Flavio Luiz Benedito; Soichi Watanabe; Gerhard Wagenblast; Thomas Geßner; Christian Lennartz; Peter Murer
Cyclometallated Ir complex comprising three N,N diaryl substituted carbene ligands, bearing substituents in the 2 position of the non-cyclometallated aryl ring; an organic electronic device, preferably an organic light-emitting diode (OLED), comprising at least one cyclometallated Ir complex as described above, a light-emitting layer comprising said cyclometallated Ir complex preferably as emitter material, preferably in combination with at least one host material, use of said cyclometallated Ir complex in an OLED and an apparatus selected from the group consisting of stationary visual display units, mobile visual display units, illumination units, units in items of clothing, units in handbags, units in accessories, units in furniture and units in wallpaper comprising said organic electronic device, preferably said OLED, or said light-emitting layer. The present invention further relates to a process for the preparation of said cyclometallated Ir complex.
191 Use of cyclohexanol derivatives as antimicrobial active compounds US15215962 2016-07-21 US10071037B2 2018-09-11 Thomas Rudolph; Tatjana Mueller
The present invention relates to the use of at least one cyclohexanol derivative of the formula (I) and/or (II) as antimicrobial active compound or as anti-acne, antidandruff, antiperspirant or deodorant active compound, to preparations comprising these compounds, and to specific cyclohexanol derivatives and to a process for the preparation thereof.
192 Color conversion films with plasmon enhanced fluorescent dyes US15415886 2017-01-26 US10059876B2 2018-08-28 Daniel Szwarcman; Evgenia Liel Kuks
Color conversion films for a LCD (liquid crystal display) having RGB (red, green, blue) color filters, as well as such displays, formulations, precursors and methods are provided, which improve display performances with respect to color gamut, energy efficiency, materials and costs. The color conversion films absorb backlight illumination and convert the energy to green and/or red emission at high efficiency, specified wavelength ranges and narrow emission peaks. For example, rhodamine-based fluorescent compounds are used in matrices produced by sol gel processes and/or UV (ultraviolet) curing processes which are configured to stabilize the compounds and extend their lifetime—to provide the required emission specifications of the color conversion films. Film integration and display configurations further enhance the display performance with color conversion films utilizing various color conversion elements. Fluorescent emission may be enhanced by plasmon resonance of coupled nanoparticles.
193 Rhodamine derivatives dyes, color-conversion-layer and uses thereof US15622158 2017-06-14 US10059843B2 2018-08-28 Evgenia Liel Kuks; Rony Schwarz; Eran Sella; Mor Shmuel Armon; Daniel Szwarcman
This invention is directed to photoluminescent compounds based on rhodamine dyes with red-shifted absorption and emission maxima and uses thereof for photoluminescence based devices.
194 LONG WAVELENGTH VOLTAGE SENSITIVE DYES US15745044 2016-07-28 US20180209987A1 2018-07-26 Evan W. Miller; Yi-Lin Huang; Alison S. Walker
The disclosure provides for provides for water-soluble near-infra red (NIR) emissive compounds, processes of making the compounds thereof, and use of the compounds therein.
195 COLOR CONVERSION FILMS COMPRISING A RHODAMINE-BASED FLUORESCENT (RBF) COMPOUND AND PLASMON ENHANCED FLUORESCENT DYES US15924302 2018-03-19 US20180208839A1 2018-07-26 Daniel Szwarcman; Evgenia Liel (Jeny) Kuks
Color conversion films for a LCD (liquid crystal display) having RGB (red, green, blue) color filters, as well as such displays, formulations, precursors and methods are provided, which improve display performances with respect to color gamut, energy efficiency, materials and costs. The color conversion films absorb backlight illumination and convert the energy to green and/or red emission at high efficiency, specified wavelength ranges and narrow emission peaks. For example, rhodamine-based fluorescent compounds are used in matrices produced by sol gel processes and/or UV (ultraviolet) curing processes which are configured to stabilize the compounds and extend their lifetime—to provide the required emission specifications of the color conversion films. Film integration and display configurations further enhance the display performance with color conversion films utilizing various color conversion elements. Fluorescent emission may be enhanced by plasmon resonance of coupled nanoparticles.
196 AZETIDINE-SUBSTITUTED FLUORESCENT COMPOUNDS US15897571 2018-02-15 US20180172677A1 2018-06-21 Luke D. LAVIS; Jonathan B. GRIMM; Jiji CHEN; Timothee LIONNET; Zhengjian ZHANG; Andrey REVYAKIN; Joel SLAUGHTER
The presently-disclosed subject matter includes azetidine-substituted fluorescent compounds, where the compounds may be used as probes, dyes, tags, and the like. The presently-disclosed subject matter also includes kits comprising the same as well as methods for using the same to detect a target substance.
197 Organic light-emitting device US14598181 2015-01-15 US09972789B2 2018-05-15 Hwan-Hee Cho; Mi-Kyung Kim; Jae-Yong Lee; Dong-Hyun Kim; Se-Hun Kim; Chang-Woong Chu
An organic light-emitting device includes a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, where the emission layer includes a first host represented by Formula 1 and a second host represented by Formula 2: The organic light-emitting device may have high efficiency and long lifespan.
198 Photoelectric conversion element and method for producing the same US14430407 2013-09-18 US09959982B2 2018-05-01 Takayuki Ishikawa; Kazuya Isobe
To provide a photoelectric conversion element being excellent in photoelectric conversion efficiency and stability of photoelectric conversion function, a method for producing the photoelectric conversion element, and a solar cell using the photoelectric conversion element. A photoelectric conversion element having a substrate, a first electrode, a photoelectric conversion layer containing a semiconductor and a sensitizing pigment, a hole transport layer having a conductive polymer, and a second electrode, wherein the hole transport layer is formed by bringing the photoelectric conversion layer into contact with a solution containing a conductive polymer precursor and an oxidizer at a ratio of 0.1<[Ox]/[M] (wherein [Ox] is the molar concentration of the oxidizer; and [M] is the molar concentration of the conductive polymer precursor), and irradiating the photoelectric conversion layer with light.
199 Organic electric-field light-emitting element, light-emitting material for organic electric-field light-emitting element, and light-emitting device, display device, and illumination device using same element US14124945 2012-06-05 US09954190B2 2018-04-24 Saki Takada; Yasunori Yonekuta; Toshihiro Ise; Tetsu Kitamura; Toru Watanabe; Wataru Sotoyama; Koji Takaku; Katsuyuki Youfu
An organic electroluminescent element that uses a compound expressed by the following general formula emits dark blue light and exhibits little change in chromaticity during brightness modulation. (n1 is an integer from 0 to 8; the R1 [groups] are each independently a substituent substituted for a hydrogen atom of the pyrene skeleton; X is CRaRb (Ra and Rb are each independently a hydrogen atom or a substituent), O, S, or SiRdRe (Rd and Re are each independently a hydrogen atom or a substituent); and A1 to A4 represent each independently either N or CRf (Rf represents a hydrogen atom or a substituent, and two adjacent Rf [groups] may jointly form a saturated or unsaturated ring, but no more than two rings may be formed jointly by two or more of the Rf [groups]).)
200 PHOTOELECTRIC CONVERSION ELEMENT, AND SOLAR CELL USING THE SAME US15840408 2017-12-13 US20180102222A1 2018-04-12 Kenji SHIROKANE; Naoyuki HANAKI; Hirotaka SATOU
Provided is a photoelectric conversion element including: a first electrode that includes a photosensitive layer containing a light absorbing agent on a conductive support; and a second electrode that is opposite to the first electrode. The light absorbing agent includes a compound having a perovskite-type crystal structure that includes a cation of an element of Group 1 in the periodic table or a cationic organic group A, a cation of a metal atom M other than the element of Group 1 in the periodic table, and an anion of an anionic atom or atomic group X. A hole transport layer, which includes a hole transporting material, is provided between the first electrode and the second electrode. The hole transporting material includes a compound represented by any one of the following Formulae (1) to (4).
QQ群二维码
意见反馈