序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 烷嵌段共聚物纳米孔泡沫体、其制备方法以及包含该泡沫体的制品 CN201080039271.8 2010-09-09 CN102482496A 2012-05-30 C.西亚加拉詹; B.詹森; S.K.拉詹德兰; V.拉杰马努里; S.E.塔德罗斯
申请公开了包括聚烷嵌段共聚物的泡沫体;该聚硅氧烷嵌段共聚物包括含有聚硅氧烷嵌段的第一嵌段和含有有机聚合物的第二嵌段;所述第二嵌段不包含聚硅氧烷;所述聚硅氧烷嵌段具有5至45个重复单元;所述泡沫体的平均孔径为小于或等于100纳米。
22 烷MQ树脂增强的硅氧烷弹性体乳液 CN200480029432.X 2004-06-23 CN100366662C 2008-02-06 Y·刘
烷乳液一旦水蒸发则形成树脂增强的弹性体膜。该乳液组合物含有由分散相,所述分散相由(i)直链羟基封端的聚二有机硅氧烷,(ii)硅氧烷MQ树脂,和(iii)有机官能的聚硅氧烷组成的硅氧烷混合物组成。通过混合各成分(i)-(iii),形成混合物,添加乳化剂和水到该混合物中,混合各成分,获得含水基础乳液,调节该基础乳液的pH到酸性或性pH,以便促进交联,和随后中和该乳液,从而制备含水硅氧烷乳液。可通过在环境条件下在基底上干燥乳液,获得弹性体膜。
23 多嵌段共聚物、其制备方法、由其制备的聚合物电解质膜、膜的制备方法和用膜的燃料电池 CN200610168607.6 2006-12-20 CN101037506A 2007-09-19 金惠庆; 李元木; 张赫; 郑镇喆; 朴三大; 张伦珠
提供包括式(1)的聚砜重复单元、式(2)的磺化聚砜重复单元、和式(3)的聚二烷基烷重复单元的多嵌段共聚物,该多嵌段共聚物的制备方法,由该多嵌段共聚物制备的聚合物电解质膜,制备该聚合物电解质膜的方法,和包括该聚合物电解质膜的燃料电池。其中l、m和n为1-200的整数;R1至R8中的每个独立地为氢、氟、或可被至少一个氟原子取代的C1-C10烷基;且X表示可以被氢离子或其他阳离子通过离子交换取代的四烷基胺阳离子。该多嵌段共聚物具有高离子传导性、高疏性、和良好的机械性能,可使甲醇穿透最小化,以及可以低成本制造。此外,该多嵌段共聚物的结构可变化以增加对用于聚合物电解质膜的溶剂的选择性。
24 Curable silicone resin composition containing inorganic oxide and optical member using same US15370452 2016-12-06 US10106666B2 2018-10-23 Ryosuke Kamitani
Provided is a curable silicone resin composition containing an inorganic oxide that may form an optical member having a relatively high refractive index and excellent optical transparency. The curable silicone resin composition may include a first curable silicone resin having a first functional group for surface bonding and a first crosslinkable functional group, a second curable silicone resin having a second functional group for surface bonding and a second crosslinkable functional group, and first and second inorganic oxide particles bonded to the first and second curable silicone resins by the first and second functional groups for surface bonding, respectively. The first and second crosslinkable functional groups may be bonded by applying energy.
25 ROOFING MEMBRANES, COMPOSITIONS, AND METHODS OF MAKING THE SAME US15836417 2017-12-08 US20180162109A1 2018-06-14 Krishnamachari Gopalan; Robert J. Lenhart; Gending Ji; Roland Herd-Smith
A roofing membrane and a method of making the same is provided. The roofing membrane includes a top layer having a flame retardant and a first silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm3; a scrim layer; and a bottom layer having a flame retardant and a second silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm3. The top and bottom layers of the roofing membrane both exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.).
26 SHOE SOLES, COMPOSITIONS, AND METHODS OF MAKING THE SAME US15836436 2017-12-08 US20180160767A1 2018-06-14 Krishnamachari Gopalan; Robert J. Lenhart; Gending Ji; Roland Herd-Smith
A shoe sole composition and method for making a shoe sole are provided. The shoe sole includes a composition comprising a foamed silane-crosslinked polyolefin elastomer having a density less than 0.50 g/cm3. The shoe sole exhibits a compression set of from about 5.0% to about 20.0%, as measured according to ASTM D 395 (6 hrs @ 50° C.). The foamed silane-crosslinked polyolefin elastomer can be produced from a blend including a first polyolefin having a density less than 0.86 g/cm3, a second polyolefin, having a crystallinity less than 40%, a silane crosslinker, a grafting initiator, a condensation catalyst, and a foaming agent.
27 Imprinting process of hot-melt type curable silicone composition for optical devices US15316071 2015-06-04 US09853193B2 2017-12-26 Masaaki Amako; Steven Swier; Haruna Yamazaki; Shin Yoshida; Makoto Yoshitake
The present disclosure relates to a method of making an optical assembly. An optical device is secured in a fixture, the optical device having an optical surface, wherein a silicone film is positioned with respect to the optical surface, the silicone film having a distal surface relative to the optical surface. The method includes, among other features, imprinting the distal surface of the silicone film to create a surface imprint in the distal surface of the silicone film.
28 Compositions of resin-linear organosiloxane block copolymers US14381714 2013-02-27 US09212262B2 2015-12-15 John Horstman; Steven Swier
A process is disclosed for preparing a resin-linear organosiloxane block copolymer by reacting a silanol terminated linear organosiloxane and an organosiloxane resin containing hydrolyzable groups to form a resin-linear organosiloxane block copolymer. The resulting resin-linear organosiloxane block copolymer is then crosslinked to sufficiently increase the average molecular weight of the resin-ituted organosiloxane block copolymer by at least 50%. The resin-linear organosiloxanes block copolymers prepared by the disclosed process may provide optically solid compositions which may be considered as “reprocessable.”
29 FABRICATION OF DIRECTIONALLY ORIENTED BLOCK COPOLYMER FILMS US14405844 2013-06-05 US20150298405A1 2015-10-22 Gurpreet Singh; Alamgir Karim
Directionally oriented block copolymer films and zone annealing processes for producing directionally oriented block films are provided. The zone annealing processes include methods of inducing horizontally oriented block copolymers through a soft sheer process and methods of inducing vertically oriented block copolymers via sharp dynamic zone annealing. The zone annealing processes are capable of both small and large scale production of directionally oriented block films. The cold zone annealing processes are also capable of being combined with graphoepitaxy methods.
30 POLYDIORGANOSILOXANE POLYMIDE COPOLYMERS HAVING ORGANIC SOFT SEGMENTS US14665243 2015-03-23 US20150197675A1 2015-07-16 Audrey A. Sherman; Stephen A. Johnson; Richard G. Hansen
Polydiorganosiloxane polyamide, block copolymers having organic soft segments and methods of making the copolymers are provided.
31 Polydiorganosiloxane polyamide copolymers having organic soft segments US14095328 2013-12-03 US09018331B2 2015-04-28 Audrey A. Sherman; Stephen A. Johnson; Richard G. Hansen
Polydiorganosiloxane polyamide, block copolymers having organic soft segments and methods of making the copolymers are provided.
32 Method for producing porous silicon molded bodies US13576336 2011-01-19 US08629193B2 2014-01-14 Manfred Hoelzl; Frauke Kirschbaum; Robert Maurer; Juergen Pfeiffer; Konrad Alfons Wierer
Thin porous moldings of silicone copolymers, suitable for use as membranes in separation processes, are prepared by forming a solution or suspension of silicone copolymer in two solvents L1 and L2, casting the suspension or solution, and removing solvent L1 to form a silicone copolymer rich phase A, effecting structure formation, and then removing solvent L2 and residues of solvent L2 to form a thin porous molding.
33 Soft foam, molded product, and shock absorber comprising the molded product US12532581 2008-03-21 US08580863B2 2013-11-12 Miaki Shibaya; Masaoki Gotou; Mitsunaga Noda; Masami Kawakami
To provide a foam-molded product which is light-weight and superior in formability, flexibility and shock absorbing capacity, and which exhibits favorable tactile impression and excellent safety, as well as a shock absorber using the same that provides favorable feel in wearing.Means for Resolution: When a foam-molded product is used which is produced by including foamed resin particles in a soft resin obtained from a silicone based polymer, as a base resin, produced by curing a liquid resin composition including: (A) a curing agent having at least two hydrosilyl groups in the molecular chain; (B) a polymer which has at least one alkenyl group in the molecular chain, comprises a saturated hydrocarbon unit or an oxyalkylene unit as a repeating unit that constitutes the main chain, and is a linear polymer having a number average molecular weight of no lower than 10,000; and (C) a hydrosilylation catalyst, the product can be suitably used in garments to which it is attached as a shock absorber at an appropriate site such as the front body, the flank part, the back body and the hip around the lumbar.
34 POLYDIORGANOSILOXANE POLYAMIDE COPOLYMERS HAVING ORGANIC SOFT SEGMENTS US13721370 2012-12-20 US20130109828A1 2013-05-02 Audrey A. Sherman; Stephen A. Johnson; Richard G. Hansen
Polydiorganosiloxane polyamide, block copolymers having organic soft segments and methods of making the copolymers are provided.
35 Polydiorganosiloxane polyamide copolymers having organic soft segments US13253620 2011-10-05 US08361626B2 2013-01-29 Audrey A. Sherman; Stephen A. Johnson; Richard G. Hansen
Polydiorganosiloxane polyamide, block copolymers having organic soft segments and methods of making the copolymers are provided.
36 Siloxane block copolymer nanoporous foams, methods of manufacture thereof and articles comprising the same US12557083 2009-09-10 US08283390B2 2012-10-09 Chinniah Thiagarajan; Bernd Jansen; Santhosh Kumar Rajendran; Vauhini RM; Safwat E. Tadros
Disclosed herein is a foam that includes a polysiloxane block copolymer; the polysiloxane block copolymer including a first block that comprises a polysiloxane block and a second block that includes an organic polymer; the second block not containing a polysiloxane; the polysiloxane block being about 5 to about 45 repeat units; the foam having average pore sizes of less than or equal to about 100 nanometers.
37 Dispersion of Fluorosilicones and Fluorine- and Silicon-Containing Surface Treatment Agent US12935344 2009-03-12 US20110124803A1 2011-05-26 Ikuo Yamamoto; Tetsuya Masutani; Masahiro Miyahara; Takashi Enomoto; Shinichi Minami; Peter Cheshire Hupfield; Samantha Reed; Avril E. Surgenor
A fluorosilicone reaction product of a mercapto or vinyl functional organopolysiloxane and a fluorine-containing monomer, and methods of preparing the fluorosilicone are disclosed. The fluorosilicone products are suitable for application to substrates such as textiles, particularly fabrics, to impart oil repellent properties to the textile. The fluorosilicone reaction product is prepared from (A) a fluorine-containing monomer of the formula CH2═C(X)COOYRf, and (B) a mercapto or vinyl functional organopolysiloxane.
38 POLYMER NETWORKS, PROCESS FOR PRODUCING SAME, AND PRODUCTS MADE THEREFROM US12792644 2010-06-02 US20100305231A1 2010-12-02 Joseph P. KENNEDY; Ummadisetty Subramanyam
The present invention relates to the production of copolymer networks, or co-networks, and to methods for preparing copolymer or co-networks. Furthermore, the present invention relates to products and/or films made from the copolymer and/or co-networks produced in accordance with the synthesis methods of the present invention. Additionally, the present invention relates to crosslinked copolymer and/or co-networks comprising at least one hydrophilic segment and at least one hydrophobic segment. In one embodiment, the hydrophilic segments include at least one poly(vinyl alcohol) (e.g., a poly(vinyl alcohol) modified with acryl amide groups) and the hydrophobic segments include at least one polysiloxane having at least one terminal —OH group (e.g., polydimethylsiloxane (PDMS)). In another embodiment, the copolymer and/or co-networks of the present invention are optically clear and highly oxophilic.
39 SILICONE MICROPARTICLES COMPRISING SILICONE ELASTOMER SPHERICAL MICROPARTICLES COATED WITH POLYORGANOSILSESQUIOXANE, AND METHOD OF PRODUCING SAME US12609429 2009-10-30 US20100112074A1 2010-05-06 Yoshinori INOKUCHI; Ryuji Horiguchi
Provided are silicone microparticles including 100 parts by mass of silicone elastomer spherical microparticles having a volume average particle diameter within a range from 0.1 to 100 μm, and 0.5 to 25 parts by mass of a polyorganosilsesquioxane that coats the surface of the silicone elastomer spherical microparticles, in which the silicone elastomer is capable of absorbing not less than 200 parts by mass of a polymethylsiloxane having a viscosity at 25° C. of not more than 10 mm2/s per 100 parts by mass of the silicone elastomer. These silicone microparticles are capable of absorbing a large amount of the above types of polymethylsiloxanes, which represent low-viscosity silicones, and can therefore suppress the greasiness, stickiness, and oily film feeling of cosmetic materials containing this type of polymethylsiloxane. The silicone microparticles can be produced by hydrolyzing and condensing an organotrialkoxysilane in a water medium, in the presence of the above silicone elastomer spherical microparticles and an alkaline material, thereby coating the surface of the silicone elastomer spherical microparticles with a polyorganosilsesquioxane.
40 SILICONE MICROPARTICLES COMPRISING SILICONE ELASTOMER SPHERICAL MICROPARTICLES COATED WITH POLYORGANOSILSESQUIOXANE, AND METHOD OF PRODUCING SAME US12609524 2009-10-30 US20100112023A1 2010-05-06 Yoshinori INOKUCHI; Ryuji Horiguchi
Provided are silicone microparticles including 100 parts by mass of silicone elastomer spherical microparticles having a volume average particle diameter within a range from 0.1 to 100 μm, and 0.5 to 25 parts by mass of a polyorganosilsesquioxane that coats the surface of the silicone elastomer spherical microparticles, in which the silicone elastomer is capable of absorbing not less than 30 parts by mass of at least one oily substance selected from the group consisting of sebum, hydrocarbon oils and ester oils per 100 parts by mass of the silicone elastomer. These silicone microparticles are capable of absorbing a large amount of the above oily substances, are able to ameliorate various problems caused by sebum such as changes in cosmetic make-up properties, changes in the color of cosmetic materials and increased shininess of cosmetic materials, and are also able to suppress the greasiness, stickiness, and oily film feeling of cosmetic materials containing at least one of liquid oils composed of hydrocarbon oils and ester oils. The silicone microparticles can be produced by hydrolyzing and condensing an organotrialkoxysilane in a water medium, in the presence of the above silicone elastomer spherical microparticles and an alkaline material, thereby coating the surface of the silicone elastomer spherical microparticles with a polyorganosilsesquioxane.
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