序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 Method for producing substrate having dispersed particles of dendrimer compound on the surface thereof, and substrate having dispersed particles of dendrimer compound on the surface thereof US13567926 2012-08-06 US09192994B2 2015-11-24 Isao Hirano; Kimihisa Yamamoto; Takane Imaoka
A method for producing a substrate having dispersed particles of a dendrimer compound on the surface thereof, the method including: an application step including dissolving a phenyl azomethine dendrimer compound in a solvent to prepare a solution, and applying the solution on the surface of a substrate; and a volatilization step including volatilizing the solvent from the solution applied on the surface of the substrate, the phenyl azomethine dendrimer compound included in the solution having a concentration of no greater than 5 μmol/L is employed.
102 THERMAL-RESPONSIVE POLYMER NETWORKS, COMPOSITIONS, AND METHODS AND APPLICATIONS RELATED THERETO US14058336 2013-10-21 US20140357806A1 2014-12-04 Jie Song; Jianwen Xu
The invention relates to materials comprising polymer network containing siloxanes or organic-based core structures, preferably the materials have thermal-responsive properties. In some embodiments, the invention relates to an organic core functionalized with polymers. In another embodiment, organic core-polymer conjugates comprise polylactone segments. The organic core-polymer conjugates may be crosslinked together to form a material, and these materials may be functionalized with bioactive compounds so that the materials have desirable biocompatibility or bioactivity when used in medical devices.
103 DECORATED MACROMOLECULAR SCAFFOLDS US14111840 2012-04-11 US20140221569A1 2014-08-07 Hubert Gaertner; Oliver Hartley
The present invention relates to a method for preparing decorated macromolecular scaffolds. The method of the invention is useful for the generation of bioactive nanoparticles for use in clinical applications. Such applications include drag and gene delivery, tumour targeting, bioimaging, tissue remodelling, generation of antiviral products and vaccines delivery.
104 Process for making a saturated dendritic hydrocarbon polymer US13329559 2011-12-19 US08623980B2 2014-01-07 David John Lohse; Nikos Hadjichristidis; Andy Haishung Tsou; Pamela J. Wright; Suzzy Chen Hsi Ho; Paul Edward Schuenzel
A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.
105 PROCESS FOR MAKING DENDRITIC POLYOLEFINS FROM TELECHELIC POLYCYCLIC OLEFINS US13341033 2011-12-30 US20130172493A1 2013-07-04 Shuji Luo; Andy Haishung Tsou
A process for making dendritic hydrocarbon polymers by reacting an amount of one or more telechelic hydrocarbon polymers with an amount of one or more multifunctional coupling agents under conditions sufficient to produce the dendritic hydrocarbon polymer. The telechelic hydrocarbon polymer is made by ring opening metathesis polymerization (ROMP) in the presence of bi-functional alkene chain terminating agents (CTAs). The dendritic hydrocarbon polymer can be hydrogenated to produce a substantially saturated dendritic hydrocarbon polymer. The dendritic polyethylenes (dPE) can be used as processability additives to provide extensional hardening in low concentrations in various conventional polyethylenes (PEs) such as HDPE, LLDPE and mLLDPE.
106 DENDRITIC ETHYLENE POLYMERS AND PROCESSES FOR MAKING US13182868 2011-07-14 US20130018120A1 2013-01-17 Andy H. Tsou; Shuji Luo; Donna J. Crowther; Gabor Kiss; Johannes M. Soulages; Pradeep P. Shirodkar
Provided is a dendritic ethylene polymer. The polymer is a dendritic polymer of an ethylene/alpha-olefin-diene copolymer and a vinyl-terminated polyethylene. There is also provided a process for making a dendritic ethylene polymer. The process includes the steps of preparing a dendritic ethylene polymer by reacting ethylene/alpha-olefin-diene copolymer with vinyl-terminated polyethylene in the presence of a radical source. There is also provided a blend and a blown film that include the dendritic ethylene polymer.
107 PROCESS FOR MAKING A SATURATED DENDRITIC HYDROCARBON POLYMER US13329559 2011-12-19 US20120157633A1 2012-06-21 David John Lohse; Nikos Hadjichristidis; Andy Haishung Tsou; Pamela J. Wright; Suzzy Chen Hsi Ho; Paul Edward Schuenzel
A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.
108 DENDRIMER AND ORGANIC LIGHT-EMITTING DEVICE USING THE SAME US13178948 2011-07-08 US20120013246A1 2012-01-19 Yoon-Hyun KWAK; Jeoung-In Yi; Seung-Gak Yang; Hee-Yeon Kim; Jae-Yong Lee
A dendrimer and an organic light-emitting device including an organic layer having the dendrimer.
109 Dielectric Materials and Methods of Preparation and Use Thereof US13007148 2011-01-14 US20110175089A1 2011-07-21 Yan Zheng; Jordan Quinn; He Yan; Yan Hu; Shaofeng Lu; Antonio Facchetti
Disclosed are dendritic macromolecule-based dielectric compositions (e.g., formulations) and materials (e.g. films) and associated devices. The dendritic macromolecules have branched ends that are functionalized with an organic group that includes at least one 3-40 membered cyclic group.
110 SYNTHESIS OF ARBORESCENT POLYMERS VIA CONTROLLED INIMER-TYPE REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER (RAFT) POLYMERIZATION US13058570 2009-08-11 US20110144268A1 2011-06-16 Judit Eva Puskas; Andrew John Heidenreich
Randomly branched polymers, such as homopolymers, copolymers, block copolymers and functionalized polymers are disclosed which may be formed by polymerizing a polymerizable monomer, such as styrene with a dithioester chain transfer agent which includes a polymerizable group. The reaction may be performed in one pot. The randomly branched polymer can have high molecular weight and broad molecular weight distribution.
111 Visible light-absorbing complex, triazine-based dendritic polymer, and organic photovoltiac device US12591650 2009-11-25 US20100137539A1 2010-06-03 Long-Li Lai; Shun-Ju Hsu; Hui-Chu Hsu
A visible light-absorbing complex includes an electron acceptor and an electron donor, the electron donor having a triazine-based dendritic polymer formed of a core group (C) and branch groups, each of the branch groups being composed of terminal groups (P) and a triazine-based moiety group. The triazine-based dendritic polymer is represented by the following formula (I): wherein G indicates the generation number, “G-1” indicating the layer number of the branch groups, n being the number of the terminal groups, m being the number of the branch groups, wherein Z1 is a divalent group containing O or N, and an atom of Z1 bonding to the triazine group should be O or N; and wherein, when G is 1, the core group should be a triazine-based core group having a triazine ring, and an atom of each of the terminal groups bonding to the triazine ring should be O or N.
112 Branched Compounds And Their Use in Sensors US12159433 2007-01-05 US20090314957A1 2009-12-24 Paul Leslie Burn; Ifor David William Samuel; Homar Barcena
The invention provides sensors comprising one or more compounds of formulae (I) and (II): [DENDRON1]p-CORE-[[X]r-[DENDRON]m]n  (I) [DENDRON1]p-[X]r-[DENDRON]q  (II) wherein CORE, X, DENDRON, DENDRON1, m, n, p, q and r are as defined herein. The optical (e.g. luminescent) and electronic properties of the compounds are capable of being altered by exposure to a number of different substances. The invention also provides the use of the compounds disclosed above in the sensing of substances, in particular explosives.
113 DIELS-ALDER CROSSLINKABLE DENDRITIC NONLINEAR OPTIC CHROMOPHORES AND POLYMER COMPOSITES US12474174 2009-05-28 US20090299021A1 2009-12-03 Kwan-Yue Jen; Zhengwei Shi; Jingdong Luo; Su Huang; Xinghua Zhou
Diels-Alder crosslinkable dendritic nonlinear optical chromophore compounds, films and crosslinked polymer composites formed from the chromophore compounds, methods for making and using the chromophore compounds, films, and crosslinked polymer composites, and electro-optic devices that include films and crosslinked polymer composites formed from the chromophore compounds.
114 Thermoplastic polymer composition comprising a hyperbranched polymer and articles made using said composition US10498255 2002-12-16 US07507474B2 2009-03-24 Joël Varlet; Florence Clement; Franck Touraud; Sandrine Rochat; Natalia Scherbakoff
The invention relates to thermoplastic compositions comprising a polymer matrix and an additive which modifies the rheological behavior of the matrix in the molten state. The purpose of the invention is to provide a preferably non-reactive additive which can be dispersed in the matrix and which can be used to obtain a good compromise in terms of rheological properties/mechanical properties. According to the invention, the additive is a hyperbranched polymer which is functionalized by R<2> radicals, R<2> being a radical of the following type: substituted or non-substituted hydrocarbon, of the silicon type, linear or branched alkyl, aromatic, arylalkyl, alkylaryl or cycloaliphatic, which can comprise one or more unsaturations and/or one or more heteroatoms. Preferably, the composition does not contain hyperbranched polymers which produce therein a reduction in the molar mass of matrix M which is greater than or equal to 7% in relation to a sample composition which comprises matrix M but which does not contain hyperbranched polymer additive(s). Said mass measurement is taken preferably using a predetermined protocol P. The invention is suitable for molding, extrusion, engineered plastics, wires and fibers.
115 Hyperbrached Polymer for Micro Devices US12092351 2006-11-08 US20080286152A1 2008-11-20 Lars Schmidt; Yves Leterrier; Jan-Anders Manson; Young-Ho Cho; Young-Hyun Jin
The invention relates to novel polymer-based microstructures, with outstanding shape accuracy and cost-effective processing. The novel polymers are based on hyperbranched macromolecules and enable remarkable property combination such as reduced shrinkage and associated low stress, high shape fidelity and high aspect ratio in patterned microstructures, with additional benefit of fast and low-cost production methods. The invention also relates to methods to produce these microstructures. The polymer-based microstructures are relevant for, but not limited to micro- and nano- technologies applications, including lab-on-a-chip devices, opto-electronic and micro- electromechanical devices, optical detection methods, in fields of use as diverse as automotive, aerospace, information technologies, medical and biotechnologies, and energy systems.
116 Polymer additives with improved permanence and surface affinity US11904512 2007-09-27 US20080027182A1 2008-01-31 John McNamara; Mervin wood; Ying Dong
Novel stabilizers that are comprised of known polymer additive moieties chemically bound to hyperbranched and/or dendritic polymers or copolymers, and novel stabilizers comprised of known polymer additive moieties chemically bound to amphiphilic copolymers exhibit superior permanence in an organic substrate as well as high surface affinity.
117 Thermoplastic polymer composition comprising a hyperbranched polymer and articles made using said composition US10498255 2002-12-16 US20060211822A1 2006-09-21 Joel Varlet; Florence Clement; Franck Touraud; Sandrine Rochat; Natalia Scherbakoff
The invention relates to thermoplastic compositions comprising a polymer matrix and an additive which modifies the rheological behaviour of the matrix in the molten state. The purpose of the invention is to provide a preferably non-reactive additive which can be dispersed in the matrix and which can be used to obtain a good compromise in terms of rheological properties/mechanical properties. According to the invention, the additive is a hyperbranched polymer which is functionalised by R<2> radicals, R<2> being a radical of the following type: substituted or non-substituted hydrocarbon, of the silicon type, linear or branched alkyl, aromatic, arylalkyl, alkylaryl or cycloaliphatic, which can comprise one or more unsaturations and/or one or more heteroatoms. Preferably, the composition does not contain hyperbranched polymers which produce therein a reduction in the molar mass of matrix M which is greater than or equal to 7% in relation to a sample composition which comprises matrix M but which does not contain hyperbranched polymer additive(s). Said mass measurement is taken preferably using a predetermined protocol P. The invention is suitable for moulding, extrusion, engineered plastics, wires and fibres.
118 Ultra_high molecular weight hybrid dendrigraft architectures US10639939 2003-08-13 US20050038197A1 2005-02-17 Donald Tomalia; Douglas Swanson
Mono-reactive dendrigrafts prepared by convergent self-branching polymerization and their subsequent grafting to linear, dendritic, and dendrigraft, branched, and hyper-branched substrates to prepare ultra-high molecular weight dendrigraft architectures using alkyl halides and aryl halides as initiators.
119 Polymer additives with improved permanence and surface affinity US10477363 2003-11-12 US20040156933A1 2004-08-12 John James McNamara; Mervin Gale Wood; Ying Dong
Novel stabilizers that are comprised of known polymer additive moieties chemically bound to hyperbranched and/or dendritic polymers or copolymers, and novel stabilizers comprised of known polymer additive moieties chemically bound to amphiphilic copolymers exhibit superior permanence in an organic substrate as well as high surface affinity.
120 Use of hyperbranched polymers and dendrimers comprising a particular group as film-forming agent, film-forming compositions comprising same and use particularly in cosmetics and pharmaceutics US09581752 2000-06-23 US06432423B1 2002-08-13 Jean Maignan; Sylvie Genard
The invention concerns the use of hyperbranched polymers and dendrimers, comprising at least one group of formula (I) in which: Y represents the oxygen atom or a NH group: and A represents a C1-C12 alkane di-yl group, linear, branched or cyclic, saturated or unsaturated; said group being optionally interrupted by one or several heteroatoms and/or substituted by a function selected among: amino (—NH2): acylamino (—NH—CO—R) in which R represents a C1-C10 alkyl group, linear, branched or cyclic, saturated or unsaturated; carboxylic acid (—COOH), ester (—COOR) in which R represents a C1-C10 alkyl group, linear, branched or cyclic, saturated or unsaturated, as film-forming agent. The invention also concerns a film-forming composition comprising said compound and its use particularly in cosmetics or pharmaceutics.
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