子分类：
| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 101 | Pyrolytic formation of metallic nanoparticles | US12051179 | 2008-03-19 | US07700710B2 | 2010-04-20 | Teddy M Keller; Manoj K. Kolel-Veetil; Syed B Qadri |
| A method and a ceramic made therefrom by: providing a composition of a compound having the formula below and a metallic component, and pyrolyzing the composition. R is an organic group. The value n is a positive integer. Q is an acetylenic repeat unit having an acetylene group, crosslinked acetylene group, (MLx)y-acetylene complex, and/or crosslinked (MLx)y-acetylene complex. M is a metal. L is a ligand. The values x and y are positive integers. The metallic component is the (MLx)y-acetylene complex in the compound or a metallic compound capable of reacting with the acetylenic repeat unit to form the (MLx)y-acetylene complex. The ceramic comprises metallic nanoparticles. | ||||||
| 102 | BIREFRINGENT METAL-CONTAINING COORDINATION POLYMERS | US12278891 | 2007-02-09 | US20090242856A1 | 2009-10-01 | Daniel Bernard Leznoff; Michael Iacov Katz |
| This application relates to metal-containing coordination polymers having high birefringent values. For example, polymers having birefringent values within the range of 0.07 to 0.45 are described. The polymers may comprise units having the formula M(L)X[M′(Z)Y]N, wherein M and M′ are the same or different metals capable of forming a coordinate complex with the Z moiety; L is a ligand; Z is selected from the group consisting of halides, pseudohalides, thiolates, alkoxides and amides; X is between 0-12; Y is between 2-9; and N is between 1-5. In particular embodiments of the invention L may be a highly anisotropic organic ligand, such as terpyridine, and Z may be a pseudohalide, such as CN. The invention also includes methods for synthesizing the coordination polymers and use of the polymers in birefringent materials and devices. In one embodiment the polymers may be processible into thin films. | ||||||
| 103 | Polymeric material made from siloxane-acetylene polymer containing metal-acetylene complex | US11239452 | 2005-09-27 | US07579430B2 | 2009-08-25 | Teddy M. Keller; Manoj Kolel-Veetil |
| A metallized polymer having a backbone having an acetylenic repeat unit and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. At least one of the acetylenic repeat units contains a (MLx)y-acetylene complex. M is a metal, L is a ligand, x and y are positive integers, R is an organic group, Cb is a carborane, and n and m are greater than or equal to zero. A composition containing a siloxane polymer and a metallic compound. The siloxane polymer has a backbone having one or more acetylene groups and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. The metallic compound is capable of reacting with the acetylene group to form a (MLx)y-acetylene complex. | ||||||
| 104 | Organic-Inorganic Hybrid Material, Composition for Synthesizing the Same, and Manufacturing Method of the Same | US12420548 | 2009-04-08 | US20090206746A1 | 2009-08-20 | Satoshi Seo; Harue Nakashima; Ryoji Nomura |
| An organic-inorganic hybrid material comprising a metal oxide and a chelating ligand is synthesized. The function of a coloring property, a light-emitting property, or semiconductivity of the organic-inorganic hybrid material can be controlled by chelating ligand. The organic-inorganic hybrid material is prepared by sol-gel method using sol which includes a metal alkoxide and/or a metal salt and a functional chelating agent | ||||||
| 105 | REVERSIBLE SELF-ASSEMBLY OF IMBEDDED METALLOMACROCYCLES WITHIN A MACROMOLECULAR SUPERSTRUCTURE | US11720088 | 2005-11-23 | US20090171088A1 | 2009-07-02 | George R. Newkome; Charles N. Moorefield; Pingshan Wang |
| In accordance with the present invention, there is provided a method for preparing a reversible, self-assembly of an imbedded hexameric metallomacrocycle within a macromolecular superstructure. The method occurs by an intramolecular mechanism in which a macromolecular skeleton possesses multiple ligands capable of reversible assembly-disassembly triggered by the presence of metal ions. | ||||||
| 106 | Inorganic Polymers and Use of Inorganic Polymers for Detecting Nitroaromatic Compounds | US11990832 | 2005-08-25 | US20090137059A1 | 2009-05-28 | William C. Trogler; Sara A. Urbas; Sarah J. Toal; Jason Sanchez |
| A method for detecting an analyze that may be present in ambient air, bound to a surface or as part of complex aqueous media that includes providing a metallole-containing polymer or copolymer, exposing the polymer or copolymer to a suspected analyze or a system suspected of including the analyze, and measuring a quenching of photoluminescence of the metallole-containing polymer or copolymer exposed to the system. Also included is a solid state inorganic-organic polymer sensor for detecting nitroaromatic compounds that includes a substrate and a thin film of a metallole-containing polymer or copolymer deposited on said substrate. | ||||||
| 107 | Organic-inorganic hybrid material, composition for synthesizing the same, and manufacturing method of the same | US10809130 | 2004-03-25 | US07517470B2 | 2009-04-14 | Satoshi Seo; Harue Nakashima; Ryoji Nomura |
| An organic-inorganic hybrid material comprising a metal oxide and a chelating ligand is synthesized. The function of a coloring property, a light-emitting property, or semiconductivity of the organic-inorganic hybrid material can be controlled by chelating ligand. The organic-inorganic hybrid material is prepared by sol-gel method using sol which includes a metal alkoxide and/or a metal salt and a functional chelating agent. | ||||||
| 108 | PYROLYTIC FORMATION OF METALLIC NANOPARTICLES | US12051179 | 2008-03-19 | US20080227624A1 | 2008-09-18 | Teddy M. Keller; Manoj K. Kolel-Veetil; Syed B. Qadri |
| A method and a ceramic made therefrom by: providing a composition of a compound having the formula below and a metallic component, and pyrolyzing the composition. The value n is a positive integer. Q is an acetylenic repeat unit having an acetylene group, crosslinked acetylene group, (MLx)y-acetylene complex, and/or crosslinked (MLx)y-acetylene complex. M is a metal. L is a ligand. The values x and y are positive integers. The metallic component is the (MLx)y-acetylene complex in the compound or a metallic compound capable of reacting with the acetylenic repeat unit to form the (MLx)y-acetylene complex. The ceramic comprises metallic nanoparticles. | ||||||
| 109 | Metal-Containing Compound and Use Thereof | US11667227 | 2005-11-16 | US20080027198A1 | 2008-01-31 | Hiroshi Naruse; Atsuo Otsuji; Mitsuo Nakamura |
| A compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin are provided. The polymerizable composition can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7. | ||||||
| 110 | CONDUCTIVE POLYMERS FROM PRECURSOR POLYMERS, METHOD OF MAKING, AND USE THEREOF | US11675842 | 2007-02-16 | US20070191576A1 | 2007-08-16 | Gregory Sotzing |
| Disclosed herein are precursor polymers containing units of heteroaryls and units of Si, Sn, Ge, or Pb, methods of producing the precursor polymers, and applications utilizing these precursor polymers to prepare conductive polymers. | ||||||
| 111 | Organic-inorganic composite forming material, organic-inorganic composite, production method thereof and optical element | US11637126 | 2006-12-12 | US20070149700A1 | 2007-06-28 | Nobuhiko Hayashi; Mitsuaki Matsumoto; Keiichi Kuramoto; Masaya Nakai |
| An organic-inorganic composite forming material which contains an organometallic polymer having an -M-O-M- bond (M denotes a metal atom), an acrylic monomer or oligomer having a hydrophilic group and inorganic particles. Preferably, the organometallic polymer has Si in the place of M and is obtained via hydrolysis and polycondensation of trialkoxysilane having a photo- or thermally-polymerizable group and dialkoxysilane having a phenyl group. | ||||||
| 112 | Ceramic material made from siloxane-acetylene polymer containing metal-acetylene complex | US11239454 | 2005-09-27 | US20070073038A1 | 2007-03-29 | Teddy Keller; Manoj Kolel-Veetil; Syed Qadri |
| A ceramic made by providing a composition and pyrolyzing the composition. The composition has siloxane polymer, metallic polymer, siloxane thermoset, and/or metallic thermoset having a backbone having: an acetylenic repeat unit; and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m. R is an organic group, Cb is a carborane, and n and m are integers greater than or equal to zero. Any crosslinking is a crosslink between acetylene groups and/or a polycarbosiloxane crosslink. The composition also has free metal atoms, metal clusters, or metal nanoparticles dispersed homogeneously throughout the composition; (MLx)y-acetylene complex in the backbone; and/or a metallic compound for forming a (MLx)y-acetylene complex. M is a metal, L is a ligand, x and y are positive integers. | ||||||
| 113 | Polymeric material made from siloxane-acetylene polymer containing metal-acetylene complex | US11239452 | 2005-09-27 | US20070073036A1 | 2007-03-29 | Teddy Keller; Manoj Kolel-Veetil |
| A metallized polymer having a backbone having an acetylenic repeat unit and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. At least one of the acetylenic repeat units contains a (MLx)y-acetylene complex. M is a metal, L is a ligand, x and y are positive integers, R is an organic group, Cb is a carborane, and n and m are greater than or equal to zero. A composition containing a siloxane polymer and a metallic compound. The siloxane polymer has a backbone having one or more acetylene groups and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. The metallic compound is capable of reacting with the acetylene group to form a (MLx)y-acetylene complex. | ||||||
| 114 | Thermoset material made from siloxane-acetylene polymer containing metal-acetylene complex | US11239448 | 2005-09-27 | US20070073027A1 | 2007-03-29 | Teddy Keller; Manoj Kolel-Veetil |
| A metallized thermoset containing a crosslinked metallized polymer having a backbone having an acetylenic repeat unit and —SiR2—(O—SiR2)n— and/or —SiR2—(O—SiR2)n-[Cb-SiR2—(O—SiR2)n]m—. At least one of the acetylenic repeat units contains a (MLx)y-acetylene complex. The metallized thermoset contains a crosslink between acetylene groups and/or a polycarbosiloxane crosslink. M is a metal, L is a ligand, x and y are positive integers, R is an organic group, Cb is a carborane, and n and m are greater than or equal to zero. A method of making a metallized thermoset by providing a metallized polymer and heating the metallized polymer. The metallized polymer contains the above backbone. Heating the metallized polymer forms crosslinks between acetylene groups and/or polycarbosiloxane crosslinks. | ||||||
| 115 | Heat resistant thermally conductive material | US10544168 | 2004-01-05 | US20060142471A1 | 2006-06-29 | Takuya Shindo |
| The object of the present invention is to provide a heat resistant thermally conductive material, to which fine powder such as dust, toner, and the like are hard to adhere, and which has good heat radiative properties. To attain this object, the present invention provides a heat resistant thermally conductive material, being made from an organic-inorganic hybrid material, which is prepared by heating a sol containing a metal or semimetal alkoxide, and an organo-silicon compound, plus a high thermally conductive filler, to gel said sol. Said organic-inorganic hybrid has excellent mold release characteristics, so that dust, toner, and the like don't easily adhere to the thermally conductive material, and if dust, toner and the like adhere to the thermally conductive material, they are easily removed therefrom. Further, said more highly thermally conductive filler imparts good heat radiative properties to said organic-inorganic hybrid. | ||||||
| 116 | Nanoscale solid-state polymeric battery system | US10380697 | 2001-10-22 | US07063918B2 | 2006-06-20 | Peter Kofinas; Steven Bullock |
| The present invention relates to a unique polymeric battery system of electrochemical cells that are connected in series, and can be of nanometer size. The polymers possess conjugated bonds along their backbones and high levels of metals. The invention also concerns methods for the fabrication of the polymers and battery system as well as methods for the use of the polymers as a nanoscale solid-state battery. | ||||||
| 117 | Synthesis and use of inorganic polymer sensor for detecting nitroaromatic compounds | US10528967 | 2003-10-06 | US20060051872A1 | 2006-03-09 | Michael Sailor; William Trogler; Honglae Sohm; Sarah Toal |
| A dehydrocoupling polycondensation method for synthesizing polymetalloles including obtaining a dihydrometallole that includes silicon or germanium atoms, designating a reducing agent for preparation of dihydrometallole monomer, measuring a predetermined molar percentage of the reducing agent corresponding to a molar amount of the dihydrometallole, selecting a catalyst, and reacting the catalyst with the dihydrometallole to obtain a polymetallole. A method for detecting an analyte that may be present in ambient air or complex aqueous media including providing a polymer or copolymer containing a metalloid-metalloid backbone, exposing the polymer or copolymer to a suspected analyte or a system suspected of including the analyte, and measuring a quenching of photoluminescence of the metallole polymer or copolymer exposed to the system. | ||||||
| 118 | Organic-inorganic hybrid material, composition for synthesizing the same, and manufacturing method of the same | US10809130 | 2004-03-25 | US20040265253A1 | 2004-12-30 | Satoshi Seo; Harue Nakashima; Ryoji Nomura |
| An organic-inorganic hybrid material chelating a metal atom of a metal oxide matrix 103 in a pendant shape is synthesized, where the organic compound (the functional chelating agent) 104 is able to develop a function of a coloring property, a light-emitting property, or semiconductivity by chelating a metal atom. As a synthesis method, sol (a composition for coating application) including a metal alkoxide and/or a metal salt and a functional chelating agent may be prepared and the organic-inorganic hybrid material may be synthesized by sol-gel method. Due to the above-mentioned structure, it is possible to synthesize an organic-inorganic hybrid material that has an organic group directly bonded to a metal oxide matrix and is able to develop a different function from that of a mere metal oxide. In other words, it is possible to realize a functional organic-inorganic hybrid material that develops a coloring property, a light-emitting property, or semiconductivity due to the organic group directly bonded to the metal oxide matrix. | ||||||
| 119 | Hybrid organic-inorganic polymer coatings with high refractive indices | US10758503 | 2004-01-15 | US20040171743A1 | 2004-09-02 | Tony D. Flaim; Yubao Wang; Ramil-Marcelo L. Mercado |
| Novel compositions and methods of using those compositions to form metal oxide films or coatings are provided. The compositions comprise an organometallic oligomer and an organic polymer or oligomer dispersed or dissolved in a solvent system. The compositions have long shelf lives and can be prepared by easy and reliable preparation procedures. The compositions can be cured to cause conversion of the composition into films of metal oxide interdispersed with organic polymer or oligomer. The cured films have high refractive indices, high optical clarities, and good mechanical stabilities at film thicknesses of greater than about 1 nullm. | ||||||
| 120 | High molecular weight polymers | US10396042 | 2003-03-25 | US20040010108A1 | 2004-01-15 | Patricia A. Bianconi; Scott Joray |
| High and ultrahigh molecular weight (MW) homo- and copolymers having a three-dimensional random network structure are disclosed. The polymers have recurring structural units of the general formula nullARnulln, wherein A can be carbon, silicon, germanium, tin atoms, or other elements and compounds. R can be the same as or different from A (in each repeating unit), and can be hydrogen, saturated linear or branched-chain hydrocarbons containing from about 1 to about 30 carbon atoms, unsaturated ring-containing or ring hydrocarbons containing from about 5 to about 14 carbon atoms in the ring, each in substituted or unsubstituted form, polymer chain groups having at least 20 recurring structural units, halogens, or other elements or compounds. The number nullnnull can be at least 20, and the high MW polymers have a molecular weight of at least 10,000 daltons, e.g., about 30,000 daltons, and as high as 1,000,000 or more daltons. | ||||||
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