序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 基化表面活性剂 CN201480071316.8 2014-12-22 CN105849087A 2016-08-10 G.阿汉赛特; S.龙; 王小军; R.V.恩布斯; B.格拉迪; J.哈维尔; 于光哲
发明提供含硫或硒化合物,所述化合物包括疏性部分和乙基化酯或乙氧基化酰胺部分以使得所述化合物具有表面活性剂性质。还提供在各种应用中使用所公开化合物或其混合物的方法。
2 适合无生命有机材料的抗静电改性和导电性改善的添加剂配制剂 CN200880006889.7 2008-02-28 CN101622329B 2013-03-13 D·波塞尔; F-O·梅林; A·郎格; A·文柯基尔; C·科尔曼
发明涉及一种用于无生命有机材料的抗静电改性和导电性改善的添加剂配制剂,其由如下组分组成:(A)1-50重量%的烯-二化硫共聚物,(B)1-50重量%的包含性氮原子且具有含至少4个原子的较长链烃基或确保(B)在无生命有机材料中的溶解性的等价结构单元的化合物,(C)0.1-30重量%的油溶性酸,和(D)1-80重量%的高沸点有机溶剂,其中这些分子类型的至少80重量%在标准压下的沸点大于150℃。
3 可发泡的模塑材料 CN97109958.8 1997-02-12 CN1168902A 1997-12-31 H·施克恩巴齐; A·施赫菲德; S·威斯
一种模塑材料或混合物通过加热用于制造泡沫塑料,所述模塑材料或混合物含有一种耐高温聚合物和至少一种含亚砜基团聚合物。该泡沫塑料用于热稳定隔离层。
4 适合无生命有机材料的抗静电改性和导电性改善的添加剂配制剂 CN200880006889.7 2008-02-28 CN101622329A 2010-01-06 D·波塞尔; F-O·梅林; A·郎格; A·文柯基尔; C·科尔曼
发明涉及一种用于无生命有机材料的抗静电改性和导电性改善的添加剂配制剂,其由如下组分组成:(A)1-50重量%的烯-二化硫共聚物,(B)1-50重量%的包含性氮原子且具有含至少4个原子的较长链烃基或确保(B)在无生命有机材料中的溶解性的等价结构单元的化合物,(C)0.1-30重量%的油溶性酸,和(D)1-80重量%的高沸点有机溶剂,其中这些分子类型的至少80重量%在标准压下的沸点大于150℃。
5 聚合物中亚砜基团的还原方法 CN94117054.3 1994-10-05 CN1109476A 1995-10-04 G·福兰克; A·舒莱彻尔; J·库尔普
发明涉及聚合物硫醚的制备方法,该方法包括a)热或,b)活性氢存在下或,c)光化学处理含式(I)的亚砜连接基团的化合物,式中符号和系数的含义见说明书,以及还原得到相应的硫醚。
6 ADDITIVE FORMULATION SUITABLE FOR ANTISTATIC MODIFICATION AND IMPROVING THE ELECTRICAL CONDUCTIVITY OF INANIMATE ORGANIC MATERIAL US13856994 2013-04-04 US20130296207A1 2013-11-07 Dietmar Posselt; Frank-Olaf Maehling; Arno Lange; Anja Vinckier; Claudius Kormann
An additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material, consisting essentially of(A) from 1 to 50% by weight of an olefin-sulfur dioxide copolymer, (B) from 1 to 50% by weight of a compound which comprises one or more basic nitrogen atoms and has at least one relatively long-chain linear or branched hydrocarbon radical having at least four carbon atoms or an equivalent structural element which ensures the solubility of component (B) in the inanimate organic material, (C) from 0.1 to 30% by weight of an oil-soluble acid and (D) from 1 to 80% by weight of a high-boiling organic solvent which consists of one or more molecule types, where at least 80% by weight of these molecule types have a boiling point of more than 150° C. at standard pressure, where the sum of all components adds up to 100% by weight.
7 Polyarylene sulphides with polymer-bound phosphonium salts and process for producing them US973638 1997-12-23 US6077918A 2000-06-20 Helmut Witteler
Phosphonium ionomers which, as random copolymers, are composed of the units (1) and (2) ##STR1## in which Ar-- is a phenylene radical or a biphenylene, naphthylene or anthrylene radical or another divalent aromatic radical and may be different units within the polymer chain;--X-- is an --S--, --SO-- and/or --SO.sub.2 -- unit,where --X-- within the polymer chain may be up to 3 different units;Z is a monovalent or polyvalent opposite ion;Ph is a phenyl radical;m is the charge of the opposite ionand the average degree of polymerization is in the range from 3 to 2000.The polymers can be used for the production of membranes, in particular for electrochemical cells.
8 Soluble polyarylene sulfoxides, a process for their preparation and their use US931554 1997-09-16 US5907029A 1999-05-25 Stefan Disch; Michael Haubs; Axel Schonfeld; Helmut Scheckenbach
The invention relates to polyarylene sulfoxides which are soluble in polar organic solvents, a process for their preparation and their use. Soluble polyarylene sulfoxides can be prepared by homogeneous partial oxidation of polyarylene sulfides. The homogeneous partial oxidation is achieved by dispersing the polyarylene sulfide in finely divided form in a solvent stable to oxidation, slowly adding a mild oxidizing agent and terminating the oxidation as soon as the polymer chains have reached a uniform degree of oxidation. The partially oxidized polyarylene sulfoxides are suitable for the production of coatings and shaped articles, such as fibers, membranes, films and nonwovens.
9 Polyarylene sulfide foams and a process for their production US955134 1997-10-21 US5789452A 1998-08-04 Georg Frank; Jurgen Kulpe; Andreas Schleicher; Helmut Scheckenbach
A foamed polyarylene sulfide according to the invention has a density which is reduced by at least 50% compared with the theoretical density of nonfoamed material, and is expediently produced by subjecting a polyarylene sulfoxide as such or a mixture of one or more polyarylene sulfides with a polyarylene sulfoxide to heat treatment. The temperature of the heat treatment is in the range from 250.degree. to 400.degree. C.
10 Process for preparing arylene sulfide sulfone/sulfoxide polymers US625244 1990-12-10 US5144004A 1992-09-01 Rex L. Bobsein
An arylene sulfide sulfone/sulfoxide polymer and a process for preparing same by contacting at least one dihaloaromatic sulfone, at least one dihaloaromatic sulfoxide, at least one organic amide, at least one sulfur-containing compound, and water.
11 Dihydroxy-pendant rigid-rod benzobisazole polymer US709250 1991-06-03 US5106940A 1992-04-21 Thuy D. Dang; Hoe H. Chuah; Loon S. Tan; Fred E. Arnold
There are provided novel rod-like heterocyclic aromatic polymers having repeating groups of the formula: ##STR1## wherein Y is --S--, --O-- or --NR--, R is -H, an alkyl group having 1 to 4 carbon atoms or an aromatic group having 1 or 2 aromatic rings, and the bullet symbol (.cndot.) indicates hydrogen bonding.
12 Sulfonium organosulfonates US346691 1982-02-08 US4451409A 1984-05-29 Gary R. Buske; Richard G. Pews
Monomeric and polymeric triarylsulfonium complex salts which may be prepared by contacting diarylsulfoxides or polymeric arylsulfoxides with aromatic compounds in the presence of an organosulfonic acid are described. An example is tris-(4-phenoxyphenyl)sulfonium methane sulfonate prepared by reaction of bis-(4-phenoxyphenyl)sulfoxide, diphenyl ether and methane sulfonic acid. The compounds demonstrate useful corrosion inhibiting properties.
13 Additive composition suitable for antistatic treatment and the conductive improvement of inanimate organic material JP2009552178 2008-02-28 JP2010520343A 2010-06-10 フィンキア アーニャ; ランゲ アルノ; コルマン クラウディウス; ポッセルト ディートマー; メーリング フランク−オラフ
An additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material, consisting essentially of (A) from 1 to 50% by weight of an olefin-sulfur dioxide copolymer, (B) from 1 to 50% by weight of a compound which comprises one or more basic nitrogen atoms and has at least one relatively long-chain linear or branched hydrocarbon radical having at least four carbon atoms or an equivalent structural element which ensures the solubility of component (B) in the inanimate organic material, (C) from 0.1 to 30% by weight of an oil-soluble acid and (D) from 1 to 80% by weight of a high-boiling organic solvent which consists of one or more molecule types, where at least 80% by weight of these molecule types have a boiling point of more than 150° C. at standard pressure, where the sum of all components adds up to 100% by weight.
14 Polyarylene sulfide and its manufacturing method with a phosphonium salt bound to the polymer JP50475197 1996-06-17 JPH11510833A 1999-09-21 ヴィッテラー,ヘルムート
(57)【要約】 ランダムコポリマーとして単位(1)および(2)よりなるホスホニウムイオノマー。 (式中、Ar−は、フェニレン基またはビフェニレン、ナフチレンもしくはアントリレン基もしくは他の二価の芳香族基であり、ポリマー鎖中では異なる単位であることができ;−X−は−S−、−SO−および/または−SO 2 −単位であり、さらにポリマー鎖中の−X−は最大3種類の異なる単位であることができ;Zは一価または多価の反対イオンであり;Phはフェニル基であり;mは反対イオンの電荷でありかつ平均重合度が3から2000の範囲にある。)該ポリマーは膜、とくに電気化学セル用膜の製造に用いることができる。
15 Foamable molding compound JP2900997 1997-02-13 JPH09227706A 1997-09-02 HERUMUUTO SHIETSUKENBATSUHA; AKUSERU SHIEENFUERUTO; JIIKUFURIITO BUAISU
PROBLEM TO BE SOLVED: To obtain a molding compound foamable in an extremely low density not requiring addition of a low molecular weight blowing agent, comprising a mixture of a sulfoxide group-containing polymer and a heat-resistant polymer as a raw material. SOLUTION: This foamable molding compound comprises (A) at least one heat-resistant polymer (preferably a thermoplastic resin such as polyether sulfone, polyarylate or polycarbonate), (B) 1-99wt.% (based on the total polymer content of a prepared molding compound) of at least one sulfoxide group- containing polymer [preferably polyphenylene sulfoxide or polyphenylene sulfide sulfoxide) and optionally (C) an additive. The amount of the component B used is preferably 1-50wt.%, especially 3-20wt.%. COPYRIGHT: (C)1997,JPO
16 JPS5516165B2 - JP2177975 1975-02-21 JPS5516165B2 1980-04-30
17 ZUR ANTISTATIKAUSRÜSTUNG UND VERBESSERUNG DER ELEKTRISCHEN LEITFÄHIGKEIT VON UNBELEBTEM ORGANISCHEN MATERIAL GEEIGNETE ADDITIVFORMULIERUNG EP08717233.4 2008-02-28 EP2132284A2 2009-12-16 POSSELT, Dietmar; MÄHLING, Frank-Olaf; LANGE, Arno; VINCKIER, Anja; KORMANN, Claudius
The invention relates to an additive formulation for the anti-static finishing and improvement of the electrical conductivity of inanimate organic material made of (A) 1 to 50% by weight of an olefin-sulfur dioxide copolymer, (B) 1 to 50% by weight of a compound having alkaline nitrogen atoms with longer-chained hydrocarbon groups with at least 4 carbon atoms or an equivalent structural element, which ensures the solubility of (B) in the inanimate organic material, (C) 0.1 to 30% by weight of an acid soluble in oil, and (D) 1 to 80% by weight of an organic solvent with a high boiling point, wherein at least 80% by weight of the molecule types have a boiling point that is higher than 150ºC at normal pressure.
18 Verfahren zur Oxidation von Polyarylensulfid zu Polyarylensulfoxid mittels Salpetersäure EP00107530.8 2000-04-07 EP1044999A3 2000-11-29 Zierer, Dirk, Dr.; Scheckenbach, Helmut, Dipl.-Ing.; Dierolf, Michael

Die Erfindung betrifft ein Verfahren zur Oxidation von Polyarylensulfid zu Polyarylensulfoxid mittels Salpetersäure, bei dem mindestens 98 % der Sulfidgruppen des Polyarylensulfides zu Sulfoxidgruppen oxidiert werden. Erfindungsgemäß wird Polyarylensulfid mit Salpetersäure in einer Konzentration im Bereich von 60 bis 80 % unter gleichzeitiger Wärmeeinwirkung behandelt. Das nach dem erfindungsgemäßen Verfahren hergestellte Polyarylensulfoxid läßt sich hervorragend als chemisches Treibmittel zum Schäumen von Thermoplasten verwenden.

19 Zweistufige Oxidation von Polyarylensulfiden EP94106567.4 1994-04-27 EP0623640B1 1998-09-30 Fleischer, Dietrich, Dr.; Strutz, Heinz, Dr.; Kulpe, Jürgen, Dr.; Schleicher, Andreas, Dr.
20 Zweistufige Oxidation von Polyarylensulfiden EP94106567.4 1994-04-27 EP0623640A1 1994-11-09 Fleischer, Dietrich, Dr.; Strutz, Heinz, Dr.; Kulpe, Jürgen, Dr.; Schleicher, Andreas, Dr.

Polyarylenthiother mit wiederkehrenden Einheiten der Formel







        [-(S-E-)a-(-SO-E-)b-(SO₂-E)c-]







in der E unabhängig voneinander Phenylen, Naphthylen oder Biphenylen bedeutet,

a und c unabhängig voneinander Werte von 0 bis kleiner 1 darstellen und b Werte von größer Null bis kleiner 1 aufweist, mit der Maßgabe, daß die Summe aus a + b + c gleich 1 ist und mindestens zwei der Indices größer Null sind werden erhalten durch Oxidation von Polyarylensulfiden in zwei Stufen, indem in erster Stufe ein Polymer in fester Form in einem Suspensionsmedium mit Ozon oxidiert wird und das erhaltene Reaktionsprodukt in zweiter Stufe in Essigsäure mit Wasserstoffperoxid in Gegenwart von katalytischen Mengen an konzentrierter Schwefelsäure und/oder unter Zusatz von Gleichgewichtspersäuren umgesetzt wird.

Die Polyarylenthioether eignen sich zur Herstellung von hochtemperatur- und hochchemikalien-resistenten Formteilen.

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