Mixed pyrylium chalcogenide of lewis base

申请号 JP27388989 申请日 1989-10-23 公开(公告)号 JPH02166166A 公开(公告)日 1990-06-26
申请人 Eastman Kodak Co; 发明人 MAIKERU REI DETSUTEI;
摘要 NEW MATERIAL: A compound of the formula [R
1 , R
4 -R
5 , and R
8 are each H, a 1-12C (hetero)aryl, or an alkyl; R
2 -R
3 and R
6 -R
7 are each a 1-12C alkyl(thio), an aryl(thio), an alkylseleno, an arylseleno, an alkyltelluro, an aryltelluro, H, a halogen, hydroxyl, an alkoxy, or amino; R
9 -R
12 are each a 1-12C alkyl, an alkoxy, H, a halogen, or cyano; (n) is 0-2; as for X
1 and X
2 , one is either Se or Te but they consist of mutually different chalcogenides; Z
- is a Lewis base)].
EXAMPLE: 2,6-di-t-Butyl-4-[3-(2,6-di-t-butyl-4H-telluropyran-4-ylidene)-1-propen-1-yl] selenopyrylium chloride.
USE: A photomechanical treatment for cancer cells.
PROCESS: The compound is produced by mixing a compound of the formula of which Z
- is an anion other than a Lewis base with an ion exchange resin containing Lewis bases, and exchanging non-Lewis base anions with Lewis bases.
COPYRIGHT: (C)1990,JPO
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