| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 81 | Azinoneutromethines | US19503 | 1993-02-19 | US5328994A | 1994-07-12 | Horst Berneth; Karin Hassenruck |
| New azinoneutromethines of the formula ##STR1## in which the symbols used have the meaning given in the description, a process for their preparation and their use in thermal and photochromic recording materials, as nonlinear optical materials, as photoconductors in electrophotography and for dyeing fibres and woven fabrics of polyester and plastics. | ||||||
| 82 | Preparation of 1:2 chromium complexes one sulfo substituted and one sulfonamido or the like substituted azo dyes | US483144 | 1990-02-21 | US5229502A | 1993-07-20 | Gerhard Back; Alois Puntener |
| A process is described for the preparation of pure, asymmetric 1:2 chromium complex dyes containing at least two groups which impart solubility in water, which process comprises reacting a mixture of two dyes of the formulaeF.sub.1 --(SO.sub.3 H).sub.t (1)andF.sub.2 --SO.sub.2 --Y (2)in which the symbols are as defined in claim 1 with a chromium donor in a molar ratio of 0.85:1.0 to 1.2:1.0 in a one-pot process under pressure at a temperature above 100.degree. C. and at a pH between 0 and 2 and then continuing the reaction at a slightly acid, neutral or slightly alkaline pH. The dyes obtained by the process according to the invention are suitable for dyeing, in particular, wool, silk, leather and synthetic polyamide fibres. | ||||||
| 83 | Method for temporarily coloring article with acid labile colorant | US591343 | 1990-10-01 | US5071440A | 1991-12-10 | John B. Hines; John G. Lever |
| An article may be temporarily colored by application of an aqueous solution of a polyoxyalkylene substituted chromophore characterized by a N.dbd.pair with an electron withdrawing group bonded to one element of the pair and an electron donating group bonded to the opposite element. The polyoxyalkylene substituent imparts solubility to the colorant and bulk to prevent penetration into interstices in the article being colored. The colorant may be subsequently decolorized in hydrolysis when an aqueous acid solution is applied to the colorant. | ||||||
| 84 | Heavy metal complex azo dyes containing a benzothiophene-1,1-dioxide, 2,1-benzothiazine-2,2-dioxide, 1,4-benzothiazine-1,1-dioxide or thienopyridine-1,1-dioxide coupling component | US150597 | 1988-02-01 | US4960870A | 1990-10-02 | Urs Lehmann |
| The heavy metal complex dyes of azo or azomethine dyes of the formula ##STR1## in which D is the radical of a dizao component of the benzene, naphthalene or heterocyclic series, K--OH is the radical of the formula ##STR2## in which the symbols A, A', B and B' each represent a carbon atom or in which one of the symbols A, A', B or B' represents a nitrogen atom while the others represent a carbon atom, R is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or substituted or unsubstituted phenyl, and the ring E can be further substituted, Y is a nitrogen atom or a CH group, and n is 0 or 1, and in which --(CO).sub.n --OH is bonded to D in a position adjacent to --N.dbd.Y--, produce dyeings having good fastnesses particular very good crock, wet, wet crock and light fastness on nitrogen-containing or hydroxyl-containing fibre materials. | ||||||
| 85 | Bis 1:2 chromium complexes of disazo and azo or azomethine dyes | US730027 | 1985-05-03 | US4661587A | 1987-04-28 | Ulrich Schlesinger; Fabio Beffa |
| Disclosed are chrome complex dyes of the formula ##STR1## and of the formula ##STR2## wherein Z and Z' independently of one another are each nitrogen or --CH--;X and X' independently of one another are each oxygen, or a group of the formula --NR--, in which R is hydrogen or C.sub.1 -C.sub.4 -alkyl, provided X is oxygen when Z is --CH-- and provided X' is oxygen when Z' is --CH--;A and B independently of one another are each a diazo component of a benzene or naphthalene radical which carries the hydroxyl or carboxyl group in the o-position with respect to the azo group;C and D independently of one another are each a benzene or naphthalene radical which carries in the o-position with respect to the azo or azomethine group a hydroxyl or carboxyl group, or the radical of an aliphatic or cycloaliphatic aminocarboxylic acid, if n.sub.2 or n.sub.3 is 1 and Z or Z' is CH;E and F independently of one another are each the radical of a coupling component when Z or Z' is nitrogen, the coupling component containing in the o- and -positions with respect to the azo group the groups X and X', respectively, or the radical of an o- hydroxyaldehyde when Z or Z' is --CH--;n, n.sub.1, n.sub.2 and n.sub.3 independently of one another are each zero or 1;Ka.sup..sym. is a cation; andG is an unsubstituted or substituted benzene or naphthalene radical which contains the OH group in the o-position with respect to the coupling position on the group G; andK is the C.sub.1 -C.sub.4 -alkyl group or a --COOR or the ##STR3## group, in which R is hydrogen or C.sub.1 -C.sub.4 -alkyl. | ||||||
| 86 | Metalized dyes, their manufacture and use | US319533 | 1981-11-09 | US4436659A | 1984-03-13 | Arthur Buhler; Hans U. Schutz |
| The present invention relates to copper, nickel, chromium or cobalt complexes of azo or azomethine dyes which contain a group of the formula ##STR1## wherein Z is a bridge Member of the formula--SO.sub.2 --, ##STR2## wherein R is hydrogen or a low molecular alkylene radical or an arylene radical, Ar is an arylene radical, m is 1 or 2 and U is a sulpho or carboxy group. | ||||||
| 87 | Carboxamide type azomethine pigment | US148498 | 1980-05-09 | US4318850A | 1982-03-09 | Fumihiko Yamamoto; Mitsuru Katayose; Kyugo Tanaka; Teruyuki Misumi |
| A compound of the formula, ##STR1## wherein R is an aromatic compound selected from the group consisting of: ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 which may be the same or different, are each selected from the group consisting of hydrogen, chlorine, a C.sub.1-2 alkyl group and a C.sub.1-2 alkoxy group and wherein Y is --SO.sub.2 --, --O--, --S--, --CO--, --N.dbd.N-- or --NHCO--; X is a halogen atom selected from the group consisting of chlorine, bromine, and fluorine; and n is zero or an integer of from 1 to 4. The compound is useful for pigments having hue from the yellow shade to the red shade and having especially high chroma. The pigments also have improved weather resistance, chemical resistance and tinting strength. | ||||||
| 88 | Copper, and nickel complexes of azo dyestuffs | US904358 | 1978-05-09 | US4215042A | 1980-07-29 | Arthur Buhler; Hans U. Schutz |
| The present invention relates to copper and nickel complexes of the formula ##STR1## wherein Me is copper or nickel;p is 1 or 2;E is the radical of a napthol or a phenol;R.sub.1 is hydrogen or lower alkyl;R.sub.2 is alkylene or arylene; andM is hydrogen, an alkali metal or ammonium.These dyes are suitable for dyeing and printing natural or synthetic polyamide materials; the dyeings obtained being characterized by their purity, depth, brilliance of shade, levelness and fastness properties. | ||||||
| 89 | Unsymmetrical azo - azo methine 1:2 chromium complex dyes | US788217 | 1977-04-18 | US4116952A | 1978-09-26 | Fabio Beffa; Gerhard Back; Eginhard Steiner |
| 1:2 Chromium complex dyes which contain one molecule of an azo or azomethine compound of the formula ##STR1## and one molecule of the azomethine compound of the formula ##STR2## COMPLEXED TO A CHROMIUM ATOM, IN WHICH FORMULAE A represents the radical of a diazo component of the benzene or naphthalene series, which carries the complex-forming group XH in ortho-position to the azo group,B represents the radical of a coupling component which couples in ortho-position to HX' or the radical of an aromatic o-hydroxyaldehyde,Z represents a nitrogen atom or the -CH group,X represents an oxygen atom or a -CO-O group,X' represents an oxygen atom, a NH group, a low molecular N-alkyl, N-aralkyl or N-aryl group, andR represents a substituted or unsubstituted aliphatic or cycloaliphatic radical,And the benzene ring a can carry a further fused benzene ring or can be substituted by halogen, nitro, alkyl and alkoxy, in particular by low molecular alkyl and alkoxy, and these compounds contain together 0 to 5 water-solubilizing groups and optionally a group of the formula--N.dbd.N--Ar--N.dbd.N--Ar' (3)and/or one to two groups of the formula--N.dbd.N--Ar" (4)wherein Ar, Ar' and Ar" represent an aromatic, carbocyclic or heterocyclic radical. These dyes are primarily suitable for dyeing natural and synthetic polyamide material. | ||||||
| 90 | Process for the coloration of hydrophobic chemical fibers by metalliferous dyestuffs of cationic character | US450112 | 1974-03-11 | US4019857A | 1977-04-26 | Antoine Georges Leon Jacques Breda |
| Process for dyeing or printing synthetic or artificial hydrophobic textile fibers in an aqueous medium with a 1:1 premetallized dyestuff complex of monocationic character of a transition metal, the cationic part of which dyestuff does not contain an ionized group (dyestuff (I)), in which the fibers are treated at a temperature at least equal to 80.degree. C. with a complexing agent (III), sparingly soluble in water and not containing an ionized group and more soluble in the fiber than in the aqueous dyeing medium of pH from 3 to 7, and with the premetallized dyestuff (I), the complexing agent being capable of fixation on the metal of the premetallized dyestuff with liberation of a proton, and synthetic or artificial hydrophobic textile fibers dyed or printed by such process. | ||||||
| 91 | Monomethine dyestuffs | US558647 | 1975-03-17 | US4018796A | 1977-04-19 | Horst Harnisch |
| The invention relates to monomethine dyestuffs of the formula ##STR1## wherein Z.sup.1 is alkyl, cycloalkyl, aralkyl or arylZ.sup.2 is hydrogen or Z.sup.1Q is CN, COOR.sup.2 or CONR.sup.3 R.sup.4,R.sup.1 u.R.sup.4 is hydrogen or alkyl,R.sup.2 is alkyl, alkenyl, aralkyl, cycloalkyl or aryl andR.sup.3 is alkyl, cycloakyl, aralkyl, aryl or acyl.The dyestuffs are suitable for the dyeing of natural and synthetic fibers, which are dyed in orange or red shades with high brilliancy. | ||||||
| 92 | Process for dyeing anionically modified synthetic fiber materials | US564104 | 1975-04-01 | US3980430A | 1976-09-14 | Hans-Peter Kuhlthau |
| Exhaustion process for dyeing anionically modified fiber materials with cationic dyestuffs from halogenated hydrocarbons, wherein are used cationic dyestuffs of the formula [F - ( R ).sub.Z ].sup.+ A.sup.-in whichF, r, z and A.sup.- have the meaning given below in the disclosure; by the claimed process an essentially improved exhaustion of the dyebaths is achieved. | ||||||
| 93 | Tintenzusammensetzung enthaltend einen besonderen Farbstoff und Tintenstrahldruckverfahren unter Verwendung derselben | DE60217454 | 2002-10-01 | DE60217454T3 | 2012-03-15 | VANMAELE LUC AGFA GEVAERTIP DEPARTMENT; LOCCULIER JOHAN CORPORATE IP DEPARTMENT; MEIJER EGBERT; JANSSEN HENRICUS; FRANSEN PIETER |
| 94 | Use of pigment dyes for coloring dispersion in aqueous media | DE60222639 | 2002-01-21 | DE60222639T4 | 2008-07-10 | SIEBER HELMUT |
| 95 | Use of pigments as disperse dyes | DE60201505 | 2002-01-14 | DE60201505T2 | 2006-03-09 | SIEBER HELMUT |
| 96 | A method for brightening of textile materials | DE50301054 | 2003-04-30 | DE50301054D1 | 2005-09-29 | WEBER DIETER; REICHELT HELMUT; WAGENBLAST GERHARD |
| 97 | The use of pigments which dispersionsstoffer | DK02729494 | 2002-01-14 | DK1360367T3 | 2005-01-17 | SIEBER HELMUT |
| 98 | Use of pigments as disperse dyes | DE60201505 | 2002-01-14 | DE60201505D1 | 2004-11-11 | SIEBER HELMUT |
| 99 | AT02729494 | 2002-01-14 | ATE278834T1 | 2004-10-15 | SIEBER HELMUT | |
| 100 | BR0206397 | 2002-01-21 | BR0206397A | 2004-02-10 | SIEBER HELMUT | |
QQ群二维码
意见反馈
意见反馈