序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
81 Naphthalene derivative JP20005985 1985-09-10 JPS6259668A 1987-03-16 YOSHIDA MASASHI
NEW MATERIAL:Naphthalene derivatives of the formula, wherein R is CnH2n+1; n is 0-4. EXAMPLE:4,6-Bis(butylamino)-2,3-dihydro-8-hydroxynaphthalene-1,5-dione. USE:Vat dyes which are oxidized in a bath at a concn. of 0.1% or above without using any oxidizing agent, to develop a color and dye fibers such as hair and wool muslin clear purple. PREPARATION:A 3,5-bis(alkylamino)-8-hydroxy-naphthoquinone is reduced in the presence of an alkali such as KOH, NaOH or Na2CO3 in a solvent such as water, an alcohol or a mixture of water and an alcohol with a reducing agent such as sodium tetrathionate or in the presence of Zn in an aq. hydrochloric acid soln. under anaerobic conditions at room temp. to reflux temp. for 1-5hr.
82 Production of 2-anilinonatpthazarin JP13370385 1985-06-19 JPS61291552A 1986-12-22 KIKUCHI MASASHI
PURPOSE: To obtain the titled compound useful as a dye, pigment intermediate, dyestuff for liquid crystals, etc., in high yield under mild conditions, by reacting naphthazarin with aniline in or without an organic solvent in the presence of a boron compound. CONSTITUTION: Naphthazarin expressed by the formula is reacted with aniline in or without an organic solvent in the presence of a boron compound selected from the group consisting of boric acid, boron acetate and boron fluoride to afford the aimed compound. The molar amount of the aniline to be used is preferably about equimolar W 20 times based on the naphthazarin. The amount of the boron compound to be used is preferably about equimolar W 20 times based on the naphthazarin. The addition of the above-mentioned boron com pound provides the aimed 2-anilinaphthazarin having anilino group at the 2-posi tion of the naphthazarin in high yield under mild conditions with suppressed formation of by-products. The reaction temperature is preferably about room temperature. COPYRIGHT: (C)1986,JPO&Japio
83 JPS6157305B2 - JP12479678 1978-10-11 JPS6157305B2 1986-12-06 KITAO TEIJIRO; MATSUOKA MASARU; NAKASUMI HIROYUKI
84 Naphthalene derivative JP19547184 1984-09-18 JPS6172063A 1986-04-14 KIKUCHI MASASHI; MATSUOKA MASAHIRO
NEW MATERIAL:The compound of formula [R is CnH2n+1 (n is 5-8)]. EXAMPLE:2-Pentylamino-5,8-dihydroxynaphthoquinone. USE:Vat dye for fiber and dye for human hair. PREPARATION:The objective compound can be prepared by reducing 2-(alkyl)- amino-5,8-dihydroxynaphthoquinone with a reducing agent such as sodium dithionate in the presence of an alkali such as KOH, NaOH, Na2CO3, etc., in water, alcohol or a mixture of water and alcohol, or in an aqueous solution of hydrochloric acid in the presence of zinc, preferably at room temperature - refluxing temperature for 1-5hr.
85 Naphthoquinone dye for liquid crystal JP9140384 1984-05-08 JPS60235886A 1985-11-22 MIURA KONOE; OZAWA TETSUO; IWANAMI JIYUNKO
NEW MATERIAL:Compounds of formula I, wherein R is alkyl, cycloalkyl, alkylcycloalkyl, alkoxy, alkoxyalkoxy, alkoxyalkoxyalkoxy, monoalkylamino, dialkylamino, phenyl, alkylphenyl, alkoxyphenyl-substd. or unsubstituted phenyl. EXAMPLE: 5-Amino-2,3-dicyane-8-(4'-n-heptylanilino)-1,4-naphthoquinone. USE: Dyes for liquid crystal having the max. wavelength at 700W900nm near the oscillating wavelength of semiconductor laser. PREPARATION: A naphthoquinone compd. of formula II is reacted with an amine compd. of formula III. COPYRIGHT: (C)1985,JPO&Japio
86 Naphthoquinone dye for thermal transfer recording JP821784 1984-01-20 JPS60151098A 1985-08-08 NIWA TOSHIO; MURATA YUUKICHI; MAEDA SHIYUUICHI
PURPOSE:To obtain a cyan color naphthoquinone dye for thermal transfer recording having a favorable hue in view of color reproduction without being pyrolyzed under the operating conditions of a thermal recording head and being resistant to light, moisture, chemicals or the like, by using a compound of a specified structural formula. CONSTITUTION:A compound of the formula, wherein each of R<1> and R<2> is alkyl, aralkyl, alkenyl, cyclohexyl, haloalkyl, alkoxyalkyl, alkoxyalkoxyalkyl, hydroxyalkyl, hydroxyalkoxyalkyl, hydroxyalkylthioalkyl, cyanoalkyl, tetrahydrofurfuryl, aralkyloxyalkyl, aryloxyalkyl, alkenyloxyalkyl, tetrahydrofurfuryloxyalkyl, alkoxycarbonylakyl, alkylcarbonyloxyalkyl or alkoxycarbonyloxyalkyl, with the proviso that both of R<1> and R<2> are not simultaneously 1-4C alkyl, is used. Accordingly, a stable and clear cyan color can be obtained.
87 Optical information recording medium JP24253683 1983-12-22 JPS60132794A 1985-07-15 INOUE HARUO; YASUI MASAAKI; NAKARAI TOYOAKI; IECHIKA YASUSHI; KUWABARA HAJIME
PURPOSE:To provide an optical information recording medium with a high reflectance, a high sensitivity and a high S/N ratio by vacuum evaporating a specified dicyanonaphthoquinone pigment on a subtrate to form a thin film with a specified thickness. CONSTITUTION:A dicyanonaphthoquinone pigment (preferably, compound of the formula II) of the formula I (R and R' are each H or arromatic residual group having two or more benzene ring in R or R') is vacuum evaporated (preferably, heated gradually at 230-300 deg.C under vacuum of less than 10<-5>Torr) to form a thin film with the thickness of 100-1,000Angstrom , preferably 400-900Angstrom and thus, a desired optical information recording medium is obtained.
88 7,10-dihydroxy-2,3,4-trihydrobenzo(f)quinoxalin-6-one derivative JP8728583 1983-05-18 JPS59213766A 1984-12-03 KITAO TEIJIROU; MATSUOKA MASARU; TAKAGI KOUICHI
NEW MATERIAL:A compound shown by the formula I (R 1WR 3 are H, or alkyl, or R 1 and R 2 may be linked to form aliphatic ring; R 4WR 6 are H, or halogen). EXAPLE:A compound shown by the formula II. USE: For coloring low-molecular weight substances such as mineral oil, liquid crystal, etc., a dyestuff for coloring sheet, fibrous material, etc. consisting of natural synthetic high polymer substance such as cellulose, polyester, polystyrene, etc., and an intermediate for dye, and pigment. PREPARATION: For example, an ethylenediamine shown by the formula III is reacted with a naphthazarin derivative shown by the formula IV or V (X is halogen) preferably at -10W150°C. COPYRIGHT: (C)1984,JPO&Japio
89 Liquid crystal dielectric body, novel dye, manufacture and electrooptical display element JP1161683 1983-01-28 JPS58129055A 1983-08-01 GIYUNTERU HAASU; GEORUKU BUEEBERU
90 Liquid crystal dielectric JP11413682 1982-07-02 JPS5837073A 1983-03-04 GIYUNTERU HAASU; GEORUKU BUEEBERU
91 Chakushokuzai JP12517374 1974-10-30 JPS5150938A 1976-05-06 EGUCHI ARAHIKO; SUZUKI YOSHIHISA; OONUKI TAKASHI; YOKOGAWA YASUNORI; HIRATA TADASHI; TOITA OSAMU
92 JPS5039330A - JP6758574 1974-06-12 JPS5039330A 1975-04-11
93 JPS4977942A - JP12227873 1973-11-01 JPS4977942A 1974-07-26
94 UTILISATION DE L'ACTINORHODINE ET DE SES DERIVES EN TANT QU'AGENT COLORANT FR1750577 2017-01-24 FR3062130B1 2020-09-04 LANDRAIN THOMAS; ADENIS MARIE SARAH; BLACHE JEREMIE; BOISSONNAT GUILLAUME
La présente invention concerne l'utilisation de l'actinorhodine et/ou de ses dérivés en tant qu'agent colorant, une composition colorante comprenant ledit agent colorant, ainsi que l'utilisation de ladite composition colorante pour colorer notamment des textiles ou des peaux, des plastiques, des cires, des matières cellulosiques ou des silicones.
95 UTILISATION DE L'ACTINORHODINE ET DE SES DERIVES EN TANT QU'AGENT COLORANT FR1750577 2017-01-24 FR3062130A1 2018-07-27 LANDRAIN THOMAS; ADENIS MARIE SARAH; BLACHE JEREMIE; BOISSONNAT GUILLAUME
La présente invention concerne l'utilisation de l'actinorhodine et/ou de ses dérivés en tant qu'agent colorant, une composition colorante comprenant ledit agent colorant, ainsi que l'utilisation de ladite composition colorante pour colorer notamment des textiles ou des peaux, des plastiques, des cires, des matières cellulosiques ou des silicones.
96 Procedimiento para la estimación de la concentración de fosfatos en células vivas, colorante xanténico y síntesis del mismo ES201330861 2013-06-10 ES2474916A1 2014-07-09 ALVAREZ PEZ JOSÉ MARÍA; CROVETTO GONZALEZ LUIS; CUERVA CARVAJAL JUAN MANUEL; GIRON GONZALEZ MARÍA DOLORES; JUSTICIA LADRON DE GUEVARA JOSÉ; ORTE GUTIERREZ ANGEL; RUEDAS RAMA MARÍA JOSÉ; SALTO GONZALEZ RAFAEL; TALAVERA RODRIGUEZ EVA MARÍA; MARTINEZ PERAGON ANGELA; PAREDES MARTINEZ JOSÉ MANUEL
Procedimiento para la estimación de la concentración de fosfatos en células vivas, colorante xanténico y síntesis del mismo. La presente invención describe un procedimiento de estimación de la concentración de fosfatos presente en células vivas a través de la medición del tiempo de decaimiento de fluorescencia de un colorante xanténico añadido a las células y sometido a una excitación mediante luz láser pulsada. También se describe un nuevo colorante xanténico derivado de la fluoresceína que posee mejores propiedades espectrales que los ya conocidos y un procedimiento de síntesis de dicho colorante.
97 Method of enhancing fluorescence AU2004224246 2004-03-25 AU2004224246B2 2010-10-28 MACKINTOSH JAMES ALEXANDER; CHOI HUNG-YOON; COGHLAN DANIEL RICHARD; KARUSO PETER HELMUTH; VEAL DUNCAN ADAM
98 Recording layer for high density optical recording medium, e.g. optical disc, includes organic dye DE102006000931 2006-01-05 DE102006000931A1 2007-05-24 LEE MING-CHIA; HUANG CHIEN-LIANG; LIAO WEN-YIH; HSIEH CHING-YU; JENG TZUAN-REN; LEE AN-TSE
A recording layer comprises an organic dye. A recording layer comprises a dye of formula (I). n : 0 or 1; X : O or C(CN) 2; A : optionally substituted cyclic alkyl group; and R 1>-R 10>H, halo, 1-18(1-18C) alkyl, 1-8(1-18C) alkoxy, 1-18(1-18C) carboxyl, optionally substituted amino, 1-8(1-18C) alkyl ester, 1-18(1-18C) carboxyl, benzene including amino or carboxyl, nitro, adamantyl carbonyl, adamantyl, alkenyl, alkynyl, amino, azo, aryl, aryloxy, arylcarbonyl, aryloxycarbonyl, arylcarbonyloxy, aryloxycarbonyloxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyloxy, alkoxycarbonyl group, carbamoyl, cyanate, cyano, formyl, formyloxy, heterocyclic, isothiocyanate, isocyano, isocyanate, nitroso, perfluoroalkyl, perfluoroalkoxy, sulfinyl, sulfonyl, silyl, or thiocyanate. Independent claims are included for: (1) a high-density optical recording medium comprising a first substrate and a cover layer, and a recording layer between the first substrate and the cover layer; and (2) a method for synthesizing the dye (I). The first substrate is 0.5-1.3 mm thick, and the cover layer is 0.01-0.7 mm thick. The first substrate comprises a land-and-groove surface on its side. A reflective layer is between the cover layer and the first substrate. A protective layer is disposed on the recording layer or the reflective layer. The recording layer is formed by spin coating, roller press, inkjet printing, or dipping. Adhering the cover layer to the reflective layer is carried out by spin coating, screen printing, or thermal glue. [Image].
99 Method of enhancing fluorescence AU2004224246 2004-03-25 AU2004224246A1 2004-10-07 MACKINTOSH JAMES ALEXANDER; CHOI HUNG-YOON; COGHLAN DANIEL RICHARD; KARUSO PETER HELMUTH; VEAL DUNCAN ADAM
100 A process for preparing benzoquinones by oxidation of phenols DE4343667 1993-12-21 DE4343667A1 1995-06-22 GESSNER THOMAS DR
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