181 |
NAPHTHOQUINONE DERIVATIVES |
GB2305874 |
1974-05-23 |
GB1459137A |
1976-12-22 |
|
1459137 Dyestuffs SANDOZ Ltd 23 May 1974 [30 May 1973 15 June 1973] 23058/74 Heading C4P The invention comprises dyestuffs of the general formula wherein R 1 is -CH=CH-CH=CH- or which may be substituted by one or two substituents from Cl, Br, methyl or C 1 -C 4 alkoxy or by an aminocarbonyl, C 1 -C 4 alkylaminocarbonyl, phenylaminocarbonyl, carboxyl, C 1 - C 4 alkoxycarbonyl or phenoxycarbonyl group, m is 1 or 2 and when m is 1 R 2 + R 3 are together cyano, 2- or 4-pyridyl, 2-quinolyl, 2,4-dihydroxy- 1,3,5-triazinyl or phenyl optionally substituted by one or two Cl, Br, methyl, C 1 -C 4 alkoxy, nitro or CN groups or a group -COR 5 where R 5 is OH, methyl C 1 -C 4 alkoxy, phenyl or phenoxy optionally substituted by one or two Cl, Br, C 1 -C 4 alkoxy, methyl or nitro groups or by one cyano group or is an optionally substituted carbonamide group or R 2 is a radical and R 3 is a divalent linking radical, when m is 2 R 2 is a carbonamide radical and R 3 is a divalent linking radical or R 2 is and R 3 is a tetravalent diphenyl radical, linking to R 2 through adjacent carbon atoms. They are prepared by (a) reacting a compound of general formula wherein R 8 is H, Cl, Br or -SO 3 M and M is an alkali metal or alkaline earth metal cation with a compound of the general formula where m, R 1 , R 2 and R 3 are as defined above or by (b) condensing a compound where m = 1 and R 2 + R 3 = COOH or an acid chloride or C 1 -C 4 alkyl ester thereof with an amine. Reaction (a) preferably takes place in an inert organic solvent at 0-200 C. advantageously in presence of a mild oxidizing agent. Reaction (b) preferably takes place in an inert anhydrous organic solvent at 20-250 C. The dyestuffs are used as disperse dyes in polyesters and for mass coloration of lacquers, viscose or cellulose acetate spinning solutions, polyethylene, polystyrene, P.V.C. rubber, synthetic leather, printing inks and paper. |
182 |
Polynuclear heterocyclic compounds and their preparation |
DE2608517 |
1976-03-02 |
DE2608517A1 |
1976-09-16 |
RIBALDONE GIUSEPPE; BORSOTTI GIAMPIERO |
|
183 |
FR2236867A1 - |
FR7423881 |
1974-07-09 |
FR2236867A1 |
1975-02-07 |
|
|
184 |
FR2231714A1 - |
FR7418770 |
1974-05-30 |
FR2231714A1 |
1974-12-27 |
|
|
185 |
Triazinyl compounds, their preparation and use |
DE2365361 |
1973-10-30 |
DE2365361A1 |
1974-08-15 |
KAUL BANSI LAL |
|
186 |
Slightly soluble naphthoquinone, their manufacture and use as dyestuffs |
DE2354198 |
1973-10-30 |
DE2354198A1 |
1974-07-18 |
KAUL BANSI LAL |
|
187 |
내광성 착색제 및 이를 포함하는 내광성 잉크 조성물 |
KR1020030017746 |
2003-03-21 |
KR1020040083179A |
2004-10-01 |
이경훈; 유승민; 정연경 |
PURPOSE: A lightfast colorant is provided, which is excellent in lightfastness, and a lightfast ink composition containing the lightfast colorant is provided, which has improved lightfastness and conservation-stability. CONSTITUTION: The lightfast colorant is represented by the formula 1, wherein Y1 is H, OH, NH2, NHR1, N(R1)2, SH, or a C1-C30 heteroalkyl, Y2 and Y3 are identically or differently H, OH, NH2, NHR1, N(R1)2, SH, a substituted or unsubstituted C1-C30 alkyl, a substituted or unsubstituted C1-C30 alkenyl, a substituted or unsubstituted C1-C30 alkynyl, and etc., n is an integer of 0-6, R is a substituted or unsubstituted C1-C30 alkylene, a substituted or unsubstituted C1-C30 alkenylene, a substituted or unsubstituted alkynylene, and etc., X is -CONH-, -NHCO-, -COO-, -OCO-, -CO-, and etc., Y is a colorant residue, and R1 is a C1-C6 alkyl. And the lightfast ink composition contains at least one lightfast colorant selected from the group consisting of the lightfast colorant represented by the formula 1 and an aqueous liquid medium. |
188 |
벤조디푸라논 화합물의 제조방법 |
KR1019930027500 |
1993-12-13 |
KR100110592B1 |
1997-01-13 |
이철우; 한기종; 홍성의 |
|
189 |
벤조디푸라논 화합물의 제조방법 |
KR1019930027500 |
1993-12-13 |
KR1019960014044B1 |
1996-10-11 |
이철우; 한기종; 홍성의 |
This invention is provided to obtain economic method for preparing synthetic dyestuff of benzodifuranone compound(I) having good quality, and the compound is made by mixing the benzofuran derivative(II) and the compound(III) in a solvent, and oxidizing the mixture. In the above formulae, R1 and R2 are respectively phenyl radical, replaced phenyl radical or naphthal radical, X is alkylcarboxylesther or cyano radical, Y is hydrogen or aryloxy radical, and Hal is chlorine or fluorine. |
190 |
피롤리돈계 청색 염료의 제조 방법 |
KR1019940020707 |
1994-08-22 |
KR1019960007695A |
1996-03-22 |
윤천; 김영순; 윤한영 |
본원발명은 하기 구조식(III)의 화합물과 구조식(II)의 아닐린 유도체를 하기 구조식(IV)의 술포닐클로라이드 화합물을 사용하여 커플링 반응시킴을 특징으로 하는 하기 구조식(I)의 피론리돈계 청색 염료를 제공한다.
상기 식에서 R
1 수소원자, C
1 -C
6 알킬기, 알릴기, 알콕시기, 페녹시에틸기, 페닐에틸기 또는 시아노알킬기를 나타내고; R
2 및 R
3 는 각각 독립적으로 C
1 -C
10 의 직쇄형 또는 분지쇄형 알킬기, 알릴기, 알콕시기, 페녹시에틸기, 알릴옥시에틸기, 페닐알킬기 또는 카르보닐알킬기를 나타내고, R은 C
1 -C
5 알킬기, 알릴기, 알콕시기 또는 p-(C
1 -C
5 알킬)페닐기를 나타낸다. |
191 |
벤조디푸라논 화합물의 제조방법 |
KR1019930027500 |
1993-12-13 |
KR1019950018310A |
1995-07-22 |
이철우; 한기종; 홍성의 |
본 발명은 하기 일반식(II)의 벤조푸란 유도체와 하기 일반식(III)의 화합물을 용매 존재하에서 반응시킨후, 산화시킴을 특징으로 하여 일반식(I)의 벤조디푸라논 염료를 제조하는 방법에 관한 것이다.
상기식에서, R
1 및 R
2 는 각각 독립적으로 페닐기, 치환된 페닐기 또는 나프틸기를 나타내며 X는 알킬카르복실에스테르 또는 시아노기를 나타내고, Y는 수소 또는 아릴옥시기를 나타내며, Hal은 염소 또는 불소를 나타낸다. 또한, 본 발명은 상기 일반식(III)의 신규한 디할로트리아진에 관한 것이다. |
192 |
백흑 제조 방법 |
KR1019570000129 |
1957-02-02 |
KR100000317B1 |
1958-07-16 |
김동규 |
|
193 |
백흑 제조 방법 |
KR1019570000129 |
1957-02-02 |
KR1019580001114B1 |
1958-04-30 |
김동규 |
|
194 |
應用於高分子太陽能電池之染料分子及包括此染料分子之高分子太陽能電池 |
TW097143477 |
2008-11-11 |
TWI385167B |
2013-02-11 |
衛靖燕; WEI, CHING YEN; 陳誼苓; CHEN, YI LING |
|