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Recovery of both brass and zinc from metallurgical residues by carbon flotation method

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专利汇可以提供Recovery of both brass and zinc from metallurgical residues by carbon flotation method专利检索,专利查询,专利分析的服务。并且A method of recovering both brass and zinc from metallurgical residue containing those metals and including slag containing zinc oxide, comprising charging the residue into a furnace, in such furnace heating the residue up to about 1,250* C., the brass which is molten at said temperature sinking to the bottom of the furnace, adding carbon reducing zinc oxide in the slag to zinc metal in vapor form, withdrawing and condensing the zinc vapor, tapping the molten slag from the furnace and tapping the molten brass from the furnace. Flux may be and normally is added to the residue to render the slag more fluid although under certain conditions addition of flux may be unnecessary. When flux is added it may comprise at least one of lime, silica, scrap glass, borax, rasorite and colemanite. The carbon reductant may comprise at least one of metallurgical coke, petroleum coke, bituminous coal, anthracite coal and graphite. The zinc vapor is withdrawn from the furnace through a first outlet passage, the slag after at least the greater portion of the zinc oxide therein has been reduced to zinc in vapor form is withdrawn from the furnace through a second outlet passage and the molten brass is withdrawn from the furnace through a third outlet passage. The furnace is preferably an electric arc furnace although a gas fired furnace or an induction furnace may be employed.,下面是Recovery of both brass and zinc from metallurgical residues by carbon flotation method专利的具体信息内容。

1. A CONTINUOUS METHOD OF RECOVERING BOTH METALLIC BRASS AND METALLIC ZINC FROM RESIDUES CONTAINING BRASS IN THE AMOUNT OFF FROM AT LEAST 1.5% OF THE CONTENTS OF SAID RESIDUE AND ZINC OXIDE IN AMOUNTS OF AT LEAST 20% OF THE BALANCE OF SAID RESIDUE, SAID RESIDUE BEING COMPRISED OF SLAGS OR MELTING FURNACE SKIMMINGS AND ADMIXTURES THEREOG, COMPRISING THE STEPS OF PERIODICALLY CHARGING THE RESIDUE INTO A FURNACE, MELTING AND HEATING SAID RESIDUE UP TO A TEMPERATURE OF ABOUT 1250*C., SAID MOLTEN BRASS SINKING TO THE BOTTOM OF THE FURNACE, PERIODICALLY ADDING CARBON TO THE SURFACE OF THE MOLTEN BATH IN FREE FLOATING FROM IN AN AMOUNT SUFFICIENT TO REDUCE THE ZINC OXIDE CONTENT OF SAID BALANCE OF SAID SLAG TO ZINC IN VAPOR FROM, CONTINUALLY WITHDRAWING AND CONDENSING SAID ZINC IN VAPOR FROM TO METALLIC ZINC, PERIODICALLY TAPPING THE MOLTEN BRASS FROM SAID FURANCE AND PERIODICALLY REMOVING THE ZINC EXHAUSTED SLAG FROM SAID FURNACE AT A FINAL ZINC OXIDE CONTENT APPROACHING 0.15% THE RATE OF ADDITION OF SAID CHARGING RESIDUE AND SAID CARBON AND THE RATE OF WITHDRAWING OF SAID VAPORIZED ZINC, AND BRASS AND SAID SPENT SLAG BEING SUCH AS TO MAINTAIN A METAL POOL, A SLAG LAYER AND FREE FLOATING CARBON AT ALL TIMES IN SAID FURNACE AT TEMPERATURE OF ABOUT 1250*C.
2. A method as claimed in claim 1 wherein flux of at least one of the class comprised of lime, silica, scrap glass, borax, rasorite and colemonite is added to the furnace for fluidity purposes.
3. The method as defined in claim 1 in which the carbon is at least one of the forms of metallurgical coke, petroluem coke, bituminous coal, anthracite coal and graphite.
4. The method as defined in claim 2 in which the carbon is at least of one of the forms of metallurgical coke, petroleum coke, bituminous coal, anthracite coal and graphite.
5. A method as defined in claim 1 in which the zinc vapor is withdrawn from the furnace through a first outlet passage; the slag, after at least the greater portion of the zinc oxide has been reduced to zinc in vapor foRm is withdrawn through a second and independent outlet passage and said brass is withdrawn from the furnace from a third independent outlet.
6. A method as defined in claim 5 wherein said zinc vapor is subsequently condensed in the presence of carbon monoxide gas generated from reduction of said zinc oxide.
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